arXiv subjects

M. De Luca

Publications and source records attributed to M. De Luca.

At least 19 recordsLinked to original sources

arXiv2019

Dense cores and star formation in the giant molecular cloud Vela~C

Context The Vela Molecular Ridge is one of the nearest (700 pc) giant molecular cloud (GMC) complexes hosting intermediate-mass (up to early B, late O stars) star formation, and is located in the outer Galaxy, inside the Galactic plane. Vela C is one of the GMCs making up the Vela Molecular Ridge, and exhibits both sub-regions of robust and sub-regions of more quiescent star formation activity, with both low- and intermediate(high)-mass star formation in progress. Aims We aim to study the individual and global properties of dense dust cores in Vela C, and aim to search for spatial variations in these properties which could be related to different environmental properties and/or evolutionary stages in the various sub-regions of Vela C. Methods We mapped the submillimetre (345 GHz) emission from vela C with LABOCA (beam size 19.2", spatial resolution ~0.07 pc at 700 pc) at the APEX telescope. We used the clump-finding algorithm CuTEx to identify the compact submillimetre sources. We also used SIMBA (250 GHz) observations, and Herschel and WISE ancillary data. The association with WISE red sources allowed the protostellar and starless cores to be separated, whereas the Herschel dataset allowed the dust temperature to be derived for a fraction of cores. The protostellar and starless core mass functions (CMFs) were constructed following two different approaches, achieving a mass completeness limit of 3.7 Msun. Results We retrieved 549 submillimetre cores, 316 of which are starless and mostly gravitationally bound (therefore prestellar in nature). Both the protostellar and the starless CMFs are consistent with the shape of a Salpeter initial mass function in the high-mass part of the distribution. Clustering of cores at scales of 1--6 pc is also found, hinting at fractionation of magnetised, turbulent gas.

astro-ph.SR↗

arXiv2018

Unusual spin properties of InP wurtzite nanowires revealed by Zeeman splitting spectroscopy

In this study, we present a complete experimental and theoretical investigation of the fundamental exciton Zeeman splitting in wurtzite InP nanowires. We determined the exciton gyromagnetic factor, $g_{exc}$, by magneto-photoluminescence spectroscopy using magnetic fields up to 29 T. We found that $g_{exc}$ is strongly anisotropic with values differing in excess of 50\% between the magnetic field oriented parallel and perpendicular to the nanowire long axis. Furthermore, for magnetic fields oriented along the nanowire axis, $g_{exc}$ is nearly three times larger than in bulk zincblende InP and it shows a marked sublinear dependence on the magnetic field, a common feature to other non-nitride III-V wurtzite nanowires but not properly understood. Remarkably, this nonlinearity originates from only one Zeeman branch characterized by a specific type of light polarization. All the experimental findings are modeled theoretically by a robust approach combining the $k \cdot p$ method with the envelope function approximation and including the electron-hole interaction. We revealed that the nonlinear features arise due to the coupling between Landau levels pertaining to the A (heavy-hole like) and B (light-hole like) valence bands of the wurtzite crystal structure. This general behavior is particularly relevant for the understanding of the spin properties of several wurtzite nanowires that host the set for the observation of topological phases potentially at the base of quantum computing platforms.

