arXiv subjects

M. Guelin

Publications and source records attributed to M. Guelin.

At least 19 recordsLinked to original sources

arXiv2025

A sub-ppm upper limit on the cosmological variations of the fine structure constant alpha

Absorption spectroscopy toward high-redshift quasars provides strong constraints on the putative variation of fundamental constants of physics on cosmological time scales. The submillimeter ground-state transitions of methylidyne (CH) and water (H2O), both molecules widespread and coeval in the interstellar medium, provide a sensitive test for variations of alpha, the fine structure constant, and mu, the proton-to-electron mass ratio, taking advantage of the unmatched spectral resolution and frequency reliability of radio techniques. We used ALMA simultaneous observations of the two species to constrain any velocity offset between their absorption profiles toward the radio-bright lensed quasars PKS1830-211 (z_abs=0.88582) and B0218+357 (z_abs=0.68466). Our observational setup minimizes instrumental errors and known sources of systematics, such as time variability of the absorption profile and frequency-dependent morphology of the background quasar. The excellent correlation between CH and H2O opacities, the large number of individual narrow velocity components, and the number of independent spectra obtained due to the intrinsic time variability of the absorption profiles ensure that even the chemical segregation bias is minimized. We obtained bulk velocity shifts delta_v = -0.048 pm 0.028 km/s and -0.13 pm 0.14 km/s (1 sigma confidence level) between CH and H2O in the direction of PKS1830-211(NE) and B0218+357(SW), respectively. These values convert into the 3sigma upper limits |Delta_alpha/alpha| < 0.55 ppm and 1.5 ppm, respectively, taking into account the independent upper limits on |Delta_mu/mu| previously obtained for these systems. These constraints on |Delta_alpha/alpha|, at look-back times of about half the present age of the Universe, are two to four times deeper than previous constraints on any other single high-z system.

astro-ph.CO↗

arXiv2024

Protonated acetylene in the z=0.89 molecular absorber toward PKS1830-211

We report the first interstellar identification of protonated acetylene, C2H3+, a fundamental hydrocarbon, in the z=0.89 molecular absorber toward the gravitationally lensed quasar PKS1830-211. The molecular species is identified from clear absorption features corresponding to the 2_12-1_01 (rest frequency 494.034 GHz) and 1_11-0_00 (431.316 GHz) ground-state transitions of ortho and para forms of C2H3+, respectively, in ALMA spectra toward the southwestern image of PKS1830-211, where numerous molecules, including other hydrocarbons, have already been detected. From the simple assumption of local thermodynamic equilibrium (LTE) with cosmic microwave background photons and an ortho-to-para ratio of three, we estimate a total C2H3+ column density of 2 x 10^12 cm^-2 and an abundance of 10^-10 compared to H_2. However, formation pumping could affect the population of metastable states, yielding a C2H3+ column density higher than the LTE value by a factor of a few. We explore possible routes to the formation of C2H3+, mainly connected to acetylene and methane, and find that the methane route is more likely in PDR environment. As one of the initial hydrocarbon building blocks, C2H3+ is thought to play an important role in astrochemistry, in particular in the formation of more complex organic molecules.

astro-ph.GA↗

arXiv2023

Cosmo-tomography toward PKS1830-211: Variability of the quasar and of its foreground molecular absorption monitored with ALMA

