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M. Ishikado

Publications and source records attributed to M. Ishikado.

At least 19 recordsLinked to original sources

Zr-based bulk metallic glass clamp cell for high-pressure inelastic neutron scattering

We report the fabrication and characterization of a Zr-based bulk metallic glass (Zr-BMG) clamp cell designed for high-pressure inelastic neutron scattering (INS) measurements. The INS spectra of the empty cell exhibit broad and featureless backgrounds, reflecting the amorphous structure of the Zr-BMG. Test measurements using a reference sample, CsFeCl$_{3}$, confirm that the neutron transmission of the Zr-BMG cell is significantly higher than that of a conventional monobloc CuBe clamp cell. These results demonstrate that the Zr-BMG clamp cell provides both enhanced neutron transparency and a clean background profile, thereby advancing high-pressure INS studies.

cond-mat.mtrl-sci

Magnetic Excitations of a Half-Filled Tl-based Cuprate

Strong electron correlations drive Mott insulator transitions. Yet, there exists no framework to classify Mott insulators by their degree of correlation. Cuprate superconductors, with their tunable doping and rich phase diagrams, offer a unique platform to investigate the evolution of these interactions. However, spectroscopic access to a clean half-filled Mott-insulating state is lacking in compounds with the highest superconducting onset temperature. To fill this gap, we introduce a pristine, half-filled thallium-based cuprate system, Tl$_2$Ba$_5$Cu$_4$O$_{x}$. Using high-resolution resonant inelastic x-ray scattering, we probe long-lived magnon excitations and uncover a pronounced kink in the magnon dispersion, marked by a simultaneous change in group velocity and lifetime broadening. Modeling the dispersion within a Hubbard-Heisenberg approach, we extract the interaction strength and compare it with other cuprate systems. Our results establish a cuprate universal relation between electron-electron interaction and magnon zone-boundary dispersion. Superconductivity seems to be optimal at intermediate correlation strength, suggesting an optimal balance between localization and itinerancy.

cond-mat.supr-con

High sensitivity of a future search for P-odd/T-odd interactions on the 0.75 eV $p$-wave resonance in $\vec{n}+^{139}\vec{\rm La}$ forward transmission determined using pulsed neutron beam

Neutron transmission experiments can offer a new type of highly sensitive search for time-reversal invariance violating (TRIV) effects in nucleon-nucleon interactions via the same enhancement mechanism observed for large parity violating (PV) effects in neutron-induced compound nuclear processes. In these compound processes, the TRIV cross-section is given as the product of the PV cross-section, a spin-factor $κ$, and a ratio of TRIV and PV matrix elements. We determined $κ$ to be $0.59\pm0.05$ for $^{139}$La+$n$ using both $(n, γ)$ spectroscopy and ($\vec{n}+^{139}\vec{\rm La}$) transmission. This result quantifies for the first time the high sensitivity of the $^{139}$La 0.75~eV $p$-wave resonance in a future search for P-odd/T-odd interactions in ($\vec{n}+^{139}\vec{\rm La}$) forward transmission.

nucl-ex

Spin dependence in the $p$-wave resonance of ${^{139}\vec{\rm{La}}+\vec{n}}$

We measured the spin dependence in a neutron-induced $p$-wave resonance by using a polarized epithermal neutron beam and a polarized nuclear target. Our study focuses on the 0.75~eV $p$-wave resonance state of $^{139}$La+$n$, where largely enhanced parity violation has been observed. We determined the partial neutron width of the $p$-wave resonance by measuring the spin dependence of the neutron absorption cross section between polarized $^{139}\rm{La}$ and polarized neutrons. Our findings serve as a foundation for the quantitative study of the enhancement effect of the discrete symmetry violations caused by mixing between partial amplitudes in the compound nuclei.

nucl-ex

Superconducting gap and pseudogap in the surface states of the iron-based superconductor PrFeAsO$_{1-y}$ studied by angle-resolved photoemission spectroscopy

