arXiv subjects

Louis-Philippe Coulombe

Publications and source records attributed to Louis-Philippe Coulombe.

At least 37 records · Page 2Linked to original sources

arXiv2025

Quantifying thermal water dissociation in the dayside photosphere of WASP-121 b using NIRPS

The intense stellar irradiation of ultra-hot Jupiters results in some of the most extreme atmospheric environments in the planetary regime. On their daysides, temperatures can be sufficiently high for key atmospheric constituents to thermally dissociate into simpler molecular species and atoms. This dissociation drastically changes the atmospheric opacities and, in turn, critically alters the temperature structure, atmospheric dynamics, and day-night heat transport. To this date, however, simultaneous detections of the dissociating species and their thermally dissociation products in exoplanet atmospheres have remained rare. Here we present the simultaneous detections of H$_2$O and its thermally dissociation product OH on the dayside of the ultra-hot Jupiter WASP-121 b based on high-resolution emission spectroscopy with the recently commissioned Near InfraRed Planet Searcher (NIRPS). We retrieve a photospheric abundance ratio of log$_{10}$(OH/H$_2$O) $= -0.15\pm{0.20}$ indicating that there is about as much OH as H$_2$O at photospheric pressures, which confirms predictions from chemical equilibrium models. We compare the dissociation on WASP-121 b with other ultra-hot Jupiters and show that a trend in agreement with equilibrium models arises. We also discuss an apparent velocity shift of $4.79^{+0.93}_{-0.97} $km s$^{-1}$ in the H$_2$O signal, which is not reproduced by current global circulation models. Finally, in addition to H$_2$O and OH, the NIRPS data reveal evidence of Fe and Mg, from which we infer a Fe/Mg ratio consistent with the solar and host star ratios. Our results demonstrate that NIRPS can be an excellent instrument to obtain simultaneous measurements of refractory and volatile molecular species, paving the way for many future studies on the atmospheric composition, chemistry, and the formation history of close-in exoplanets.

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arXiv2025

Detailed Architecture of the L 98-59 System and Confirmation of a Fifth Planet in the Habitable Zone

The L 98-59 system, identified by TESS in 2019, features three transiting exoplanets in compact orbits of 2.253, 3.691, and 7.451 days around an M3V star, with an outer 12.83-day non-transiting planet confirmed in 2021 using ESPRESSO. The planets exhibit a diverse range of sizes (0.8-1.6 R$_{\oplus}$), masses (0.5-3 M$_{\oplus}$), and likely compositions (Earth-like to possibly water-rich), prompting atmospheric characterization studies with HST and JWST. Here, we analyze 16 new TESS sectors and improve radial velocity (RV) precision of archival ESPRESSO and HARPS data using a line-by-line framework, enabling stellar activity detrending via a novel differential temperature indicator. We refine the radii of L 98-59 b, c, and d to 0.837 $\pm$ 0.019 R$_{\oplus}$, 1.329 $\pm$ 0.029 R$_{\oplus}$, 1.627 $\pm$ 0.041 R$_{\oplus}$, respectively. Combining RVs with transit timing variations (TTV) of L 98-59 c and d from TESS and JWST provides unprecedented constraints on the masses and eccentricities of the planets. We report updated masses of 0.46 $\pm$ 0.11 M$_{\oplus}$ for b, 2.00 $\pm$ 0.13 M$_{\oplus}$ for c, and 1.64 $\pm$ 0.07 M$_{\oplus}$ for d, and a minimum mass of 2.82 $\pm$ 0.19 M$_{\oplus}$ for e. We additionally confirm L 98-59\,f, a non-transiting super-Earth with a minimal mass of 2.80 $\pm$ 0.30 M$_{\oplus}$ on a 23.06-day orbit inside the Habitable Zone. The TTVs of L 98-59 c and d (<3 min, $P_{\rm TTV} = 396$ days) constrain the eccentricities of all planets to near-circular orbits ($e \lesssim 0.04$). An internal structure analysis of the transiting planets reveals increasing water-mass fractions ($f_{\rm H_{2}O}$) with orbital distance, reaching $f_{\rm H_{2}O} \approx 0.16$ for L 98-59\ d. We predict eccentricity-induced tidal heating in L 98-59 b with heat fluxes comparable to those of Io, potentially driving volcanic activity.

