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M. A. Cordiner

Publications and source records attributed to M. A. Cordiner.

At least 19 recordsLinked to original sources

Perihelion observations of interstellar comet 3I/ATLAS with the IRAM 30-m telescope

3I/ATLAS is the third interstellar comet identified as passing through the Solar System. Its high outgassing activity and favourable perihelion passage on October 29, 2025 UT provided an excellent opportunity to investigate the composition of its coma gases through millimeter spectroscopy. We present observations undertaken with the IRAM 30-m telescope on November 1--3, 2025 at an heliocentric distance of 1.36--1.37 au. Lines of HCN, CH$_3$OH, CO, and H$_2$CO are well detected, and $\sim$4$σ$ detections are obtained for CS and CH$_3$CN. The search for H$_2$S was unsuccessful. Abundances of CO, H$_2$CO, CH$_3$OH, and CH$_3$CN relative to HCN are in the upper ranges of values measured in Solar System comets. The sulfur-to-carbon abundance ratio in 3I/ATLAS's coma is at most the minimum value observed in comets. The unusually low expansion velocity of coma gases suggests a near-nucleus gas flow driven by heavy molecules such as CO$_2$, and/or a large fraction of the gaseous production coming from subliming icy grains.

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A Multi-Wavelength Study of Comet C/2022 E3 (ZTF): Complementary ALMA and JWST Investigations of Water and Methanol in Cometary Comae

Long-period comets, which are often considered to be representative of material in the protoplanetary disk that formed the Solar System, are ideal to investigate the question of chemical inheritance in astronomy. Determining the chemistry of comets, both individually and as a population, has become of great importance in comparative studies against sources representative of evolutionary precursors to planetary systems. Contemporaneous observations of long-period comet C/2022 E3 (ZTF) were obtained with the JWST and the Atacama Large Millimeter/submillimeter Array (ALMA) in early 2023 March. This work focuses on \ce{CH3OH} measurements from both ALMA and JWST as well as \ce{H2O} measurements from JWST. Radiative transfer modeling of \ce{CH3OH} and \ce{H2O} was performed to investigate spatial variations in rotational temperature, column density, and production rates, as well as a comparison of derived values between the two telescopes. Most of the spatial distributions of the modeled values are centrally peaked, and the modeled values from JWST are all within the error bars of the average values from ALMA. C/2022 E3 (ZTF) also displays an enhancement in modeled rotational temperature in the anti-Sunward direction that is shown to be statistically significant. Based on non-LTE radiative transfer modeling, the declining \ce{H2O} rotational temperatures as a function of nucleocentric distance observed by JWST can be explained primarily as a result of rotational line cooling. The values derived in this work are in general agreement with single-dish millimeter-wave observations.

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A D/H Ratio Consistent with Earth's Water in Halley-type Comet 12P from ALMA HDO Mapping

Isotopic measurements of Solar System bodies provide a primary paradigm within which to understand the origins and histories of planetary materials. The D/H ratio in particular, helps reveal the relationship between (and heritage of) different H$_2$O reservoirs within the Solar System. Here we present interferometric maps of water (H$_2$O) and semiheavy water (HDO) in the gas-phase coma of a comet (Halley-type comet 12P/Pons-Brooks), obtained using the Atacama Large Millimeter/submillimeter Array (ALMA). The maps are consistent with outgassing of both H$_2$O and HDO directly from the nucleus, and imply a coma D/H ratio (for water) of $(1.71 \pm 0.44)\times10^{-4}$. This is at the lower end of the range of previously-observed values in comets, and is consistent with D/H in Earth's ocean water. Our results suggest a possible common heritage between a component of the Oort cloud's water ice reservoir, and the water that was delivered to the young Earth during the early history of the Solar System.

