arXiv subjects

M. Hofmann

Publications and source records attributed to M. Hofmann.

At least 19 recordsLinked to original sources

arXiv2026

Efficient formation and identification of single emitters in 4H-SiC following maskless heavy ion implantation

Single photon emitters in silicon carbide (SiC) are a leading platform for scalable quantum technologies. Recent interest has focused on oxygen-vacancy-related emitters, which show exceptionally high optical brightness and strong spin readout contrast. One barrier to scalable quantum devices based on these emitters is the challenge of maskless formation and rapid identification. Here, we demonstrate the formation of isolated bright single emitters in 4H-SiC, using low-energy maskless implantation of heavy ions bismuth and tin. Following annealing, up to 18% of implanted sites host a single emitter, with optimal yields achieved at annealing temperatures of 900-1000 degrees C. Occupancy statistics are modelled to estimate the implantation dose that maximises single-emitter yield. We introduce a tiered characterisation scheme, where a simple intensity threshold isolates single-emitter candidates, confirmed through photon correlation measurements, after which correlations between polarisation, saturation count rate and magnetic resonance frequency assign emitter type. It is shown that time-consuming low-temperature spectroscopy is not necessary to distinguish emitter types. Together, maskless heavy-ion implantation and selective screening offer an efficient route to forming and rapidly identifying near-surface single emitters for room-temperature quantum technologies such as quantum sensing.

quant-ph↗

arXiv2025

Chiral Electron Momentum Distribution upon Strong-Field Ionization of Atoms

We present a scheme to synthesize a three-dimensional laser field that produces a chiral electron momentum distribution upon strong-field ionization of atoms. Our approach employs two orthogonally propagating two-color laser beams. This results in a time-dependent three-dimensional electric field vector of the combined light field which varies for different positions within the focal volume. For each position, we conduct a simulation of the corresponding electron momentum distribution that includes non-adiabatic dynamics and Coulomb interaction after tunneling. For suitable laser parameters, only a small region of the focal volume contributes to the final momentum distribution. Thus, integrating over all position coordinates, a specific chiral laser field dominates. This leads to a volume-averaged electron momentum distribution, which is chiral, as well. This work will serve as a benchmark for future strong-field experiments aiming at the synthetization of well-defined, three-dimensional laser fields.

physics.atom-ph↗

arXiv2024

Sub-cycle resolved strong field ionization of chiral molecules and the origin of chiral photoelectron asymmetries

We report on strong field ionization of S- and R-propylene oxide in circularly polarized two-color laser fields. We find that the relative helicity of the two single color laser fields affects the photoelectron circular dichroism (PECD). Further, we observe that PECD is modulated as a function of the sub-cycle release time of the electron. Our experimental observations are successfully described by a heuristic model based on electrons in chiral initial states, which are selectively liberated by the laser field and, after tunneling, interact with an achiral Coulomb potential.

physics.atom-ph↗

arXiv2023

Ideal Two-Color Field Ratio for Holographic Angular Streaking of Electrons

We study strong field ionization of molecular hydrogen in highly intense co-rotating two-color (CoRTC) laser fields. The measured electron momentum distributions show alternating half-rings (AHR) that are characteristic for sub-cycle interference. We report on the role of the two-color field ratio for the visibility of this sub-cycle interference. The ratio of the peak electric field at 780 nm compared to the peak electric field at 390 nm $E_{780}/E_{390}$ is varied from 0.037 to 0.18. We find very good agreement with the results from our semiclassical simulation. We conclude that the AHR pattern is visible if two conditions are fulfilled. First, the amplitudes of the two pathways that lead to the sub-cycle interference have to be similar, which is the case for low two-color field ratios $E_{780}/E_{390}$. Second, the phase difference of the two pathways must be strong enough to allow for destructive interference, which is the case for high two-color field ratios $E_{780}/E_{390}$. For typical experimental conditions, we find that two-color field ratios $E_{780}/E_{390}$ in the range from 0.037 to 0.12 lead to good visibility of the AHR pattern. This guides future experiments to measure the Wigner time delay using holographic angular streaking of electrons (HASE).

physics.atom-ph↗

arXiv2023

Angular dependence of the Wigner time delay upon strong field ionization from an aligned p-orbital

We present experimental data on the strong-field ionization of the argon dimer in a co-rotating two-color (CoRTC) laser field. We observe a sub-cycle interference pattern in the photoelectron momentum distribution and infer the Wigner time delay using holographic angular streaking of electrons (HASE). We find that the Wigner time delay varies by more than 400 attoseconds as a function of the electron emission direction with respect to the molecular axis. The measured time delay is found to be independent of the parity of the dimer-cation and is in good agreement with our theoretical model based on the ionization of an aligned atomic p-orbital.