cond-mat.mes-hall↗

arXiv2014

Widespread Rotationally-Hot Hydronium Ion in the Galactic Interstellar Medium

We present new observations of the (6,6) and (9,9) inversion transitions of the hydronium ion toward Sagittarius B2(N) and W31C. Sensitive observations toward Sagittarius B2(N) show that the high, ~ 500 K, rotational temperatures characterizing the population of the highly-excited metastable H3O+ rotational levels are present over a wide range of velocities corresponding to the Sagittarius B2 envelope, as well as the foreground gas clouds between the Sun and the source. Observations of the same lines toward W31C, a line of sight that does not intersect the Central Molecular Zone, but instead traces quiescent gas in the Galactic disk, also imply a high rotational temperature of ~ 380 K, well in excess of the kinetic temperature of the diffuse Galactic interstellar medium. While it is plausible that some fraction of the molecular gas may be heated to such high temperatures in the active environment of the Galactic center, characterized by high X-ray and cosmic ray fluxes, shocks and high degree of turbulence, this is unlikely in the largely quiescent environment of the Galactic disk clouds. We suggest instead that the highly-excited states of the hydronium ion are populated mainly by exoergic chemical formation processes and temperature describing the rotational level population does not represent the physical temperature of the medium. The same arguments may be applicable to other symmetric top rotors, such as ammonia. This offers a simple explanation to the long-standing puzzle of the presence of a pervasive, hot molecular gas component in the central region of the Milky Way. Moreover, our observations suggest that this is a universal process, not limited to the active environments associated with galactic nuclei.

astro-ph.GA↗

arXiv2013

Far-Infrared Spectroscopy of the Galactic Center. Hot Molecular Gas: Shocks versus Radiation near SgrA*

We present a 52-671um spectral scan toward SgrA* taken with the PACS and SPIRE spectrometers onboard Herschel. The achieved angular resolution allows us to separate, for the first time at far-IR wavelengths, the emission toward the central cavity (gas in the inner central parsec of the galaxy) from that of the surrounding circum-nuclear disk. The spectrum toward SgrA* is dominated by strong [OIII], [OI], [CII], [NIII], [NII], and [CI] fine structure lines (in decreasing order of luminosity) arising in gas irradiated by UV-photons from the central stellar cluster. In addition, rotationally excited lines of 12CO (from J=4-3 to 24-23), 13CO, H2O, OH, H3O+, HCO+ and HCN, as well as ground-state absorption lines of OH+, H2O+, H3O+, CH+, H2O, OH, HF, CH and NH are detected. The excitation of the 12CO ladder is consistent with a hot isothermal component at Tk ~ 10^{3.1} K and n(H2)< 10^4 cm^{-3}. It is also consistent with a distribution of temperature components at higher density with most CO at Tk<300 K. The detected molecular features suggest that, at present, neither very enhanced X-ray, nor cosmic-ray fluxes play a dominant role in the heating of the hot molecular gas. The hot CO component (either the bulk of the CO column or just a small fraction depending on the above scenario) results from a combination of UV- and shock-driven heating. If irradiated dense clumps/clouds do not exist, shocks likely dominate the heating of the hot molecular gas. This is consistent with the high-velocity gas detected toward SgrA*.

astro-ph.GA↗

arXiv2013

Hydrogen chloride in diffuse interstellar clouds along the line of sight to W31C (G10.6-0.4)

We report the detection of hydrogen chloride, HCl, in diffuse molecular clouds on the line of sight towards the star-forming region W31C (G10.6-0.4). The J = 1-0 lines of the two stable HCl isotopologues, H35Cl and H37Cl, are observed using the 1b receiver of the Heterodyne Instrument for the Far-Infrared (HIFI) aboard the Herschel Space Observatory. The HCl line is detected in absorption, over a wide range of velocities associated with diffuse clouds along the line of sight to W31C. The analysis of the absorption strength yields a total HCl column density of few 10^13 cm^-2, implying that HCl accounts for ~0.6 % of the total gasphase chlorine, which exceeds by a factor of ~6 the theoretical model predictions. This result is comparable to those obtained from the chemically-related species H2Cl+ and HCl+, for which large column densities have also been reported on the same line of sight. The source of discrepancy between models and observations is still unknown; however, the detection of these Cl-bearing molecules, provides key constraints for the chlorine chemistry in the diffuse gas.

