arXiv subjects
Publications and source records attributed to M. Arndt.
This article is a collection of contributions from speakers at the 2025 DEAMN [Dynamics of Electrons in Atomic and Molecular Nanoclusters] workshop at the Majorana Centre in Erice. Not ordinary contributions to a conference proceeding, this gives a new and different perspective on the work done by the workshop participants.
The analysis of proteins in the gas phase benefits from detectors that exhibit high efficiency and precise spatial resolution. Although modern secondary electron multipliers already address numerous analytical requirements, new methods are desired for macromolecules at low energy. Previous studies have proven the sensitivity of superconducting detectors to high-energy particles in time-of-flight mass spectrometry. Here we explore a new energy regime and demonstrate that superconducting nanowire detectors are exceptionally well suited for quadrupole mass spectrometry. Our detectors exhibit an outstanding quantum yield at remarkably low impact energies. Notably, at low ion energy, their sensitivity surpasses conventional ion detectors by three orders of magnitude, and they offer the possibility to discriminate molecules by their impact energy and charge. By combining these detectors into arrays, we demonstrate low-energy ion beam profilometry, while our cryogenic electronics pave the way for future developments of highly integrated detectors.
The maximal speed $v^\ast$ for magnetic flux quanta is determined by the energy relaxation of unpaired electrons and is thus essential for superconducting microstrip single-photon detectors (SMSPDs). However, the deduction of $v^\ast$ from the current-voltage ($I$-$V$) curves at zero magnetic field is hindered by the unknown number of vortices, $n_\mathrm{v}$, as a small number of fast-moving vortices can induce the same voltage as a large number of slow-moving ones. Here, we introduce an approach for the quantitative determination of $n_\mathrm{v}$ and $v^\ast$. The idea is based on the Aslamazov and Larkin prediction of kinks in the $I$-$V$ curves of wide and short superconducting constrictions when the number of fluxons crossing the constriction is increased by one. We realize such conditions in wide MoSi thin strips with slits milled by a focused ion beam and reveal quantum effects in a macroscopic system. By observing kinks in the $I$-$V$ curves with increase of the transport current, we evidence a crossover from a single- to multi-fluxon dynamics and deduce $v^\ast\simeq12\,$km/s. Our experimental observations are augmented with numerical modeling results which reveal a transition from a vortex chain over a vortex jet to a vortex river with increase of $n_\mathrm{v}$ and the vortex velocity. Our findings are essential for the development of 1D and 2D few-fluxon devices and provide a demanded approach for the deduction of $v^\ast$ at the SMSPD operation conditions.
Grain boundary wetting as a preliminary stage for zinc induced grain boundary weakening and embrittlement in a Zn coated press hardened 20MnB8 steel was analyzed by means of electron backscatter diffraction, Auger electron spectroscopy, energy dispersive X-ray analysis, atom probe tomography and transmission electron microscopy on the nanometer scale. Microcracks at prior austenite grain boundaries were observed and structures that developed after microcrack formation were identified. Zn/Fe intermetallic phases with grain sizes smaller than 100 nm in diameter are present at the crack surfaces and at the wedge-shaped crack tips. In order to get a complete picture, including the microstructure before cracking, an undeformed, electrolytically coated reference sample which underwent the same heat treatment as the press hardened material was investigated. Here, Zn, in the order of one atomic layer or less, could be found along prior austenite grain boundaries several micrometers away from the actual Zn/Fe phases in the coating. Such a grain boundary weakening by Zn wetting of prior austenitic grain boundaries during austenitization and/or hot forming is a necessary condition for microcrack formation.
