arXiv subjects

M. J. Mumma

Publications and source records attributed to M. J. Mumma.

18 recordsLinked to original sources

arXiv2020

Unusually High CO Abundance of the First Active Interstellar Comet

Comets spend most of their lives at large distances from any star, during which time their interior compositions remain relatively unaltered. Cometary observations can therefore provide direct insight into the chemistry that occurred during their birth at the time of planet formation. To-date, there have been no confirmed observations of parent volatiles (gases released directly from the nucleus) of a comet from any planetary system other than our own. Here we present high-resolution, interferometric observations of 2I/Borisov, the first confirmed interstellar comet, obtained using the Atacama Large Millimeter/submillimeter Array (ALMA) on 15th-16th December 2019. Our observations reveal emission from hydrogen cyanide (HCN), and carbon monoxide (CO), coincident with the expected position of 2I/Borisov's nucleus, with production rates Q(HCN)=$(7.0\pm1.1)\times10^{23}$ s$^{-1}$ and Q(CO)=$(4.4\pm0.7)\times10^{26}$ s$^{-1}$. While the HCN abundance relative to water (0.06-0.16%) appears similar to that of typical, previously observed comets in our Solar System, the abundance of CO (35-105%) is among the highest observed in any comet within 2 au of the Sun. This shows that 2I/Borisov must have formed in a relatively CO-rich environment - probably beyond the CO ice-line in the very cold, outer regions of a distant protoplanetary accretion disk, as part of a population of small, icy bodies analogous to our Solar System's own proto-Kuiper Belt.

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arXiv2019

ALMA Autocorrelation Spectroscopy of Comets: The HCN/H^13CN ratio in C/2012 S1 (ISON)

The Atacama Large Millimeter/submillimeter Array (ALMA) is a powerful tool for high-resolution mapping of comets, but the main interferometer (comprised of 50x12-m antennas) is insensitive to the largest coma scales due to a lack of very short baselines. In this work, we present a new technique employing ALMA autocorrelation data (obtained simultaneously with the interferometric observations), effectively treating the entire 12-m array as a collection of single-dish telescopes. Using combined autocorrelation spectra from 28 active antennas, we recovered extended HCN coma emission from comet C/2012 S1 (ISON), resulting in a fourteen-fold increase in detected line brightness compared with the interferometer. This resulted in the first detection of rotational emission from H^13CN in this comet. Using a detailed coma radiative transfer model accounting for optical depth and non-LTE excitation effects, we obtained an H^12CN/H^13CN ratio of 88+-18, which matches the terrestrial value of 89, consistent with a lack of isotopic fractionation in HCN during comet formation in the protosolar accretion disk. The possibility of future discoveries in extended sources using autocorrelation spectroscopy from the main ALMA array is thus demonstrated.

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arXiv2017

Mapping Vinyl Cyanide and Other Nitriles in Titan's Atmosphere Using ALMA

Vinyl cyanide (C$_2$H$_3$CN) is theorized to form in Titan's atmosphere via high-altitude photochemistry and is of interest regarding the astrobiology of cold planetary surfaces due to its predicted ability to form cell membrane-like structures (azotosomes) in liquid methane. In this work, we follow up on the initial spectroscopic detection of C$_2$H$_3$CN on Titan by Palmer et al. (2017) with the detection of three new C$_2$H$_3$CN rotational emission lines at submillimeter frequencies. These new, high-resolution detections have allowed for the first spatial distribution mapping of C$_2$H$_3$CN on Titan. We present simultaneous observations of C$_2$H$_5$CN, HC$_3$N, and CH$_3$CN emission, and obtain the first (tentative) detection of C$_3$H$_8$ (propane) at radio wavelengths. We present disk-averaged vertical abundance profiles, two-dimensional spatial maps, and latitudinal flux profiles for the observed nitriles. Similarly to HC$_3$N and C$_2$H$_5$CN, which are theorized to be short-lived in Titan's atmosphere, C$_2$H$_3$CN is most abundant over the southern (winter) pole, whereas the longer-lived CH$_3$CN is more concentrated in the north. This abundance pattern is consistent with the combined effects of high-altitude photochemical production, poleward advection, and the subsequent reversal of Titan's atmospheric circulation system following the recent transition from northern to southern winter. We confirm that C$_2$H$_3$CN and C$_2$H$_5$CN are most abundant at altitudes above 200 km. Using a 300 km step model, the average abundance of C$_2$H$_3$CN is found to be $3.03\pm0.29$ ppb, with a C$_2$H$_5$CN/C$_2$H$_3$CN abundance ratio of $2.43\pm0.26$. Our HC$_3$N and CH$_3$CN spectra can be accurately modeled using abundance gradients above the tropopause, with fractional scale-heights of $2.05\pm0.16$ and $1.63\pm0.02$, respectively.

