arXiv subjects

M. E. Portnoi

Publications and source records attributed to M. E. Portnoi.

At least 19 recordsLinked to original sources

arXiv2026

Tuneable terahertz transitions in zigzag graphene nanoribbons

We show that a transverse electric field applied to a zigzag graphene nanoribbon opens a band gap whose energy can be tuned through the terahertz (THz) range. The field breaks the reflection symmetry of the ribbon, allowing optical transitions that are forbidden in its absence. The relative strengths of transitions polarized parallel and transverse to the ribbon depend strongly on excitation frequency and become equal at a particular frequency. At this frequency, each helicity selectively excites carriers in only one of the two field-induced edge-state valleys, with the selected valley reversed for the opposite helicity. Since this excitation occurs away from the valley minima, the photoexcited carriers have finite group velocity, giving rise to a circular photogalvanic response. Van Hove singularities enhance radiative recombination at the band edge, providing a route towards compact, tunable THz emitters.

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arXiv2026

Valley separation of photoexcited carriers in bilayer graphene

We derive the angular generation density of photoexcited carriers in gapless and gapped Bernal bilayer graphene. Exploiting the strong anisotropy of the band structure of bilayer graphene at low energies due to trigonal warping, we show that charge carriers belonging to different valleys propagate to different sides of the light spot upon photoexcitation. Importantly, in this low-energy regime, inter-valley electron-phonon scattering is suppressed, thereby protecting the valley index. This optically induced valley polarization can be further enhanced via momentum alignment associated with linearly-polarized light. We then consider gapped bilayer graphene (for example with the gap induced by external top- and back-gates) and show that it exhibits valley-dependent optical selection rules with circularly-polarized light analogous to other gapped Dirac materials, such as transition metal dichalcogenides. Consequently, gapped bilayer graphene can be exploited to optically detect valley polarization. Thus, we predict an optical valley Hall effect - the emission of two different circular polarizations from different sides of the light spot, upon linearly-polarized excitation. We also propose two realistic experimental setups in gapless and gapped bilayer graphene as a basis for novel optovalleytronic devices operating in the elusive terahertz regime.

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arXiv2024

Designer gapped and tilted Dirac cones in lateral graphene superlattices

We show that a planar array of bipolar waveguides in graphene can be used to engineer gapped and tilted two-dimensional Dirac cones within the electronic band structure. The presence of these gapped and tilted Dirac cones is demonstrated through a superlattice tight-binding model and verified using a transfer matrix calculation. By varying the applied gate voltages, the tilt parameter of these Dirac cones can be controlled and their gaps can be tuned to fall in the terahertz range. The possibility of gate-tunable gapped Dirac cones gives rise to terahertz applications via interband transitions and designer Landau level spectra both of which can be controlled via Dirac cone engineering. We anticipate that our paper will encourage Dirac cone tilt and gap engineering for gate-tunable device applications in lateral graphene superlattices.

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arXiv2024

Failure of the Mott's formula for the Thermopower in Carbon Nanotubes

Well-known Mott's formula links the thermoelectric power characterised by Seebeck coefficient to conductivity. We calculate analytically the thermoelectric current and Seebeck coefficient in one-dimensional systems and show that, while the prediction of Mott's formula is valid for Dirac fermions, it is misleading for the carriers having a parabolic dispersion. We apply the developed formalism to metallic single wall carbon nanotubes and obtain a non-trivial non-monotonic dependence of the Seebeck coefficient on the chemical potential. We emphasize that, in contrast to Mott's formula, the classical Kelvin's formula that links thermoelectric power to the temperature derivative of the chemical potential is perfectly valid in carbon nanotubes in the ballistic regime. Interestingly, however, the Kelvin's formula fails in two- and three-dimensional systems in the ballistic regime.

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arXiv2024

Bipolar electron waveguides in two-dimensional materials with tilted Dirac cones

We show that the (2+1)-dimensional massless Dirac equation, which includes a tilt term, can be reduced to the biconfluent Heun equation for a broad range of scalar confining potentials, including the well-known Morse potential. Applying these solutions, we investigate a bipolar electron waveguide in 8-$Pmmn$ borophene, formed by a well and barrier, both described by the Morse potential. We demonstrate that the ability of two-dimensional materials with tilted Dirac cones to localize electrons in both a barrier and a well can be harnessed to create pseudogaps in their electronic spectrum. These pseudogaps can be tuned through varying the applied top-gate voltage. Potential opto-valleytronic and terahertz applications are discussed.