Optical resonators are increasingly important tools in science and technology. Their applications range from laser physics, atomic clocks, molecular spectroscopy, and single-photon generation to the detection, trapping and cooling of atoms or nano-scale objects. Many of these applications benefit from strong mode confinement and high optical quality factors, making small mirrors of high surface-quality desirable. Building such devices in silicon yields ultra-low absorption at telecom wavelengths and enables integration of micro-structures with mechanical, electrical and other functionalities. Here, we push optical resonator technology to new limits by fabricating lithographically aligned silicon mirrors with ultra-smooth surfaces, small and wellcontrolled radii of curvature, ultra-low loss and high reflectivity. We build large arrays of microcavities with finesse greater than F = 500,000 and a mode volume of 330 femtoliters at wavelengths near 1550 nm. Such high-quality micro-mirrors open up a new regime of optics and enable unprecedented explorations of strong coupling between light and matter.
To improve both scalability and noise-filtering capability of a Transition-Edge Sensor (TES), a new concept of a thin-film detector is suggested, which is based on embedding a microbridge TES into a high-Q planar GHz range resonator weakly coupled to a 50 Ohm-readout transmission line. Such a TES element is designed as a hot-electron microbolometer coupled to a THz range antenna and as a load of the resonator at the same time. A weak THz signal coupled to the antenna heats the microbridge TES, thus reducing the quality factor of the resonator and leading to a power increment in the readout line. The power-to-power conversion gain, an essential figure of merit, is estimated to be above 10. To demonstrate the basic concept, we fabricated and tested a few submicron sized devices from Nb thin films for operation temperature about 5 K. The dc and rf characterization of the new device is made at a resonator frequency about 5.8 GHz. A low-noise HEMT amplifier is used in our TES experiments without the need for a SQUID readout. The optical sensitivity to blackbody radiation within the frequency band 600-700 GHz is measured as $\sim3\times 10^{-14} \textrm W/\sqrt{\textrm Hz}$ at Tc {\approx} 5 K at bath temperature ~ 1.5 K.
We propose a new detection technique based on radio-frequency (RF) bias and readout of an antenna-coupled superconducting nanobolometer. This approach is suitable for Frequency-Division-Multiplexing (FDM) readout of large arrays using broadband low-noise RF amplifier. We call this new detector RFTES. This feasibility study was made on demonstrator devices which are made in all-Nb technology and operate at 4.2 K. The studied RFTES devices consist of an antenna-coupled superconducting nanobolometer made of ultrathin niobium films with transition temperature Tc = 5.2 K. The 0.65-THz antenna and nanobolometer are embedded as a load into a GHz-range coplanar niobium resonator (Tc = 8.9 K, Q = 4000). To heat the superconducting Nb nanobolometer close to the Tc, the RF power at resonator frequency f = 5.8 GHz is applied via a transmission line which is weakly coupled (-11 dB) to the loaded resonator. The THz-antenna of RFTES was placed in the focus of a sapphire immersion lens inside a He4-cryostat equipped with an optical window and a semiconductor RF amplifier. We have demonstrated optical response of the RFTES to THz radiation. The demonstrator receiver system employing the RFTES device showed an optical Noise-Equivalent Power (NEP) 1e-14 W/sqrt(Hz) at 4.2 K.
Alloying Ti-Al-N coatings with Ta has proven to enhance their hardness, thermal stability, and oxidation resistance. However, especially for arc-evaporated Ti-Al-Ta-N coatings only limited information on the detailed influence of the elements on various properties is available. Therefore, we have developed arc-evaporated Ti1-x-yAlxTayN coatings with various Al (x = 0.50 - 0.65) and Ta (y = 0.00 - 0.15) contents. While the thermal stability of our coatings during annealing in inert He atmosphere increases with increasing Ta content, best results are obtained for specific Ta-Al ratios during oxidation. Single phase cubic Ti0.32Al0.60Ta0.08N yields a mass-gain of only ~5 % after 5 h at 950 °C in synthetic air, whereas Ti0.35Al0.65N is completely oxidized after 15 min. This is in part based on the suppressed anatase and direct rutile TiO2 formation at a defined Ta-Al content. Consequently, the anatase-to-rutile transformation, generally observed for Ti1-xAlxN, is absent. This reduces the generation of pores and cracks within the oxide scale and especially at the nitride-oxide interface, leading to the formation of a protective rutile and corundum based oxide scale. This is also reflected in the pronounced decrease in activation energy for the protective scale formation from 232 kJ/mol for Ti0.35Al0.65N down to 14.5 kJ/mol for Ti0.32Al0.60Ta0.08N. Based on our results we can conclude that especially phase transformations within the oxide scale need to be suppressed, as the connected volume changes lead to the formation of cracks and pores.