astro-ph.GA↗

arXiv2013

Spitzer-IRAC survey of molecular jets in Vela-D

We present a survey of H2 jets from young protostars in the Vela-D molecular cloud (VMR-D), based on Spitzer -IRAC data between 3.6 and 8.0 micron. Our search has led to the identification of 15 jets and about 70 well aligned knots within 1.2 squared degree. We compare the IRAC maps with observations of the H2 1-0 S(1) line at 2.12 micron, with a Spitzer-MIPS map at 24 and 70 micron, and with a map of the dust continuum emission at 1.2 mm. We find a association between molecular jets and dust peaks. The jet candidate exciting sources have been searched for in the published catalog of the Young Stellar Objects of VMR-D. We selected all the sources of Class II or earlier which are located close to the jet center and aligned with it.The association between jet and exciting source was validated by estimating the differential extinction between the jet opposite lobes. We are able to find a best-candidate exciting source in all but two jets. Four exciting sources are not (or very barely) observed at wavelengths shorter than 24 micron, suggesting they are very young protostars. Three of them are also associated with the most compact jets. The exciting source Spectral Energy Distributions have been modeled by means of the photometric data between 1.2 micron and 1.2 mm. From SEDs fits we derive the main source parameters, which indicate that most of them are low-mass protostars. A significant correlation is found between the projected jet length and the [24] - [70] color, which is consistent with an evolutionary scenario according to which shorter jets are associated with younger sources. A rough correlation is found between IRAC line cooling and exciting source bolometric luminosity, in agreement with the previous literature. The emerging trend suggests that mass loss and mass accretion are tightly related phenomena and that both decrease with time.

astro-ph.GA↗

arXiv2012

Water absorption in Galactic translucent clouds: conditions and history of the gas derived from Herschel/HIFI PRISMAS observations

We present Herschel/HIFI observations of nine transitions of \hho and \hheo towards six high-mass star-forming regions, obtained as part of the PRISMAS Key Program. Water vapor in translucent clouds is detected in absorption along every sightline. We derive the column density of \hho or \hheo for the lower energy level of each transition observed. The total water column density is about a few $10^{13} \rm{cm^{-2}}$. We find that the abundance of water relative to hydrogen nuclei is $1\times10^{-8}$ in agreement with models for oxygen chemistry with high cosmic ray ionization rates. Relative to \hh, the abundance of water is remarkably constant at $5\times10^{-8}$. The abundance of water in excited levels is at most 15%, implying that the excitation temperature $T_{ex}$ in the ground state transitions is below 10 K. The column densities derived from the two ortho ground state transitions indicates that $T_{ex}\simeq5$ K and that the density $n($\hh$)$ in the clouds is $\le10^4 \rm{cm^{-3}}$. For most clouds we derive a water ortho-to-para ratio consistent with the value of 3 expected in thermodynamic equilibrium in the high temperature limit. Two clouds with large column densities exhibit a ratio significantly below 3. This may argue that the history of water molecules includes a cold phase, either when the molecules were formed on cold grains, or when they later become at least partially thermalized with the cold gas ($\sim25$ K) in the shielded, low temperature regions of the clouds; evidently, they have not yet fully thermalized with the warmer ($\sim50$ K) translucent portions of the clouds.

astro-ph.GA↗

arXiv2012

Nitrogen hydrides in interstellar gas II. Analysis of Herschel/HIFI observations towards W49N and G10.6-0.4 (W31C)

We have used the Herschel-HIFI instrument to observe interstellar nitrogen hydrides along the sight-lines towards W49N and G10.6-0.4 in order to elucidate the production pathways leading to nitrogen-bearing species in diffuse gas. All detections show absorption by foreground material over a wide range of velocities, as well as absorption associated directly with the hot-core source itself. As in the previously published observations towards G10.6-0.4, the NH, NH2 and NH3 spectra towards W49N show strikingly similar and non-saturated absorption features. We decompose the absorption of the foreground material towards W49N into different velocity components in order to investigate whether the relative abundances vary among the velocity components, and, in addition, we re-analyse the absorption lines towards G10.6-0.4 in the same manner. Abundances, with respect to molecular hydrogen, in each velocity component are estimated using CH. The analysis points to a co-existence of the nitrogen hydrides in diffuse or translucent interstellar gas with a high molecular fraction. Towards both sources, we find that NH is always at least as abundant as both o-NH2 and o-NH3, in sharp contrast to previous results for dark clouds. We find relatively constant N(NH)/N(o-NH3) and N(o-NH2)/N(o-NH3) ratios with mean values of 3.2 and 1.9 towards W49N, and 5.4 and 2.2 towards G10.6-0.4, respectively. The mean abundance of o-NH3 is ~2x10^-9 towards both sources. The nitrogen hydrides also show linear correlations with CN and HNC towards both sources, and looser correlations with CH. The upper limits on the NH+ abundance indicate column densities < 2 - 14 % of N(NH). Surprisingly low values of the ammonia ortho-to-para ratio are found in both sources, ~0.5 - 0.7 +- 0.1. This result cannot be explained by current models as we had expected to find a value of unity or higher.