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arXiv2023

Quantum confinement in Dirac-like nanostructures

In Westminster Abbey, in a nave near to Newton's monument, lies a memorial stone to Paul Dirac. The inscription on the stone includes the relativistic wave equation for an electron: the Dirac equation. At the turn of the 21st century, it was discovered that this eponymous equation was not simply the preserve of particle physics. The isolation of graphene by Andre Geim and Konstantin Novoselov in Manchester led to the exploration of a novel class of materials - Dirac materials - whose electrons behave like Dirac particles. While the mobility of these quasi-relativistic electrons is attractive from the perspective of potential ultrafast devices, it also presents a distinct challenge: how to confine Dirac particles so as to avoid making inherently leaky devices? Here we discuss the unconventional quantum tunnelling of Dirac particles, we explain a strategy to create bound states electrostatically, and we briefly review some pioneering experiments seeking to trap Dirac electrons.

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arXiv2023

Polarization-sensitive photoluminescence from aligned carbon chains terminated by gold clusters

We synthesize a thin film composed of long carbyne chains terminated by gold clusters and study its optical properties. The presence of gold particles stabilizes longer chains and leads to their alignment. We show that the gold clusters also act as a source of electron doping thus changing the intensity of photoluminescence from quadratic dependence on the pumping intensity without gold to linear with gold. We also observe that the excitation of the film at the gold plasmon frequency causes the blue shift of photoluminescence and estimate on the basis of this effect the minimum length of the carbyne chains. The high degree of alignment of the gold-terminated carbyne chains results in strongly anisotropic light absorption characterized by a distinctive cosine dependence on the angle between the carbyne molecule and polarization plane of the excitation. This paves the way for a new class of ultimately-thin polarization sensitive emitters to be used in future integrated quantum photonics devices.

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arXiv2023

Stark effect tunable terahertz transitions in finite carbon chains

We employ a tight-binding model to calculate the optical selection rules of gold-terminated carbyne chains in the presence of an applied electric field. We show that both the magnitude of the edge-state gap and the strength of optical transitions across it can be tuned via the Stark effect. In the case of sufficiently long carbyne chains, the dipole transitions between edge states occur within the THz frequency range.

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arXiv2023

Momentum alignment and the optical valley Hall effect in low-dimensional Dirac materials

We study the momentum alignment of photoexcited carriers and the optical control of valley population in gapless and gapped two-dimensional Dirac materials. The trigonal warping effect leads to the spatial separation of charge carriers belonging to different valleys upon linearly polarized high-frequency photoexcitation. Valley separation in gapped materials can be detected by measuring the degree of circular polarization of band-edge photoluminescence at different sides of the sample or light spot (optical valley Hall effect). We demonstrate that the celebrated Rashba effect, caused by substrate-induced system asymmetry, leads to a strong anisotropy in the low-energy part of the spectrum. This results in optical valley separation by a linearly polarized excitation at much lower frequencies compared to the high-energy trigonal warping regime. We also show that the momentum alignment phenomenon explains the giant enhancement of near-band-edge interband optical transitions in narrow-gap carbon nanotubes and graphene nanoribbons independent of the mechanism of the gap formation. These enhanced transitions can be used in terahertz emitters based on low-dimensional Dirac materials.

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arXiv2023

Optical valley separation in two-dimensional semimetals with tilted Dirac cones

Two-dimensional semimetals with tilted Dirac cones in the electronic band structure are shown to exhibit spatial separation of carriers belonging to different valleys under illumination. In stark contrast to gapped Dirac materials this optovalleytronic phenomenon occurs in systems with intact inversion and time-reversal symmetry that host massless Dirac cones in the band structure, thereby retaining the exceptional graphene-like transport properties. As a result we demonstrate that optical valley separation is possible at arbitrarily low photon frequencies including the deep infrared and terahertz regimes with full gate tunability via Pauli blocking. As a specific example of our theory, we demonstrate tunable valley separation in the proposed two-dimensional tilted Dirac cone semimetal 8-$Pmmn$ borophene for incident infrared photons at room temperature.

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arXiv2022

Tuning terahertz transitions in cyclo[n]carbon rings

We develop an analytic model for an ideal polyyne ring which describes the induced THz gap in the molecular spectrum due to the Stark effect. This simple model can also be used to describe an odd-dimered cyclocarbon which has undergone a spontaneous symmetry-breaking event (due to the Jahn-Teller effect) as an effective dipole across an ideal ring. We show that both the size of the gap, and the strength of optical transitions across it, can be modulated by varying the external electric field strength. A THz emission scheme based on optical excitation is proposed, thus paving the way for a new class of THz emitters based on cyclo[n]carbon.

