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M. Küppers

Publications and source records attributed to M. Küppers.

At least 19 recordsLinked to original sources

In-flight calibration of ESA Hera's HyperScout-H imager

ESA's Hera space mission is on its way to the mission target, the binary asteroid (65803) Didymos. HyperScout-H, one of the instruments onboard Hera, is a hyperspectral imager operating in the visible and near-infrared regions between 0.65 and 0.95 microns. HyperScout-H will enable a detailed assessment of the composition of both objects, Didymos and its satellite Dimorphos, the characterization of space weathering effects, and the possible presence of exogenous material on their surfaces. To monitor instrument functionality, calibration exposures are acquired regularly. This article describes the in-flight calibrations carried out for HyperScout-H during the commissioning and cruise phases. Bias and dark exposures, as well as stellar field observations, were acquired several times after launch. We update the calibration data and monitor instrument performance in the space environment. In five images, the surface of Mars fills the entire field of view, enabling cross-validation of HyperScout-H results with those reported by other Mars missions. The calibration data indicate that the bias pattern is stable, the dark current remains negligible for short exposures, and the detector response is highly linear. We quantify the field-of-view alignment and geometric distortion, and evaluate the point spread function based on the stellar field observations. Stellar observations and Mars swing-by data provide updated radiometric calibration constants, suggesting that in-flight conditions have slightly modified the detector's spectral response. In-flight calibrations are essential to ensure data quality and reliability. The results obtained for HyperScout-H demonstrate that the instrument can achieve its scientific goals in observations of the Didymos-Dimorphos system.

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Cometary surface dust layers built out of millimetre-scale aggregates: dependence of modelled cometary gas production on the layer transport properties

The standard approach to obtaining knowledge about the properties of the surface layer of a comet from observations of gas production consists of two stages. First, various thermophysical models are used to calculate gas production for a few sets of parameters. Second, a comparison of observations and theoretical predictions is performed. This approach is complicated because the values of many model characteristics are known only approximately. Therefore, it is necessary to investigate the sensitivity of the simulated outgassing to variations in the properties of the surface layer. This problem was recently considered by us for aggregates up to tens of microns in size. For millimetre-size aggregates, a qualitative extension of the method used to model the structural characteristics of the layer is required. It is also necessary to study the role of radiative thermal conductivity, which may play an important role for such large particles. We investigated layers constructed from large aggregates and having various thicknesses and porosity and evaluated the effective sublimation of water ice at different heliocentric distances. For radiative conductivity, approximate commonly used models and the complicated model based on the Dense Medium Radiative Transfer theory were compared. It was shown that for millimetre-size aggregates careful consideration of the radiative thermal conductivity is required since this mechanism of energy transfer may change the resulting gas productivity by several times. We demonstrate that our model is more realistic for an evolved comet than simple models parameterising the properties of the cometary surface layer, yet maintains comparable computational complexity.

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Water, hydrogen cyanide, carbon monoxide, and dust production from distant comet 29P/Schwassmann-Wachmann 1

