arXiv subjects

Lucy M. Ziurys

Publications and source records attributed to Lucy M. Ziurys.

14 recordsLinked to original sources

arXiv2025

Molecules and Chemistry in Red Supergiants

The envelopes of Red Supergiants (RSGs) have a unique chemical environment not seen in other types of stars. They foster an oxygen-rich synthesis but are tempered by sporadic and chaotic mass loss, which distorts the envelope and creates complex outflow sub-structures consisting of knots, clumps, and arcs. Near the stellar photosphere, molecules and grains form under approximate LTE conditions, as predicted by chemical models. However, the complicated outflows appear to have distinct chemistries generated by shocks and dust destruction. Various RSG envelopes have been probed for their molecular content, mostly by radio and millimeter observations; however, VY Canis Majoris (VY CMa) and NML Cygni (NML Cyg) display the highest chemical complexity, and also the most complicated envelope structure. Thus far, over 29 different molecules have been identified in the envelopes of RSGs. Some molecules are common for circumstellar gas, including CO, SiO, HCN and H$_2$O, which have abundances of $\sim$$10^{-6}$--$10^{-4}$, relative to H$_2$. More exotic oxides have additionally been discovered, such as AlO, AlOH, PO, TiO$_2$, and VO, with abundances of $\sim$$10^{-9}$--$10^{-7}$. RSG shells support intricate maser emission in OH, H$_2$O and SiO, as well. Studies of isotope ratios in molecules suggest dredge-up at least into the H-burning shell, but further exploration is needed.

astro-ph.SR↗

arXiv2018

Laboratory Studies of Methane and Its Relationship to Prebiotic Chemistry

In order to examine how the terrestrial life emerged, a number of laboratory experiments have been conducted since the 1950s. Methane has been one of the key molecules in these studies. In earlier studies, strongly reducing gas mixtures containing methane and ammonia were mainly used to simulate possible reactions in primitive Earth atmosphere, and amino acids and other organic compounds were detected. Since the primitive Earth atmosphere was estimated to be less reducing, contribution of extraterrestrial organics to the origin of life is considered quite important. Extraterrestrial organic chemistry has been experimentally and theoretically studied intensively, including laboratory experiments simulating interstellar molecular reactions. Endogenous and exogenous organics should have been supplied to the primitive ocean. Now submarine hydrothermal systems are considered one of the plausible sites of generation of life. Experiments simulating submarine hydrothermal systems where methane played an important role are now intensively being conducted. We have recognized the importance of such studies on possible reactions in other solar system bodies to understand the origins of life. Titan and other icy bodies, where methane plays significant roles, are especially good targets to be studied. In the case of Titan, not only methane-containing atmospheres but also liquidospheres composed of methane and other hydrocarbons have been used in simulation experiments. This paper summarizes experiments simulating various terrestrial and extraterrestrial environments, and possible roles of methane in chemical evolution are discussed.

astro-ph.EP↗

arXiv2018

Detection of intrinsic source structure at ~3 Schwarzschild radii with Millimeter-VLBI observations of SAGITTARIUS A*

We report results from very long baseline interferometric (VLBI) observations of the supermassive black hole in the Galactic center, Sgr A*, at 1.3 mm (230 GHz). The observations were performed in 2013 March using six VLBI stations in Hawaii, California, Arizona, and Chile. Compared to earlier observations, the addition of the APEX telescope in Chile almost doubles the longest baseline length in the array, provides additional {\it uv} coverage in the N-S direction, and leads to a spatial resolution of $\sim$30 $μ$as ($\sim$3 Schwarzschild radii) for Sgr A*. The source is detected even at the longest baselines with visibility amplitudes of $\sim$4-13% of the total flux density. We argue that such flux densities cannot result from interstellar refractive scattering alone, but indicate the presence of compact intrinsic source structure on scales of $\sim$3 Schwarzschild radii. The measured nonzero closure phases rule out point-symmetric emission. We discuss our results in the context of simple geometric models that capture the basic characteristics and brightness distributions of disk- and jet-dominated models and show that both can reproduce the observed data. Common to these models are the brightness asymmetry, the orientation, and characteristic sizes, which are comparable to the expected size of the black hole shadow. Future 1.3 mm VLBI observations with an expanded array and better sensitivity will allow a more detailed imaging of the horizon-scale structure and bear the potential for a deep insight into the physical processes at the black hole boundary.