In order to study the possible superconductivity at the polar surfaces of 1111-type iron-based superconductors, which is doped with a large amount of holes in spite of the electron doping in bulk materials, we have performed angle-resolved photoemission spectroscopy (ARPES) studies on superconducting PrFeAsO$_{1-y}$~crystals. We have indeed observed the opening of a superconducting gap on surface-derived hole pockets as well as on a bulk-derived hole pocket. The superconducting gap is found to open on the surface-derived hole pockets below the bulk $T_c$, which suggests that the surface superconductivity is possibly induced by proximity effect from the bulk. We have also observed the opening of a large pseudogap on the surface-derived hole pockets, which is similar to the pseudogap in 122-type bulk superconductors doped with a smaller amount of holes. This suggests that the opening of a large pseudogap is a characteristic property of hole-doped iron-based superconductors.

cond-mat.supr-con

$\mathbf{q}=\mathbf{0}$ long-range magnetic order in centennialite CaCu$_3$(OD)$_6$Cl$_2$$\cdot$0.6D$_2$O: A spin-1/2 perfect kagome antiferromagnet with $J_1$-$J_2$-$J_d$

Crystal and magnetic structures of the mineral centennialite CaCu$_3$(OH)$_6$Cl$_2\cdot0.6$H$_2$O are investigated by means of synchrotron x-ray diffraction and neutron diffraction measurements complemented by density functional theory (DFT) and pseudofermion functional renormalization group (PFFRG) calculations. CaCu$_3$(OH)$_6$Cl$_2\cdot0.6$H$_2$O crystallizes in the $P\bar{3}m1$ space group and Cu$^{2+}$ ions form a geometrically perfect kagome network with antiferromagnetic $J_1$. No intersite disorder between Cu$^{2+}$ and Ca$^{2+}$ ions is detected. CaCu$_3$(OH)$_6$Cl$_2\cdot0.6$H$_2$O enters a magnetic long-range ordered state below $T_\text{N}=7.2$~K, and the $\mathbf{q}=\mathbf{0}$ magnetic structure with negative vector spin chirality is obtained. The ordered moment at 0.3~K is suppressed to $0.58(2)μ_\text{B}$. Our DFT calculations indicate the presence of antiferromagnetic $J_2$ and ferromagnetic $J_d$ superexchange couplings of a strength which places the system at the crossroads of three magnetic orders (at the classical level) and a spin-$\frac{1}{2}$ PFFRG analysis shows a dominance of $\mathbf{q}=\mathbf{0}$ type magnetic correlations, consistent with and indicating proximity to the observed $\mathbf{q}=\mathbf{0}$ spin structure. The results suggest that this material is located close to a quantum critical point and is a good realization of a $J_1$-$J_2$-$J_d$ kagome antiferromagnet.

cond-mat.str-el

Spin gap and L modulated intensity at the low-energy incommensurate magnetic fluctuations in the superconducting state of Sr2RuO4

Low-energy incommensurate (IC) magnetic fluctuations in the multiband superconductor Sr$_2$RuO$_4$ is investigated by high-resolution inelastic neutron scattering measurements and random phase approximation (RPA) calculations. Below $T_\text{c}$, the substantial spin gap is observed at $\mathbf{Q}_\text{IC}=(0.3, 0.3, L)$ where the quasi-one-dimensional $α$ and $β$ sheets consisting of the Fermi surfaces are in good nesting conditions. $L$ modulated intensity of the low-energy IC magnetic fluctuations and our RPA calculations indicate that the superconducting gaps regarding the $α$ and $β$ sheets have the horizontal line nodes.

cond-mat.supr-con

Coexisting spin resonance and long-range magnetic order of Eu in EuRbFe$_4$As$_4$