29P/Schwassmann-Wachmann 1 is a distant Centaur/comet, showing persistent CO-driven activity and frequent outbursts. We used the Herschel space observatory in 2010, 2011, and 2013 to observe H$_2$O and NH$_3$ and to image the dust coma. Observations with the IRAM 30 m were undertaken in 2007, 2010, 2011, and 2021 to monitor the CO production rate and to search for HCN. Modeling was performed to constrain the size of the sublimating icy grains and to derive the dust production rate. HCN is detected for the first time in comet 29P (at 5$σ$ in the line area). H$_2$O is detected as well, but not NH$_3$. H$_2$O and HCN line shapes differ strongly from the CO line shape, indicating that these two species are released from icy grains. CO production rates are in the range (2.9-5.6) $\times$ 10$^{28}$ s$^{-1}$ (1400--2600 kg s$^{-1}$). A correlation between the CO production rate and coma brightness is observed, as is a correlation between CO and H$_2$O production. The correlation obtained between the excess of CO production and excess of dust brightness with respect to the quiescent state is similar to that established for the continuous activity of comet Hale-Bopp. The measured $Q$(H$_2$O)/$Q$(CO) and $Q$(HCN)/$Q$(CO) production rate ratios are 10.0 $\pm$ 1.5 % and 0.12 $\pm$ 0.03 %, respectively, averaging the April-May 2010 measurements ($Q$(H$_2$O) = (4.1 $\pm$ 0.6) $\times$ 10$^{27}$ s$^{-1}$, $Q$(HCN) = (4.8 $\pm$ 1.1) $\times$ 10$^{25}$ s$^{-1}$). We derive three independent and similar values of the effective radius of the nucleus, $\sim$ 31 $\pm$ 3 km. The inferred dust mass-loss rates during quiescent phases are in the range 30-120 kg s$^{-1}$, indicating a dust-to-gas mass ratio $<$ 0.1 during quiescent activity. We conclude that strong local heterogeneities exist on the surface of 29P, with quenched dust activity from most of the surface, but not in outbursting regions.

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ESASky SSOSS: Solar System Object Search Service and the case of Psyche

We introduce in this work the Solar System Object Search Service (SSOSS), a service aimed at providing the scientific community with a search service for all potential detections of SSOs among the ESA astronomy archival imaging data. We illustrate its functionalities using the case of asteroid (16) Psyche, for which no information in the far-IR (70-500 μm) has previously been reported, to derive its thermal properties in preparation for the upcoming NASA Psyche mission. This service performs a geometrical cross-match of the orbital path of each object with respect to the public high-level imaging footprints stored in the ESA archives. For this first release, three missions were chosen: XMM-Newton, the Hubble Space Telescope (HST), and Herschel Observatory. We present a catalog listing all potential detections of asteroids within estimated limiting magnitude or flux limit in Herschel, XMM-Newton, and HST archival imaging data, including 909 serendipitous detections in Herschel images, 985 in XMM-Newton Optical Monitor camera images, and over 32,000 potential serendipitous detections in HST images. We also present a case study: the analysis of the thermal properties of Psyche from four serendipitous Herschel detections, combined with previously published thermal IR measurements. We see strong evidence for an unusual drop in (hemispherical spectral) emissivity, from 0.9 at 100 μm down to about 0.6 at 350 μm, followed by a possible but not well-constrained increase towards 500 μm, comparable to what was found for Vesta. The combined thermal data set puts a strong constraint on Psyche's thermal inertia (between 20 to 80$J m^{-2} s^{-1/2} K^{-1}$) and favours an intermediate to low level surface roughness (below 0.4 for the rms of surface slopes).

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Linking surface morphology, composition, and activity on the nucleus of 67P/Churyumov-Gerasimenko

The Rosetta space probe accompanied comet 67P/Churyumov-Gerasimenko for more than two years, obtaining an unprecedented amount of unique data of the comet nucleus and inner coma. This work focuses identifying the source regions of faint jets and outbursts and on studying the spectrophotometric properties of some outbursts. We use observations acquired with the OSIRIS/NAC camera during July-October 2015, that is, close to perihelion. More than 200 jets of different intensities were identified directly on the nucleus. Some of the more intense outbursts appear spectrally bluer than the comet dark terrain in the vivible-to-near-infrared region. We attribute this spectral behavior to icy grains mixed with the ejected dust. Some of the jets have an extremely short lifetime. They appear on the cometary surface during the color sequence observations, and vanish in less than some few minutes after reaching their peak. We also report a resolved dust plume observed in May 2016 at a resolution of 55 cm/pixel, which allowed us to estimate an optical depth of $\sim$0.65 and an ejected mass of $\sim$ 2200 kg. We present the results on the location, duration, and colors of active sources on the nucleus of 67P from the medium-resolution (i.e., 6-10 m/pixel) images acquired close to perihelion passage. The observed jets are mainly located close to boundaries between different morphological regions. Jets depart not only from cliffs, but also from smooth and dust-covered areas, from fractures, pits, or cavities that cast shadows and favor the recondensation of volatiles. This study shows that faint jets or outbursts continuously contribute to the cometary activity close to perihelion passage, and that these events are triggered by illumination conditions. Faint jets or outbursts are not associated with a particular terrain type or morphology.

