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M. J. Greenall

Publications and source records attributed to M. J. Greenall.

20 records · Page 2Linked to original sources

Fluid adsorption near an apex: Covariance between complete and critical wetting

Critical wetting is an elusive phenomenon for solid-fluid interfaces. Using interfacial models we show that the diverging length scales, which characterize complete wetting at an apex, precisely mimic critical wetting with the apex angle behaving as the contact angle. Transfer matrix, renormalization group (RG) and mean field analysis (MF) shows this covariance is obeyed in 2D, 3D and for long and short ranged forces. This connection should be experimentally accesible and provides a means of checking theoretical predictions for critical wetting.

cond-mat.stat-mech↗

Wedge covariance for 2D filling and wetting

A comprehensive theory of interfacial fluctuation effects occurring at 2D wedge (corner) filling transitions in pure (thermal disorder) and impure (random bond-disorder) systems is presented. Scaling theory and the explicit results of transfer matrix and replica trick studies of interfacial Hamiltonian models reveal that, for almost all examples of intermolecular forces, the critical behaviour at filling is fluctuation-dominated, characterised by universal critical exponents and scaling functions that depend only on the wandering exponent $ζ$. Within this filling fluctuation (FFL) regime, the critical behaviour of the mid-point interfacial height, probability distribution function, local compressibility and wedge free energy are identical to corresponding quantities predicted for the strong-fluctuation (SFL) regime for critical wetting transitions at planar walls. In particular the wedge free energy is related to the SFL regime point tension which is calculated for systems with random-bond disorder using the replica trick. The connection with the SFL regime for all these quantities can be expressed precisely in terms of special wedge covariance relations which complement standard scaling theory and restrict the allowed values of the critical exponents for both FFL filling and SFL critical wetting.

cond-mat.soft↗