Magnetic excitations and magnetic structure of EuRbFe$_4$As$_4$ were investigated by inelastic neutron scattering (INS), neutron diffraction, and random phase approximation (RPA) calculations. Below the superconducting transition temperature $T_\text{c}=36.5$~K, the INS spectra exhibit the neutron spin resonances at $Q_\text{res}=1.27(2)$~$\textÅ^{-1}$ and $1.79(3)$~$\textÅ^{-1}$. They correspond to the $\mathbf{Q}=(0.5,0.5,1)$ and $(0.5,0.5,3)$ nesting wave vectors, showing three dimensional nature of the band structure. The characteristic energy of the neutron spin resonance is $E_\text{res}=17.7(3)$~meV corresponding to $5.7(1)k_\text{B}T_\text{c}$. Observation of the neutron spin resonance mode and our RPA calculations in conjunction with the recent optical conductivity measurements are indicative of the $s_\pm$ superconducting pairing symmetry in EuRbFe$_4$As$_4$. In addition to the neutron spin resonance mode, upon decreasing temperature below the magnetic transition temperature $T_\text{N}=15$~K, the spin wave excitation originating in the long-range magnetic order of the Eu sublattice was observed in the low-energy inelastic channel. Single-crystal neutron diffraction measurements demonstrate that the magnetic propagation vector of the Eu sublattice is $\mathbf{k}=(0, 0, 0.25)$, representing the three-dimensional antiferromagnetic order. Linear spin wave calculations assuming the obtained magnetic structure with the intra- and inter-plane nearest neighbor exchange couplings of $J_1/k_\text{B}=-1.31$~K and $J_c/k_\text{B}=0.08$~K can reproduce quantitatively the observed spin wave excitation. Our results show that superconductivity and long-range magnetic order of Eu coexist in EuRbFe$_4$As$_4$ whereas the coupling between them is rather weak.

cond-mat.supr-con

Band Structure of Overdoped Cuprate Superconductors: Density Functional Theory Matching Experiments

A comprehensive angle resolved photoemission spectroscopy study of the band structure in single layer cuprates is presented with the aim of uncovering universal trends across different materials. Five different hole- and electron-doped cuprate superconductors (La$_{1.59}$Eu$_{0.2}$Sr$_{0.21}$CuO$_4$, La$_{1.77}$Sr$_{0.23}$CuO$_4$, Bi$_{1.74}$Pb$_{0.38}$Sr$_{1.88}$CuO$_{6+δ}$, Tl$_{2}$Ba$_{2}$CuO$_{6+δ}$, and Pr$_{1.15}$La$_{0.7}$Ce$_{0.15}$CuO$_{4}$) have been studied with special focus on the bands with predominately $d$-orbital character. Using light polarization analysis, the $e_g$ and $t_{2g}$ bands are identified across these materials. A clear correlation between the $d_{3z^2-r^2}$ band energy and the apical oxygen distance $d_\mathrm{A}$ is demonstrated. Moreover, the compound dependence of the $d_{x^2-y^2}$ band bottom and the $t_{2g}$ band top is revealed. Direct comparison to density functional theory (DFT) calculations employing hybrid exchange-correlation functionals demonstrates excellent agreement. We thus conclude that the DFT methodology can be used to describe the global band structure of overdoped single layer cuprates on both the hole and electron doped side.

cond-mat.supr-con

Quantum magnetisms in uniform triangular lattices Li2AMo3O8 (A = In, Sc)

Molecular based spin-1/2 triangular lattice systems such as LiZn$_2$Mo$_3$O$_8$ have attracted research interest. Distortions, defects, and intersite disorder are suppressed in such molecular-based magnets, and intrinsic geometrical frustration gives rise to unconventional and unexpected ground states. Li$_2$$A$Mo$_3$O$_8$ ($A$ = In or Sc) is such a compound where spin-1/2 Mo$_3$O$_{13}$ clusters in place of Mo ions form the uniform triangular lattice. Their ground states are different according to the $A$ site. Li$_2$InMo$_3$O$_8$ undergoes conventional $120^\circ$ long-range magnetic order below $T_\text{N}=12$~K whereas isomorphic Li$_2$ScMo$_3$O$_8$ exhibits no long-range magnetic order down to 0.5~K. Here, we report exotic magnetisms in Li$_2$InMo$_3$O$_8$ and Li$_2$ScMo$_3$O$_8$ investigated by muon spin rotation ($μ$SR) and inelastic neutron scattering (INS) spectroscopies using polycrystalline samples. Li$_2$InMo$_3$O$_8$ and Li$_2$ScMo$_3$O$_8$ show completely different behaviors observed in both $μ$SR and INS measurements, representing their different ground states. Li$_2$InMo$_3$O$_8$ exhibits spin wave excitation which is quantitatively described by the nearest neighbor anisotropic Heisenberg model based on the $120^\circ$ spin structure. In contrast, Li$_2$ScMo$_3$O$_8$ undergoes short-range magnetic order below 4~K with quantum-spin-liquid-like magnetic fluctuations down to the base temperature. Origin of the different ground states is discussed in terms of anisotropies of crystal structures and magnetic interactions.