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arXiv2025

A water-rich interior in the temperate sub-Neptune K2-18 b revealed by JWST

Temperate sub-Neptunes are compelling targets for detecting liquid-water oceans beyond the Solar System. If water-rich and lacking massive hydrogen-helium envelopes, these planets could sustain liquid layers beneath their atmospheres despite sizes larger than Earth. Previous observations of the temperate sub-Neptune K2-18 b revealed an H2-dominated atmosphere rich in CH4, with moderate evidence for CO2 and tentative signs of dimethyl sulfide (DMS). Here we present four new JWST/NIRSpec transit observations of K2-18 b. The resulting high-precision transmission spectrum robustly detects both CH4 and CO2, precisely measuring their abundances and firmly establishing the planet's water-rich nature: either a thick envelope with >10% H2O by volume or a thin atmosphere above a liquid-water ocean. The spectrum reveals no detectable H2O, NH3, or CO. The absence of atmospheric water vapor suggests an efficient cold trap, while the nondetections of NH3 and CO support the scenario of a small H2-rich atmosphere overlying a liquid reservoir. However, alternative models that include these gases can also reproduce the spectrum within uncertainties, highlighting the need for deeper observations. The spectrum only contains marginal signals of DMS, methyl mercaptan (CH3SH), and nitrous oxide (N2O), with none exceeding 3 sigma in model preference and all falling below ~2 sigma without imposing a strong super-Rayleigh haze. Meanwhile, our self-consistent photochemical models show that DMS and CH3SH may form abiotically in massive H2-rich atmospheres of high metallicity, making it important to consider additional indicators for their potential use as biosignatures. K2-18 b, a cool, water-rich world, stands out as one of the most promising temperate sub-Neptunes for exploring the emergence of liquid-water environments in non-Earth-like planets, motivating further characterization of its atmosphere and interior.

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arXiv2025

JWST NIRISS Transmission Spectroscopy of the Super-Earth GJ 357b, a Favourable Target for Atmospheric Retention

We present a JWST NIRISS/SOSS transmission spectrum of the super-Earth GJ 357 b: the first atmospheric observation of this exoplanet. Despite missing the first $\sim$40 % of the transit due to using an out-of-date ephemeris, we still recover a transmission spectrum that does not display any clear signs of atmospheric features. We perform a search for Gaussian-shaped absorption features within the data but find that this analysis yields comparable fits to the observations as a flat line. We compare the transmission spectrum to a grid of atmosphere models and reject, to 3-$σ$ confidence, atmospheres with metallicities $\lesssim$100$\times$ solar ($\sim$4 g/mol) with clouds at pressures down to 0.01 bar. We analyse how the retention of a secondary atmosphere on GJ 357 b may be possible due to its higher escape velocity compared to an Earth-sized planet and the exceptional inactivity of its host star relative to other M2.5V stars. The star's XUV luminosity decays below the threshold for rapid atmospheric escape early enough that the volcanic revival of an atmosphere of several bars of CO$_2$ is plausible, though subject to considerable uncertainty. Finally, we model the feasibility of detecting an atmosphere on GJ 357 b with MIRI/LRS, MIRI photometry, and NIRSpec/G395H. We find that, with two eclipses, it would be possible to detect features indicative of an atmosphere or surface. Further to this, with 3-4 transits, it would be possible to detect a 1 bar nitrogen-rich atmosphere with 1000 ppm of CO$_2$.