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Tensile Strength of 67P/Churyumov-Gerasimenko Nucleus Material from Overhangs

We directly measure twenty overhanging cliffs on the surface of comet 67P/Churyumov-Gerasimenko extracted from the latest shape model and estimate the minimum tensile strengths needed to support them against collapse under the comet's gravity. We find extremely low strengths of around one Pa or less (one to five Pa, when scaled to a metre length). The presence of eroded material at the base of most overhangs, as well as the observed collapse of two features and implied previous collapse of another, suggests that they are prone to failure and that true material strengths are close to these lower limits (although we only consider static stresses and not dynamic stress from, for example, cometary activity). Thus, a tensile strength of a few pascals is a good approximation for the tensile strength of 67P's nucleus material, which is in agreement with previous work. We find no particular trends in overhang properties with size, over the $\sim10-100$ m range studied here, or location on the nucleus. There are no obvious differences, in terms of strength, height or evidence of collapse, between the populations of overhangs on the two cometary lobes, suggesting that 67P is relatively homogenous in terms of tensile strength. Low material strengths are supportive of cometary formation as a primordial rubble pile or by collisional fragmentation of a small (tens of km) body.

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Constraints on cometary surface evolution derived from a statistical analysis of 67P's topography

We present a statistical analysis of the distribution of large scale topographic features on comet 67P/Churyumov-Gerasimenko. We observe that the cumulative cliff height distribution across the surface follows a power law with a slope equal to -1.69 +- 0.02. When this distribution is studied independently for each region, we find a good correlation between the slope of the power law and the orbital erosion rate of the surface. For instance, the northern hemisphere topography is dominated by structures on the 100~m scale while the southern hemisphere topography, illuminated at perihelion, is dominated by 10~m scale terrain features. Our study suggest that the current size of a cliff is controlled not only by material cohesion but by the dominant erosional process in each region. This observation can be generalized to other comets, where we argue that primitive nuclei are characterized by the presence of large cliffs with a cumulative height power index equal to or above -1.5, while older, eroded cometary surfaces have a power index equal to or below -2.3. In effect, our model shows that a measure of the topography provides a quantitative assessment of a comet's erosional history, i.e. its evolutionary age.

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Seasonal Mass Transfer on the Nucleus of Comet 67P/Chuyumov-Gerasimenko

We collect observational evidence that supports the scheme of mass transfer on the nucleus of comet 67P/Churyumov-Gerasimenko. The obliquity of the rotation axis of 67P causes strong seasonal variations. During perihelion the southern hemisphere is four times more active than the north. Northern territories are widely covered by granular material that indicates back fall originating from the active south. Decimetre sized chunks contain water ice and their trajectories are influenced by an anti-solar force instigated by sublimation. OSIRIS observations suggest that up to 20 % of the particles directly return to the nucleus surface taking several hours of travel time. The back fall covered northern areas are active if illuminated but produce mainly water vapour. The decimetre chunks from the nucleus surface are too small to contain more volatile compounds such as CO 2 or CO. This causes a north-south dichotomy of the composition measurements in the coma. Active particles are trapped in the gravitational minimum of Hapi during northern winter. They are "shock frozen" and only reactivated when the comet approaches the sun after its aphelion passage. The insolation of the big cavity is enhanced by self-heating, i. e. reflection and IR radiation from the walls. This, together with the pristinity of the active back fall, explains the early observed activity of the Hapi region. Sobek may be a role model for the consolidated bottom of Hapi. Mass transfer in the case of 67P strongly influences the evolution of the nucleus and the interpretation of coma measurements.