cond-mat.str-el

Three-Dimensional Fermi Surface of Overdoped La-Based Cuprates

We present a soft x-ray angle-resolved photoemission spectroscopy study of the overdoped high-temperature superconductors La$_{2-x}$Sr$_x$CuO$_4$ and La$_{1.8-x}$Eu$_{0.2}$Sr$_x$CuO$_4$. In-plane and out-of-plane components of the Fermi surface are mapped by varying the photoemission angle and the incident photon energy. No $k_z$ dispersion is observed along the nodal direction, whereas a significant antinodal $k_z$ dispersion is identified. Based on a tight-binding parametrization, we discuss the implications for the density of states near the van-Hove singularity. Our results suggest that the large electronic specific heat found in overdoped La$_{2-x}$Sr$_x$CuO$_4$ can not be assigned to the van-Hove singularity alone. We therefore propose quantum criticality induced by a collapsing pseudogap phase as a plausible explanation for observed enhancement of electronic specific heat.

cond-mat.supr-con

Quasi-Static Internal Magnetic Field Detected in the Pseudogap Phase of Bi$_{2+x}$Sr$_{2-x}$CaCu$_2$O$_{8+δ}$ by $μ$SR

We report muon spin relaxation ($μ$SR) measurements of optimally-doped and overdoped Bi$_{2+x}$Sr$_{2-x}$CaCu$_2$O$_{8+δ}$ (Bi2212) single crystals that reveal the presence of a weak temperature-dependent quasi-static internal magnetic field of electronic origin in the superconducting (SC) and pseudogap (PG) phases. In both samples the internal magnetic field persists up to 160~K, but muon diffusion prevents following the evolution of the field to higher temperatures. We consider the evidence from our measurments in support of PG order parameter candidates, namely, electronic loop currents and magnetoelectric quadrupoles.

cond-mat.supr-con

Spin Resonance in the New-Structure-Type Iron-Based Superconductor CaKFe4As4

The dynamical spin susceptibility in the new-structure-type iron-based superconductor CaKFe$_4$As$_4$ was investigated by using a combination of inelastic neutron scattering (INS) measurements and random phase approximation (RPA) calculations. Powder INS measurements show that the spin resonance at $Q_\text{res}=1.17(1)$~$\textÅ^{-1}$, corresponding to the $(π,π)$ nesting wave vector in tetragonal notation, evolves below $T_\text{c}$. The characteristic energy of the spin resonance $E_\text{res}=12.5$~meV is smaller than twice the size of the superconducting gap ($2Δ$). The broad energy feature of the dynamical susceptibility of the spin resonance can be explained by the RPA calculations, in which the different superconducting gaps on different Fermi surfaces are taken into account. Our INS and PRA studies demonstrate that the superconducting pairing nature in CaKFe$_4$As$_4$ is the $s_\pm$ symmetry.

cond-mat.supr-con

Investigation of potential fluctuating intra-unit cell magnetic order in cuprates by muon spin relaxation

We report low temperature muon spin relaxation (muSR) measurements of the high-transition-temperature (Tc) cuprate superconductors Bi{2+x}Sr{2-x}CaCu2O{8+δ} and YBa2Cu3O6.57, aimed at detecting the mysterious intra-unit cell (IUC) magnetic order that has been observed by spin polarized neutron scattering in the pseudogap phase of four different cuprate families. A lack of confirmation by local magnetic probe methods has raised the possibility that the magnetic order fluctuates slowly enough to appear static on the time scale of neutron scattering, but too fast to affect $μ$SR or nuclear magnetic resonance (NMR) signals. The IUC magnetic order has been linked to a theoretical model for the cuprates, which predicts a long-range ordered phase of electron-current loop order that terminates at a quantum crictical point (QCP). Our study suggests that lowering the temperature to T ~ 25 mK and moving far below the purported QCP does not cause enough of a slowing down of fluctuations for the IUC magnetic order to become detectable on the time scale of muSR. Our measurements place narrow limits on the fluctuation rate of this unidentified magnetic order.