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arXiv2025

Continuous helium absorption from the leading and trailing tails of WASP-107b

The detection of helium escaping the atmosphere of exoplanets has revolutionized our understanding of atmospheric escape and exoplanetary evolution. Using high-precision spectroscopic observations from the James Webb Space Telescope (JWST) NIRISS-SOSS mode, we report the detection of significant helium absorption during the pre-transit phase of WASP-107b (17$σ$), as well as in the transit and post-transit phases. This unique continuous helium absorption begins approximately 1.5 hours before the planet's ingress and reveals the presence of an extended thermosphere. The observations show a maximum transit depth of 2.395$\% \pm$ 0.01$\%$ near the helium triplet (36$σ$; at NIRISS-SOSS resolution $\sim$ 700). Our ellipsoidal model of the planetary thermosphere matches well the measured light curve suggesting an outflow extending to tens of planetary radii. Furthermore, we confidently detect water absorption (log10 H2O=-2.5 $\pm$ 0.6), superimposed with a short-wavelength slope which we attribute to a prominent signature from unocculted stellar spots (5.2$σ$), rather than a small-particle haze slope. We place an upper limit on the abundance of K (log10 K$<$-4.86, or K/H$<$ 75$\times$ stellar) at 2$σ$, which is consistent with the O/H super-solar metallicity estimate. This study underscores the transformative potential of JWST for tracing atmospheric and mass-loss processes, while offering a benchmark for future studies targeting helium escape and its implications for planetary evolution.

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arXiv2025

Escaping Helium and a Highly Muted Spectrum Suggest a Metal-Enriched Atmosphere on Sub-Neptune GJ3090b from JWST Transit Spectroscopy

Sub-Neptunes, the most common planet type, remain poorly understood. Their atmospheres are expected to be diverse, but their compositions are challenging to determine, even with JWST. Here, we present the first JWST spectroscopic study of the warm sub-Neptune GJ3090b (2.13R$_\oplus$, Teq~700 K) which orbits an M2V star, making it a favourable target for atmosphere characterization. We observed four transits of GJ3090b; two each using JWST NIRISS/SOSS and NIRSpec/G395H, yielding wavelength coverage from 0.6-5.2 $μ$m. We detect the signature of the 10833 Å metastable Helium triplet at a statistical significance of 5.5$σ$ with an amplitude of 434$\pm$79 ppm, marking the first such detection in a sub-Neptune with JWST. This amplitude is significantly smaller than predicted by solar-metallicity forward models, suggesting a metal-enriched atmosphere which decreases the mass-loss rate and attenuates the Helium feature amplitude. Moreover, we find that stellar contamination, in the form of the transit light source effect, dominates the NIRISS transmission spectra, with unocculted spot and faculae properties varying across the two visits separated in time by approximately six months. Free retrieval analyses on the NIRSpec/G395H spectrum find tentative evidence for highly muted features and a lack of CH4. These findings are best explained by a high metallicity atmosphere (>100x solar at 3$σ$ confidence, for clouds at $\sim μ$bar pressures) using chemically-consistent retrievals and self-consistent model grids. Further observations of GJ3090b are needed for tighter constraints on the atmospheric abundances, and to gain a deeper understanding of the processes that led to its potential metal enrichment.

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arXiv2025

A Moderate Albedo from Reflecting Aerosols on the Dayside of WASP-80 b Revealed by JWST/NIRISS Eclipse Spectroscopy