astro-ph.GA↗

arXiv2016

Persistent Asymmetric Structure of Sagittarius A* on Event Horizon Scales

The Galactic Center black hole Sagittarius A* (Sgr A*) is a prime observing target for the Event Horizon Telescope (EHT), which can resolve the 1.3 mm emission from this source on angular scales comparable to that of the general relativistic shadow. Previous EHT observations have used visibility amplitudes to infer the morphology of the millimeter-wavelength emission. Potentially much richer source information is contained in the phases. We report on 1.3 mm phase information on Sgr A* obtained with the EHT on a total of 13 observing nights over 4 years. Closure phases, the sum of visibility phases along a closed triangle of interferometer baselines, are used because they are robust against phase corruptions introduced by instrumentation and the rapidly variable atmosphere. The median closure phase on a triangle including telescopes in California, Hawaii, and Arizona is nonzero. This result conclusively demonstrates that the millimeter emission is asymmetric on scales of a few Schwarzschild radii and can be used to break 180-degree rotational ambiguities inherent from amplitude data alone. The stability of the sign of the closure phase over most observing nights indicates persistent asymmetry in the image of Sgr A* that is not obscured by refraction due to interstellar electrons along the line of sight.

astro-ph.GA↗

arXiv2015

Resolved Magnetic-Field Structure and Variability Near the Event Horizon of Sagittarius A*

Near a black hole, differential rotation of a magnetized accretion disk is thought to produce an instability that amplifies weak magnetic fields, driving accretion and outflow. These magnetic fields would naturally give rise to the observed synchrotron emission in galaxy cores and to the formation of relativistic jets, but no observations to date have been able to resolve the expected horizon-scale magnetic-field structure. We report interferometric observations at 1.3-millimeter wavelength that spatially resolve the linearly polarized emission from the Galactic Center supermassive black hole, Sagittarius A*. We have found evidence for partially ordered fields near the event horizon, on scales of ~6 Schwarzschild radii, and we have detected and localized the intra-hour variability associated with these fields.

astro-ph.HE↗

arXiv2015

Interstellar Detection of Methyl Isocyanate CH$_3$NCO in Sgr B2(N): A Link from Molecular Clouds to Comets

A new interstellar molecule, CH$_3$NCO (methyl isocyanate), has been detected using the 12 m telescope of the Arizona Radio Observatory (ARO). CH$_3$NCO was identified in spectra covering 48 GHz (68-116 GHz) in the 3 mm segment of a broadband survey of Sgr B2(N). Thirty very favorable rotational lines (K$_a$ = 0 and K$_a$ = 1 only; E$_u$ < 60 K) originating in five consecutive transitions (J = 8 $\rightarrow$ 7, 9 $\rightarrow$ 8, 10 $\rightarrow$ 9, 11 $\rightarrow$ 10, and 12 $\rightarrow$ 11) in both the A and E internal rotation species are present in this frequency range. Emission was observed at all of the predicted frequencies, with seventeen lines appearing as distinct, uncontaminated spectral features, clearly showing the classic a-type, asymmetric top pattern, with T$_R$* ~ 20-70 mK. The CH$_3$NCO spectra also appear to exhibit two velocities components near V$_{LSR}$ ~ 62 and 73 km s$^{-1}$, both with $Δ$V$_{1/2}$ ~ 10 km s$^{-1}$ - typical of molecules such as CH$_2$CHCN, HNCO, and HCOOCH$_3$ in Sgr B2(N). The column density of CH$_3$NCO in Sgr B2(N) was determined to be N$_{tot}$ ~ 2.3 x 10$^{13}$ cm$^{-2}$ and 1.5 x 10$^{13}$ cm$^{-2}$ for the 62 and 73 km s$^{-1}$ components, corresponding to fractional abundances, relative to H$_2$, of f ~ 7.6 x 10$^{-12}$ and 5.0 x 10$^{-12}$, respectively. CH$_3$NCO was recently detected in volatized material from comet 67P/Churyumov-Gerasimenko by Rosetta's Philae lander, with an abundance ~1.3% of water; in Sgr B2(N), CH$_3$NCO is roughly ~0.04% of the H$_2$O abundance.

astro-ph.SR↗

arXiv2015

230 GHz VLBI observations of M87: event-horizon-scale structure at the enhanced very-high-energy $\rm γ$-ray state in 2012

We report on 230 GHz (1.3 mm) VLBI observations of M87 with the Event Horizon Telescope using antennas on Mauna Kea in Hawaii, Mt. Graham in Arizona and Cedar Flat in California. For the first time, we have acquired 230 GHz VLBI interferometric phase information on M87 through measurement of closure phase on the triangle of long baselines. Most of the measured closure phases are consistent with 0$^{\circ}$ as expected by physically-motivated models for 230 GHz structure such as jet models and accretion disk models. The brightness temperature of the event-horizon-scale structure is $\sim 1 \times 10^{10}$ K derived from the compact flux density of $\sim 1$ Jy and the angular size of $\sim 40 $ $\rm μ$as $\sim$ 5.5 $R_{\rm s}$, which is broadly consistent with the peak brightness of the radio cores at 1-86 GHz located within $\sim 10^2$ $R_{\rm s}$. Our observations occurred in the middle of an enhancement in very-high-energy (VHE) $\rm γ$-ray flux, presumably originating in the vicinity of the central black hole. Our measurements, combined with results of multi-wavelength observations, favor a scenario in which the VHE region has an extended size of $\sim$20-60 $R_{\rm s}$.

