arXiv subjects

Lorenz Willmann

Publications and source records attributed to Lorenz Willmann.

13 recordsLinked to original sources

arXiv2025

2D transverse laser cooling of a hexapole focused beam of cold BaF molecules

A cryogenic buffer gas beam, an electrostatic hexapole lens, and 2D transverse Doppler laser cooling are combined to produce a bright beam of barium monofluoride ($^{138}$Ba$^{19}$F) molecules. Experimental results and trajectory simulations are used to study the laser cooling effect as a function of laser detuning, laser power, laser alignment, and interaction time. A scattering rate of 6.1(1.4) $\times 10^{5}$ s$^{-1}$ on the laser cooling transition is obtained; this is $14 \%$ of the expected maximum, which is attributed to limited control of the magnetic field used to remix dark states. Using 3 tuneable lasers with appropriate sidebands and detuning, each molecule scatters approximately 400 photons during 2D laser cooling, limited by the interaction time and scattering rate. Leaks to dark states are less than 10$\%$. The experimental results are used to benchmark the trajectory simulations to predict the achievable flux 3.5 m downstream for a planned $e$EDM experiment.

physics.atom-ph↗

arXiv2024

Manipulating a beam of barium fluoride molecules using an electrostatic hexapole

An electrostatic hexapole lens is used to manipulate the transverse properties of a beam of barium fluoride molecules from a cryogenic buffer gas source. The spatial distribution of the beam is measured by recording state-selective laser-induced fluorescence on an emccd camera, providing insight into the intensity and transverse position spread of the molecular beam. Although the high mass and unfavorable Stark shift of barium fluoride pose a considerable challenge, the number of molecules in the low-field seeking component of the N=1 state that pass a 4 mm diameter aperture 712 mm behind the source is increased by a factor of 12. Furthermore, it is demonstrated that the molecular beam can be displaced by up to +/-5 mm by moving the hexapole lens. Our measurements agree well with numerical trajectory simulations. We discuss how electrostatic lenses may be used to increase the sensitivity of beam experiments such as the search for the electric dipole moment of the electron.

physics.atom-ph↗

arXiv2022

Characterization of a continuous muon source for the Muon-Induced X-ray Emission (MIXE) Technique

The toolbox for material characterization has never been richer than today. Great progress with all kinds of particles and interaction methods provide access to nearly all properties of an object under study. However, a tomographic analysis of the subsurface region remains still a challenge today. In this regard, the Muon-Induced X-ray Emission (MIXE) technique has seen rebirth fueled by the availability of high intensity muon beams. We report here a study conducted at the Paul Scherrer Institute (PSI). It demonstrates that the absence of any beam time-structure leads to low pile-up events and a high signal-to-noise ratio (SNR) with less than one hour acquisition time per sample or data point. This performance creates the perspective to open this technique to a wider audience for the routine investigation of non-destructive and depth-sensitive elemental compositions, for example in rare and precious samples. Using a hetero-structured sample of known elements and thicknesses, we successfully detected the characteristic muonic X-rays, emitted during the capture of a negative muon by an atom, and the gamma-rays resulting from the nuclear capture of the muon, characterizing the capabilities of MIXE at PSI. This sample emphasizes the quality of a continuous beam, and the exceptional SNR at high rates. Such sensitivity will enable totally new statistically intense aspects in the field of MIXE, e.g. elemental 3D-tomography and chemical analysis. Therefore, we are currently advancing our proof-of-concept experiments with the goal of creating a full fledged permanently operated user station to make MIXE available to the wider scientific community as well as industry.

physics.app-ph↗

arXiv2022

Benchmarking of the Fock space coupled cluster method and uncertainty estimation: Magnetic hyperfine interaction in the excited state of BaF