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Improved Carbon and Nitrogen Isotopic Ratios for CH$_3$CN in Titan's Atmosphere Using ALMA

Titan, Saturn's largest satellite, maintains an atmosphere composed primarily of nitrogen (N$_2$) and methane (CH$_4$) that leads to a complex organic chemistry. Some of the nitriles (CN-bearing organics) on Titan are known to have substantially enhanced $^{15}$N abundances compared to Earth and to Titan's dominant nitrogen (N$_2$) reservoir. The $^{14}$N/$^{15}$N isotopic ratio in Titan's nitriles can provide better constraints on the synthesis of nitrogen-bearing organics in planetary atmospheres as well as insights into the origin of Titan's large nitrogen abundance. Using high signal-to-noise ratio ($>13$), disk-integrated observations obtained with the Atacama Large Millimeter/submillimeter Array (ALMA) Band 6 receiver (211-275 GHz), we measure the $^{14}$N/$^{15}$N and $^{12}$C/$^{13}$C isotopic ratios of acetonitrile (CH$_3$CN) in Titan's stratosphere. Using the Nonlinear optimal Estimator for MultivariatE spectral analySIS (NEMESIS), we derived the CH$_3$CN/$^{13}$CH$_3$CN ratio to be 89.2 $\pm$ 7.0 and the CH$_3$CN/CH$_3$$^{13}$CN ratio to be 91.2 $\pm$ 6.0, in agreement with the $^{12}$C/$^{13}$C ratio in Titan's methane, and other Solar System species. We found the $^{14}$N/$^{15}$N isotopic ratio to be 68.9 $\pm$ 4.2, consistent with previously derived values for HCN and HC$_3$N, confirming an enhanced $^{15}$N abundance in Titan's nitriles compared with the bulk atmospheric N$_2$ value of $^{14}$N/$^{15}$N = 168, in agreement with chemical models incorporating isotope-selective photodissociation of N$_2$ at high altitudes.

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Evidence for Surprising Heavy Nitrogen Isotopic Enrichment in Comet 46P/Wirtanen's Hydrogen Cyanide

46P/Wirtanen is a Jupiter-family comet, probably originating from the Solar System's Kuiper belt, that now resides on a 5.4 year elliptical orbit. During its 2018 apparition, comet 46P passed unusually close to the Earth (within 0.08 au), presenting an outstanding opportunity for close-up observations of its inner coma. Here we present observations of HCN, H$^{13}$CN and HC$^{15}$N emission from 46P using the Atacama Compact Array (ACA). The data were analyzed using the SUBLIME non-LTE radiative transfer code to derive $^{12}$C/$^{13}$C and $^{14}$N/$^{15}$N ratios. The HCN/H$^{13}$CN ratio is found to be consistent with a lack of significant $^{13}$C fractionation, whereas the HCN/HC$^{15}$N ratio of $68\pm27$ (using our most conservative $1σ$ uncertainties), indicates a strong enhancement in $^{15}$N compared with the solar and terrestrial values. The observed $^{14}$N/$^{15}$N ratio is also significantly lower than the values of $\sim140$ found in previous comets, implying a strong $^{15}$N enrichment in 46P's HCN. This indicates that the nitrogen in Jupiter-family comets could reach larger isotopic enrichments than previously thought, with implications for the diversity of $^{14}$N/$^{15}$N ratios imprinted into icy bodies at the birth of the Solar System.

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A JWST/MIRI analysis of the ice distribution and PAH emission in the protoplanetary disk HH 48 NE

Ice-coated dust grains provide the main reservoir of volatiles that play an important role in planet formation processes and may become incorporated into planetary atmospheres. However, due to observational challenges, the ice abundance distribution in protoplanetary disks is not well constrained. We present JWST/MIRI observations of the edge-on disk HH 48 NE carried out as part of the IRS program Ice Age. We detect CO$_2$, NH$_3$, H$_2$O and tentatively CH$_4$ and NH$_4^+$. Radiative transfer models suggest that ice absorption features are produced predominantly in the 50-100 au region of the disk. The CO$_2$ feature at 15 micron probes a region closer to the midplane (z/r = 0.1-0.15) than the corresponding feature at 4.3 micron (z/r = 0.2-0.6), but all observations trace regions significantly above the midplane reservoirs where we expect the bulk of the ice mass to be located. Ices must reach a high scale height (z/r ~ 0.6; corresponding to modeled dust extinction Av ~ 0.1), in order to be consistent with the observed vertical distribution of the peak ice optical depths. The weakness of the CO$_2$ feature at 15 micron relative to the 4.3 micron feature and the red emission wing of the 4.3 micron CO$_2$ feature are both consistent with ices being located at high elevation in the disk. The retrieved NH$_3$ abundance and the upper limit on the CH$_3$OH abundance relative to H$_2$O are significantly lower than those in the interstellar medium (ISM), but consistent with cometary observations. Full wavelength coverage is required to properly study the abundance distribution of ices in disks. To explain the presence of ices at high disk altitudes, we propose two possible scenarios: a disk wind that entrains sufficient amounts of dust, thus blocking part of the stellar UV radiation, or vertical mixing that cycles enough ices into the upper disk layers to balance ice photodesorption.