Time variability of astronomical sources provides crude information on their typical size and on the implied physical mechanisms. PKS1830-211 is a remarkable radio-bright lensed quasar with a foreground molecular absorber at z=0.89. Small-scale morphological changes in the core-jet structure of the quasar -- which is magnified by the lensing -- result in a varying illumination of the absorber screen, which in turn causes variations in the absorption profile. We aim to study the time variations of the system [...] in order to obtain constraints on both the quasar activity and small-scale structures in the ISM of the absorber. We used ALMA to monitor the submm continuum emission, together with the absorption spectra of the H2O and CH molecules, with 17 visits spread over six months in 2016. [...] From the continuum data, we followed the evolution of the flux density, flux-density ratio, spectral index, and differential polarization between the two lensed images of the quasar; all quantities show significant variations related to the intrinsic activity of the quasar. We propose a simple parametric model of a core plus a ballistic plasmon to account for the continuum evolution, from which we constrain a time delay of 25+/-3~days between lensed images. The spectral lines reveal significant variations in the foreground absorption. A PCA highlights apparent wavy time variations, possibly linked to the helical jet precession period of the quasar. From the deep averaged spectra towards the SW image, we detect the absorption of 13CH and estimate an abundance ratio of 12CH/13CH~150. We also measure the oxygen isotopic ratios, 16O/18O=65.3+/-0.7 and 18O/17O=11.5+/-0.5. Finally, we find a remarkable continuous shallow trough in the water absorption spanning a velocity interval of nearly 500 km/s. This broad absorption could be the signature of an extra-planar molecular component. [Abridged]

astro-ph.GA↗

arXiv2023

Discovery of two metallic cyanoacetylides in IRC+10216: HMgCCCN and NaCCCN

We report on the detection of a series of six lines in the ultra-deep Q-band integration toward IRC+10216 carried out with the Yebes 40m telescope, which are in harmonic relation with integer quantum numbers J from 12 to 18. After a detailed analysis of all possible carriers, guided by high-level quantum chemical calculations, we conclude that the lines belong to HMgCCCN, named hydromagnesium cyanoacetylide. The rotational temperature and column density derived for HMgCCCN are 17.1 +/- 2.8K and (3.0 +/- 0.6) e12 cm-2, respectively. The observed abundance ratio between MgCCCN and HMgCCCN is 3. In addition, we report the discovery in space, also toward IRC+10216, of sodium cyanoacetylide, NaCCCN, for which accurate laboratory data are available. For this species we derive a rotational temperature of 13.5 +/- 1.7K and a column density of (1.2 +/- 0.2) e11 cm-2.

astro-ph.GA↗

arXiv2023

Discovery of the C7N- anion in TMC-1 and IRC+10216

We report on the discovery of the C7N- anion towards the starless core TMC-1 and towards the carbon-rich evolved star IRC+10216. We used the data of the QUIJOTE line survey towards TMC-1 and found six lines in perfect harmonic frequency relation from J=27-26 up to J=32-31. The frequency of the lines can be reproduced with a rotational constant and a distortion constant of B=582.68490+/-0.00024 MHz and D=4.01+/-0.13 Hz, respectively. The standard deviation of the fit is 4 kHz. Towards IRC+10216, we identify 17 lines from J=27-26 up to J=43-42; their frequencies are also in harmonic relation, providing B=582.6827+/-0.00085 MHz and D=3.31+/-0.31 Hz. The nearly exact coincidence of the rotational and distortion constants in both sources points unambiguously to a common molecular carrier. Taking into account the chemical peculiarities of both sources, the carrier could be a radical or an anion. The radical can be discarded, as the observed lines belong to a singlet species. Hence, the most plausible carrier is an anion. High-level ab initio calculations indicate that C7N-, for which we compute a rotational constant of B=582.0 MHz and a dipole moment of 7.5 D, is the carrier of the lines in both sources. We predict the neutral C7N to have a ground electronic state 2Pi and a dipole moment around 1 D. Because of this low dipole moment value and to its much larger rotational partition function, its lines are expected to be well below the sensitivity of our data for both sources.

astro-ph.GA↗

arXiv2020

Detection of deuterated molecules, but not of lithium hydride, in the z=0.89 absorber toward PKS1830-211

