arXiv subjects

M. Frey

Publications and source records attributed to M. Frey.

5 recordsLinked to original sources

arXiv2026

Hierarchical Interdiffusion Kinetics in Nanoscale Ni/Al Multilayers

Reactive metallic multilayers store chemical energy that can be released rapidly through interdiffusion and intermetallic formation. Predictive control of this heat release requires distinguishing transport and phase-formation processes that occur in rapid succession. Here we combine free-standing nanoscale Ni/Al multilayers with chip-based flash calorimetry and isoconversional kinetic analysis over five orders of magnitude in heating rate. Selected reaction states are quenched and examined by scanning transmission electron microscopy. This workflow separates pre-ignition interdiffusion into two regimes and quantifies activation energies of (81 $\pm$ 24) and (168 $\pm$ 17) kJ/mol, consistent with grain-boundary and lattice diffusion of Ni in Al, respectively. Microscopy supports this assignment: no significant compositional changes are observed after the first regime, whereas the second increases the Ni content of the Al layers and produces Ni-enriched features spaced by 5$-$10 nm, matching the Al grain size. These results identify the Al grain-boundary network as the dominant low-barrier pathway, providing rapid transport across the Al layers and priming lattice-mediated mixing and intermetallic phase formation. More broadly, the workflow links calorimetric signatures to pathway-specific kinetics and transient microstructures, enabling direct assessment of how microstructural design redirects coupled transport and reaction pathways in reactive multilayers and other materials driven far from equilibrium.

cond-mat.mtrl-sci↗

arXiv2023

Denser glasses relax faster: a competition between rejuvenation and aging during in-situ high pressure compression at the atomic scale

A fascinating feature of metallic glasses is their ability to explore different configurations under mechanical deformations. This effect is usually observed through macroscopic observables, while little is known on the consequence of the deformation at atomic level. Using the new generation of synchrotrons, we probe the atomic motion and structure in a metallic glass under hydrostatic compression, from the onset of the perturbation up to a severely-compressed state. While the structure indicates reversible densification under compression, the dynamic is dramatically accelerated and exhibits a hysteresis with two regimes. At low pressures, the atomic motion is heterogeneous with avalanche-like rearrangements suggesting rejuvenation, while under further compression, aging leads to a super-diffusive dynamics triggered by internal stresses inherent to the glass. These results highlight the complexity of the atomic motion in non-ergodic systems and support a theory recently developed to describe the surprising rejuvenation and strain hardening of metallic glasses under compression.

cond-mat.dis-nn↗

arXiv2020

Wave vector dependence of the dynamics in supercooled metallic liquids

We present a detailed investigation of the wave vector dependence of collective atomic motion in Au49Cu26.9Si16.3Ag5.5Pd2.3 and Pd42.5Cu27Ni9.5P21 supercooled liquids close to the glass transition temperature. Using x-ray photon correlation spectroscopy in a precedent uncovered spatial range of only few interatomic distances, we show that the microscopic structural relaxation process follows in phase the structure with a marked slowing down at the main average inter-particle distance. This behavior is accompanied by dramatic changes in the shape of the intermediate scattering functions which suggest the presence of large dynamical heterogeneities at length-scales corresponding to few particle diameters. A ballistic-like mechanism of particle motion seems to govern the structural relaxation of the two systems in the highly viscous phase, likely associated to hopping of caged particles in agreement with theoretical studies.

cond-mat.soft↗

arXiv2017

Evolution of a beam dynamics model for the transport lines in a proton therapy facility

Despite the fact that the first-order beam dynamics models allow an approximated evaluation of the beam properties, their contribution is essential during the conceptual design of an accelerator or beamline. However, during the commissioning some of their limitations appear in the comparison against measurements. The extension of the linear model to higher order effects is, therefore, demanded. In this paper, the effects of particle-matter interaction have been included in the model of the transport lines in the proton therapy facility at the Paul Scherrer Institut (PSI) in Switzerland. To improve the performance of the facility, a more precise model was required and has been developed with the multi-particle open source beam dynamics code called OPAL (Object oriented Particle Accelerator Library). In OPAL, the Monte Carlo simulations of Coulomb scattering and energy loss are performed seamless with the particle tracking. Beside the linear optics, the influence of the passive elements (e.g. degrader, collimators, scattering foils and air gaps) on the beam emittance and energy spread can be analysed in the new model. This allows for a significantly improved precision in the prediction of beam transmission and beam properties. The accuracy of the OPAL model has been confirmed by numerous measurements.

physics.acc-ph↗

arXiv2014

Hydration shell effects in the relaxation dynamics of photoexcited Fe-II complexes in water

We study the relaxation dynamics of photoexcited Fe-II complexes dissolved in water and identify the relaxation pathway which the molecular complex follows in presence of a hydration shell of bound water at the interface between the complex and the solvent. Starting from a low-spin state, the photoexcited complex can reach the high-spin state via a cascade of different possible transitions involving electronic as well as vibrational relaxation processes. By numerically exact path integral calculations for the relaxational dynamics of a continuous solvent model, we find that the vibrational life times of the intermittent states are of the order of a few ps. Since the electronic rearrangement in the complex occurs on the time scale of about 100 fs, we find that the complex first rearranges itself in a high-spin and highly excited vibrational state, before it relaxes its energy to the solvent via vibrational relaxation transitions. By this, the relaxation pathway can be clearly identified. We find that the life time of the vibrational states increases with the size of the complex (within a spherical model), but decreases with the thickness of the hydration shell, indicating that the hydration shell acts as an additional source of fluctuations.

physics.atm-clus↗