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arXiv2017

The 67P/Churyumov-Gerasimenko observation campaign in support of the Rosetta mission

We present a summary of the campaign of remote observations that supported the European Space Agency's Rosetta mission. Telescopes across the globe (and in space) followed comet 67P/Churyumov-Gerasimenko from before Rosetta's arrival until nearly the end of mission in September 2016. These provided essential data for mission planning, large-scale context information for the coma and tails beyond the spacecraft, and a way to directly compare 67P with other comets. The observations revealed 67P to be a relatively `well behaved' comet, typical of Jupiter family comets and with activity patterns that repeat from orbit-to-orbit. Comparison between this large collection of telescopic observations and the in situ results from Rosetta will allow us to better understand comet coma chemistry and structure. This work is just beginning as the mission ends -- in this paper we present a summary of the ground-based observations and early results, and point to many questions that will be addressed in future studies.

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arXiv2017

ALMA mapping of rapid gas and dust variations in comet C/2012 S1 (ISON): new insights into the origin of cometary HNC

Observations of the sungrazing comet C/2012 S1 (ISON) were carried out using the Atacama Large Millimeter/submillimeter Array (ALMA) at a heliocentric distance of 0.58-0.54 AU (pre-perihelion) on 2013 November 16-17. Temporally resolved measurements of the coma distributions of HNC, CH$_3$OH, H$_2$CO and dust were obtained over the course of about an hour on each day. During the period UT 10:10-11:00 on Nov. 16, the comet displayed a remarkable drop in activity, manifested as a $>42$% decline in the molecular line and continuum fluxes. The H$_2$CO observations are consistent with an abrupt, $\approx50$% reduction in the cometary gas production rate soon after the start of our observations. On Nov. 17, the total observed fluxes remained relatively constant during a similar period, but strong variations in the morphology of the HNC distribution were detected as a function of time, indicative of a clumpy, intermittent outflow for this species. Our observations suggest that at least part of the detected HNC originated from degradation of nitrogen-rich organic refractory material, released intermittently from confined regions of the nucleus. By contrast, the distributions of CH$_3$OH and H$_2$CO during the Nov. 17 observations were relatively uniform, consistent with isotropic outflow and stable activity levels for these species. These results highlight a large degree of variability in the production of gas and dust from comet ISON during its pre-perihelion outburst, consistent with repeated disruption of the nucleus interspersed with periods of relative quiescence.

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arXiv2017

Thermal physics of the inner coma: ALMA studies of the methanol distribution and excitation in comet C/2012 K1 (PanSTARRS)

We present spatially and spectrally-resolved observations of CH$_3$OH emission from comet C/2012 K1 (PanSTARRS) using The Atacama Large Millimeter/submillimeter Array (ALMA) on 2014 June 28-29. Two-dimensional maps of the line-of-sight average rotational temperature ($T_{rot}$) were derived, covering spatial scales $0.3''-1.8''$ (corresponding to sky-projected distances $ρ\sim500$-2500 km). The CH$_3$OH column density distributions are consistent with isotropic, uniform outflow from the nucleus, with no evidence for extended sources of CH$_3$OH in the coma. The $T_{rot}(ρ)$ radial profiles show a significant drop within a few thousand kilometers of the nucleus, falling from about 60 K to 20 K between $ρ=0$ and 2500 km on June 28, whereas on June 29, $T_{rot}$ fell from about 120 K to 40 K between $ρ=$ 0 km and 1000 km. The observed $T_{rot}$ behavior is interpreted primarily as a result of variations in the coma kinetic temperature due to adiabatic cooling of the outflowing gas, as well as radiative cooling of the CH$_3$OH rotational levels. Our excitation model shows that radiative cooling is more important for the $J=7-6$ transitions (at 338 GHz) than for the $K=3-2$ transitions (at 252 GHz), resulting in a strongly sub-thermal distribution of levels in the $J=7-6$ band at $ρ\gtrsim1000$ km. For both bands, the observed temperature drop with distance is less steep than predicted by standard coma theoretical models, which suggests the presence of a significant source of heating in addition to the photolytic heat sources usually considered.

