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Luiz A. Meneghetti Jr.

Publications and source records attributed to Luiz A. Meneghetti Jr..

2 recordsLinked to original sources

Beyond Impedance Additivity: A Systematic Nonlinear Perspective on Memristor Associations

We investigate the validity of the superposition principle and impedance additivity in AC circuits containing a memristive device connected in series with a resistor, capacitor, or inductor. While the series association of impedances is a cornerstone of linear circuit theory, its applicability to memory-bearing nonlinear systems remains largely unexplored. Using a state-dependent memristive model, we numerically analyze the stationary current response under sinusoidal excitation and characterize the resulting harmonic spectra, Bode diagrams, and Nyquist plots. To assess whether the fundamental response can still be interpreted through an equivalent-circuit framework, we introduce the concept of an apparent memristor, whose effective parameters are extracted directly from the composite impedance. We show that, although the fundamental harmonic can be accurately reproduced by an apparent equivalent circuit over selected parameter ranges, the effective parameters differ substantially from those of the isolated memristor, revealing a renormalization induced by the coupling to the passive element. More importantly, we identify parameter regimes in which the apparent-circuit description breaks down altogether, particularly for capacitor and inductor-coupled systems, demonstrating that the composite impedance cannot generally be expressed as the sum of independent impedances. These results establish boundaries for the use of equivalent-circuit models in memory-enabled electronic systems and provide practical guidelines for the interpretation of impedance spectroscopy in nonlinear devices exhibiting memory.

cond-mat.mtrl-sci↗

A New Approach to Characterize Charge Transport and Hysteresis in Perovskite Solar Cells

Perovskite solar cells (PSCs) have emerged as a promising photovoltaic technology, already achieving efficiencies surpassing 25%. However, effects such as hysteresis are commonly observed due to the interplay of ionic and electronic transport occurring over different timescales. Despite the widespread use of impedance spectroscopy (IS), physical interpretation in PSCs is specially challenging due to memory effects. In this study, we focus on integrating experimental data with an analytical device transport model. The PSCs under investigation were fabricated using a Cs$_{0.17}$FA$_{0.83}$Pb(I$_{0.83}$Br$_{0.17}$)$_3$ active layer between Nb$_2$O$_5$/TiO$_2$ (compact/mesoporous) and Spiro-OMeTAD. Our fully analytical charge transport model incorporates independent charge transport channels, enabling the correlation of experimental observations in both dark and under illumination. We employed IS together with various voltammetry techniques to reveal the dynamics of the transport processes, including voltage pulses and both small and large amplitude sinusoidal excitations. Although small perturbations are commonly used in IS, our findings demonstrate that large sinusoidal excitation provides new valuable insights in the transition from capacitive to inductive-like responses. The proposed model based purely on charge trapping and generation effectively captures device behavior under both small and large voltages without inductive elements, validated through accurate simulations of hysteresis and other electrical phenomena.

physics.app-ph↗