We present an investigation of the performance of the relativistic multi-reference Fock-space coupled cluster (FSCC) method for predicting molecular hyperfine structure (HFS) constants, including a thorough computational study to estimate the associated uncertainties. In particular, we considered the $^{19}$F HFS constant in the ground and excited states of BaF. Due to a larger basis set dependence, the uncertainties on the excited state results (16-85%) were found to be significantly larger than those on the ground state constants ($\sim$2%). The ab initio values were compared to the recent experimental results, and good overall agreement within the theoretical uncertainties was found. This work demonstrates the predictive power of the FSCC method and the reliability of the established uncertainty estimates, which can be crucial in cases where the calculated property cannot be directly compared to experiment.

physics.atom-ph↗

arXiv2021

Systematic study and uncertainty evaluation of $P,T$-odd molecular enhancement factors in BaF

A measurement of the magnitude of the electric dipole moment of the electron (eEDM) larger than that predicted by the Standard Model (SM) of particle physics is expected to have a huge impact on the search for physics beyond the SM. Polar diatomic molecules containing heavy elements experience enhanced sensitivity to parity ($P$) and time-reversal ($T$)-violating phenomena, such as the eEDM and the scalar-pseudoscalar (S-PS) interaction between the nucleons and the electrons, and are thus promising candidates for measurements. The NL-\textit{e}EDM collaboration is preparing an experiment to measure the eEDM and S-PS interaction in a slow beam of cold BaF molecules [Eur. Phys. J. D, 72, 197 (2018)]. Accurate knowledge of the electronic structure parameters, $W_d$ and $W_s$, connecting the eEDM and the S-PS interaction to the measurable energy shifts is crucial for the interpretation of these measurements. In this work we use the finite field relativistic coupled cluster approach to calculate the $W_d$ and $W_s$ parameters in the ground state of the BaF molecule. Special attention was paid to providing a reliable theoretical uncertainty estimate based on investigations of the basis set, electron correlation, relativistic effects and geometry. Our recommended values of the two parameters, including conservative uncertainty estimates, are 3.13 $\pm$ $0.12 \times 10^{24}\frac{\text{Hz}}{e\cdot \text{cm}}$ for $W_d$ and 8.29 $\pm$ 0.12 kHz for $W_s$.

physics.atom-ph↗

arXiv2019

High accuracy theoretical investigations of CaF, SrF, and BaF and implications for laser-cooling

The NL-eEDM collaboration is building an experimental setup to search for the permanent electric dipole moment of the electron in a slow beam of cold barium fluoride molecules [Eur. Phys. J. D, 72, 197 (2018)]. Knowledge of molecular properties of BaF is thus needed to plan the measurements and in particular to determine an optimal laser-cooling scheme. Accurate and reliable theoretical predictions of these properties require incorporation of both high-order correlation and relativistic effects in the calculations. In this work theoretical investigations of the ground and the lowest excited states of BaF and its lighter homologues, CaF and SrF, are carried out in the framework of the relativistic Fock-space coupled cluster (FSCC) and multireference configuration interaction (MRCI) methods. Using the calculated molecular properties, we determine the Franck-Condon factors (FCFs) for the $A^2Π_{1/2} \rightarrow X^2Σ^{+}_{1/2}$ transition, which was successfully used for cooling CaF and SrF and is now considered for BaF. For all three species, the FCFs are found to be highly diagonal. Calculations are also performed for the $B^2Σ^{+}_{1/2} \rightarrow X^2Σ^{+}_{1/2}$ transition recently exploited for laser-cooling of CaF; it is shown that this transition is not suitable for laser-cooling of BaF, due to the non-diagonal nature of the FCFs in this system. Special attention is given to the properties of the $A'^2Δ$ state, which in the case of BaF causes a leak channel, in contrast to CaF and SrF species where this state is energetically above the excited states used in laser-cooling. We also present the dipole moments of the ground and the excited states of the three molecules and the transition dipole moments (TDMs) between the different states.

