arXiv subjects

M. Carvajal

Publications and source records attributed to M. Carvajal.

5 recordsLinked to original sources

arXiv2024

Degeneracy in excited-state quantum phase transitions of two-level bosonic models and its influence on system dynamics

Excited-state quantum phase transitions (ESQPTs) strongly influence the spectral properties of collective many-body quantum systems, changing degeneracy patterns in different quantum phases. Level degeneracies, in turn, affect the system's dynamics. We analyze the degeneracy dependence on the size of two-level boson models with a $u(n+1)$ dynamical algebra, where $n$ is the number of collective degrees of freedom. Below the ESQPT critical energy of these models, the energy gap between neighboring levels that belong to different symmetry sectors gets close to zero as the system size increases. We report and explain why this gap goes to zero exponentially for systems with one collective degree of freedom, but algebraically in models with more than one degree of freedom. As a consequence, we show that the infinite-time average of out-of-time-order correlators is an ESQPT order parameter in finite systems with $n=1$, but in systems with $n>1$, this average only works as an order parameter in the mean-field limit.

quant-ph↗

arXiv2021

Quantum fidelity susceptibility in excited state quantum phase transitions: application to the bending spectra of nonrigid molecules

We characterize excited state quantum phase transitions in the two dimensional limit of the vibron model with the quantum fidelity susceptibility, comparing the obtained results with the information provided by the participation ratio. As an application, we perform fits using a four-body algebraic Hamiltonian to bending vibrational data for several molecular species and, using the optimized eigenvalues and eigenstates, we locate the eigenstate closest to the barrier to linearity and determine the linear or bent character of the different overtones.

quant-ph↗

arXiv2019

Ab initio spectroscopic characterization of the radical CH$_3$OCH$_2$ at low temperatures

Spectroscopic and structural properties of methoxymethyl radical (CH$_3$OCH$_2$, RDME) are determined using explicitly correlated ab initio methods. This radical of astrophysical and atmospheric relevance has not been fully characterized at low temperatures, which has delayed the astrophysical searches. We provide rovibrational parameters, excitations to the low energy electronic states, torsional and inversion barriers and low vibrational energy levels. In the electronic ground state (X$^2$A), which appears "clean" from non-adiabatic effects, the minimum energy structure is an asymmetric geometry which rotational constants and dipole moment have been determined to be A$_0$=46718.6745 MHz, B$_0$=10748.4182 MHz, and C$_0$=9272.5105 MHz, and 1.432 D ($μ_A$=0.6952 D, $μ_B$=1.215 D, $μ_C$=0.3016 D), respectively. A variational procedure has been applied to determine torsion-inversion energy levels. Each level splits into 3 subcomponents (A$_1$/A$_2$ and E) corresponding to the three methyl torsion minima. Although the potential energy surface presents 12 minima, at low temperatures, the infrared band shapes correspond to a surface with only three minima because the top of the inversion V$^α$ barrier at $α=0^{\circ}$ (109 cm$^{-1}$) stands below the zero point vibrational energy and the CH$_2$ torsional barrier is relatively high ($\sim$2000 cm$^{-1}$). The methyl torsion barrier was computed to be $\sim$500 cm$^{-1}$ and produces a splitting of 0.01 cm$^{-1}$ of the ground vibrational state.

physics.chem-ph↗

arXiv2007

Science with the new generation high energy gamma- ray experiments

This Conference is the fifth of a series of Workshops on High Energy Gamma- ray Experiments, following the Conferences held in Perugia 2003, Bari 2004, Cividale del Friuli 2005, Elba Island 2006. This year the focus was on the use of gamma-ray to study the Dark Matter component of the Universe, the origin and propagation of Cosmic Rays, Extra Large Spatial Dimensions and Tests of Lorentz Invariance.

astro-ph↗

arXiv2007

GAW - An Imaging Atmospheric Cherenkov Telescope with Large Field of View

GAW, acronym for Gamma Air Watch, is a Research and Development experiment in the TeV range, whose main goal is to explore the feasibility of large field of view Imaging Atmospheric Cherenkov Telescopes. GAW is an array of three relatively small telescopes (2.13 m diameter) which differs from the existing and presently planned projects in two main features: the adoption of a refractive optics system as light collector and the use of single photoelectron counting as detector working mode. The optics system allows to achieve a large field of view (24x24 squared degrees) suitable for surveys of large sky regions. The single photoelectron counting mode in comparison with the charge integration mode improves the sensitivity by permitting also the reconstruction of events with a small number of collected Cherenkov photons. GAW, which is a collaboration effort of Research Institutes in Italy, Portugal and Spain, will be erected in the Calar Alto Observatory (Sierra de Los Filabres - Andalucia, Spain), at 2150 m a.s.l.). The first telescope will be settled within Autumn 2007. This paper shows the main characteristics of the experiment and its expected performance.

astro-ph↗