astro-ph.GA↗

arXiv2012

The chemistry of C3 & Carbon Chain Molecules in DR21(OH)

(Abridged) We have observed velocity resolved spectra of four ro-vibrational far-infrared transitions of C3 between the vibrational ground state and the low-energy nu2 bending mode at frequencies between 1654--1897 GHz using HIFI on board Herschel, in DR21(OH), a high mass star forming region. Several transitions of CCH and c-C3H2 have also been observed with HIFI and the IRAM 30m telescope. A gas and grain warm-up model was used to identify the primary C3 forming reactions in DR21(OH). We have detected C3 in absorption in four far-infrared transitions, P(4), P(10), Q(2) and Q(4). The continuum sources MM1 and MM2 in DR21(OH) though spatially unresolved, are sufficiently separated in velocity to be identified in the C3 spectra. All C3 transitions are detected from the embedded source MM2 and the surrounding envelope, whereas only Q(4) & P(4) are detected toward the hot core MM1. The abundance of C3 in the envelope and MM2 is \sim6x10^{-10} and \sim3x10^{-9} respectively. For CCH and c-C3H2 we only detect emission from the envelope and MM1. The observed CCH, C3, and c-C3H2 abundances are most consistent with a chemical model with n(H2)\sim5x10^{6} cm^-3 post-warm-up dust temperature, T_max =30 K and a time of \sim0.7-3 Myr. Post warm-up gas phase chemistry of CH4 released from the grain at t\sim 0.2 Myr and lasting for 1 Myr can explain the observed C3 abundance in the envelope of DR21(OH) and no mechanism involving photodestruction of PAH molecules is required. The chemistry in the envelope is similar to the warm carbon chain chemistry (WCCC) found in lukewarm corinos. The observed lower C3 abundance in MM1 as compared to MM2 and the envelope could be indicative of destruction of C3 in the more evolved MM1. The timescale for the chemistry derived for the envelope is consistent with the dynamical timescale of 2 Myr derived for DR21(OH) in other studies.

astro-ph.GA↗

arXiv2012

Comparative study of CH+ and SH+ absorption lines observed towards distant star-forming regions

Aims. The HIFI instrument onboard Herschel has allowed high spectral resolution and sensitive observations of ground-state transi- tions of three molecular ions: the methylidyne cation CH+, its isotopologue 13CH+, and sulfanylium SH+. Because of their unique chemical properties, a comparative analysis of these cations provides essential clues to the link between the chemistry and dynamics of the diffuse interstellar medium. Methods. The CH+, 13CH+, and SH+ lines are observed in absorption towards the distant high-mass star-forming regions (SFRs) DR21(OH), G34.3+0.1, W31C, W33A, W49N, and W51, and towards two sources close to the Galactic centre, SgrB2(N) and SgrA*+50. All sight lines sample the diffuse interstellar matter along pathlengths of several kiloparsecs across the Galactic Plane. In order to compare the velocity structure of each species, the observed line profiles were deconvolved from the hyperfine structure of the SH+ transition and the CH+, 13CH+, and SH+ spectra were independently decomposed into Gaussian velocity components. To analyse the chemical composition of the foreground gas, all spectra were divided, in a second step, into velocity intervals over which the CH+, 13CH+, and SH+ column densities and abundances were derived. Results. SH+ is detected along all observed lines of sight, with a velocity structure close to that of CH+ and 13CH+. The linewidth distributions of the CH+, SH+, and 13CH+ Gaussian components are found to be similar. These distributions have the same mean (<δ\u{psion}> ~ 4.2 km s-1) and standard deviation (σ(δ\u{psion}) ~ 1.5 km s-1). This mean value is also close to that of the linewidth distribution of the CH+ visible transitions detected in the solar neighbourhood. We show that the lack of absorption components narrower than 2 km s-1 is not an artefact caused by noise: the CH+, 13CH+, and SH+ line profiles are therefore statistically broader than those of most species detected in absorption in diffuse interstellar gas (e. g. HCO+, CH, or CN). The SH+/CH+ column density ratio observed in the components located away from the Galactic centre spans two orders of magnitude and correlates with the CH+ abundance. Conversely, the ratio observed in the components close to the Galactic centre varies over less than one order of magnitude with no apparent correlation with the CH+ abundance. The observed dynamical and chemical properties of SH+ and CH+ are proposed to trace the ubiquitous process of turbulent dissipation, in shocks or shears, in the diffuse ISM and the specific environment of the Galactic centre regions.