Deuterium and lithium are light elements of high cosmological and astrophysical importance. In this work we report the first detection of deuterated molecules and a search for lithium hydride, 7LiH, at redshift z=0.89 in the spiral galaxy intercepting the line of sight to the quasar PKS1830-211. We used ALMA to observe several submillimeter lines of ND, NH2D, and HDO, and their related isotopomers NH2, NH3, and H2^18O, in absorption against the southwest image of the quasar, allowing us to derive XD/XH abundance ratios. The absorption spectra mainly consist of two distinct narrow velocity components for which we find remarkable differences. One velocity component shows XD/XH abundances that is about 10 times larger than the primordial elemental D/H ratio, and no variability of the absorption profile during the time span of our observations. [...] The second component has XD/XH abundances that are 100 times larger than the primordial D/H ratio, a deepening of the absorption by a factor of two within a few months, and a rich chemical composition, with relative enhancements of N2H+, CH3OH, SO2, and complex organic molecules. We therefore speculate that this component is associated with the analog of a Galactic dark cloud, while the first component is likely more diffuse. Our search for the 7LiH (1--0) line was unsuccessful and we derive an upper limit 7LiH/H2 = 4 x 10^-13 (3sigma) in the z=0.89 absorber toward PKS1830-211. Besides, with ALMA archival data, we could not confirm the previous tentative detections of this line in the z=0.68 absorber toward B0218+357; we derive an upper limit 7LiH/H2 = 5 x 10^-11 (3sigma), although this is less constraining than our limit toward PKS1830-211. We conclude that, as in the Milky Way, only a tiny fraction of lithium nuclei are possibly bound in LiH in these absorbers at intermediate redshift.

astro-ph.GA↗

arXiv2017

The growth of carbon chains in IRC+10216 mapped with ALMA

Linear carbon chains are common in various types of astronomical molecular sources. Possible formation mechanisms involve both bottom-up and top-down routes. We have carried out a combined observational and modeling study of the formation of carbon chains in the C-star envelope IRC+10216, where the polymerization of acetylene and hydrogen cyanide induced by ultraviolet photons can drive the formation of linear carbon chains of increasing length. We have used ALMA to map the emission of 3 mm rotational lines of the hydrocarbon radicals C2H, C4H, and C6H, and the CN-containing species CN, C3N, HC3N, and HC5N with an angular resolution of 1". The spatial distribution of all these species is a hollow, 5-10" wide, spherical shell located at a radius of 10-20" from the star, with no appreciable emission close to the star. Our observations resolve the broad shell of carbon chains into thinner sub-shells which are 1-2" wide and not fully concentric, indicating that the mass loss process has been discontinuous and not fully isotropic. The radial distributions of the species mapped reveal subtle differences: while the hydrocarbon radicals have very similar radial distributions, the CN-containing species show more diverse distributions, with HC3N appearing earlier in the expansion and the radical CN extending later than the rest of the species. The observed morphology can be rationalized by a chemical model in which the growth of polyynes is mainly produced by rapid gas-phase chemical reactions of C2H and C4H radicals with unsaturated hydrocarbons, while cyanopolyynes are mainly formed from polyynes in gas-phase reactions with CN and C3N radicals.

astro-ph.SR↗

arXiv2016

OH+ and H2O+ absorption toward PKS1830-211

We report the detection of OH+ and H2O+ in the z=0.89 absorber toward the lensed quasar PKS1830-211. The abundance ratio of OH+ and H2O+ is used to quantify the molecular hydrogen fraction (fH2) and the cosmic-ray ionization rate of atomic hydrogen (zH) along two lines of sight, located at ~2 kpc and ~4 kpc to either side of the absorber's center. The molecular fraction decreases outwards, from ~0.04 to ~0.02, comparable to values measured in the Milky Way at similar galactocentric radii. For zH, we find values of ~2x10^-14 s^-1 and ~3x10^-15 s^-1, respectively, which are slightly higher than in the Milky Way at comparable galactocentric radii, possibly due to a higher average star formation activity in the z=0.89 absorber. The ALMA observations of OH+, H2O+, and other hydrides toward PKS1830-211 reveal the multi-phase composition of the absorbing gas. Taking the column density ratios along the southwest and northeast lines of sight as a proxy of molecular fraction, we classify the species ArH+, OH+, H2Cl+, H2O+, CH, and HF as tracing gases increasingly more molecular. Incidentally, our data allow us to improve the accuracy of H2O+ rest frequencies and thus refine the spectroscopic parameters.