astro-ph.HE↗

arXiv2014

Global empirical potentials from purely rotational measurements

The recent advent of chirped-pulse FTMW technology has created a plethora of pure rotational spectra for molecules for which no vibrational information is known. The growing number of such spectra demands a way to build empirical potential energy surfaces for molecules, without relying on any vibrational measurements. Using ZnO as an example, we demonstrate a powerful technique for efficiently accomplishing this. We first measure eight new ultra-high precision ($\pm2$ kHz) pure rotational transitions in the $X$-state of ZnO. Combining them with previous high-precision ($\pm50$ kHz) pure rotational measurements of different transitions in the same system, we have data that spans the bottom 10\% of the well. Despite not using any vibrational information, our empirical potentials are able to determine the size of the vibrational spacings and bond lengths, with precisions that are more than three and two orders of magnitude greater, respectively, than the most precise empirical values previously known, and the most accurate \emph{ab initio} calculations in today's reach. By calculating the $C_{6},$ $C_{8},$ and $C_{10}$ long-range constants and using them to anchor the top of the well, our potential is \emph{globally} in excellent agreement with \emph{ab initio} calculations, without the need for vibrational spectra and without the need for \emph{any} data in the top 90\% of the well.

physics.chem-ph↗

arXiv2013

Fine-scale structure of the quasar 3C 279 Measured with 1.3 mm very long baseline interferometry

We report results from 5-day VLBI observations of the well-known quasar 3C 279 at 1.3 mm (230 GHz) in 2011. The measured nonzero closure phases on triangles including stations in Arizona, California and Hawaii indicate that the source structure is spatially resolved. We find an unusual inner jet direction at scales of $\sim$1 parsec extending along the northwest-southeast direction (PA = $127^{\circ}\pm3^{\circ}$), as opposed to other (previously) reported measurements on scales of a few parsecs showing inner jet direction extending to the southwest. The 1.3 mm structure corresponds closely with that observed in the central region of quasi-simultaneous super-resolution VLBA images at 7 mm. The closure phase changed significantly on the last day when compared with the rest of observations, indicating that the inner jet structure may be variable on daily timescales. The observed new direction of the inner jet shows inconsistency with the prediction of a class of jet precession models. Our observations indicate a brightness temperature of $\sim 8\times10^{10}$ K in the 1.3 mm core, much lower than that at centimeter wavelengths. Observations with better uv coverage and sensitivity in the coming years will allow the discrimination between different structure models and will provide direct images of the inner regions of the jet with 20--30 $μ$as (5--7 light months) resolution.

astro-ph.HE↗

arXiv2012

Jet Launching Structure Resolved Near the Supermassive Black Hole in M87

Approximately 10% of active galactic nuclei exhibit relativistic jets, which are powered by accretion of matter onto super massive black holes. While the measured width profiles of such jets on large scales agree with theories of magnetic collimation, predicted structure on accretion disk scales at the jet launch point has not been detected. We report radio interferometry observations at 1.3mm wavelength of the elliptical galaxy M87 that spatially resolve the base of the jet in this source. The derived size of 5.5 +/- 0.4 Schwarzschild radii is significantly smaller than the innermost edge of a retrograde accretion disk, suggesting that the M87 jet is powered by an accretion disk in a prograde orbit around a spinning black hole.

astro-ph.HE↗

arXiv2012

Resolving the inner jet structure of 1924-292 with the EVENT HORIZON TELESCOPE

We present the first 1.3 mm (230 GHz) very long baseline interferometry model image of an AGN jet using closure phase techniques with a four-element array. The model image of the quasar 1924-292 was obtained with four telescopes at three observatories: the James Clerk Maxwell Telescope (JCMT) on Mauna Kea in Hawaii, the Arizona Radio Observatory's Submillimeter Telescope (SMT) in Arizona, and two telescopes of the Combined Array for Research in Millimeterwave Astronomy (CARMA) in California in April 2009. With the greatly improved resolution compared with previous observations and robust closure phase measurement, the inner jet structure of 1924-292 was spatially resolved. The inner jet extends to the northwest along a position angle of $-53^\circ$ at a distance of 0.38\,mas from the tentatively identified core, in agreement with the inner jet structure inferred from lower frequencies, and making a position angle difference of $\sim 80^{\circ}$ with respect to the cm-jet. The size of the compact core is 0.15\,pc with a brightness temperature of $1.2\times10^{11}$\,K. Compared with those measured at lower frequencies, the low brightness temperature may argue in favor of the decelerating jet model or particle-cascade models. The successful measurement of closure phase paves the way for imaging and time resolving Sgr A* and nearby AGN with the Event Horizon Telescope.