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ALMA Spectroscopy of Europa: A Search for Active Plumes

The subsurface ocean of Europa is a high priority target in the search for extraterrestrial life, but direct investigations are hindered by the presence of a thick, exterior ice shell. Here we present spectral line and continuum maps of Europa obtained over four epochs in May-June 2021 using the Atacama Large Millimeter/submillimeter Array (ALMA), to search for molecular emission from atmospheric plumes, with the aim of investigating subsurface processes. Using a 3D physical model, we obtained upper limits for the plume abundances of HCN, H$_2$CO, SO$_2$ and CH$_3$OH. If active plume(s) were present, they contained very low abundances of these molecules. Assuming a total gas production rate of $10^{29}$ s$^{-1}$, our H$_2$CO abundance upper limit of $<0.016$\% is more than an order of magnitude less than measured in the Enceladus plume by the Cassini spacecraft, implying a possible chemical difference between the plume source materials for these two icy moons.

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Variability in Titan's Mesospheric HCN and Temperature Structure as Observed by ALMA

The temperature structure of Titan's upper atmosphere exhibits large variability resulting from numerous spatially and temporally irregular external energy sources, seasonal changes, and the influence of molecular species produced via photochemistry. In particular, Titan's relatively abundant HCN is thought to provide substantial cooling to the upper atmosphere through rotational emission, balancing UV/EUV heating and thermal conduction. Here, we present the analysis of ALMA observations of Titan from 2012, 2014, 2015, and 2017, corresponding to planetocentric solar longitudes of ~34-89$^{\circ}$, including vertical HCN and temperature profiles retrieved from the lower mesosphere through the thermosphere (~350-1200 km; $3\times10^{-2}$-$2\times10^{-8}$ mbar). Throughout the atmosphere, temperature profiles differ by 10 to 30 K between observations approximately one Earth year apart, particularly from 600-900 km. We find evidence for a large imbalance in Titan's upper atmospheric energy budget between 2014 and 2015, where the mesospheric thermal structure changes significantly and marks the transition between a mesopause located at ~600 km ($2\times10^{-4}$ mbar) and at ~800 km ($3\times10^{-6}$ mbar). The retrieved HCN abundances vary dramatically during the 2012 to 2017 time period as well, showing close to 2 orders of magnitude difference in abundance at 1000 km. However, the change in HCN abundance does not appear to fully account for the variation in mesospheric temperatures over the $L_S\sim$34-89$^{\circ}$ period. These measurements provide additional insight into the variability of Titan's mesospheric composition and thermal structure following its 2009 vernal equinox, and motivate continued investigation of the origins of such rapid changes in Titan's atmosphere throughout its seasonal cycle.

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Charting Circumstellar Chemistry of Carbon-rich AGB Stars: I. ALMA 3 mm spectral surveys

AGB stars are major contributors to the chemical enrichment of the ISM through nucleosynthesis and extensive mass loss. Most of our current knowledge of AGB atmospheric and circumstellar chemistry, in particular in a C-rich environment, is based on observations of the carbon star IRC+10216. We aim to obtain a more generalised understanding of the chemistry in C-rich AGB CSEs by studying a sample of three carbon stars, IRAS15194-5115, IRAS15082-4808, and IRAS07454-7112, and test the archetypal status often attributed to IRC+10216. We performed spatially resolved, unbiased spectral surveys in ALMA Band 3. We identify a total of 132 rotational transitions from 49 molecular species. There are two main morphologies of the brightness distributions: centrally-peaked (e.g. HCN) and shell-like (e.g. C$_2$H). We estimated the sizes of the molecular emitting regions using azimuthally-averaged radial profiles of the line brightness distributions, and derived abundance estimates. Of the shell distributions, the cyanopolyynes peak at slightly smaller radii than the hydrocarbons, and CN and HNC show the most extended emission. The emitting regions for each species are the smallest for IRAS07454-7112. We find that, within the uncertainties of the analysis, the three stars present similar abundances for most species, also compared to IRC+10216. We find that SiO is more abundant in our three stars compared to IRC+10216. Our estimated isotopic ratios match well the literature values for the sources. The observed circumstellar chemistry appears very similar across our sample and compared to that of IRC+10216, both in terms of the relative location of the emitting regions and molecular abundances. This implies that, to a first approximation, the chemical models tailored to IRC+10216 are able to reproduce the observed chemistry in C-rich envelopes across roughly an order of magnitude in wind density.

