arXiv subjects

M. I. Smith

Publications and source records attributed to M. I. Smith.

3 recordsLinked to original sources

arXiv2026

Direct measurement of the Orderphobic Effect

Fluctuation-induced forces, such as the Critical Casimir Effect (CCE), are fundamental mechanisms driving organization and self-assembly near second-order phase transitions. The existence of a comparable, universal force for systems undergoing a first-order transition has remained an unresolved fundamental question. The proposed Orderphobic Effect is one such potential mechanism. It arises from minimisation of the interfacial free energy between solutes that locally nucleate a disordered phase. Here, we report the first experimental demonstration and quantitative measurement of the Orderphobic Effect. Using a driven, non-equilibrium quasi-2D granular fluid undergoing a first-order order-disorder transition, we show that specifically designed solutes in an ordered phase nucleate a coexisting ``bubble'' of the disordered phase. By analysing its capillary fluctuations, we confirm that this phenomenon occurs due to the proximity to phase-coexistence, and we directly quantify the attractive force by measuring the interaction free energy between solutes. The observation of this general fluctuation-mediated force in a non-equilibrium steady state strongly supports its claimed universality. Our work establishes the Orderphobic Effect as the first-order equivalent to the CCE, providing a new, general route for controlling self-assembly and aggregation in soft matter and non-equilibrium systems.

cond-mat.stat-mech↗

arXiv2021

Topographic control of order in quasi-2D granular phase transitions

We experimentally investigate the nature of 2D phase transitions in a quasi-2D granular fluid. Using a surface decorated with periodically spaced dimples we observe interfacial tension between coexisting liquid and crystal phases. Measurements of the orientational and translational order parameters and associated susceptibilities indicate that the surface topography alters the order of the phase transition from a two-step continuous one to a first-order liquid-crystal one. The interplay of boundary inelasticity and geometry, either order-promoting or inhibiting, controls the wetting of the granular crystal / fluid. This order induced wetting has important consequences, determining how coexisting phases separate spatially.

cond-mat.soft↗

arXiv2011

Dilatancy in the flow and fracture of stretched colloidal suspensions

Concentrated particulate suspensions, commonplace in the pharmaceutical, cosmetic and food industries, display intriguing rheology. In particular, the dramatic increase in viscosity with strain rate (shear thickening and jamming) which is often observed at high volume fractions, is of strong practical and fundamental importance. Yet manufacture of these products and their subsequent dispensing often involves flow geometries substantially different from that of simple shear flow experiments. Here we show that the elongation and breakage of a filament of a colloidal fluid under tensile loading is closely related to the jamming transition seen in its shear rheology. However, the modified flow geometry reveals important additional effects. Using a model system with nearly hard-core interactions, we provide evidence of surprisingly strong viscoelasticity in such a colloidal fluid under tension. With high speed photography we also directly observe dilatancy and granulation effects, which lead to fracture above a critical elongation rate.

cond-mat.soft↗