astro-ph.HE↗

arXiv2010

1.3 mm Wavelength VLBI of Sagittarius A*: Detection of Time-Variable Emission on Event Horizon Scales

Sagittarius A*, the ~4 x 10^6 solar mass black hole candidate at the Galactic Center, can be studied on Schwarzschild radius scales with (sub)millimeter wavelength Very Long Baseline Interferometry (VLBI). We report on 1.3 mm wavelength observations of Sgr A* using a VLBI array consisting of the JCMT on Mauna Kea, the ARO/SMT on Mt. Graham in Arizona, and two telescopes of the CARMA array at Cedar Flat in California. Both Sgr A* and the quasar calibrator 1924-292 were observed over three consecutive nights, and both sources were clearly detected on all baselines. For the first time, we are able to extract 1.3 mm VLBI interferometer phase information on Sgr A* through measurement of closure phase on the triangle of baselines. On the third night of observing, the correlated flux density of Sgr A* on all VLBI baselines increased relative to the first two nights, providing strong evidence for time-variable change on scales of a few Schwarzschild radii. These results suggest that future VLBI observations with greater sensitivity and additional baselines will play a valuable role in determining the structure of emission near the event horizon of Sgr A*.

astro-ph.GA↗

arXiv2009

A Multi-Wavelength Study of Parent Volatile Abundances in Comet C/2006 M4 (SWAN)

Volatile organic emissions were detected post-perihelion in the long period comet C/2006 M4 (SWAN) in October and November 2006. Our study combines target-of-opportunity observations using the infrared Cryogenic Echelle Spectrometer (CSHELL) at the NASA-IRTF 3-m telescope, and millimeter wavelength observations using the Arizona Radio Observatory (ARO) 12-m telescope. Five parent volatiles were measured with CSHELL (H2O, CO, CH3OH, CH4, and C2H6), and two additional species (HCN and CS) were measured with the ARO 12-m. These revealed highly depleted CO and somewhat enriched CH3OH compared with abundances observed in the dominant group of long-period (Oort cloud) comets in our sample and similar to those observed recently in Comet 8P/Tuttle. This may indicate highly efficient H-atom addition to CO at very low temperature (~ 10 - 20 K) on the surfaces of interstellar (pre-cometary) grains. Comet C/2006 M4 had nearly "normal" C2H6 and CH4, suggesting a processing history similar to that experienced by the dominant group. When compared with estimated water production at the time of the millimeter observations, HCN was slightly depleted compared with the normal abundance in comets based on IR observations but was consistent with the majority of values from the millimeter. The ratio CS/HCN in C/2006 M4 was within the range measured in ten comets at millimeter wavelengths. The higher apparent H-atom conversion efficiency compared with most comets may indicate that the icy grains incorporated into C/2006 M4 were exposed to higher H-atom densities, or alternatively to similar densities but for a longer period of time.

astro-ph.EP↗

arXiv2008

Event-horizon-scale structure in the supermassive black hole candidate at the Galactic Centre

The cores of most galaxies are thought to harbour supermassive black holes, which power galactic nuclei by converting the gravitational energy of accreting matter into radiation (ref 1). Sagittarius A*, the compact source of radio, infrared and X-ray emission at the centre of the Milky Way, is the closest example of this phenomenon, with an estimated black hole mass that is 4 million times that of the Sun (refs. 2,3). A long-standing astronomical goal is to resolve structures in the innermost accretion flow surrounding Sgr A* where strong gravitational fields will distort the appearance of radiation emitted near the black hole. Radio observations at wavelengths of 3.5 mm and 7 mm have detected intrinsic structure in Sgr A*, but the spatial resolution of observations at these wavelengths is limited by interstellar scattering (refs. 4-7). Here we report observations at a wavelength of 1.3 mm that set a size of 37 (+16, -10; 3-sigma) microarcseconds on the intrinsic diameter of Sgr A*. This is less than the expected apparent size of the event horizon of the presumed black hole, suggesting that the bulk of SgrA* emission may not be not centred on the black hole, but arises in the surrounding accretion flow.

astro-ph↗