physics.atom-ph↗

arXiv2018

Measuring the electric dipole moment of the electron in BaF

We investigate the merits of a measurement of the permanent electric dipole moment of the electron ($e$EDM) with barium monofluoride molecules, thereby searching for phenomena of CP violation beyond those incorporated in the Standard Model of particle physics. Although the BaF molecule has a smaller enhancement factor in terms of the effective electric field than other molecules used in current studies (YbF, ThO and ThF$^+$), we show that a competitive measurement is possible by combining Stark-deceleration, laser-cooling and an intense primary cold source of BaF molecules. With the long coherent interaction times obtainable in a cold beam of BaF, a sensitivity of $5\times10^{-30}$ e$\cdot$cm for an $e$EDM is feasible. We describe the rationale, the challenges and the experimental methods envisioned to achieve this target.

physics.atom-ph↗

arXiv2015

Matter-Antimatter Asymmetry - Aspects at Low Energy

The apparent dominance of matter over antimatter in our universe is an obvious and puzzling fact which cannot be adequately explained in present physical frameworks that assume matter-antimatter symmetry at the big bang. However, our present knowledge of starting conditions and of known sources of CP violation are both insufficient to explain the observed asymmetry. Therefore ongoing research on matter-antimatter differences is strongly motivated as well as attempts to identify viable new mechanisms that could create the present asymmetry. Here we concentrate on possible precision experiments at low energies towards a resolution of this puzzle.

hep-ph↗

arXiv2015

Lifetime measurement of the 5d$^2$D$_{5/2}$ state in Ba$^+$

The lifetime of the metastable 5d$^2$D$_{5/2}$ state has been measured for a single trapped Ba$^+$ ion in a Paul trap in Ultra High Vacuum (UHV) in the 10$^{-10}$ mbar pressure range. A total of 5046 individual periods when the ion was shelved in this state have been recorded. A preliminary value $τ_{D_{5/2}} = 26.4(1.7)$~s is obtained through extrapolation to zero residual gas pressure.

physics.atom-ph↗

arXiv2002

Inelastic Collision Rates of Trapped Metastable Hydrogen

We report the first detailed decay studies of trapped metastable (2S) hydrogen. By two-photon excitation of ultracold H samples, we have produced clouds of at least 5x10^7 magnetically trapped 2S atoms at densities greater than 4x10^10 cm^-3 and temperatures below 100 \muK. We derive experimental values for the total 2S-2S two-body loss rate constant in this temperature regime. Our results are in the range of recent theoretical calculations. We also find experimental upper limits on the rate constant for loss due to inelastic 1S-2S collisions.

physics.atom-ph↗

arXiv1998

Bose-Einstein Condensation of Atomic Hydrogen

We have observed Bose-Einstein condensation (BEC) of trapped atomic hydrogen, and studied it by two-photon spectroscopy of the 1S-2S transition. In these lecture notes we briefly review the history of spin-polarized atomic hydrogen and describe the final steps to BEC. Laser spectroscopy, which probes the difference in mean field energy of the 1S and 2S states, is used to study the condensate, which has a peak density of 4.8e15 cm^-3 and population of 10^9.

physics.atom-ph↗

arXiv1998

Cold Collision Frequency Shift of the 1S-2S Transition in Hydrogen

We have observed the cold collision frequency shift of the 1S-2S transition in trapped spin-polarized atomic hydrogen. We find $Δν_{1S-2S} = -3.8(8)\times 10^{-10} n Hz cm^3$, where $n$ is the sample density. From this we derive the 1S-2S s-wave triplet scattering length, $a_{1S-2S}=-1.4(3)$ nm, which is in fair agreement with a recent calculation. The shift provides a valuable probe of the distribution of densities in a trapped sample.

physics.atom-ph↗

arXiv1998

Bose-Einstein Condensation of Atomic Hydrogen

We report observation of Bose-Einstein condensation of a trapped, dilute gas of atomic hydrogen. The condensate and normal gas are studied by two-photon spectroscopy of the 1S-2S transition. Interactions among the atoms produce a shift of the resonance frequency proportional to density. The condensate is clearly distinguished by its large frequency shift. The peak condensate density is 4.8 +/- 1.1 \times 10^{15} cm^{-3}, corresponding to a condensate population of 10^9 atoms. The BEC transition occurs at about T=50 uK and n=1.8 \times 10^{14} cm^{-3}.

physics.atom-ph↗