arXiv subjects

Lucy C. Auton

Publications and source records attributed to Lucy C. Auton.

7 recordsLinked to original sources

arXiv2025

Development and experimental validation of a mathematical model for fluoride-removal filters comprising chemically treated mineral rich carbon

Excessive fluoride intake can lead to dental and skeletal fluorosis, among other health issues. Naturally occurring fluoride and industrial runoff can result in concentrations far exceeding the World Health Organization's recommended limits in water supplies. In this study, we derive a model incorporating the dominant mechanisms governing fluoride removal from drinking water using the two adsorbents mineral-rich carbon (MRC) and chemically treated mineral-rich carbon (TMRC). Using both new and previously published experimental data, we validate the model for MRC, TMRC, and their mixture, using both batch and column data. Despite the filters containing approximately 40:1 MRC:TMRC ratio by mass, we find that TMRC dominates fluoride removal, while MRC contributes at early and late times. The full column model, which uses parameters from isotherm batch studies, achieves excellent agreement with experimental breakthrough data across varying inlet concentrations and flow rates (R$^2>0.991$, SSE$<0.0632$). Motivated by this, we propose a reduced model based solely on TMRC adsorption, with a single fitting parameter, which still performs well across all breakthrough curves (R$^2 > 0.983$, SSE $<0.117$). The simplicity of this model means that it is straightforward and inexpensive to work with numerically. In both models, batch and column behaviours are reconciled and, for the case of breakthrough curves with varying inlet concentrations, a set of globally optimised parameters is found. The strong agreement with experimental data supports the model's robustness and reinforces the physical interpretability of its parameters. These models for MRC and TMRC provide a foundation for filter optimisation and future efforts aimed at improving fluoride removal in resource-limited settings.

physics.chem-ph↗

arXiv2023

Mathematical model for fluoride-removal filters

We develop a model that captures the dominant chemical mechanisms involved in the removal of fluoride from water by a novel adsorbent comprising mineral rich carbon (MRC) and chemically treated mineral rich carbon (TMRC). Working with experimental data, we validate the model for both MRC and TMRC based on the underlying chemical reactions. The model we derive from the chemical composition of TMRC and MRC shows good agreement with experimental results.

physics.flu-dyn↗

arXiv2023

An analytical investigation into solute transport and sorption via intra-particle diffusion in the dual-porosity limit

We develop a mathematical model for adsorption based on averaging the flow around, and diffusion inside, adsorbent particles in a column. The model involves three coupled partial differential equations for the contaminant concentration both in the carrier fluid and within the particle as well as the adsorption rate. The adsorption rate is modelled using the Sips equation, which is suitable for describing both physical and chemical adsorption mechanisms. Non-dimensionalisation is used to determine the controlling parameter groups as well as to determine negligible terms and so reduce the system complexity. The inclusion of intra-particle diffusion introduces new dimensionless parameters to those found in standard works, including a form of internal Damköhler number and a new characteristic time scale. We provide a numerical method for the full model and show how in certain situations a travelling wave approach can be utilized to find analytical solutions. The model is validated against available experimental data for the removal of Mercury(II) and CO$_\text{2}$. The results show excellent agreement with measurements of column outlet contaminant concentration and provide insights into the underlying chemical reactions.

cond-mat.other↗

arXiv2021

A homogenised model for flow, transport and sorption in a heterogeneous porous medium