astro-ph.GA↗

arXiv2010

Nitrogen hydrides in interstellar gas: Herschel/HIFI observations towards G10.6-0.4 (W31C)

The HIFI instrument on board the Herschel Space Observatory has been used to observe interstellar nitrogen hydrides along the sight-line towards G10.6-0.4 in order to improve our understanding of the interstellar chemistry of nitrogen. We report observations of absorption in NH N=1-0, J=2-1 and ortho-NH2 1_1,1-0_0,0. We also observed ortho-NH3 1_0-0_0, and 2_0-1_0, para-NH3 2_1-1_1, and searched unsuccessfully for NH+. All detections show emission and absorption associated directly with the hot-core source itself as well as absorption by foreground material over a wide range of velocities. All spectra show similar, non-saturated, absorption features, which we attribute to diffuse molecular gas. Total column densities over the velocity range 11-54 km/s are estimated. The similar profiles suggest fairly uniform abundances relative to hydrogen, approximately 6*10^-9, 3*10^-9, and 3*10^-9 for NH, NH2, and NH3, respectively. These abundances are discussed with reference to models of gas-phase and surface chemistry.

astro-ph.GA↗

arXiv2010

Detection of hydrogen fluoride absorption in diffuse molecular clouds with Herschel/HIFI: a ubiquitous tracer of molecular gas

We discuss the detection of absorption by interstellar hydrogen fluoride (HF) along the sight line to the submillimeter continuum sources W49N and W51. We have used Herschel's HIFI instrument in dual beam switch mode to observe the 1232.4762 GHz J = 1 - 0 HF transition in the upper sideband of the band 5a receiver. We detected foreground absorption by HF toward both sources over a wide range of velocities. Optically thin absorption components were detected on both sight lines, allowing us to measure - as opposed to obtain a lower limit on - the column density of HF for the first time. As in previous observations of HF toward the source G10.6-0.4, the derived HF column density is typically comparable to that of water vapor, even though the elemental abundance of oxygen is greater than that of fluorine by four orders of magnitude. We used the rather uncertain N(CH)-N(H2) relationship derived previously toward diffuse molecular clouds to infer the molecular hydrogen column density in the clouds exhibiting HF absorption. Within the uncertainties, we find that the abundance of HF with respect to H2 is consistent with the theoretical prediction that HF is the main reservoir of gas-phase fluorine for these clouds. Thus, hydrogen fluoride has the potential to become an excellent tracer of molecular hydrogen, and provides a sensitive probe of clouds of small H2 column density. Indeed, the observations of hydrogen fluoride reported here reveal the presence of a low column density diffuse molecular cloud along the W51 sight line, at an LSR velocity of ~ 24kms-1, that had not been identified in molecular absorption line studies prior to the launch of Herschel.

astro-ph.GA↗

arXiv2010

Herschel/HIFI measurements of the ortho/para ratio in water towards Sagittarius B2(M) and W31C