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arXiv2022

Optical absorption in two-dimensional materials with tilted Dirac cones

The interband optical absorption of linearly polarised light by two-dimensional (2D) semimetals hosting tilted and anisotropic Dirac cones in the bandstructure is analysed theoretically. Super-critically tilted (type-II) Dirac cones are characterised by an absorption that is highly dependent on the incident photon polarisation and frequency, and is tunable by changing the Fermi level with a back-gate voltage. Type-II Dirac cones exhibit open Fermi surfaces and large regions of the Brillouin zone where the valence and conduction bands sit either above or below the Fermi level. As a consequence, unlike their sub-critically tilted (type-I) counterparts, type-II Dirac cones have many states that are Pauli blocked even when the Fermi level is tuned to the level crossing point. We analyse the interplay of the tilt parameter with the Fermi velocity anisotropy, demonstrating that the optical response of a Dirac cone cannot be described by its tilt alone. As a special case of our general theory we discuss the proposed 2D type-I semimetal 8-$Pmmn$ Borophene. Guided by our in-depth analytics we develop an optical recipe to fully characterise the tilt and Fermi velocity anisotropy of any 2D tilted Dirac cone solely from its absorption spectrum. We expect our work to encourage Dirac cone engineering as a major route to create gate-tunable thin-film polarisers.

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arXiv2021

Mapping borophene onto graphene: Quasi-exact solutions for guiding potentials in tilted Dirac cones

We show that if the solutions to the (2+1)-dimensional massless Dirac equation for a given 1D potential are known, then they can be used to obtain the eigenvalues and eigenfunctions for the same potential, orientated at an arbitrary angle, in a tilted anisotropic 2D Dirac material. This simple set of transformations enables all the exact and quasi-exact solutions associated with 1D quantum wells in graphene to be applied to the confinement problem in tilted Dirac materials such as borophene. We also show that smooth electron waveguides in tilted Dirac materials can be used to manipulate the degree of valley polarization of quasiparticles travelling along a particular direction of the channel. We examine the particular case of the hyperbolic secant potential to model realistic top-gated structures for valleytronic applications.

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arXiv2021

Terahertz transitions in finite carbon chains

We predict an optical effect associated with systems which exhibit topologically protected states separated by a finite distance. We develop a tight-binding model to calculate the optical selection rules in linear chains of atoms of different lengths, and show the crucial importance of edge states. For long enough molecules the interband transitions involving these edge states are in the highly sought-after THz frequency range. Although we have specifically considered finite carbon chains terminated by gold nanoparticles, the main results of our work can be generalized to various systems which exhibit topologically protected states separated by a finite distance.

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arXiv2020

Bipolar electron waveguides in graphene

We show analytically that the ability of Dirac materials to localize an electron in both a barrier and a well can be utilized to open a pseudo-gap in graphene's spectrum. By using narrow top-gates as guiding potentials, we demonstrate that graphene bipolar waveguides can create a non-monotonous one-dimensional dispersion along the electron waveguide, whose electrostatically controllable pseudo-band-gap is associated with strong terahertz transitions in a narrow frequency range.

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arXiv2020

Guided modes and terahertz transitions for two-dimensional Dirac fermions in a smooth double-well potential

The double-well problem for the two-dimensional Dirac equation is solved for a family of quasi-one-dimensional potentials in terms of confluent Heun functions. We demonstrate that for a double well separated by a barrier, both the energy level splitting associated with the wavefunction overlap of well states, and the gap size of the avoided crossings associated with well and barrier state repulsion, can be controlled via the parameters of the potential. The transitions between the two states comprising a doublet, as well as transitions across the pseudo-gaps are strongly allowed, highly anisotropic, and for realistic graphene devices can be tuned to fall within the highly desirable terahertz frequency range.

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arXiv2019

Carbon nanotube array as a van der Waals two-dimensional hyperbolic material

We use an ab-initio approach to design and study a novel two-dimensional material - a planar array of carbon nanotubes separated by an optimal distance defined by the van der Waals interaction. We show that the energy spectrum for an array of quasi-metallic nanotubes is described by a strongly anisotropic hyperbolic dispersion and formulate a model low-energy Hamiltonian for its semi-analytical treatment. Periodic-potential-induced lifting of the valley degeneracy for an array of zigzag narrow-gap nanotubes leads to the band gap collapse. In contrast, the band gap is opened in an array of gapless armchair tubes. These unusual spectra, marked by pronounced van Hove singularities in the low-energy density of states, open the opportunity for interesting physical effects and prospective optoelectronic applications.

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arXiv2019

Trapping charge carriers in low-dimensional Dirac materials

We consider the problem of confining the famously elusive Dirac-like quasiparticles, as found in some recently discovered low-dimensional systems. After briefly surveying the existing theoretical proposals for creating bound states in Dirac materials, we study relativistic excitations with a position-dependent mass term. With the aid of an exactly-solvable model, we show how bound states begin to emerge after a critical condition on the size of the mass term is met. We also reveal some exotic properties of the unusual confinement discovered, including an elegant chevron structure of the bound state energies as a function of the size of the mass.

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