A major challenge in flow through porous media is to better understand the link between microstructure and macroscale flow and transport. For idealised microstructures, the mathematical framework of homogenisation theory can be used for this purpose. Here, we consider a two-dimensional microstructure comprising an array of obstacles of smooth but arbitrary shape, the size and spacing of which can vary along the length of the porous medium. We use homogenisation via the method of multiple scales to systematically upscale a novel problem involving cells of varying area to obtain effective continuum equations for macroscale flow and transport. The equations are characterised by the local porosity, a local anisotropic flow permeability, an effective local anisotropic solute diffusivity, and an effective local adsorption rate. These macroscale properties depend nontrivially on the two degrees of microstructural geometric freedom in our problem: obstacle size, and obstacle spacing. We exploit this dependence to construct and compare scenarios where the same porosity profile results from different combinations of obstacle size and spacing. We focus on a simple example geometry comprising circular obstacles on a rectangular lattice, for which we numerically determine the macroscale permeability and effective diffusivity. We investigate scenarios where the porosity is spatially uniform but the permeability and diffusivity are not. Our results may be useful in the design of filters, or for studying the impact of deformation on transport in soft porous media.

physics.flu-dyn↗

arXiv2019

Large poroelasto-plastic deformations due to radially outward fluid injection

Flow-induced failure of granular materials is relevant to a broad range of geomechanical applications. Plasticity, which is the inherent failure mechanism of most granular materials, enables large deformations that can invalidate linearised models. Motivated by fluid injection into a borehole, we develop a steady-state model for the large deformation of a thick-walled, partially-permeable, elastic--perfectly-plastic annulus with a pressurised inner cavity. We account for pre-existing compressive stresses, as would be present in the subsurface, by subtracting a compressed initial state from our solutions to provide the additional disturbance due to fluid injection. We also introduce a simple parameter that allows for a smooth transition from an impermeable material (i.e., subject to mechanical loading at the inner wall) to a fully permeable material (i.e., subject to an internal pore-pressure gradient), which would be relevant to coated boreholes and very-low-permeability materials. We focus on the difference between poroelastic and poroelasto-plastic deformations, the role of kinematic and constitutive nonlinearity, and the transition from impermeable to fully permeable. We find that plasticity can enable much larger deformations while predicting much smaller stresses. The former makes model choice increasingly important in the plastic region, while the elastic region remains insensitive to these changes. We also find that, for a fixed total stress at the inner wall, materials experience larger deformations and generally larger stresses as they transition from impermeable to fully permeable.

physics.app-ph↗

arXiv2018

From arteries to boreholes: Transient response of a poroelastic cylinder to fluid injection

The radially outward flow of fluid through a porous medium occurs in many practical problems, from transport across vascular walls to the pressurisation of boreholes in the subsurface. When the driving pressure is non-negligible relative to the stiffness of the solid structure, the poromechanical coupling between the fluid and the solid can control both the steady-state and the transient mechanics of the system. Very large pressures or very soft materials lead to large deformations of the solid skeleton, which introduce kinematic and constitutive nonlinearity that can have a nontrivial impact on these mechanics. Here, we study the transient response of a poroelastic cylinder to sudden fluid injection. We consider the impacts of kinematic and constitutive nonlinearity, both separately and in combination, and we highlight the central role of driving method in the evolution of the response. We show that the various facets of nonlinearity may either accelerate or decelerate the transient response relative to linear poroelasticity, depending on the boundary conditions and the initial geometry, and that an imposed fluid pressure leads to a much faster response than an imposed fluid flux.

physics.flu-dyn↗

arXiv2017

From arteries to boreholes: Steady-state response of a poroelastic cylinder to fluid injection

The radially outward flow of fluid into a porous medium occurs in many practical problems, from transport across vascular walls to the pressurisation of boreholes. As the driving pressure becomes non-negligible relative to the stiffness of the solid structure, the poromechanical coupling between the fluid and the solid has an increasingly strong impact on the flow. For very large pressures or very soft materials, as is the case for hydraulic fracturing and arterial flows, this coupling can lead to large deformations and, hence, to strong deviations from a classical, linear-poroelastic response. Here, we study this problem by analysing the steady-state response of a poroelastic cylinder to fluid injection. We consider the qualitative and quantitative impacts of kinematic and constitutive nonlinearity, highlighting the strong impact of deformation-dependent permeability. We show that the wall thickness (thick vs. thin) and the outer boundary condition (free vs. constrained) play a central role in controlling the mechanics.

physics.flu-dyn↗