Secondary eclipse observations of exoplanets at near-infrared wavelengths enable the detection of thermal emission and reflected stellar light, providing insights into the thermal structure and aerosol composition of their atmospheres. These properties are intertwined, as aerosols influence the energy budget of the planet. WASP-80 b is a warm gas giant with an equilibrium temperature of 825 K orbiting a bright late-K/early-M dwarf, and for which the presence of aerosols in its atmosphere have been suggested from previous HST and Spitzer observations. We present an eclipse spectrum of WASP-80 b obtained with JWST NIRISS/SOSS, spanning 0.68 to 2.83 $μ$m, which includes the first eclipse measurements below 1.1 $μ$m for this exoplanet, extending our ability to probe light reflected by its atmosphere. When a reflected light geometric albedo is included in the atmospheric retrieval, our eclipse spectrum is best explained by a reflected light contribution of $\sim$30 ppm at short wavelengths, although further observations are needed to statistically confirm this preference. We measure a dayside brightness temperature of $T_{\rm B}=811_{-70}^{+69}$ K and constrain the reflected light geometric albedo across the SOSS wavelength range to $A_{\rm g}=0.204_{-0.056}^{+0.051}$, allowing us to estimate a 1-$σ$ range for the Bond albedo of $0.148\lesssim A_{\rm B}\lesssim0.383$. By comparing our spectrum with aerosol models, we find that manganese sulfide and silicate clouds are disfavored, while cloud species with weak-to-moderate near-infrared reflectance, along with soots or low formation-rate tholin hazes, are consistent with our eclipse spectrum.

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arXiv2025

Low 4.5 μm Dayside Emission Disfavors a Dark Bare-Rock scenario for the Hot Super-Earth TOI-431 b

The full range of conditions under which rocky planets can host atmospheres remains poorly understood, especially in the regime of close-in orbits around late-type stars. One way to assess the presence of atmospheres on rocky exoplanets is to measure their dayside emission as they are eclipsed by their host stars. Here, we present Spitzer observations of the 4.5 $μ$m secondary eclipses of the rocky super-Earth TOI-431 b, whose mass and radius indicate an Earth-like bulk composition (3.07 $\pm$ 0.35 M$_{\oplus}$, 1.28 $\pm$ 0.04 R$_{\oplus}$). Exposed to more than 2000 times the irradiation of Earth, dayside temperatures of up to 2400K are expected if the planet is a dark bare-rock without a significant atmosphere. Intriguingly, despite the strong stellar insolation, we measure a secondary eclipse depth of only 33 $\pm$ 22 ppm, which corresponds to a dayside brightness temperature of $1520_{-390}^{+360}$K. This notably low eclipse depth disagrees with the dark bare-rock scenario at the 2.5$σ$ level, and suggests either that the planet is surrounded by an atmosphere, or that it is a bare-rock with a highly reflective surface. In the atmosphere scenario, the low dayside emission implies the efficient redistribution of heat to the nightside, or by molecular absorption in the 4-5 $μ$m bandpass. In the bare-rock scenario, a surface composition made of a high-albedo mineral species such as ultramafic rock can lead to reduced thermal emission consistent with low eclipse depth measurement. Follow-up spectroscopic observations with the James Webb Space Telescope hold the key to constraining the nature of the planet.

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arXiv2025

Highly reflective white clouds on the western dayside of an exo-Neptune

Highly-irradiated gas giant exoplanets are predicted to show circulation patterns dominated by day-to-night heat transport and a spatial distribution of clouds that is driven by advection and local heating. Hot-Jupiters have been extensively studied from broadband phase-curve observations at infrared and optical wavelengths, but spectroscopic observations in the reflected light are rare and the regime of smaller and higher-metallicity ultra-hot planets, such as hot-Neptunes, remains largely unexplored to date. Here we present the phase-resolved reflected-light and thermal-emission spectroscopy of the ultra-hot Neptune LTT 9779b, obtained through observing its full phase-curve from 0.6 to 2.8 $μ$m with JWST NIRISS/SOSS. We detect an asymmetric dayside in reflected light (3.1$σ$ significance) with highly-reflective white clouds on the western dayside (A = 0.79$\pm$0.15) and a much lower-albedo eastern dayside (A = 0.41$\pm$0.10), resulting in an overall dayside albedo of A = 0.50$\pm$0.07. The thermal phase curve is symmetric about the substellar point, with a dayside effective temperature of T$_\mathrm{eff,day}$ = 2,260$^{+40}_{-50}$ K and a cold nightside (T$_\mathrm{eff,night}$ <1,330 K at 3-$σ$ confidence), indicative of short radiative timescales. We propose an atmospheric circulation and cloud distribution regime in which heat is transported eastward from the dayside towards the cold nightside by an equatorial jet, leading to a colder western dayside where temperatures are sufficiently low for the condensation of silicate clouds.

