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Luca Mercatelli

Publications and source records attributed to Luca Mercatelli.

2 recordsLinked to original sources

Comparative study of different functionalized graphene-nanoplatelet aqueous nanofluids for solar energy applications

The optical properties of nanofluids are peculiar and interesting for a variety of applications. Among them, the high light extinction coefficient of nanofluids can be useful in linear parabolic concentrating solar systems, while their properties under high light irradiation intensities can be exploited for direct solar steam generation. The optical characterization of colloids, including the study of non-linear optical properties, is thus a needed step to design the use of such novel materials for solar energy exploitation. In this work, we analysed two different types of nanofluids, consisting of polycarboxylate chemically modified graphene nanoplatelets (P-GnP) and sulfonic acid-functionalized graphene nanoplatelets (S-GnP) dispersed in water, at three concentrations from 0.005 wt% to 0.05 wt%. Moderately stable nanofluids were achieved with favourable light extinction properties, as well as a non-linear optical behaviour under high input solar intensities.

physics.app-ph

Optical properties of dense zirconium and tantalum diborides for solar thermal absorbers

Ultra-high temperature ceramics (UHTCs) are interesting materials for a large variety of applications under extreme conditions. This paper reports on the production and extensive characterization of highly dense, pure zirconium and tantalum diborides, with particular interest to their potential utilization in the thermal solar energy field. Monolithic bulk samples are produced by Spark Plasma Sintering starting from elemental reactants or using metal diboride powders previously synthesized by Self-propagating High-temperature Synthesis (SHS). Microstructural and optical properties of products obtained by the two processing methods have been comparatively evaluated. We found that pure diborides show a good spectral selectivity, which is an appealing characteristic for solar absorber applications. No, or very small, differences in the optical properties have been evidenced when the two investigated processes adopted for the fabrication of dense TaB2 and ZrB2, respectively, are compared.

cond-mat.mtrl-sci