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Distance determination method of dust particles using Rosetta OSIRIS NAC and WAC data

The ESA Rosetta spacecraft has been tracking its target, the Jupiter-family comet 67P/Churyumov-Gerasimenko, in close vicinity for over two years. It hosts the OSIRIS instruments: the Optical, Spectroscopic, and Infrared Remote Imaging System composed of two cameras, see e.g. Keller et al. (2007). In some imaging sequences dedicated to observe dust particles in the comet's coma, the two cameras took images at the same time. The aim of this work is to use these simultaneous double camera observations to calculate the dust particles' distance to the spacecraft. As the two cameras are mounted on the spacecraft with an offset of 70 cm, the distance of particles observed by both cameras can be determined by a shift of the particles' apparent trails on the images. This paper presents first results of the ongoing work, introducing the distance determination method for the OSIRIS instrument and the analysis of an example particle. We note that this method works for particles in the range of about 500 m - 6000 m from the spacecraft.

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Decimetre-scaled spectrophotometric properties of the nucleus of comet 67P/Churyumov-Gerasimenko from OSIRIS observations

We present the results of the photometric and spectrophotometric properties of the 67P/Churyumov-Gerasimenko nucleus derived with the OSIRIS instrument during the closest fly-by over the comet, which took place on 14 th February 2015 at a distance of {\~} 6 km from the surface. Several images covering the 0°-33° phase angle range were acquired, and the spatial resolution achieved was 11 cm/pxl. The flown-by region is located on the big lobe of the comet, near the borders of the Ash, Apis and Imhotep regions. Our analysis shows that this region features local heterogeneities at the decimetre scale. We observed difference of reflectance up to 40{\%} between bright spots and sombre regions, and spectral slope variations up to 50{\%}. The spectral reddening effect observed globally on the comet surface by Fornasier et al. (2015) is also observed locally on this region, but with a less steep behaviour. We note that numerous metre-sized boulders, which exhibit a smaller opposition effect, also appear spectrally redder than their surroundings. In this region, we found no evidence linking observed bright spots to exposed water-ice-rich material. We fitted our dataset using the Hapke 2008 photometric model. The region overflown is globally as dark as the whole nucleus (geometric albedo of 6.8{\%}) and it has a high porosity value in the uppermost-layers (86{\%}). These results of the photometric analysis at a decimetre scale indicate that the photometric properties of the flown-by region are similar to those previously found for the whole nucleus.

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Are fractured cliffs the source of cometary dust jets ? Insights from OSIRIS/Rosetta at 67P

Dust jets, i.e. fuzzy collimated streams of cometary material arising from the nucleus, have been observed in-situ on all comets since the Giotto mission flew by comet 1P/Halley in 1986. Yet their formation mechanism remains unknown. Several solutions have been proposed, from localized physical mechanisms on the surface/sub-surface (see review in Belton (2010)) to purely dynamical processes involving the focusing of gas flows by the local topography (Crifo et al. 2002). While the latter seems to be responsible for the larger features, high resolution imagery has shown that broad streams are composed of many smaller features (a few meters wide) that connect directly to the nucleus surface. We monitored these jets at high resolution and over several months to understand what are the physical processes driving their formation, and how this affects the surface. Using many images of the same areas with different viewing angles, we performed a 3-dimensional reconstruction of collimated jets, and linked them precisely to their sources on the nucleus. Results.We show here observational evidence that the Northern hemisphere jets of comet 67P arise from areas with sharp topographic changes and describe the physical processes involved. We propose a model in which active cliffs are the main source of jet-like features, and therefore the regions eroding the fastest on comets. We suggest that this is a common mechanism taking place on all comets.

