arXiv subjects

M. Jaafar

Publications and source records attributed to M. Jaafar.

4 recordsLinked to original sources

arXiv2020

A multi-technique approach to understanding delithiation damage in LiCoO2 thin films

We report on the delithiation of LiCoO2 thin films using oxalic acid (C2H2O4) with the goal of understanding the structural degradation of an insertion oxide associated with Li chemical extraction. Using a multi-technique approach that includes synchrotron radiation x-ray diffraction, scanning electron microscopy, micro Raman spectroscopy, photoelectron spectroscopy and conductive atomic force microscopy we reveal the balance between selective Li extraction and structural damage. We identify three different delithiation regimes, related to surface processes, bulk delithiation and damage generation. We find that only a fraction of the grains is affected by the delithiation process, which may create local inhomogeneities. The chemical route to Li extraction provides additional opportunities to investigate delithiation while avoiding the complications associated with electrolyte breakdown and could simplify in situ measurements.

cond-mat.mtrl-sci↗

arXiv2020

Improved graphene blisters by ultrahigh pressure sealing

Graphene is a very attractive material for nanomechanical devices and membrane applications. Graphene blisters based on silicon oxide micro-cavities are a simple but relevant example of nanoactuators. A drawback of this experimental set up is that gas leakage through the graphene-SiO2 interface contributes significantly to the total leak rate. Here we study the diffusion of air from pressurized graphene drumheads on SiO2 micro-cavities and propose a straightforward method to improve the already strong adhesion between graphene and the underlying SiO2 substrate, resulting in reduced leak rates. This is carried out by applying controlled and localized ultrahigh pressure (> 10 GPa) with an Atomic Force Microscopy diamond tip. With this procedure, we are able to significantly approach the graphene layer to the SiO2 surface around the drumheads, thus enhancing the interaction between them allowing us to better seal the graphene-SiO2 interface, which is reflected in up to ~ 4 times lower leakage rates. Our work opens an easy way to improve the performance of graphene as a gas membrane on a technological relevant substrate such as SiO2.

cond-mat.mtrl-sci↗

arXiv2010

Control of the chirality and polarity of magnetic vortices in triangular nanodots

Magnetic vortex dynamics in lithographically prepared nanodots is currently a subject of intensive research, particularly after recent demonstration that the vortex polarity can be controlled by in-plane magnetic field. This has stimulated the proposals of non-volatile vortex magnetic random access memories. In this work, we demonstrate that triangular nanodots offer a real alternative where vortex chirality, in addition to polarity, can be controlled. In the static regime, we show that vortex chirality can be tailored by applying in-plane magnetic field, which is experimentally imaged by means of Variable-Field Magnetic Force Microscopy. In addition, the polarity can be also controlled by applying a suitable out-of-plane magnetic field component. The experiment and simulations show that to control the vortex polarity, the out-of-plane field component, in this particular case, should be higher than the in-plane nucleation field. Micromagnetic simulations in the dynamical regime show that the magnetic vortex polarity can be changed with short-duration magnetic field pulses, while longer pulses change the vortex chirality.

cond-mat.mtrl-sci↗

arXiv2007

Remanence of Ni nanowire arrays: Influence of size and labyrinth magnetic structure

The influence of the macroscopic size of the Ni nanowire array system on their remanence state has been investigated. A simple magnetic phenomenological model has been developed to obtain the remanence as a function of the magnetostatic interactions in the array. We observe that, due to the long range of the dipolar interactions between the wires, the size of the sample strongly influence the remanence of the array. On the other hand, the magnetic state of nanowires has been studied by variable field magnetic force microscopy for different remanent states. The distribution of nanowires with the magnetization in up or down directions and the subsequent remanent magnetization has been deduced from the magnetic images. The existence of two short-range magnetic orderings with similar energies can explain the typical labyrinth pattern observed in magnetic force microscopy images of the nanowire arrays.

cond-mat.mtrl-sci↗