physics.atom-ph↗

arXiv2022

Experimental fingerprint of the electron's longitudinal momentum at the tunnel exit in strong field ionization

We present experimental data on the strong field tunnel ionization of argon in a counter-rotating two-color (CRTC) laser field. We find that the initial momentum component along the tunneling direction changes sign comparing the rising and the falling edge of the CRTC field. If the initial momentum at the tunnel exit points in the direction of the ion at the instant of tunneling, this manifests as an enhanced Coulomb interaction of the outgoing electron with its parent ion. Our conclusions are in accordance with predictions based on strong field approximation.

physics.atom-ph↗

arXiv2021

Fourfold Differential Photoelectron Circular Dichroism

We report on a joint experimental and theoretical study of photoelectron circular dichroism (PECD) in methyloxirane. By detecting O 1s-photoelectrons in coincidence with fragment ions, we deduce the molecule's orientation and photoelectron emission direction in the laboratory frame. Thereby, we retrieve a fourfold differential PECD clearly beyond 50%. This strong chiral asymmetry is reproduced by ab initio electronic structure calculations. Providing such a pronounced contrast makes PECD of fixed-in-space chiral molecules an even more sensitive tool for chiral recognition in the gas phase.

physics.atm-clus↗

arXiv2021

Photoelectron circular dichroism of O 1$s$-photoelectrons of uniaxially oriented trifluoromethyloxirane: Energy dependence and sensitivity to molecular configuration

The photoelectron circular dichroism (PECD) of the O 1s-photoelectrons of trifluoromethyloxirane(TFMOx) is studied experimentally and theoretically for different photoelectron kinetic energies. The experiments were performed employing circularly polarized synchrotron radiation and coincidentelectron and fragment ion detection using Cold Target Recoil Ion Momentum Spectroscopy. The corresponding calculations were performed by means of the Single Center method within the relaxed-core Hartree-Fock approximation. We concentrate on the energy dependence of the differential PECD of uniaxially oriented TFMOx molecules, which is accessible through the employed coincident detection. We also compare results for differential PECD of TFMOx to those obtained for the equivalent fragmentation channel and similar photoelectron kinetic energy of methyloxirane (MOx), studied in our previous work. Thereby, we investigate the influence of the substitution of the methyl-group by the trifluoromethyl-group at the chiral center on the molecular chiral response. Finally, the presently obtained angular distribution parameters are compared to those available in literature.

physics.chem-ph↗

arXiv2021

A new route for enantio-sensitive structure determination by photoelectron scattering on molecules in the gas phase

X-ray as well as electron diffraction are powerful tools for structure determination of molecules. Studies on randomly oriented molecules in the gas-phase address cases in which molecular crystals cannot be generated or the interaction-free molecular structure is to be addressed. Such studies usually yield partial geometrical information, such as interatomic distances. Here, we present a complementary approach, which allows obtaining insight to the structure, handedness and even detailed geometrical features of molecules in the gas phase. Our approach combines Coulomb explosion imaging, the information that is encoded in the molecular frame diffraction pattern of core-shell photoelectrons and ab initio computations. Using a loop-like analysis scheme we are able to deduce specific molecular coordinates with sensitivity even to the handedness of chiral molecules and the positions of individual atoms, as, e.g., protons.

physics.chem-ph↗

arXiv2020

Strong Differential Photoion Circular Dichroism in Strong-Field Ionization of Chiral Molecules

We investigate the differential ionization probability of chiral molecules in the strong field regime as a function of the helicity of the incident light. To this end, we analyze the fourfold ionization of bromochlorofluoromethane (CHBrClF) with subsequent fragmentation into four charged fragments and different dissociation channels of the singly ionized methyloxirane. We observe a variation of the differential ionization probability in a range of several percent. Accordingly, we conclude that the helicity of light is a quantity that should be considered for the theoretical description of the strong field ionization rate of chiral molecules.

physics.atom-ph↗

arXiv2017

Evidence of sub-surface energy storage in comet 67P from the outburst of 2016 July 3

On 3 July 2016, several instruments on board ESA's Rosetta spacecraft detected signs of an outburst event on comet 67P, at a heliocentric distance of 3.32 AU from the sun, outbound from perihelion. We here report on the inferred properties of the ejected dust and the surface change at the site of the outburst. The activity coincided with the local sunrise and continued over a time interval of 14 - 68 minutes. It left a 10m-sized icy patch on the surface. The ejected material comprised refractory grains of several hundred microns in size, and sub-micron-sized water ice grains. The high dust mass production rate is incompatible with the free sublimation of crystalline water ice under solar illumination as the only acceleration process. Additional energy stored near the surface must have increased the gas density. We suggest a pressurized sub-surface gas reservoir, or the crystallization of amorphous water ice as possible causes.