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Gravitational slopes, geomorphology, and material strengths of the nucleus of comet 67P/Churyumov-Gerasimenko from OSIRIS observations

We study the link between gravitational slopes and the surface morphology on the nucleus of comet 67P/Churyumov-Gerasimenko and provide constraints on the mechanical properties of the cometary material. We computed the gravitational slopes for five regions on the nucleus that are representative of the different morphologies observed on the surface, using two shape models computed from OSIRIS images by the stereo-photoclinometry (SPC) and stereo-photogrammetry (SPG) techniques. We estimated the tensile, shear, and compressive strengths using different surface morphologies and mechanical considerations. The different regions show a similar general pattern in terms of the relation between gravitational slopes and terrain morphology: i) low-slope terrains (0-20 deg) are covered by a fine material and contain a few large ($>$10 m) and isolated boulders, ii) intermediate-slope terrains (20-45 deg) are mainly fallen consolidated materials and debris fields, with numerous intermediate-size boulders from $<$1 m to 10 m for the majority of them, and iii) high-slope terrains (45-90 deg) are cliffs that expose a consolidated material and do not show boulders or fine materials. The best range for the tensile strength of overhangs is 3-15 Pa (upper limit of 150 Pa), 4-30 Pa for the shear strength of fine surface materials and boulders, and 30-150 Pa for the compressive strength of overhangs (upper limit of 1500 Pa). The strength-to-gravity ratio is similar for 67P and weak rocks on Earth. As a result of the low compressive strength, the interior of the nucleus may have been compressed sufficiently to initiate diagenesis, which could have contributed to the formation of layers. Our value for the tensile strength is comparable to that of dust aggregates formed by gravitational instability and tends to favor a formation of comets by the accrection of pebbles at low velocities.

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Temporal morphological changes in the Imhotep region of comet 67P/Churyumov-Gerasimenko

We report on the first major temporal morphological changes observed on the surface of the nucleus of comet 67P/Churyumov-Gerasimenko, in the smooth terrains of the Imhotep region. We use images of the OSIRIS cameras onboard Rosetta to follow the temporal changes from 24 May 2015 to 11 July 2015. The morphological changes observed on the surface are visible in the form of roundish features, which are growing in size from a given location in a preferential direction, at a rate of 5.6 - 8.1$\times$10$^{-5}$ m s$^{-1}$ during the observational period. The location where changes started and the contours of the expanding features are bluer than the surroundings, suggesting the presence of ices (H$_2$O and/or CO$_2$) exposed on the surface. However, sublimation of ices alone is not sufficient to explain the observed expanding features. No significant variations in the dust activity pattern are observed during the period of changes.

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Spectrophotometric properties of the nucleus of comet 67P/Churyumov-Gerasimenko from the OSIRIS instrument onboard the ROSETTA spacecraft

The Rosetta mission of the European Space Agency has been orbiting the comet 67P/Churyumov-Gerasimenko (67P) since August 2014 and is now in its escort phase. A large complement of scientific experiments designed to complete the most detailed study of a comet ever attempted are onboard Rosetta. We present results for the photometric and spectrophotometric properties of the nucleus of 67P derived from the OSIRIS imaging system, which consists of a Wide Angle Camera (WAC) and a Narrow Angle Camera (NAC). The disk-averaged phase function of the nucleus of 67P shows a strong opposition surge with a G parameter value of -0.13$\pm$0.01 in the HG system formalism and an absolute magnitude $H_v(1,1,0)$ = 15.74$\pm$0.02 mag. The integrated spectrophotometry in 20 filters covering the 250-1000 nm wavelength range shows a red spectral behavior, without clear absorption bands except for a potential absorption centered at $\sim$ 290 nm that is possibly due to SO$_2$ ice. The nucleus shows strong phase reddening, with disk-averaged spectral slopes increasing from 11\%/(100 nm) to 16\%/(100 nm) in the 1.3$^{\circ}$--54$^{\circ}$ phase angle range. The geometric albedo of the comet is 6.5$\pm$0.2\% at 649 nm, with local variations of up to $\sim$ 16\% in the Hapi region. From the disk-resolved images we computed the spectral slope together with local spectrophotometry and identified three distinct groups of regions (blue, moderately red, and red). The Hapi region is the brightest, the bluest in term of spectral slope, and the most active surface on the comet. Local spectrophotometry shows an enhancement of the flux in the 700-750 nm that is associated with coma emissions.

