Lutz Mädler | Searcharxiv

arXiv2026

Bubble detachment from circular cavities and flat surfaces

We determine the maximum stable volume of bubbles attached to flat surfaces as a function of contact radius, contact angle, and capillary length. By solving the Young-Laplace equation using a shooting method, we calculate equilibrium bubble shapes and determine when bubbles detach through three distinct modes: necking at the cavity, sideways instability, and spreading followed by necking on the surrounding surface. Our predicted detachment volumes agree well with experimental measurements of electrolytic, boiling, and carbonated bubbles, as well as pendant drops. These results bring together and extend previous analytical estimates and, by symmetry, also apply directly to pendant drops.

physics.flu-dyn↗

arXiv2026

A geometric reformulation of the bilevel parameter optimization problem to a single level non-linear programming problem with applications to phase equilibria

Phase equilibrium problems are central to chemical engineering, underpinning tasks ranging from separation process design to the development of thermodynamic models. A particularly challenging computational task is the generation of phase envelopes: rigorously fitting thermodynamic models to real world data with well behaved predictions requires solving a computationally expensive bilevel optimization problem. We present a geometric reformulation of this parameter estimation problem that restates the bilevel program as a single level problem that is significantly easier to solve. The solution of the single level problem is proven to be the globally optimal solution of the bilevel problem when specialized global optimization solvers are used. In addition, the method retains the constraints that guarantee a well behaved fitted model, such as enforcing the correct number of phase splits, excluding spurious phases, and ensuring stability in regions of instability. This allows the practitioner to reliably and efficiently fit mathematically complex thermodynamic models to data, and potentially enables highly accurate and rigorous modelling of problems in computational thermodynamics that were previously intractable. Finally, an algorithm is presented that is proven to converge for any black box thermodynamic model. Only an expression of the Gibbs free energy is required, no derivatives are needed, and convergence is guaranteed for the broadest class of non-smooth, non-continuous models.

math.OC↗