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A JWST inventory of protoplanetary disk ices: The edge-on protoplanetary disk HH 48 NE, seen with the Ice Age ERS program

Ices are the main carriers of volatiles in protoplanetary disks and are crucial to our understanding of the chemistry that ultimately sets the organic composition of planets. The ERS program Ice Age on the JWST follows the ice evolution through all stages of star and planet formation. JWST/NIRSpec observations of the edge-on Class II protoplanetary disk HH~48~NE reveal spatially resolved absorption features of the major ice components H$_2$O, CO$_2$, CO, and multiple weaker signatures from less abundant ices NH$_3$, OCN$^-$, and OCS. Isotopologue $^{13}$CO$_2$ ice has been detected for the first time in a protoplanetary disk. Since multiple complex light paths contribute to the observed flux, the ice absorption features are filled in by ice-free scattered light. The $^{12}$CO$_2$/$^{13}$CO$_2$ ratio of 14 implies that the $^{12}$CO$_2$ feature is saturated, without the flux approaching 0, indicative of a very high CO$_2$ column density on the line of sight, and a corresponding abundance with respect to hydrogen that is higher than ISM values by a factor of at least a few. Observations of rare isotopologues are crucial, as we show that the $^{13}$CO$_2$ observation allows us to determine the column density of CO$_2$ to be at an order of magnitude higher than the lower limit directly inferred from the observed optical depth. Radial variations in ice abundance, e.g., snowlines, are significantly modified since all observed photons have passed through the full radial extent of the disk. CO ice is observed at perplexing heights in the disk, extending to the top of the CO-emitting gas layer. We argue that the most likely interpretation is that we observe some CO ice at high temperatures, trapped in less volatile ices like H$_2$O and CO$_2$. Future radiative transfer models will be required to constrain the implications on our current understanding of disk physics and chemistry.

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Gas Sources from the Coma and Nucleus of Comet 46P/Wirtanen Observed Using ALMA

Gas-phase molecules in cometary atmospheres (comae) originate primarily from (1) outgassing by the nucleus, (2) sublimation of icy grains in the near-nucleus coma, and (3) coma (photo-)chemical processes. However, the majority of cometary gases observed at radio wavelengths have yet to be mapped, so their production/release mechanisms remain uncertain. Here we present observations of six molecular species towards comet 46P/Wirtanen, obtained using the Atacama Large Millimeter/submillimeter Array (ALMA) during the comet's unusually close (~0.1 au) approach to Earth in December 2018. Interferometric maps of HCN, CH3OH, CH3CN, H2CO, CS and HNC were obtained at an unprecedented sky-projected spatial resolution of up to 25 km, enabling the nucleus and coma sources of these molecules to be accurately quantified. The HCN, CH3OH and CH3CN spatial distributions are consistent with production by direct outgassing from (or very near to) the nucleus, with a significant proportion of the observed CH3OH originating from sublimation of icy grains in the near-nucleus coma (at a scale-length $L_p=36\pm7$ km). On the other hand, H2CO, CS and HNC originate primarily from distributed coma sources (with $L_p$ values in the range 550-16,000 km), the identities of which remain to be established. The HCN, CH3OH and HNC abundances in 46P are consistent with the average values previously observed in comets, whereas the H2CO, CH3CN and CS abundances are relatively low.

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Phosphine in the Venusian Atmosphere: A Strict Upper Limit from SOFIA GREAT Observations

The presence of phosphine (PH$_3$) in the atmosphere of Venus was reported by Greaves et al. (2021a), based on observations of the J=1-0 transition at 267 GHz using ground-based, millimeter-wave spectroscopy. This unexpected discovery presents a challenge for our understanding of Venus's atmosphere, and has led to a reappraisal of the possible sources and sinks of atmospheric phosphorous-bearing gases. Here we present results from a search for PH$_3$ on Venus using the GREAT instrument aboard the SOFIA aircraft, over three flights conducted in November 2021. Multiple PH$_3$ transitions were targeted at frequencies centered on 533 GHz and 1067 GHz, but no evidence for atmospheric PH$_3$ was detected. Through radiative transfer modeling, we derived a disk-averaged upper limit on the PH$_3$ abundance of 0.8 ppb in the altitude range 75-110 km, which is more stringent than previous ground-based studies.