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Herschel observations of gas and dust in comet C/2006 W3 (Christensen) at 5 AU from the Sun

We aimed to measure the H2O and dust production rates in C/2006 W3 (Christensen) with the Herschel Space Observatory at a heliocentric distance of ~ 5 AU. We have searched for emission in the H2O and NH3 ground-state rotational transitions at 557 GHz and 572 GHz, simultaneously, with HIFI onboard Herschel on UT 1.5 September 2010. Photometric observations of the dust coma in the 70 and 160 μm channels were acquired with the PACS instrument on UT 26.5 August 2010. A tentative 4-σ H2O line emission feature was found in the spectra obtained with the HIFI wide-band and high-resolution spectrometers, from which we derive a water production rate of $2.0(5) \times 10^{27}$ molec. s$^{-1}$. A 3-σ upper limit for the ammonia production rate of <$1.5 \times 10^{27}$ molec. s$^{-1}$ is obtained taking into account the contribution from all hyperfine components. The blueshift of the water line detected by HIFI suggests preferential emission from the subsolar point. However, it is also possible that water sublimation occurs in small ice-bearing grains that are emitted from an active region on the nucleus surface at a speed of ~ 0.2 km s$^{-1}$. The dust thermal emission was detected in the 70 and 160 μm filters, with a more extended emission in the blue channel. The dust production rates, obtained for a dust size distribution index that explains the fluxes at the photocenters of the PACS images, lie in the range 70-110 kg s$^{-1}$. Scaling the CO production rate measured post-perihelion at 3.20 and 3.32 AU, these values correspond to a dust-to-gas production rate ratio in the range 0.3-0.4. The dust production rates derived in August 2010 are roughly one order of magnitude lower than in September 2009, suggesting that the dust-to-gas production rate ratio remained approximately constant during the period when the activity became increasingly dominated by CO outgassing.

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Searches for HCl and HF in comets 103P/Hartley 2 and C/2009 P1 (Garradd) with the Herschel space observatory

HCl and HF are expected to be the main reservoirs of fluorine and chlorine wherever hydrogen is predominantly molecular. They are found to be strongly depleted in dense molecular clouds, suggesting freeze-out onto grains in such cold environments. We can then expect that HCl and HF were also the major carriers of Cl and F in the gas and icy phases of the outer solar nebula, and were incorporated into comets. We aimed to measure the HCl and HF abundances in cometary ices as they can provide insights on the halogen chemistry in the early solar nebula. We searched for the J(1-0) lines of HCl and HF at 626 and 1232 GHz, respectively, using the HIFI instrument on board the Herschel Space Observatory. HCl was searched for in comets 103P/Hartley 2 and C/2009 P1 (Garradd), whereas observations of HF were conducted in comet C/2009 P1. In addition, observations of H$_2$O and H$_2^{18}$O lines were performed in C/2009 P1 to measure the H$_2$O production rate. Three lines of CH$_3$OH were serendipitously observed in the HCl receiver setting. HCl is not detected, whereas a marginal (3.6-$σ$) detection of HF is obtained. The upper limits for the HCl abundance relative to water are 0.011% and 0.022%, for 103P and C/2009 P1, respectively, showing that HCl is depleted with respect to the solar Cl/O abundance by a factor more than 6$^{+6}_{-3}$ in 103P, where the error is related to the uncertainty in the chlorine solar abundance. The marginal HF detection obtained in C/2009 P1 corresponds to an HF abundance relative to water of (1.8$\pm$0.5) $\times$ 10$^{-4}$, which is approximately consistent with a solar photospheric F/O abundance. The observed depletion of HCl suggests that HCl was not the main reservoir of chlorine in the regions of the solar nebula where these comets formed. HF was possibly the main fluorine compound in the gas phase of the outer solar nebula.