cond-mat.supr-con

Spin nematic susceptibility studied by inelastic neutron scattering in FeSe

Mechanism of unconventional superconductivity in FeSe has been intensely scrutinized recently because of a variety of exotic properties unprecedented for other iron-based superconductors. A central unanswered question concerns the origin of the interaction that causes the nematic transition at $T_s=90\,K$ without accompanying magnetic order. Elucidating the nature of spin excitations in the normal state is a key to addressing this issue. Here we report, from inelastic neutron-scattering measurements in FeSe single crystals, that high-energy spin excitation spectra of FeSe exhibit characteristic energy dependence with missing intensity at around 70-80$\,$meV, which are very different from other iron-based superconductors. Despite of the strongest electron correlations among the iron-based superconductor family, the spectra are qualitatively at variance with the local moment model and can be essentially described by the itinerant electron picture. Moreover, the dynamical spin susceptibility above $T_s$ is only weakly temperature dependent, which is in stark contrast to the Curie-Weiss behavior of the electronic nematic susceptibility, suggesting that the nematic transition is not likely driven by spin but by orbital degrees of freedom.

cond-mat.supr-con

Resonant inelastic x-ray scattering study of entangled spin-orbital excitations in superconducting PrFeAsO0.7

Low-energy electron excitation spectra were measured on a single crystal of a typical iron-based superconductor PrFeAsO$_{0.7}$ using resonant inelastic X-ray scattering (RIXS) at the Fe-$L_3$ edge. Characteristic RIXS features are clearly observed around 0.5, 1-1.5 and 2-3 eV energy losses. These excitations are analyzed microscopically with theoretical calculations using a 22-orbital model derived from first-principles electronic structure calculation. Based on the agreement with the experiment, the RIXS features are assigned to Fe-$d$ orbital excitations which, at low energies, are accompanied by spin flipping and dominated by Fe $d_{yz}$ and $d_{xz}$ orbital characters. Furthermore, our calculations suggest dispersive momentum dependence of the RIXS excitations below 0.5 eV, and predict remarkable splitting and merging of the lower-energy excitations in momentum space. Those excitations, which were not observed in the present experiment, highlight the potential of RIXS with an improved energy resolution to unravel new details of the electronic structure of the iron-based superconductors.

cond-mat.str-el

Magnetic form factor analysis on detwinned single crystal of BaFe$_2$As$_2$

We have performed neutron diffraction measurement on a single crystal of parent compound of iron-based superconductor, BaFe$_2$As$_2$ at 12~K. In order to investigate in-plane anisotropy of magnetic form factor in the antiferromagnetic phase, the detwinned single crystal is used in the measurement. The magnetic structure factor and magnetic form factor are well explained by the spin densities consisting of $3d_{yz}$ electrons with a fraction of about 40~\% and the electrons in the other four $3d$ orbitals with each fraction of about 15~\%. Such anisotropic magnetic form factor is qualitatively consistent with the anisotropic magnetic behaviors observed in the antiferromagnetic phase of the parent compound of iron-based superconductor.

cond-mat.supr-con

Cooperative order in the weakly magnetic domain of LaFeAsO$_{1-x}$F$_{x}$ near the doping phase boundary

Spatial phase separation into mesoscopic domains of non-magnetic [superconducting (SC) below Tc = 25.5 K] and two kinds of magnetic phases, one showing disordered spin density wave (d-SDW) order and another associated with glassy weak magnetism (WM), are observed below ~100 K by muon spin rotation (muSR) in LaFeAsO1-xFx for x = 0.057(3) which is near the boundary of these phases on the doping phase diagram. In contrast to the competing order observed in the regular SDW phase of Ba(Fe1-xCox)2As2, the WM domain exhibits cooperative coupling of superconducting and magnetic order parameters as inferred from strong diamagnetism and associated negative shift of muSR frequency just below Tc.

cond-mat.str-el