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Radiative processes as diagnostics of cometary atmospheres

In this chapter, we provide a review of radiative processes in cometary atmospheres spanning a broad range of wavelengths, from radio to X-rays. We focus on spectral modeling, observational opportunities, and anticipated challenges in the interpretation of new observations, based on our current understanding of the atomic and molecular processes occurring in the atmospheres of small, icy bodies. Close to the surface, comets possess a thermalized atmosphere that traces the irregular shape of the nucleus. Gravity is too low to retain the gas, which flows out to form a large, collisionless exosphere (coma) that interacts with the heliospheric radiation environment. As such, cometary comae represent conditions that are familiar in the context of planetary atmosphere studies. However, the outer comae are tenuous, with densities lower than those found in vacuum chambers on Earth. Comets, therefore, provide us with unique natural laboratories that can be understood using state-of-the-art theoretical treatments of the relevant microphysical processes. Radiative processes offer direct diagnostics of the local physical conditions, as well as the macroscopic coma properties.These can be used to improve our understanding of comets and other astrophysical environments such as icy moons and the interstellar medium.

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The Isotopic Links from Planet Forming Regions to the Solar System

Isotopic ratios provide a powerful tool for understanding the origins of materials, including the volatile and refractory matter within solar system bodies. Recent high sensitivity observations of molecular isotopologues, in particular with ALMA, have brought us new information on isotopic ratios of hydrogen, carbon, nitrogen and oxygen in star and planet forming regions as well as the solar system objects. Solar system exploration missions, such as Rosetta and Cassini, have given us further new insights. Meanwhile, the recent development of sophisticated models for isotope chemistry including detailed gas-phase and grain surface reaction network has made it possible to discuss how isotope fractionation in star and planet forming regions is imprinted into the icy mantles of dust grains, preserving a record of the initial isotopic state of solar system materials. This chapter reviews recent progress in observations of molecular isotopologues in extra-solar planet forming regions, prestellar/protostellar cores and protoplanetary disks, as well as objects in our solar system -- comets, meteorites, and planetary/satellite atmospheres -- and discusses their connection by means of isotope chemical models.

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A SUBLIME 3D Model for Cometary Coma Emission: the Hypervolatile-Rich Comet C/2016 R2 (PanSTARRS)

The coma of comet C/2016 R2 (PanSTARRS) is one of the most chemically peculiar ever observed, in particular due to its extremely high CO/H2O and N2+/H2O ratios}, and unusual trace volatile abundances. However, the complex shape of its CO emission lines, as well as uncertainties in the coma structure and excitation, has lead to ambiguities in the total CO production rate. We performed high resolution, spatially, spectrally and temporally resolved CO observations using the James Clerk Maxwell Telescope (JCMT) and Submillimeter Array (SMA) to elucidate the outgassing behaviour of C/2016 R2. Results are analyzed using a new, time-dependent, three dimensional radiative transfer code (SUBLIME), incorporating for the first time, accurate state-to-state collisional rate coefficients for the CO--CO system. The total CO production rate was found to be in the range $(3.8-7.6)\times10^{28}$ s$^{-1}$ between 2018-01-13 and 2018-02-01, with a mean value of $(5.3\pm0.6)\times10^{28}$ s$^{-1}$ at r_H = 2.8-2.9 au. The emission is concentrated in a near-sunward jet, with an outflow velocity $0.51\pm0.01$ km/s, compared to $0.25\pm0.01$ km/s in the ambient (and night-side) coma. Evidence was also found for an extended source of CO emission, possibly due to icy grain sublimation around $1.2\times10^5$ km from the nucleus. Based on the coma molecular abundances, we propose that the nucleus ices of C/2016 R2 can be divided into a rapidly sublimating apolar phase, rich in CO, CO2, N2 and CH3OH, and a predominantly frozen (or less abundant), polar phase containing more H2O, CH4, H2CO and HCN.