We present Herschel/HIFI observations of the fundamental rotational transitions of ortho- and para-H$_2^{16}$O and H$_2^{18}$O in absorption towards Sagittarius~B2(M) and W31C. The ortho/para ratio in water in the foreground clouds on the line of sight towards these bright continuum sources is generally consistent with the statistical high-temperature ratio of 3, within the observational uncertainties. However, somewhat unexpectedly, we derive a low ortho/para ratio of $2.35 \pm 0.35$, corresponding to a spin temperature of $\sim$27~K, towards Sagittarius~B2(M) at velocities of the expanding molecular ring. Water molecules in this region appear to have formed with, or relaxed to, an ortho/para ratio close to the value corresponding to the local temperature of the gas and dust.

astro-ph.GA↗

arXiv2010

Herschel/HIFI observations of interstellar OH+ and H2O+ towards W49N: a probe of diffuse clouds with a small molecular fraction

We report the detection of absorption by interstellar hydroxyl cations and water cations, along the sight-line to the bright continuum source W49N. We have used Herschel's HIFI instrument, in dual beam switch mode, to observe the 972 GHz N = 1 - 0 transition of OH+ and the 1115 GHz 1(11) - 0(00) transition of ortho-H2O+. The resultant spectra show absorption by ortho-H2O+, and strong absorption by OH+, in foreground material at velocities in the range 0 to 70 km/s with respect to the local standard of rest. The inferred OH+/H2O+ abundance ratio ranges from ~ 3 to ~ 15, implying that the observed OH+ arises in clouds of small molecular fraction, in the 2 - 8% range. This conclusion is confirmed by the distribution of OH+ and H2O+ in Doppler velocity space, which is similar to that of atomic hydrogen, as observed by means of 21 cm absorption measurements, and dissimilar from that typical of other molecular tracers. The observed OH+/H abundance ratio of a few E-8 suggests a cosmic ray ionization rate for atomic hydrogen of (0.6 - 2.4) E-16 s-1, in good agreement with estimates inferred previously for diffuse clouds in the Galactic disk from observations of interstellar H3+ and other species.

astro-ph.GA↗

arXiv2010

Excitation and Abundance of C3 in star forming cores:Herschel/HIFI observations of the sight-lines to W31C and W49N

We present spectrally resolved observations of triatomic carbon (C3) in several ro-vibrational transitions between the vibrational ground state and the low-energy nu2 bending mode at frequencies between 1654-1897 GHz along the sight-lines to the submillimeter continuum sources W31C and W49N, using Herschel's HIFI instrument. We detect C3 in absorption arising from the warm envelope surrounding the hot core, as indicated by the velocity peak position and shape of the line profile. The sensitivity does not allow to detect C3 absorption due to diffuse foreground clouds. From the column densities of the rotational levels in the vibrational ground state probed by the absorption we derive a rotation temperature (T_rot) of ~50--70 K, which is a good measure of the kinetic temperature of the absorbing gas, as radiative transitions within the vibrational ground state are forbidden. It is also in good agreement with the dust temperatures for W31C and W49N. Applying the partition function correction based on the derived T_rot, we get column densities N(C3) ~7-9x10^{14} cm^{-2} and abundance x(C3)~10^{-8} with respect to H2. For W31C, using a radiative transfer model including far-infrared pumping by the dust continuum and a temperature gradient within the source along the line of sight we find that a model with x(C3)=10^{-8}, T_kin=30-50 K, N(C3)=1.5 10^{15} cm^{-2} fits the observations reasonably well and provides parameters in very good agreement with the simple excitation analysis.

