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M. E. Suss

Publications and source records attributed to M. E. Suss.

3 recordsLinked to original sources

Capacitive Deionization -- defining a class of desalination technologies

Over the past decade, capacitive deionization (CDI) has realized a surge in attention in the field of water desalination and can now be considered as an important technology class, along with reverse osmosis and electrodialysis. While many of the recently developed technologies no longer use a mechanism that follows the strict definition of the term "capacitive", these methods nevertheless share many common elements that encourage treating them with similar metrics and analyses. Specifically, they all involve electrically driven removal of ions from a feed stream, storage in an electrode (i.e., ion electrosorption) and release, in charge/discharge cycles. Grouping all these methods in the technology class of CDI makes it possible to treat evolving new technologies in standardized terms and compare them to other technologies in the same class.

physics.app-ph

Induced Charge Capacitive Deionization: The electrokinetic response of a porous particle to an external electric field

We demonstrate the phenomenon of induced-charge capacitive deionization (ICCDI) that occurs around a porous and conducting particle immersed in an electrolyte, under the action of an external electric field. The external electric field induces an electric dipole in the porous particle, leading to its capacitive charging by both cations and anions at opposite poles. This regime is characterized by a long charging time which results in significant changes in salt concentration in the electrically neutral bulk, on the scale of the particle. We qualitatively demonstrate the effect of advection on the spatio-temporal concentration field which, through diffusiophoresis, may introduce corrections to the electrophoretic mobility of such particles.

physics.flu-dyn

Theory of water desalination by porous electrodes with fixed chemical charge

Water desalination by capacitive deionization (CDI) is performed via electrochemical cells consisting of two porous carbon electrodes. Upon transferring charge from one electrode to the other, ions are removed from the feedwater by electrosorption into electrical double layers (EDLs) within the micropores of the porous carbon. When using electrodes containing fixed chemical charge in the micropores, various counterintuitive observations have been made, such as "inverted CDI" where upon charging, ions are released from the electrode, and the feedwater is only desalinated when the cell is discharging. We set up an EDL model including chemical charge that explains these observations and makes predictions for a working range of enhanced desalination by CDI.

cond-mat.mtrl-sci