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Lucas A. Pressley

Publications and source records attributed to Lucas A. Pressley.

2 recordsLinked to original sources

The Reverse Quantum Limit: Implications for Unconventional Quantum Oscillations in YbB$_{12}$

Beyond the quantum limit, many-body effects are expected to induce unusual electronic phase transitions. Materials possessing metallic ground states with strong interactions between localized and itinerant electronic states are natural candidates for the realization of such quantum phases. However, the electronic correlations responsible for increasing the likelihood of novel phases simultaneously place the quantum limit beyond the reach of laboratory magnets. Here we propose these difficulties can be surmounted in materials with strong correlations and insulating ground states. Strong correlations in insulators and high magnetic fields conspire to fill Landau levels in the reverse order compared to conventional metals, such that the lowest Landau level is the first observed. Consequently, the quantum limit in strongly correlated insulators is reached in reverse and at fields accessible in laboratories. Quantum oscillations measured at high fields in YbB12 are shown to have features consistent with the reverse quantum limit. These include how quantum oscillations move in lock step with the angular evolution of the insulator-metal transition and the field dependence of the quantum oscillation frequency. We argue that close to the insulator-metal transition, the insulating state should be viewed through the lens of a magnetic field-induced electronic instability affecting the lowest Landau level states in the quantum limit.

cond-mat.str-el↗

Twisting of 2D kagomé sheets in layered intermetallics

Chemical bonding in 2D layered materials and van der Waals solids is central to understanding and harnessing their unique electronic, magnetic, optical, thermal and superconducting properties. Here we report the discovery of spontaneous, bidirectional, bilayer twisting (twist angle ~ 4.5°) in the metallic kagomé MgCo6Ge6 at T = 100(2) K via X-ray diffraction measure-ments, enabled by the preparation of single crystals by the Laser Bridgman method. Despite the appearance of static twisting on cooling from T ~ 300 K to 100 K, no evidence for a phase transition was found in physical properties measurements. Combined with the presence of an Einstein phonon mode contribution in the specific heat, this implies that the twisting exists at all temperatures but is thermally fluctuating at room temperature. Crystal Orbital Hamilton Population analysis demonstrates that the cooperative twisting between layers stabilizes the Co-kagomé network when coupled to strongly bonded and rigid (Ge2) dimers that connect adjacent layers. Further modelling of the displacive disorder in the crystal structure shows the presence of second, Mg-deficient, stacking sequence. This alternative stacking sequence also exhibits inter-layer twisting, but with a different pattern, consistent with the change in electron count due to removal of Mg. Magnetization, resistivity, and low-temperature specific heat measurements are all consistent with a Pauli paramagnetic, strongly correlated metal. Our results provide crucial insight into how chemical concepts lead to interesting electronic structures and behaviors in layered materials.

cond-mat.mtrl-sci↗