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arXiv2025

Promise and Peril: Stellar Contamination and Strict Limits on the Atmosphere Composition of TRAPPIST-1c from JWST NIRISS Transmission Spectra

Attempts to probe the atmospheres of rocky planets around M dwarfs present both promise and peril. While their favorable planet-to-star radius ratios enable searches for even thin secondary atmospheres, their high activity levels and high-energy outputs threaten atmosphere survival. Here, we present the 0.6--2.85\,$μ$m transmission spectrum of the 1.1\,$\rm R_\oplus$, $\sim$340\,K rocky planet TRAPPIST-1\,c obtained over two JWST NIRISS/SOSS transit observations. Each of the two spectra displays 100--500\,ppm signatures of stellar contamination. Despite being separated by 367\,days, the retrieved spot and faculae properties are consistent between the two visits, resulting in nearly identical transmission spectra. Jointly retrieving for stellar contamination and a planetary atmosphere reveals that our spectrum can rule out hydrogen-dominated, $\lesssim$300$\times$ solar metallicity atmospheres with effective surface pressures down to 10\,mbar at the 3-$σ$ level. For high-mean molecular weight atmospheres, where O$_2$ or N$_2$ is the background gas, our spectrum disfavors partial pressures of more than $\sim$10\,mbar for H$_2$O, CO, NH$_3$ and CH$_4$ at the 2-$σ$ level. Similarly, under the assumption of a 100\% H$_2$O, NH$_3$, CO, or CH$_4$ atmosphere, our spectrum disfavors thick, $>$1\,bar atmospheres at the 2-$σ$ level. These non-detections of spectral features are in line with predictions that even heavier, CO$_2$-rich, atmospheres would be efficiently lost on TRAPPIST-1\,c given the cumulative high-energy irradiation experienced by the planet. Our results further stress the importance of robustly accounting for stellar contamination when analyzing JWST observations of exo-Earths around M dwarfs, as well as the need for high-fidelity stellar models to search for the potential signals of thin secondary atmospheres.

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arXiv2024

Transmission spectroscopy of WASP-52 b with JWST NIRISS: Water and helium atmospheric absorption, alongside prominent star-spot crossings

In the era of exoplanet studies with JWST, the transiting, hot gas giant WASP-52 b provides an excellent target for atmospheric characterization through transit spectroscopy. WASP-52 b orbits an active K-type dwarf recognized for its surface heterogeneities, such as star-spots and faculae, which offers challenges to atmospheric characterization via transmission spectroscopy. Previous transit observations have detected active regions on WASP-52 through crossing events in transit light-curves and via the spectral imprint of unocculted magnetic regions on transmission spectra. Here, we present the first JWST observations of WASP-52 b. Our JWST NIRISS/SOSS transit observation, obtained through the GTO 1201 Program, detects two clear spot-crossing events that deform the 0.6-2.8 $μ$m transit light-curves of WASP-52 b. We find that these two occulted spots combined cover about 2.4 % of the stellar surface and have temperatures about 400-500 K colder than the stellar photosphere. Our NIRISS/SOSS transmission spectrum is best-fit by an atmosphere with H$_2$O (10.8 $σ$), He (7.3 $σ$, with evidence of an escaping tail at $\sim$ 2.9 $σ$), hints of K (2.5 $σ$), and unocculted star-spots and faculae (3.6 $σ$). The retrieved H$_2$O abundance ($\log$ H$_2$O $\approx -4 \pm 1$) is consistent with a subsolar or solar atmospheric metallicity for two independent data reductions. Our results underscore the importance of simultaneously modelling planetary atmospheres and unocculted stellar heterogeneities when interpreting transmission spectra of planets orbiting active stars and demonstrate the necessity of considering different stellar contamination models that account for both cold and hot active regions.