astro-ph.GA↗

arXiv2016

Isotopic ratios at z=0.68 from molecular absorption lines toward B 0218+357

Isotopic ratios of heavy elements are a key signature of the nucleosynthesis processes in stellar interiors. The contribution of successive generations of stars to the metal enrichment of the Universe is imprinted on the evolution of isotopic ratios over time. We investigate the isotopic ratios of carbon, nitrogen, oxygen, and sulfur through millimeter molecular absorption lines arising in the z=0.68 absorber toward the blazar B 0218+357. We find that these ratios differ from those observed in the Galactic interstellar medium, but are remarkably close to those in the only other source at intermediate redshift for which isotopic ratios have been measured to date, the z=0.89 absorber in front of PKS1830-211. The isotopic ratios in these two absorbers should reflect enrichment mostly from massive stars, and they are indeed close to the values observed toward local starburst galaxies. Our measurements set constraints on nucleosynthesis and chemical evolution models.

astro-ph.GA↗

arXiv2015

The peculiar distribution of CH3CN in IRC+10216 seen by ALMA

IRC+10216 is a circumstellar envelope around a carbon-rich evolved star which contains a large variety of molecules. According to interferometric observations, molecules are distributed either concentrated around the central star or as a hollow shell with a radius of 15". We present ALMA Cycle 0 band 6 observations of the J=14-13 rotational transition of CH3CN in IRC+10216, obtained with an angular resolution of 0.76x0.61". The bulk of the emission is distributed as a hollow shell located at just 2" from the star, with a void of emission in the central region up to a radius of 1". This spatial distribution is markedly different from those found to date in this source for other molecules. Our analysis indicate that methyl cyanide is not formed neither in the stellar photosphere nor far in the outer envelope, but at radial distances as short as 1-2", reaching a maximum abundance of 0.02 molecules cm-3 at 2" from the star. Standard chemical models of IRC+10216 predict that the bulk of CH3CN molecules should be present at a radius of 15", where other species such as polyyne radicals and cyanopolyynes are observed, with an additional inner component within 1" from the star. The non-uniform structure of the circumstellar envelope and grain surface processes are discussed as possible causes of the peculiar distribution of methyl cyanide in IRC+10216.

astro-ph.SR↗

arXiv2015

Probing non polar interstellar molecules through their protonated form: Detection of protonated cyanogen (NCCNH+)

Cyanogen (NCCN) is the simplest member of the series of dicyanopolyynes. It has been hypothesized that this family of molecules can be important constituents of interstellar and circumstellar media, although the lack of a permanent electric dipole moment prevents its detection through radioastronomical techniques. Here we present the first solid evidence of the presence of cyanogen in interstellar clouds through the detection of its protonated form toward the cold dark clouds TMC-1 and L483. Protonated cyanogen (NCCNH+) has been identified through the J=5-4 and J=10-9 rotational transitions using the 40m radiotelescope of Yebes and the IRAM 30m telescope. We derive beam averaged column densities for NCCNH+ of (8.6+/-4.4)e10 cm-2 in TMC-1 and (3.9+/-1.8)e10 cm-2 in L483, which translate to fairly low fractional abundances relative to H2, in the range (1-10)e-12. The chemistry of protonated molecules in dark clouds is discussed, and it is found that, in general terms, the abundance ratio between the protonated and non protonated forms of a molecule increases with increasing proton affinity. Our chemical model predicts an abundance ratio NCCNH+/NCCN of 1e-4, which implies that the abundance of cyanogen in dark clouds could be as high as (1-10)e-8 relative to H2, i.e., comparable to that of other abundant nitriles such as HCN, HNC, and HC3N.

astro-ph.GA↗

arXiv2015

Discovery of SiCSi in IRC+10216: A missing link between gas and dust carriers of SiC bonds

We report the discovery in space of a disilicon species, SiCSi, from observations between 80 and 350 GHz with the IRAM 30m radio telescope. Owing to the close coordination between laboratory experiments and astrophysics, 112 lines have now been detected in the carbon-rich star CWLeo. The derived frequencies yield improved rotational and centrifugal distortion constants up to sixth order. From the line profiles and interferometric maps with the Submillimeter Array, the bulk of the SiCSi emis- sion arises from a region of 6 arcseconds in radius. The derived abundance is comparable to that of SiC2. As expected from chemical equilibrium calculations, SiCSi and SiC2 are the most abundant species harboring a SiC bond in the dust formation zone and certainly both play a key role in the formation of SiC dust grains.