astro-ph.GA↗

arXiv2010

The Spitzer-IRAC Point Source Catalog of the Vela-D Cloud

This paper presents the observations of the Cloud D in the Vela Molecular Ridge, obtained with the IRAC camera onboard the Spitzer Space Telescope at the wavelengths λ= 3.6, 4.5, 5.8, 8.0 μm. A photometric catalog of point sources, covering a field of approximately 1.2 square degrees, has been extracted and complemented with additional available observational data in the millimeter region. Previous observations of the same region, obtained with the Spitzer MIPS camera in the photometric bands at 24 μm and 70 μm, have also been reconsidered to allow an estimate of the spectral slope of the sources in a wider spectral range. A total of 170,299 point sources, detected at the 5-sigma sensitivity level in at least one of the IRAC bands, have been reported in the catalog. There were 8796 sources for which good quality photometry was obtained in all four IRAC bands. For this sample, a preliminary characterization of the young stellar population based on the determination of spectral slope is discussed; combining this with diagnostics in the color-magnitude and color-color diagrams, the relative population of young stellar objects in the different evolutionary classes has been estimated and a total of 637 candidate YSOs have been selected. The main differences in their relative abundances have been highlighted and a brief account for their spatial distribution is given. The star formation rate has been also estimated and compared with the values derived for other star forming regions. Finally, an analysis of the spatial distribution of the sources by means of the two-point correlation function shows that the younger population, constituted by the Class I and flat-spectrum sources, is significantly more clustered than the Class II and III sources.

astro-ph.GA↗

arXiv2010

Interstellar OH+, H2O+ and H3O+ along the sight-line to G10.6-0.4

We report the detection of absorption lines by the reactive ions OH+, H2O+ and H3O+ along the line of sight to the submillimeter continuum source G10.6$-$0.4 (W31C). We used the Herschel HIFI instrument in dual beam switch mode to observe the ground state rotational transitions of OH+ at 971 GHz, H2O+ at 1115 and 607 GHz, and H3O+ at 984 GHz. The resultant spectra show deep absorption over a broad velocity range that originates in the interstellar matter along the line of sight to G10.6$-$0.4 as well as in the molecular gas directly associated with that source. The OH+ spectrum reaches saturation over most velocities corresponding to the foreground gas, while the opacity of the H2O+ lines remains lower than 1 in the same velocity range, and the H3O+ line shows only weak absorption. For LSR velocities between 7 and 50 kms$^{-1}$ we estimate total column densities of $N$(OH+) $> 2.5 \times 10^{14}$ cm$^{-2}$, $N$(H2O+) $\sim 6 \times 10^{13}$ cm$^{-2}$ and $N$(H3O+) $\sim 4.0 \times 10^{13}$ cm$^{-2}$. These detections confirm the role of O$^+$ and OH$^+$ in initiating the oxygen chemistry in diffuse molecular gas and strengthen our understanding of the gas phase production of water. The high ratio of the OH+ by the H2O+ column density implies that these species predominantly trace low-density gas with a small fraction of hydrogen in molecular form.

astro-ph.GA↗

arXiv2010

Strong absorption by interstellar hydrogen fluoride: Herschel/HIFI observations of the sight-line to G10.6-0.4 (W31C)

We report the detection of strong absorption by interstellar hydrogen fluoride along the sight-line to the submillimeter continuum source G10.6-0.4 (W31C). We have used Herschel's HIFI instrument, in dual beam switch mode, to observe the 1232.4763 GHz J=1-0 HF transition in the upper sideband of the Band 5a receiver. The resultant spectrum shows weak HF emission from G10.6-0.4 at LSR velocities in the range -10 to -3 km/s, accompanied by strong absorption by foreground material at LSR velocities in the range 15 to 50 km/s. The spectrum is similar to that of the 1113.3430 GHz 1(11)-0(00) transition of para-water, although at some frequencies the HF (hydrogen fluoride) optical depth clearly exceeds that of para-H2O. The optically-thick HF absorption that we have observed places a conservative lower limit of 1.6E+14 cm-2 on the HF column density along the sight-line to G10.6-0.4. Our lower limit on the HF abundance, 6E-9 relative to hydrogen nuclei, implies that hydrogen fluoride accounts for between ~ 30 and 100% of the fluorine nuclei in the gas phase along this sight-line. This observation corroborates theoretical predictions that - because the unique thermochemistry of fluorine permits the exothermic reaction of F atoms with molecular hydrogen - HF will be the dominant reservoir of interstellar fluorine under a wide range of conditions.

astro-ph.GA↗