arXiv subjects

M. Hartl

Publications and source records attributed to M. Hartl.

27 records · Page 2Linked to original sources

arXiv2021

Constructed wetlands operated as bioelectrochemical systems for the removal of organic micropollutants

The removal of organic micropollutants (OMPs) has been investigated in constructed wetlands (CWs) operated as bioelectrochemical systems (BES). The operation of CWs as BES (CW-BES), either in the form of microbial fuel cells (MFC) or microbial electrolysis cells (MEC), has only been investigated in recent years. The presented experiment used CW meso-scale systems applying a realistic horizontal flow regime and continuous feeding of real urban wastewater spiked with four OMPs (pharmaceuticals), namely carbamazepine (CBZ), diclofenac (DCF), ibuprofen (IBU) and naproxen (NPX). The study evaluated the removal efficiency of conventional CW systems (CW-control) as well as CW systems operated as closed-circuit MFCs (CW-MFCs) and MECs (CW-MECs). Although a few positive trends were identified for the CW-BES compared to the CW-control (higher average CBZ, DCF and NPX removal by 10-17% in CW-MEC and 5% in CW-MFC), these proved to be not statistically significantly different. Mesoscale experiments with real wastewater could thus not confirm earlier positive effects of CW-BES found under strictly controlled laboratory conditions with synthetic wastewaters.

q-bio.QM↗

arXiv2020

MFC-based biosensor for domestic wastewater COD assessment in constructed wetlands

In the context of natural-based wastewater treatment technologies (such as constructed wetlands - CW) the use of a low-cost, continuous-like biosensor tool for the assessment of operational conditions is of key importance for plant management optimization. The objective of the present study was to assess the potential use of constructed wetland microbial fuel cells (CW-MFC) as a domestic wastewater COD assessment tool. For the purpose of this work four lab-scale CW-MFCs were set up and fed with pre-settled domestic wastewater at different COD concentrations. Under laboratory conditions two different anodic materials were tested (graphite rods and gravel). Furthermore, a pilot-plant based experiment was also conducted to confirm the findings previously recorded for lab-scale experiments. Results showed that in spite of the low coulombic efficiencies recorded, either gravel or graphite-based anodes were suitable for the purposes of domestic wastewater COD assessment. Significant linear relationships could be established between inlet COD concentrations and CW-MFC Ecell whenever contact time was above 10 hours. Results also showed that the accuracy of the CW-MFC was greatly compromised after several weeks of operation. Pilot experiments showed that CW-MFC presents a good bio-indication response between week 3 and 7 of operation (equivalent to an accumulated organic loading between 100 and 200 g COD/m2, respectively). Main conclusion of this work is that of CW-MFC could be used as an "alarm-tool" for qualitative continuous influent water quality assessment rather than a precise COD assessment tool due to a loss of precision after several weeks of operation.

q-bio.QM↗

arXiv2017

Complex spectral line profiles resulting from cryogenic deformation of the SINFONI/SPIFFI diffraction gratings

The integral field spectrograph, SPIFFI, has complex line profile shapes that vary with wavelength and pixel scale, the origins of which have been sought since the instrument construction. SPIFFI is currently operational as part of SINFONI at the VLT, and will be upgraded and incorporated into the new VLT instrument ERIS. We conducted an investigation of the line profiles based on measurements we could take with the instrument calibration unit, as well as laboratory measurements of spare SPIFFI optical components. Cryogenic measurements of a spare SPIFFI diffraction grating showed significant periodic deformation. These measurements match the cryogenic deformation expected from bimetallic bending stress based on a finite element analysis of the lightweighted grating blank. The periodic deformation of the grating surface gives rise to satellite peaks in the diffraction pattern of the grating. An optical simulation including the cryogenic grating deformation reproduces the behavior of the SPIFFI line profiles with both wavelength and pixel scale as measured with the instrument calibration unit. The conclusion is that cryogenic deformation of the diffraction gratings is responsible for the non-ideal line profiles, and that the diffraction gratings should be replaced during the upgrade for optimal instrument performance.

astro-ph.IM↗

arXiv2016

Making SPIFFI SPIFFIER: Upgrade of the SPIFFI instrument for use in ERIS and performance analysis from re-commissioning