astro-ph.GA↗

arXiv2014

Molecular shells in IRC+10216: tracing the mass loss history

The ejecta of thermally-pulsating AGB stars largely control the chemical evolution of galaxies. Yet, both, the mass-loss process and the gas chemical composition remain poorly understood. We present maps of the extended 12CO and 13CO emission in IRC+10216, the envelope of CW Leo, the high mass loss star the closest to the Sun. IRC+10216 is nearly spherical and expands radially with a velocity of 14.5 km/s. The observations, made with the IRAM 30-m telescope, have a sensibility, calibration, and angular resolution far higher than previous studies. The angular resolution is 11", which corresponds to an expansion time of 500 yr. The CO emission consists of a centrally peaked pedestal and a series of bright, nearly spherical shells. It peaks on CW Leo and remains relatively strong up to 180". Further out it becomes very weak and vanishes as CO gets photodissociated. The CO maps allow to trace the mass loss history in the last 8000 yr. The bright CO shells denote overdense regions, which indicate that the mass loss process is highly variable on timescales of hundreds of years. The new data, however, infirm previous claims of a strong decrease of the average mass loss in the last few thousand years. The overdense shells are not perfectly concentric and extend farther to the N-NW. The typical shell separation is 800-1000 yr in the middle of the envelope, but seems to increase outwards. The shell-intershell brightness contrast is $\geq$ 3. All those key features can be accounted for if CW Leo has a companion star with a period of $\sim$ 800 yr that increases the mass loss rate when it comes close to periastron. Higher angular resolution observations are needed to fully resolve the dense shells and measure the density contrast. The latter plays an essential role for our understanding of the envelope chemistry.

astro-ph.SR↗

arXiv2014

An ALMA Early Science survey of molecular absorption lines toward PKS1830-211 -- Analysis of the absorption profiles

We present the first results of an ALMA spectral survey of strong absorption lines for common interstellar species in the z=0.89 molecular absorber toward the lensed blazar PKS1830-211. The dataset brings essential information on the structure and composition of the absorbing gas in the foreground galaxy. In particular, we find absorption over large velocity intervals (gtrsim 100 km/s) toward both lensed images of the blazar. This suggests either that the galaxy inclination is intermediate and that we sample velocity gradients or streaming motions in the disk plane, that the molecular gas has a large vertical distribution or extraplanar components, or that the absorber is not a simple spiral galaxy but might be a merger system. The number of detected species is now reaching a total of 42 different species plus 14 different rare isotopologues toward the SW image, and 14 species toward the NE line-of-sight. The abundances of CH, H2O, HCO+, HCN, and NH3 relative to H2 are found to be comparable to those in the Galactic diffuse medium. Of all the lines detected so far toward PKS1830-211, the ground-state line of ortho-water has the deepest absorption. We argue that ground-state lines of water have the best potential for detecting diffuse molecular gas in absorption at high redshift.

astro-ph.GA↗

arXiv2014

Detection of chloronium and measurement of the 35Cl/37Cl isotopic ratio at z=0.89 toward PKS1830-211

We report the first extragalactic detection of chloronium (H2Cl+), in the z=0.89 absorber in front of the lensed blazar PKS1830-211. The ion is detected through its 1_11-0_00 line along two independent lines of sight toward the North-East and South-West images of the blazar. The relative abundance of H2Cl+ is significantly higher (by a factor ~7) in the NE line of sight, which has a lower H2/H fraction, indicating that H2Cl+ preferably traces the diffuse gas component. From the ratio of the H2^35Cl+ and H2^37Cl+ absorptions toward the SW image, we measure a 35Cl/37Cl isotopic ratio of 3.1 (-0.2; +0.3) at z=0.89, similar to that observed in the Galaxy and the solar system.