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arXiv2016

Measuring the Distribution and Excitation of Cometary CH3OH Using ALMA

The Atacama Large Millimeter/submillimeter Array (ALMA) was used to obtain measurements of spatially and spectrally resolved CH$_3$OH emission from comet C/2012 K1 (PanSTARRS) on 28-29 June 2014. Detection of 12-14 emission lines of CH$_3$OH on each day permitted the derivation of spatially-resolved rotational temperature profiles (averaged along the line of sight), for the innermost 5000 km of the coma. On each day, the CH$_3$OH distribution was centrally peaked and approximately consistent with spherically symmetric, uniform outflow. The azimuthally-averaged CH$_3$OH rotational temperature ($T_{rot}$) as a function of sky-projected nucleocentric distance ($ρ$), fell by about 40 K between $ρ=0$ and 2500 km on 28 June, whereas on 29 June, $T_{rot}$ fell by about 50 K between $ρ=$0 km and 1500 km. A remarkable ($\sim50$ K) rise in $T_{rot}$ at $ρ=$1500-2500 km on 29 June was not present on 28 June. The observed variations in CH$_3$OH rotational temperature are interpreted primarily as a result of variations in the coma kinetic temperature due to adiabatic cooling, and heating through Solar irradiation, but collisional and radiative non-LTE excitation processes also play a role.

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arXiv2015

Ethyl cyanide on Titan: Spectroscopic detection and mapping using ALMA

We report the first spectroscopic detection of ethyl cyanide (C$_2$H$_5$CN) in Titan's atmosphere, obtained using spectrally and spatially resolved observations of multiple emission lines with the Atacama Large Millimeter/submillimeter array (ALMA). The presence of C$_2$H$_5$CN in Titan's ionosphere was previously inferred from Cassini ion mass spectrometry measurements of C$_2$H$_5$CNH$^+$. Here we report the detection of 27 rotational lines from C$_2$H$_5$CN (in 19 separate emission features detected at $>3σ$ confidence), in the frequency range 222-241 GHz. Simultaneous detections of multiple emission lines from HC$_3$N, CH$_3$CN and CH$_3$CCH were also obtained. In contrast to HC$_3$N, CH$_3$CN and CH$_3$CCH, which peak in Titan's northern (spring) hemisphere, the emission from C$_2$H$_5$CN is found to be concentrated in the southern (autumn) hemisphere, suggesting a distinctly different chemistry for this species, consistent with a relatively short chemical lifetime for C$_2$H$_5$CN. Radiative transfer models show that most of the C$_2$H$_5$CN is concentrated at altitudes 300-600 km, suggesting production predominantly in the mesosphere and above. Vertical column densities are found to be in the range (2-5)$\times10^{14}$ cm$^{-2}$.

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arXiv2014

ALMA measurements of the HNC and HC$_3$N distributions in Titan's atmosphere

We present spectrally and spatially-resolved maps of HNC and HC$_3$N emission from Titan's atmosphere, obtained using the Atacama Large Millimeter/submillimeter Array (ALMA) on 2013 November 17. These maps show anisotropic spatial distributions for both molecules, with resolved emission peaks in Titan's northern and southern hemispheres. The HC$_3$N maps indicate enhanced concentrations of this molecule over the poles, consistent with previous studies of Titan's photochemistry and atmospheric circulation. Differences between the spectrally-integrated flux distributions of HNC and HC$_3$N show that these species are not co-spatial. The observed spectral line shapes are consistent with HNC being concentrated predominantly in the mesosphere and above (at altitudes $z\gtrsim 400$ km), whereas HC$_3$N is abundant at a broader range of altitudes ($z\approx70$-600 km). From spatial variations in the HC$_3$N line profile, the locations of the HC$_3$N emission peaks are shown to be variable as a function of altitude. The peaks in the integrated emission from HNC and the line core (upper-atmosphere) component of HC$_3$N (at $z\gtrsim300$ km) are found to be asymmetric with respect to Titan's polar axis, indicating that the mesosphere may be more longitudinally-variable than previously thought. The spatially-integrated HNC and HC$_3$N spectra are modeled using the NEMESIS planetary atmosphere code and the resulting best-fitting disk-averaged vertical mixing ratio (VMR) profiles are found to be in reasonable agreement with previous measurements for these species. Vertical column densities of the best-fitting gradient models for HNC and HC$_3$N are $1.9\times10^{13}$ cm$^{-2}$ and $2.3\times10^{14}$ cm$^{-2}$, respectively.