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Detection of Dynamical Instability in Titan's Thermospheric Jet

Similar to Earth, Saturn's largest moon, Titan, possesses a system of high-altitude zonal winds (or jets) that encircle the globe. Using the Atacama Large Millimeter/submillimeter Array (ALMA) in August 2016, Lellouch et al. (2019) discovered an equatorial jet at much higher altitudes than previously known, with a surprisingly fast speed of up to ~340 m/s, but the origin of such high velocities is not yet understood. We obtained spectrally and spatially resolved ALMA observations in May 2017 to map Titan's 3D global wind field and compare our results with a reanalysis of the August 2016 data. Doppler wind velocity maps were derived in the altitude range ~300-1000 km (from the upper stratosphere to the thermosphere). At the highest, thermospheric altitudes, a 47% reduction in the equatorial zonal wind speed was measured over the 9-month period (corresponding to L_s = 82-90 degrees on Titan). This is interpreted as due to a dramatic slowing and loss of confinement (broadening) of the recently-discovered thermospheric equatorial jet, as a result of dynamical instability. These unexpectedly-rapid changes in the upper-atmospheric dynamics are consistent with strong variability of the jet's primary driving mechanism.

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Detection of CH$_3$C$_3$N in Titan's Atmosphere

Titan harbors a dense, organic-rich atmosphere primarily composed of N$_2$ and CH$_4$, with lesser amounts of hydrocarbons and nitrogen-bearing species. As a result of high sensitivity observations by the Atacama Large Millimeter/submillimeter Array (ALMA) in Band 6 ($\sim$230-272 GHz), we obtained the first spectroscopic detection of CH$_3$C$_3$N (methylcyanoacetylene or cyanopropyne) in Titan's atmosphere through the observation of seven transitions in the $J = 64\rightarrow63$ and $J = 62\rightarrow61$ rotational bands. The presence of CH$_3$C$_3$N on Titan was suggested by the Cassini Ion and Neutral Mass Spectrometer detection of its protonated form: C$_4$H$_3$NH$^+$, but the atmospheric abundance of the associated (deprotonated) neutral product is not well constrained due to the lack of appropriate laboratory reaction data. Here, we derive the column density of CH$_3$C$_3$N to be (3.8-5.7)$\times10^{12}$ cm$^{-2}$ based on radiative transfer models sensitive to altitudes above 400 km Titan's middle atmosphere. When compared with laboratory and photochemical model results, the detection of methylcyanoacetylene provides important constraints for the determination of the associated production pathways (such as those involving CN, CCN, and hydrocarbons), and reaction rate coefficients. These results also further demonstrate the importance of ALMA and (sub)millimeter spectroscopy for future investigations of Titan's organic inventory and atmospheric chemistry, as CH$_3$C$_3$N marks the heaviest polar molecule detected spectroscopically in Titan's atmosphere to date.

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Unusually High CO Abundance of the First Active Interstellar Comet

Comets spend most of their lives at large distances from any star, during which time their interior compositions remain relatively unaltered. Cometary observations can therefore provide direct insight into the chemistry that occurred during their birth at the time of planet formation. To-date, there have been no confirmed observations of parent volatiles (gases released directly from the nucleus) of a comet from any planetary system other than our own. Here we present high-resolution, interferometric observations of 2I/Borisov, the first confirmed interstellar comet, obtained using the Atacama Large Millimeter/submillimeter Array (ALMA) on 15th-16th December 2019. Our observations reveal emission from hydrogen cyanide (HCN), and carbon monoxide (CO), coincident with the expected position of 2I/Borisov's nucleus, with production rates Q(HCN)=$(7.0\pm1.1)\times10^{23}$ s$^{-1}$ and Q(CO)=$(4.4\pm0.7)\times10^{26}$ s$^{-1}$. While the HCN abundance relative to water (0.06-0.16%) appears similar to that of typical, previously observed comets in our Solar System, the abundance of CO (35-105%) is among the highest observed in any comet within 2 au of the Sun. This shows that 2I/Borisov must have formed in a relatively CO-rich environment - probably beyond the CO ice-line in the very cold, outer regions of a distant protoplanetary accretion disk, as part of a population of small, icy bodies analogous to our Solar System's own proto-Kuiper Belt.

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