arXiv subjects

M. I. Radulescu

Publications and source records attributed to M. I. Radulescu.

5 recordsLinked to original sources

arXiv2021

On the two separate decay time scales of a detonation wave modelled by the Burgers equation and their relation to its chaotic dynamics

This study uses a simplified detonation model to investigate the behaviour of detonations with galloping-like pulsations. The reactive Burgers equation is used for the hydrodynamic equation, coupled to a pulsed source whereby all the shocked reactants are simultaneously consumed at fixed time intervals. The model mimics the short periodic amplifications of the shock front followed by relatively lengthy decays seen in galloping detonations. Numerical simulations reveal a saw tooth evolution of the front velocity with a period-averaged detonation speed equal to the Chapman-Jouguet velocity. The detonation velocity exhibits two distinct groups of decay time scales, punctuated by reaction pulses. At each pulse, a rarefaction wave is created at the reaction front's last position. A characteristic investigation reveals that characteristics originating from the head of this rarefaction take 1.57 periods to reach and attenuate the detonation front, while characteristics at the tail take an additional period. The leading characteristics are amplified twice, by passing through the reaction fronts of subsequent pulses, before arriving at the shock front, whilst the trailing characteristics are amplified three times. This leads to the two distinct groups of time scales seen in the detonation front speed.

physics.flu-dyn↗

arXiv2020

Viscous jetting and Mach stem bifurcation in shock reflections: experiments and simulations

Shock reflection experiments are performed to study the large-scale convective mixing created by the forward jetting phenomenon. Experiments are performed at a wedge angle of $θ_{\mathrm{w}} = 30^{\circ}$ in nitrogen, propane-oxygen, and hexane with incident shock Mach numbers up to $M = 4$. Experiments are complimented by shock-resolved viscous simulations of triple point reflection in hexane for $M = 2.5$ to $6$. Inviscid simulations are performed over a wider range of parameters. Reynolds numbers up to $Re \lesssim 10^3$ are covered by simulations and Reynolds numbers of $Re \sim 10^5$ are covered by experiments. The study shows that as the isentropic exponent is lowered, and as the Mach number and Reynolds number are increased, the forward jet approaches the Mach stem, forms a vortex, deforms the shock front and in some cases bifurcates the Mach stem. Experiments show Kelvin-Helmholtz instabilities in the vortex cause large-scale convective mixing behind the Mach stem at low isentropic exponents ($γ\le 1.15$). The limits of Mach stem bifurcation (triple Mach-White reflection) in inviscid simulations are plotted in the phase space of $M$- $θ_{\mathrm{w}}$-$γ$. A maximum isentropic exponent of $γ\approx 1.3$ is found beyond which bifurcation does not occur (at $θ_{\mathrm{w}} = 30^{\circ}$). This closely matches the boundary between irregular/regular detonation cellular structures.

physics.flu-dyn↗

arXiv2020

The Effect of the Polytropic Index γ on the Structure of Gaseous Detonations

The present study aims to clarify the effect of the polytropic index (i.e., the ratio of specific heats in the context of a perfect gas) on the detonation structure. This is addressed by two-dimensional numerical simulations. To ease the clarification of the role of gasdynamics, a simple Arrhenius kinetic law is used for the chemical model. The activation energy, normalized by the shock temperature, is kept constant to obtain the same reaction rate sensitivity to temperature in all considered mixtures. This procedure dissociates the gasdynamic effects from the chemistry effects. The numerical results reveal that in mixtures with low polytropic indicies, the convective mixing is enhanced compared to mixtures with higher polytropic indicies. The mixing is evaluated using Lagrangian tracers. Moreover, mixtures with low polytropic indicies are found to have a shorter reaction length than mixtures with high polytropic indicies. Also, for the range of parameters considered in this study the results indicate that Mach stem bifurcation in detonations due to jetting is primarily a gasdynamic driven mechanism.

physics.flu-dyn↗

arXiv2020

Multiplicity of detonation regimes in systems with a multi-peaked thermicity

The study investigates detonations with multiple quasi-steady velocities that have been observed in the past in systems with multi-peaked thermicity, using Fickett's detonation analogue. A steady state analysis of the travelling wave predicts multiple states, however, all but the one with the highest velocity develop a singularity after the sonic point. Simulations show singularities are associated with a shock wave which overtakes all sonic points, establishing a detonation travelling at the highest of the predicted velocities. Under a certain parameter range, the steady-state detonation can have multiple sonic points and solutions. Embedded shocks can exist behind sonic points, where they link the weak and strong solutions. Sonic points whose characteristics do not diverge are found to be unstable, and to be the source of the embedded shocks. Numerical simulations show that these shocks are only quasi-stable. This is believed to be due in part to a feature of the model which permits shocks anywhere behind a sonic point.

physics.flu-dyn↗

arXiv2019

Non-equilibrium effects on thermal ignition using hard sphere molecular dynamics simulations

The present study addresses the role of molecular non-equilibrium effects in thermal ignition problems. We consider a single binary reaction of the form A+B -> C+C. Molecular dynamics calculations were performed for activation energies ranging between RT and 7.5RT and heat release of 2.5RT and 10RT. The evolution of up to 10,000 particles was calculated as the system undergoes a thermal ignition at constant volume. Ensemble averages of 100 calculations for each parameter set permitted to determine the ignition delay, along with a measure of the stochasticity of the process. A well behaved convergence to large system sizes is also demonstrated. The ignition delay calculations were compared with those obtained at the continuum level using rates derived from kinetic theory: the standard rate assuming that the distribution of the speed of the particles is the Maxwell-Boltzmann distribution, and the perturbed rates by Prigogine and Xhrouet [1] for an isothermal system, and Prigogine and Mahieu [2] for an energy releasing reaction, obtained by the Chapman-Enskog perturbation procedure. The molecular results were found in very good agreement with the latter at low temperatures, confirming that non-equilibrium effects promote the formation of energetic particles, that serve as seeds for subsequent reaction events: i.e., hot spots. This effect was found to lower the ignition delay by up to 30%. At high temperatures, the ignition delay obtained from the standard equilibrium rate was found to be up to 60% longer than the molecular calculations. This effect is due to the rapidity of the reactive collisions that do not allow the system to equilibrate. For this regime, none of the perturbation solutions obtained by the Chapman-Enskog procedure were valid. This study thus shows the importance of non-equilibrium effects in thermal ignition problems, for most temperatures of practical interest.

physics.chem-ph↗