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arXiv2014

Mapping the release of volatiles in the inner comae of comets C/2012 F6 (Lemmon) and C/2012 S1 (ISON) using the Atacama Large Millimeter/Submillimeter Array

Results are presented from the first cometary observations using the Atacama Large Millimeter/Submillimeter Array (ALMA), including measurements of the spatially-resolved distributions of HCN, HNC, H$_2$CO and dust within the comae of two comets: C/2012 F6 (Lemmon) and C/2012 S1 (ISON), observed at heliocentric distances of 1.5 AU and 0.54 AU, respectively. These observations (with angular resolution $\approx0.5''$), reveal an unprecedented level of detail in the distributions of these fundamental cometary molecules, and demonstrate the power of ALMA for quantitative measurements of the distributions of molecules and dust in the inner comae of typical bright comets. In both comets, HCN is found to originate from (or within a few hundred km of) the nucleus, with a spatial distribution largely consistent with spherically-symmetric, uniform outflow. By contrast, the HNC distributions are clumpy and asymmetrical, with peaks at cometocentric radii $\sim$500-1000~km, consistent with release of HNC in collimated outflow(s). Compared to HCN, the H$_2$CO distribution in comet Lemmon is very extended. The interferometric visibility amplitudes are consistent with coma production of H$_2$CO and HNC from unidentified precursor material(s) in both comets. Adopting a Haser model, the H$_2$CO parent scale-length is found to be a few thousand km in Lemmon and only a few hundred km in ISON, consistent with destruction of the precursor by photolysis or thermal degradation at a rate which scales in proportion to the Solar radiation flux.

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arXiv2012

The formation heritage of Jupiter Family Comet 10P/Tempel 2 as revealed by infrared spectroscopy

We present spectral and spatial information for major volatile species in Comet 10P/Tempel 2, based on high-dispersion infrared spectra acquired on UT 2010 July 26 (heliocentric distance Rh = 1.44 AU) and September 18 (Rh = 1.62 AU), following the comet's perihelion passage on UT 2010 July 04. The total production rate for water on July 26 was (1.90 +/- 0.12) x 10^28 molecules s-1, and abundances of six trace gases (relative to water) were: CH3OH (1.58% +/- 0.23), C2H6 (0.39% +/- 0.04), NH3 (0.83% +/- 0.20), and HCN (0.13% +/- 0.02). A detailed analysis of intensities for water emission lines provided a rotational temperature of 35 +/- 3 K. The mean OPR is consistent with nuclear spin populations in statistical equilibrium (OPR = 3.01 +/- 0.18), and the (1-sigma) lower bound corresponds to a spin temperature > 38 K. Our measurements were contemporaneous with a jet-like feature observed at optical wavelengths. The spatial profiles of four primary volatiles display strong enhancements in the jet direction, which favors release from a localized vent on the nucleus. The measured IR continuum is much more sharply peaked and is consistent with a dominant contribution from the nucleus itself. The peak intensities for H2O, CH3OH, and C2H6 are offset by ~200 km in the jet direction, suggesting the possible existence of a distributed source, such as the release of icy grains that subsequently sublimed in the coma. On UT September 18, no obvious emission lines were present in our spectra, nevertheless we obtained a 3-sigma upper limit Q(H2O) < 2.86 x 10^27 molecules s-1.