astro-ph.EP↗

arXiv2017

Seasonal Mass Transfer on the Nucleus of Comet 67P/Chuyumov-Gerasimenko

We collect observational evidence that supports the scheme of mass transfer on the nucleus of comet 67P/Churyumov-Gerasimenko. The obliquity of the rotation axis of 67P causes strong seasonal variations. During perihelion the southern hemisphere is four times more active than the north. Northern territories are widely covered by granular material that indicates back fall originating from the active south. Decimetre sized chunks contain water ice and their trajectories are influenced by an anti-solar force instigated by sublimation. OSIRIS observations suggest that up to 20 % of the particles directly return to the nucleus surface taking several hours of travel time. The back fall covered northern areas are active if illuminated but produce mainly water vapour. The decimetre chunks from the nucleus surface are too small to contain more volatile compounds such as CO 2 or CO. This causes a north-south dichotomy of the composition measurements in the coma. Active particles are trapped in the gravitational minimum of Hapi during northern winter. They are "shock frozen" and only reactivated when the comet approaches the sun after its aphelion passage. The insolation of the big cavity is enhanced by self-heating, i. e. reflection and IR radiation from the walls. This, together with the pristinity of the active back fall, explains the early observed activity of the Hapi region. Sobek may be a role model for the consolidated bottom of Hapi. Mass transfer in the case of 67P strongly influences the evolution of the nucleus and the interpretation of coma measurements.

astro-ph.EP↗

arXiv2017

The highly active Anhur-Bes regions in the 67P/Churyumov - Gerasimenko comet: results from OSIRIS/ROSETTA observations

The Southern hemisphere of the 67P/Churyumov-Gerasimenko comet has become visible from Rosetta only since March 2015. It was illuminated during the perihelion passage and therefore it contains the regions that experienced the strongest heating and erosion rate, thus exposing the subsurface most pristine material. In this work we investigate, thanks to the OSIRIS images, the geomorphology, the spectrophotometry and some transient events of two Southern hemisphere regions: Anhur and part of Bes. Bes is dominated by outcropping consolidated terrain covered with fine particle deposits, while Anhur appears strongly eroded with elongated canyon-like structures, scarp retreats, different kinds of deposits, and degraded sequences of strata indicating a pervasive layering. We discovered a new 140 m long and 10 m high scarp formed in the Anhur/Bes boundary during/after the perihelion passage, close to the area where exposed CO$_2$ and H$_2$O ices were previously detected. Several jets have been observed originating from these regions, including the strong perihelion outburst, an active pit, and a faint optically thick dust plume. We identify several areas with a relatively bluer slope (i.e. a lower spectral slope value) than their surroundings, indicating a surface composition enriched with some water ice. These spectrally bluer areas are observed especially in talus and gravitational accumulation deposits where freshly exposed material had fallen from nearby scarps and cliffs. The investigated regions become spectrally redder beyond 2 au outbound when the dust mantle became thicker, masking the underlying ice-rich layers.

astro-ph.EP↗

arXiv2017

Constraints on cometary surface evolution derived from a statistical analysis of 67P's topography

We present a statistical analysis of the distribution of large scale topographic features on comet 67P/Churyumov-Gerasimenko. We observe that the cumulative cliff height distribution across the surface follows a power law with a slope equal to -1.69 +- 0.02. When this distribution is studied independently for each region, we find a good correlation between the slope of the power law and the orbital erosion rate of the surface. For instance, the northern hemisphere topography is dominated by structures on the 100~m scale while the southern hemisphere topography, illuminated at perihelion, is dominated by 10~m scale terrain features. Our study suggest that the current size of a cliff is controlled not only by material cohesion but by the dominant erosional process in each region. This observation can be generalized to other comets, where we argue that primitive nuclei are characterized by the presence of large cliffs with a cumulative height power index equal to or above -1.5, while older, eroded cometary surfaces have a power index equal to or below -2.3. In effect, our model shows that a measure of the topography provides a quantitative assessment of a comet's erosional history, i.e. its evolutionary age.

astro-ph.EP↗

arXiv2017

Modeling of the outburst on July 29th, 2015 observed with OSIRIS cameras in the southern hemisphere of comet 67P/Churyumov-Gerasimenko