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arXiv2024

CRIRES+ and ESPRESSO reveal an atmosphere enriched in volatiles relative to refractories on the ultra-hot Jupiter WASP-121b

One of the outstanding goals of the planetary science community is to measure the present-day atmospheric composition of planets and link this back to formation. As giant planets are formed by accreting gas, ices, and rocks, constraining the relative amounts of these components is critical to understand their formation and evolution. For most known planets, including the Solar System giants, this is difficult as they reside in a temperature regime where only volatile elements (e.g., C, O) can be measured, while refractories (e.g., Fe, Ni) are condensed to deep layers of the atmosphere where they cannot be remotely probed. With temperatures allowing for even rock-forming elements to be in the gas phase, ultra-hot Jupiter atmospheres provide a unique opportunity to simultaneously probe the volatile and refractory content of giant planets. Here we directly measure and obtain bounded constraints on the abundances of volatile C and O as well as refractory Fe and Ni on the ultra-hot giant exoplanet WASP-121b. We find that ice-forming elements are comparatively enriched relative to rock-forming elements, potentially indicating that WASP-121b formed in a volatile-rich environment much farther away from the star than where it is currently located. The simultaneous constraint of ice and rock elements in the atmosphere of WASP-121b provides insights into the composition of giant planets otherwise unattainable from Solar System observations.

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arXiv2024

JWST/NIRISS reveals the water-rich "steam world" atmosphere of GJ 9827 d

With sizable volatile envelopes but smaller radii than the solar system ice giants, sub-Neptunes have been revealed as one of the most common types of planet in the galaxy. While the spectroscopic characterization of larger sub-Neptunes (2.5-4R$_\oplus$) has revealed hydrogen-dominated atmospheres, smaller sub-Neptunes (1.6--2.5R$_\oplus$) could either host thin, rapidly evaporating hydrogen-rich atmospheres or be stable metal-rich "water worlds" with high mean molecular weight atmospheres and a fundamentally different formation and evolutionary history. Here, we present the 0.6--2.8$μ$m JWST NIRISS/SOSS transmission spectrum of GJ 9827 d, the smallest (1.98 R$_\oplus$) warm (T$_\mathrm{eq, A_B=0.3} \sim 620$K) sub-Neptune where atmospheric absorbers have been detected to date. Our two transit observations with NIRISS/SOSS, combined with the existing HST/WFC3 spectrum, enable us to break the clouds-metallicity degeneracy. We detect water in a highly metal-enriched "steam world" atmosphere (O/H of $\sim 4$ by mass and H$_2$O found to be the background gas with a volume mixing ratio of >31%). We further show that these results are robust to stellar contamination through the transit light source effect. We do not detect escaping metastable He, which, combined with previous nondetections of escaping He and H, supports the steam atmosphere scenario. In water-rich atmospheres, hydrogen loss driven by water photolysis happens predominantly in the ionized form which eludes observational constraints. We also detect several flares in the NIRISS/SOSS light-curves with far-UV energies of the order of 10$^{30}$ erg, highlighting the active nature of the star. Further atmospheric characterization of GJ 9827 d probing carbon or sulfur species could reveal the origin of its high metal enrichment.