SPIFFI is an AO-fed integral field spectrograph operating as part of SINFONI on the VLT, which will be upgraded and reused as SPIFFIER in the new VLT instrument ERIS. In January 2016, we used new technology developments to perform an early upgrade to optical subsystems in the SPIFFI instrument so ongoing scientific programs can make use of enhanced performance before ERIS arrives in 2020. We report on the upgraded components and the performance of SPIFFI after the upgrade, including gains in throughput and spatial and spectral resolution. We show results from re-commissioning, highlighting the potential for scientific programs to use the capabilities of the upgraded SPIFFI. Finally, we discuss the additional upgrades for SPIFFIER which will be implemented before it is integrated into ERIS.

astro-ph.IM↗

arXiv2016

MICADO: first light imager for the E-ELT

MICADO will equip the E-ELT with a first light capability for diffraction limited imaging at near-infrared wavelengths. The instrument's observing modes focus on various flavours of imaging, including astrometric, high contrast, and time resolved. There is also a single object spectroscopic mode optimised for wavelength coverage at moderately high resolution. This contribution provides an overview of the key functionality of the instrument, outlining the scientific rationale for its observing modes. The interface between MICADO and the adaptive optics system MAORY that feeds it is summarised. The design of the instrument is discussed, focussing on the optics and mechanisms inside the cryostat, together with a brief overview of the other key sub-systems.

astro-ph.IM↗

arXiv2014

An aperture masking mode for the MICADO instrument

MICADO is a near-IR camera for the Europea ELT, featuring an extended field (75" diameter) for imaging, and also spectrographic and high contrast imaging capabilities. It has been chosen by ESO as one of the two first-light instruments. Although it is ultimately aimed at being fed by the MCAO module called MAORY, MICADO will come with an internal SCAO system that will be complementary to it and will deliver a high performance on axis correction, suitable for coronagraphic and pupil masking applications. The basis of the pupil masking approach is to ensure the stability of the optical transfer function, even in the case of residual errors after AO correction (due to non common path errors and quasi-static aberrations). Preliminary designs of pupil masks are presented. Trade-offs and technical choices, especially regarding redundancy and pupil tracking, are explained.

astro-ph.IM↗

arXiv2013

The Upscattering of Ultracold Neutrons from the polymer $[C_6 H_{12}]_n$

It is generally accepted that the main cause of ultracold neutron (UCN) losses in storage traps is the upscattering to the thermal energy range by hydrogen adsorbed on the surface of the trap walls. However, the data on which this conclusion is based are poor and contradictory. Here, we report a measurement, performed at the Los Alamos National Laboratory UCN source, of the average energy of the flux of upscattered neutrons after the interaction of UCN with hydrogen bound in semicrystalline polymer PMP (tradename TPX), [C$_{6}$H$_{12}$]$_n$. Our analysis, performed with the MCNP code based on the application of the neutron scattering law to UCN upscattered by bound hydrogen in semicrystalline polyethylene, [C$_{2}$H$_{4}$]$_n$, leads us to a flux average energy value of 26$\pm3$ meV in contradiction with previously reported experimental values of 10 to 13 meV and in agreement with the theoretical models of neutron heating implemented in the MCNP code.

cond-mat.mtrl-sci↗

arXiv2008

Quadratic maps between modules

We introduce a notion of $R$-quadratic maps between modules over a commutative ring $R$ which generalizes several classical notions arising in linear algebra and group theory. On a given module $M$ such maps are represented by $R$-linear maps on a certain module $P^2_R(M)$. The structure of this module is described in term of the symmetric tensor square $Sym^2_R(M)$, the degree 2 component $Γ^2_R(M)$ of the divided power algebra over $M$, and the ideal $I_2$ of $R$ generated by the elements $r^2-r$, $r\in R$. The latter is shown to represent quadratic derivations on $R$ which arise in the theory of modules over square rings. This allows to extend the classical notion of nilpotent $R$-group of class 2 with coefficients in a 2-binomial ring $R$ to any ring $R$. We provide a functorial presentation of $I_2$ and several exact sequences embedding the modules $P^2_R(M)$ and $Γ^2_R(M)$.

math.AC↗

arXiv2008

Dimension quotients

We present two approaches, one homological and the other simplicial, for the investigation of dimension quotients of groups. The theory is illustrated, in particular, with a conceptual discussion of the fourth and fifth dimension quotients.

math.GR↗