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arXiv2012

The chemical composition of CO-rich comet C/2009 P1 (Garradd) at Rh = 2.4 and 2.0 AU before perihelion

We quantified ten parent volatiles in comet C/2009 P1 (Garradd) before perihelion, through high-dispersion infrared spectra acquired with CRIRES at ESO's VLT on UT 2011 August 07 (Rh = 2.4 AU) and September 17-21 (Rh = 2.0 AU). On August 07, water was searched but not detected at an upper limit (3σ) of 2.1 \times 10^28 s-1, while ethane was detected with a production rate of 6.1 \times 10^26 s-1 (apparent mixing ratio > 2.90%). On September 17-21, the mean production rate for water was 8.4 \times 10^28 s-1, and abundance ratios (relative to water) of detected trace species were: CO (12.51%), CH3OH (3.90%), CH4 (1.24%), C2H6 (1.01%) and HCN (0.36%). Upper limits (3σ) to abundances for four minor species were: NH3 (1.55%), C2H2 (0.13%), HDO (0.89%) and OCS (0.20%). Given the relatively large heliocentric distance, we explored the effect of water not being fully sublimated within our FOV and identified the 'missing' water fraction needed to reconcile the retrieved abundance ratios with the mean values found for "organics-normal". The individual spatial profiles of parent volatiles and the continuum displayed rather asymmetric outgassing. Indications of H2O and CO gas being released in different directions suggest different active vents and/or the possible existence of polar and apolar ice aggregates in the nucleus. The high fractional abundance of CO identifies comet C/2009 P1 as a CO-rich comet.

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arXiv2012

First Detection of Near-Infrared Line Emission from Organics in Young Circumstellar Disks

We present an analysis of high-resolution spectroscopy of several bright T Tauri stars using the VLT/CRIRES and Keck/NIRSPEC spectrographs, revealing the first detections of emission from HCN and C2H2 in circumstellar disks at near-infrared wavelengths. Using advanced data reduction techniques we achieve a dynamic range with respect to the disk continuum of ~500 at 3 microns, revealing multiple emission features of H2O, OH, HCN, and C2H2. We also present stringent upper limits for two other molecules thought to be abundant in the inner disk, CH4 and NH3. Line profiles for the different detected molecules are broad but centrally peaked in most cases, even for disks with previously determined inclinations of greater than 20 degrees, suggesting that the emission has both a Keplerian and non-Keplerian component as observed previously for CO emission. We apply two different modeling strategies to constrain the molecular abundances and temperatures: we use a simplified single-temperature LTE slab model with a Gaussian line profile to make line identifications and determine a best-fit temperature and initial abundance ratios, and we compare these values with constraints derived from a detailed disk radiative transfer model assuming LTE excitation but utilizing a realistic temperature and density structure. Abundance ratios from both sets of models are consistent with each other and consistent with expected values from theoretical chemical models, and analysis of the line shapes suggests the molecular emission originates from within a narrow region in the inner disk (R < 1 AU).

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arXiv2011

Temporal and Spatial Aspects of Gas Release During the 2010 Apparition of Comet 103P/Hartley-2

We report measurements of eight primary volatiles (H2O, HCN, CH4, C2H6, CH3OH, C2H2, H2CO, and NH3) and two product species (OH and NH2) in comet 103P/Hartley-2 using high dispersion infrared spectroscopy. We quantified the long- and short-term behavior of volatile release over a three-month interval that encompassed the comet's close approach to Earth, its perihelion passage, and flyby of the comet by the Deep Impact spacecraft during the EPOXI mission. We present production rates for individual species, their mixing ratios relative to water, and their spatial distributions in the coma on multiple dates. The production rates for water, ethane, HCN, and methanol vary in a manner consistent with independent measures of nucleus rotation, but mixing ratios for HCN, C2H6, & CH3OH are independent of rotational phase. Our results demonstrate that the ensemble average composition of gas released from the nucleus is well defined, and relatively constant over the three-month interval (September 18 through December 17). If individual vents vary in composition, enough diverse vents must be active simultaneously to approximate (in sum) the bulk composition of the nucleus. The released primary volatiles exhibit diverse spatial properties which favor the presence of separate polar and apolar ice phases in the nucleus, establish dust and gas release from icy clumps (and also, directly from the nucleus), and provide insights into the driver for the cyanogen (CN) polar jet. The spatial distributions of C2H6 & HCN along the near-polar jet (UT 19.5 October) and nearly orthogonal to it (UT 22.5 October) are discussed relative to the origin of CN. The ortho-para ratio (OPR) of water was 2.85 \pm 0.20; the lower bound (2.65) defines Tspin > 32 K. These values are consistent with results returned from ISO in 1997.