The generation of organic particle beams is studied in combination with photoionization using uv radiation at 266 nm and vuv light at 157 nm. Single-photon ionization with pulsed vuv light turns out to be sensitive enough to detect various large neutral biomolecular complexes ranging from metal-amino acid complexes to nucleotide clusters and aggregates of polypeptides. Different biomolecular clusters are shown to exhibit rather specific binding characteristics with regard to the various metals that are co-desorbed in the source. We also find that the ion signal of gramicidin can be increased by a factor of fifteen when the photon energy is increased from 4.66 eV to 7.9 eV.
We present a proof-of-principle study of superconducting single photon detectors (SSPD) for the detection of individual neutral molecules/nanoparticles at low energies. The new detector is applied to characterize a laser desorption source for biomolecules and it allows to retrieve the arrival time distribution of a pulsed molecular beam containing the amino acid tryptophan, the polypeptide gramicidin as well as insulin, myoglobin and hemoglobin. We discuss the experimental evidence that the detector is actually sensitive to isolated neutral particles.
We report on the characterization of a superconducting nanowire detector for ions at low kinetic energies. We measure the absolute single particle detection efficiency $η$ and trace its increase with energy up to $η= 100$ %. We discuss the influence of noble gas adsorbates on the cryogenic surface and analyze their relevance for the detection of slow massive particles. We apply a recent model for the hot spot formation to the incidence of atomic ions at energies between 0.2-1 keV. We suggest how the differences observed for photons and atoms or molecules can be related to the surface condition of the detector and we propose that the restoration of proper surface conditions may open a new avenue to SSPD-based optical spectroscopy on molecules and nanoparticles.
Second Generation advanced high strength steel is the material of choice for modern automotive structural parts because of its outstanding maximal elongation and tensile strength. Nonetheless there is still a lack of corrosion protection for this material due to the fact that cost efficient hot dip galvanizing can not be applied. The reason for the insufficient coatability with zinc is found in the segregation of manganese to the surface during annealing and the formation of manganese oxides prior coating. This work analyses the structure and chemical composition of the surface oxides on so called nano-TWIP (twinning induced plasticity) steel on the nanoscopic scale after hot dip galvanizing in a simulator with employed analytical methods comprising scanning Auger electron spectroscopy (SAES), energy dispersive x-ray spectroscopy (EDX), and focused ion beam (FIB) for cross section preparation. By the combination of these methods it was possible to obtain detailed chemical images serving a better understanding which processes exactly occur on the surface of this novel kind of steel and how to promote in the future for this material system galvanic protection.
This is a collection of statements gathered on the occasion of the Quantum Physics of Nature meeting in Vienna.
We discuss matter wave experiments in a near-field interferometer and focus on dephasing phenomena due to inertial forces. Their presence may result in a significant reduction of the observed interference contrast, even though they do not lead to genuine decoherence. We provide quantitative estimates for the most important effects and demonstrate experimentally the strong influence of acoustic vibrations. Since the effects of inertial forces get increasingly important for the interferometry with more massive particles they have to be identified and compensated in future experiments.
We demonstrate a near-field Talbot-Lau interferometer for C-70 fullerene molecules. Such interferometers are particularly suitable for larger masses. Using three free-standing gold gratings of one micrometer period and a transversally incoherent but velocity-selected molecular beam, we achieve an interference fringe visibility of 40 % with high count rate. Both the high visibility and its velocity dependence are in good agreement with a quantum simulation that takes into account the van der Waals interaction of the molecules with the gratings and are in striking contrast to a classical moire model.