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arXiv2024

Biases in Exoplanet Transmission Spectra Introduced by Limb Darkening Parametrization

One of the main endeavors of the field of exoplanetary sciences is the characterization of exoplanet atmospheres on a population level. The current method of choice to accomplish this task is transmission spectroscopy, where the apparent radius of a transiting exoplanet is measured at multiple wavelengths in search of atomic and molecular absorption features produced by the upper atmosphere constituents. To extract the planetary radius from a transit light curve, it is necessary to account for the decrease in luminosity away from the center of the projected stellar disk, known as the limb darkening. Physically-motivated parametrizations of the limb darkening, in particular of the quadratic form, are commonly used in exoplanet transit light-curve fitting. Here, we show that such parametrizations can introduce significant wavelength-dependent biases in the transmission spectra currently obtained with all instrument modes of the JWST, and thus have the potential to affect atmospheric inferences. To avoid such biases, we recommend the use of standard limb-darkening parametrizations with wide uninformative priors that allow for non-physical stellar intensity profiles in the transit fits, and thus for a complete and symmetrical exploration of the parameter space. We further find that fitting the light curves at the native resolution results in errors on the measured transit depths that are significantly smaller compared to light curves that are binned in wavelength before fitting, thus potentially maximizing the amount of information that can be extracted from the data.

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arXiv2024

Transmission Spectroscopy of the Habitable Zone Exoplanet LHS 1140 b with JWST/NIRISS

LHS 1140 b is the second-closest temperate transiting planet to the Earth with an equilibrium temperature low enough to support surface liquid water. At 1.730$\pm$0.025 R$_\oplus$, LHS 1140 b falls within the radius valley separating H$_2$-rich mini-Neptunes from rocky super-Earths. Recent mass and radius revisions indicate a bulk density significantly lower than expected for an Earth-like rocky interior, suggesting that LHS 1140 b could either be a mini-Neptune with a small envelope of hydrogen ($\sim$0.1% by mass) or a water world (9--19% water by mass). Atmospheric characterization through transmission spectroscopy can readily discern between these two scenarios. Here, we present two JWST/NIRISS transit observations of LHS 1140 b, one of which captures a serendipitous transit of LHS 1140 c. The combined transmission spectrum of LHS 1140 b shows a telltale spectral signature of unocculted faculae (5.8 $σ$), covering $\sim$20% of the visible stellar surface. Besides faculae, our spectral retrieval analysis reveals tentative evidence of residual spectral features, best-fit by Rayleigh scattering from an N$_2$-dominated atmosphere (2.3 $σ$), irrespective of the consideration of atmospheric hazes. We also show through Global Climate Models (GCM) that H$_2$-rich atmospheres of various compositions (100$\times$, 300$\times$, 1000$\times$solar metallicity) are ruled out to $>$10 $σ$. The GCM calculations predict that water clouds form below the transit photosphere, limiting their impact on transmission data. Our observations suggest that LHS 1140 b is either airless or, more likely, surrounded by an atmosphere with a high mean molecular weight. Our tentative evidence of an N$_2$-rich atmosphere provides strong motivation for future transmission spectroscopy observations of LHS 1140 b.

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arXiv2024

JWST Reveals CH$_4$, CO$_2$, and H$_2$O in a Metal-rich Miscible Atmosphere on a Two-Earth-Radius Exoplanet