astro-ph.GA↗

arXiv2013

Probing the jet base of the blazar PKS1830-211 from the chromatic variability of its lensed images. Serendipitous ALMA observations of a strong gamma-ray flare

The launching mechanism of the jets of active galactic nuclei is observationally poorly constrained, due to the large distances to these objects and the very small scales (sub-parsec) involved. In order to better constrain theoretical models, it is especially important to get information from the region close to the physical base of the jet, where the plasma acceleration takes place. In this paper, we report multi-epoch and multi-frequency continuum observations of the z=2.5 blazar PKS1830-211 with ALMA, serendipitously coincident with a strong $γ$-ray flare reported by Fermi-LAT. The blazar is lensed by a foreground z=0.89 galaxy, with two bright images of the compact core separated by 1". Our ALMA observations individually resolve these two images (although not any of their substructures), and we study the change of their relative flux ratio with time (four epochs spread over nearly three times the time delay between the two lensed images) and frequency (between 350 and 1050 GHz, rest-frame of the blazar), during the $γ$-ray flare. In particular, we detect a remarkable frequency-dependent behaviour of the flux ratio, which implies the presence of a chromatic structure in the blazar (i.e., a core-shift effect). We rule out the possiblity of micro- and milli-lensing effects and propose instead a simple model of plasmon ejection in the blazar's jet to explain the time and frequency variability of the flux ratio. We suggest that PKS1830-211 is likely one of the best sources to probe the activity at the base of a blazar's jet at submillimeter wavelengths, thanks to the peculiar geometry of the system. The implications of the core-shift in absorption studies of the foreground z=0.89 galaxy (e.g., constraints on the cosmological variations of fundamental constants) are discussed.

astro-ph.CO↗

arXiv2013

H2O emission in high-z ultra-luminous infrared galaxies

Using IRAM PdBI we report the detection of H2O in six new lensed ultra-luminous starburst galaxies at high redshift, discovered in the Herschel H-ATLAS survey. The sources are detected either in the 2_{02}-1_{11} or 2_{11}-2_{02} H_2O emission lines with integrated line fluxes ranging from 1.8 to 14 Jy.km/s. The corresponding apparent luminosities are mu x L_H2O ~ 3-12 x 10^8 Lo, where mu is the lensing magnification factor (3 < mu < 12). These results confirm that H2O lines are among the strongest molecular lines in such galaxies, with intensities almost comparable to those of the high-J CO lines, and same profiles and line widths (200-900 km/s) as the latter. With the current sensitivity of PdBI, H2O can therefore easily be detected in high-z lensed galaxies (with F(500um) > 100 mJy) discovered in the Herschel surveys. Correcting the luminosities for lensing amplification, L_H2O is found to have a strong dependence on the IR luminosity, varying as ~L_IR^{1.2}. This relation which needs to be confirmed with better statistics, may indicate a role of radiative (IR) excitation of the H2O lines, and implies that high-z galaxies with L_IR >~ 10^13 Lo tend to be very strong emitters in H2O, that have no equivalent in the local universe.

astro-ph.CO↗

arXiv2012

A precise and accurate determination of the cosmic microwave background temperature at z=0.89

According to the Big Bang theory and as a consequence of adiabatic expansion of the Universe, the temperature of the cosmic microwave background (CMB) increases linearly with redshift. This relation is, however, poorly explored, and detection of any deviation would directly lead to (astro-)physics beyond the standard model. We aim at measuring the temperature of the CMB with an accuracy of a few percent at z=0.89 toward the molecular absorber in the galaxy lensing the quasar PKS1830-211. We adopt a Monte-Carlo Markov Chain approach, coupled with predictions from the non-LTE radiative transfer code RADEX, to solve the excitation of a set of various molecular species directly from their spectra. We determine Tcmb=5.08 pm 0.10 K at 68% confidence level. Our measurement is consistent with the value Tcmb=5.14 K predicted by the standard cosmological model with adiabatic expansion of the Universe. This is the most precise determination of Tcmb at z>0 to date.

astro-ph.CO↗