Images of the nucleus and the coma (gas and dust) of comet 67P/Churyumov- Gerasimenko have been acquired by the OSIRIS (Optical, Spectroscopic, and Infrared Remote Imaging System) cameras since March 2014 using both the Wide Angle Camera (WAC) and the Narrow Angle Camera (NAC). We use images from the NAC camera to study a bright outburst observed in the southern hemisphere on July 29, 2015. The high spatial resolution of the NAC is needed to localize the source point of the outburst on the surface of the nucleus. The heliocentric distance is 1.25 au and the spacecraft-comet distance is 186 km. Aiming to better understand the physics that led to the outgassing, we used the Direct Simulation Monte Carlo (DSMC) method to study the gas flow close to the nucleus and the dust trajectories. The goal is to understand the mechanisms producing the outburst. We reproduce the opening angle of the outburst in the model and constrain the outgassing ratio between the outburst source and the local region. The outburst is in fact a combination of both gas and dust, in which the active surface is approximately 10 times more active than the average rate found in the surrounding areas. We need a number of dust particles 7.83 $\times$ 10$^{11}$ - 6.90 $\times$ 10$^{15}$ (radius 1.97 - 185 {\mu}m), which corresponds to a mass of dust 220 - 21 $\times$ 10$^{3}$kg.

astro-ph.EP↗

arXiv2017

Distance determination method of dust particles using Rosetta OSIRIS NAC and WAC data

The ESA Rosetta spacecraft has been tracking its target, the Jupiter-family comet 67P/Churyumov-Gerasimenko, in close vicinity for over two years. It hosts the OSIRIS instruments: the Optical, Spectroscopic, and Infrared Remote Imaging System composed of two cameras, see e.g. Keller et al. (2007). In some imaging sequences dedicated to observe dust particles in the comet's coma, the two cameras took images at the same time. The aim of this work is to use these simultaneous double camera observations to calculate the dust particles' distance to the spacecraft. As the two cameras are mounted on the spacecraft with an offset of 70 cm, the distance of particles observed by both cameras can be determined by a shift of the particles' apparent trails on the images. This paper presents first results of the ongoing work, introducing the distance determination method for the OSIRIS instrument and the analysis of an example particle. We note that this method works for particles in the range of about 500 m - 6000 m from the spacecraft.

astro-ph.EP↗

arXiv2016

Decimetre-scaled spectrophotometric properties of the nucleus of comet 67P/Churyumov-Gerasimenko from OSIRIS observations

We present the results of the photometric and spectrophotometric properties of the 67P/Churyumov-Gerasimenko nucleus derived with the OSIRIS instrument during the closest fly-by over the comet, which took place on 14 th February 2015 at a distance of {\~} 6 km from the surface. Several images covering the 0{\deg}-33{\deg} phase angle range were acquired, and the spatial resolution achieved was 11 cm/pxl. The flown-by region is located on the big lobe of the comet, near the borders of the Ash, Apis and Imhotep regions. Our analysis shows that this region features local heterogeneities at the decimetre scale. We observed difference of reflectance up to 40{\%} between bright spots and sombre regions, and spectral slope variations up to 50{\%}. The spectral reddening effect observed globally on the comet surface by Fornasier et al. (2015) is also observed locally on this region, but with a less steep behaviour. We note that numerous metre-sized boulders, which exhibit a smaller opposition effect, also appear spectrally redder than their surroundings. In this region, we found no evidence linking observed bright spots to exposed water-ice-rich material. We fitted our dataset using the Hapke 2008 photometric model. The region overflown is globally as dark as the whole nucleus (geometric albedo of 6.8{\%}) and it has a high porosity value in the uppermost-layers (86{\%}). These results of the photometric analysis at a decimetre scale indicate that the photometric properties of the flown-by region are similar to those previously found for the whole nucleus.

astro-ph.EP↗

arXiv2016

Summer fireworks on comet 67P

During its two years mission around comet 67P/Churyumov-Gerasimenko, ESA's Rosetta spacecraft had the unique opportunity to follow closely a comet in the most active part of its orbit. Many studies have presented the typical features associated to the activity of the nucleus, such as localized dust and gas jets. Here we report on series of more energetic transient events observed during the three months surrounding the comet's perihelion passage in August 2015. We detected and characterized 34 outbursts with the Rosetta cameras, one every 2.4 nucleus rotation. We identified 3 main dust plume morphologies associated to these events: a narrow jet, a broad fan, and more complex plumes featuring both previous types together. These plumes are comparable in scale and temporal variation to what has been observed on other comets. We present a map of the outbursts source locations, and discuss the associated topography. We find that the spatial distribution sources on the nucleus correlates well with morphological region boundaries, especially in areas marked by steep scarps or cliffs. Outbursts occur either in the early morning or shortly after the local noon, indicating two potential processes: Morning outbursts may be triggered by thermal stresses linked to the rapid change of temperature, afternoon events are most likely related to the diurnal or seasonal heat wave reaching volatiles buried under the first surface layer. In addition, we propose that some events can be the result of a completely different mechanism, in which most of the dust is released upon the collapse of a cliff.

astro-ph.EP↗