Even though sub-Neptunes likely represent the most common outcome of planet formation, their natures remain poorly understood. In particular, planets near 1.5-2.5$\,R_\oplus$ often have bulk densities that can be explained equally well with widely different compositions and interior structures, resulting in grossly divergent implications for their formation. Here, we present the full 0.6-5.2$\,μ\mathrm{m}$ JWST NIRISS/SOSS+NIRSpec/G395H transmission spectrum of the 2.2$\,R_\oplus$ TOI-270d ($4.78\,M_\oplus$, $T_\mathrm{eq}$=350-380 K), delivering unprecedented sensitivity for atmospheric characterization in the sub-Neptune regime. We detect five vibrational bands of CH$_4$ at 1.15, 1.4, 1.7, 2.3, and 3.3$\,μ$m (9.4$σ$), the signature of CO$_2$ at 4.3$\,μ$m (4.8$σ$), water vapor (2.5$σ$), and potential signatures of SO$_2$ at 4.0$\,μ\mathrm{m}$ and CS$_2$ at 4.6$\,μ\mathrm{m}$. Intriguingly, we find an overall highly metal-rich atmosphere, with a mean molecular weight of $5.47_{-1.14}^{+1.25}$. We infer an atmospheric metal mass fraction of $58_{-12}^{+8}\%$ and a C/O of $0.47_{-0.19}^{+0.16}$, indicating that approximately half the mass of the outer envelope is in high-molecular-weight volatiles (H$_2$O, CH$_4$, CO, CO$_2$) rather than H$_2$/He. We introduce a sub-Neptune classification scheme and identify TOI-270d as a "miscible-envelope sub-Neptune" in which H$_2$/He is well-mixed with the high-molecular-weight volatiles in a miscible supercritical metal-rich envelope. For a fully miscible envelope, we conclude that TOI-270d's interior is $90_{-4}^{+3}\,$wt$\,\%$ rock/iron, indicating that it formed as a rocky planet that accreted a few wt % of H$_2$/He, with the overall envelope metal content explained by magma-ocean/envelope reactions without the need for significant ice accretion. TOI-270d may well be an archetype of the overall population of sub-Neptunes.

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arXiv2024

Muted Features in the JWST NIRISS Transmission Spectrum of Hot-Neptune LTT 9779 b

The hot-Neptune desert is one of the most sparsely populated regions of the exoplanet parameter space, and atmosphere observations of its few residents can provide insights into how such planets have managed to survive in such an inhospitable environment. Here, we present transmission observations of LTT 9779 b, the only known hot-Neptune to have retained a significant H/He-dominated atmosphere, taken with JWST NIRISS/SOSS. The 0.6-2.85$μ$m transmission spectrum shows evidence for muted spectral features, rejecting a perfectly flat line at >5$σ$. We explore water and methane-dominated atmosphere scenarios for LTT 9779 b's terminator, and retrieval analyses reveal a continuum of potential combinations of metallicity and cloudiness. Through comparisons to previous population synthesis works and our own interior structure modelling, we are able to constrain LTT 9779 b's atmosphere metallicity to 20-850x solar. Within this range of metallicity, our retrieval analyses prefer solutions with clouds at mbar pressures, regardless of whether the atmosphere is water- or methane-dominated -- though cloud-free atmospheres with metallicities >500x solar cannot be entirely ruled out. By comparing self-consistent atmosphere temperature profiles with cloud condensation curves, we find that silicate clouds can readily condense in the terminator region of LTT 9779 b. Advection of these clouds onto the day-side could explain the high day-side albedo previously inferred for this planet and be part of a feedback loop aiding the survival of LTT 9779 b's atmosphere in the hot-Neptune desert.

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arXiv2024

Nightside clouds and disequilibrium chemistry on the hot Jupiter WASP-43b

Hot Jupiters are among the best-studied exoplanets, but it is still poorly understood how their chemical composition and cloud properties vary with longitude. Theoretical models predict that clouds may condense on the nightside and that molecular abundances can be driven out of equilibrium by zonal winds. Here we report a phase-resolved emission spectrum of the hot Jupiter WASP-43b measured from 5-12 $μ$m with JWST's Mid-Infrared Instrument (MIRI). The spectra reveal a large day-night temperature contrast (with average brightness temperatures of 1524$\pm$35 and 863$\pm$23 Kelvin, respectively) and evidence for water absorption at all orbital phases. Comparisons with three-dimensional atmospheric models show that both the phase curve shape and emission spectra strongly suggest the presence of nightside clouds which become optically thick to thermal emission at pressures greater than ~100 mbar. The dayside is consistent with a cloudless atmosphere above the mid-infrared photosphere. Contrary to expectations from equilibrium chemistry but consistent with disequilibrium kinetics models, methane is not detected on the nightside (2$σ$ upper limit of 1-6 parts per million, depending on model assumptions).

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