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arXiv2010

Swift UVOT Grism Spectroscopy of Comets: A First Application to C/2007 N3 (Lulin)

We observed comet C/2007 N3 (Lulin) twice on UT 28 January 2009, using the UV grism of the Ultraviolet and Optical Telescope (UVOT) on board the Swift Gamma Ray Burst space observatory. Grism spectroscopy provides spatially resolved spectroscopy over large apertures for faint objects. We developed a novel methodology to analyze grism observations of comets, and applied a Haser comet model to extract production rates of OH, CS, NH, CN, C3, C2, and dust. The water production rates retrieved from two visits on this date were $6.7 \pm 0.7$ and 7.9 $\pm$ 0.7 x 1E28 molecules s-1, respectively. Jets were sought (but not found) in the white-light and `OH' images reported here, suggesting that the jets reported by Knight and Schleicher (2009) are unique to CN. Based on the abundances of its carbon-bearing species, comet Lulin is `typical' (i.e., not `depleted') in its composition.

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arXiv2009

Water in the Near IR spectrum of Comet 8P/Tuttle

High resolution spectra of Comet 8P/Tuttle were obtained in the frequency range 3440.6-3462.6 cm-1 on 3 January 2008 UT using CGS4 with echelle grating on UKIRT. In addition to recording strong solar pumped fluorescent (SPF) lines of H2O, the long integration time (152 miutes on target) enabled eight weaker H2O features to be assigned, most of which had not previously been identified in cometary spectra. These transitions, which are from higher energy upper states, are similar in character to the so-called 'SH' lines recorded in the post Deep Impact spectrum of comet Tempel 1 (Barber et al., 2007). We have identified certain characteristics that these lines have in common, and which in addition to helping to define this new class of cometary line, give some clues to the physical processes involved in their production. Finally, we derive an H2O rotational temperature of 62+/- K and a water production rate of (1.4+/-0.3)E28 molecules/s.

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arXiv2008

The unusual volatile composition of the Halley-type comet 8P/Tuttle: Addressing the existence of an Inner Oort Cloud

We measured organic volatiles (CH4, CH3OH, C2H6, H2CO), CO, and water in comet 8P/Tuttle, a comet from the Oort cloud reservoir now in a short-period Halley-type orbit. We compare its composition with two other comets in Halley-type orbits, and with comets of the "organics-normal" and "organics-depleted" classes. Chemical gradients are expected in the comet-forming region of the proto-planetary disk, and an individual comet should reflect its specific heritage. If Halley-type comets came from the inner Oort cloud as proposed, we see no common characteristics that could distinguish such comets from those that were stored in the outer Oort cloud.

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arXiv2008

The Peculiar Volatile Composition of Comet 8P/Tuttle: A Contact Binary of Chemically Distinct Cometesimals?

We report measurements of eight native (i.e., released directly from the comet nucleus) volatiles (H2O, HCN, CH4, C2H2, C2H6, CO, H2CO, and CH3OH) in comet 8P/Tuttle using NIRSPEC at Keck 2. Comet Tuttle reveals a truly unusual composition, distinct from that of any comet observed to date at infrared wavelengths. The prominent enrichment of methanol relative to water contrasts the depletions of other molecules, especially C2H2 and HCN. We suggest that the nucleus of 8P/Tuttle may contain two cometesimals characterized by distinct volatile composition. The relative abundances C2/CN, C2/OH, and CN/OH in 8P/Tuttle (measured at optical/near-UV wavelengths) differ substantially from the mixing ratios of their potential parents (C2H2/HCN, C2H2/H2O, and HCN/H2O) found in this work. Based on this comparison, our results do not support C2H2 and HCN being the principal precursors for respectively C2 and CN in Tuttle. The peculiar native composition observed in 8P/Tuttle (compared to other comets) provides new strong evidence for chemical diversity in the volatile materials stored in comet nuclei. We discuss the implications of this diversity for expected variations in the deuterium enrichment of water among comets.

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