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Herschel and IRAM-30m Observations of Comet C/2012 S1 (ISON) at 4.5 AU from the Sun

Our goal was to characterize the distant gaseous and dust activity of comet C\2012 S1 (ISON), inbound, from observations of H2O, CO and the dust coma in the far-infrared and submillimeter domains. In this paper, we report observations undertaken with the Herschel Space Observatory on 8 & 13 March 2013 (rh = 4.54 - 4.47AU) and with the 30m telescope of Institut de Radioastronomie Millimétrique (IRAM) in March and April 2013 (rh = 4.45 - 4.18 AU). The HIFI instrument aboard Herschel was used to observe the H$_{2}$O $1_{10}-1_{01}$ line at 557 GHz, whereas images of the dust coma at 70 and 160 μm were acquired with the PACS instrument. Spectra acquired at the IRAM 30m telescope cover the CO J(2-1) line at 230.5 GHz. The spectral observations were analysed with excitation and radiative transfer models. A model of dust thermal emission taking into account a range of dust sizes is used to analyse the PACS maps. While H$_{2}$O was not detected in our 8 March 2013 observation, we derive a sensitive 3 $σ$ upper limit of QH$_{2}$O < 3.5 x 10$^{26}$ molecules/s for this date. A marginal 3.2 $σ$ detection of CO is found, corresponding to a CO production rate of QCO = 3.5 x 10$^{27}$ molecules/s. The Herschel PACS measurements show a clear detection of the coma and tail in both the 70 μm and 160 μm maps. Under the assumption of a 2 km radius nucleus, we infer dust production rates in the range 10 - 13 kg/s or 40 - 70 kg/s depending on whether a low or high gaseous activity from the nucleus surface is assumed. We constrain the size distribution of the emitted dust by comparing PACS 70 and 160 μm data, and considering optical data. Size indices between -4 and -3.6 are suggested. The morphology of the tail observed on 70 μm images can be explained by the presence of grains with ages older than 60 days.

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A survey of volatile species in Oort cloud comets C/2001 Q4 (NEAT) and C/2002 T7 (LINEAR) at millimeter wavelengths

The line emission in the coma was measured in the comets C/2001 Q4 (NEAT) and C/2002 T7 (LINEAR), that were observed on five consecutive nights, 7-11 May 2004, at heliocentric distances of 1.0 and 0.7 AU, respectively, by means of high-resolution spectroscopy using the 10-m Submillimeter Telescope (SMT). We present a search for six parent- and product-volatile species (HCN, H2CO, CO, CS, CH3OH, and HNC) in both comets. Multiline observations of the CH3OH J = 5-4 series allow us to estimate the rotational temperature using the rotation diagram technique. We derive rotational temperatures of 54(9) K for C/2001 Q4 (NEAT) and 119(34) K for C/2002 T7 (LINEAR) that are roughly consistent with observations of other comets at similar distances from the Sun. The gas production rates of material are computed using a spherically symmetric molecular excitation code that includes collisions between neutrals and electrons. We find an HCN production rate of 2.96(5)e26 molec.s-1 for comet C/2001 Q4 (NEAT), corresponding to a mixing ratio with respect to H2O of 1.12(2)e-3. The mean HCN production rate during the observing period is 4.54(10)e26 molec.s-1 for comet C/2002 T7 (LINEAR), which gives a Q_HCN/Q_H2O mixing ratio of 1.51(3)e-3. With systematically lower mixing ratios in comet C/2001 Q4 (NEAT), production rate ratios of the observed species with respect to H2O lie within the typical ranges of dynamically new comets in both objects. We find a relative low abundance of CO in C/2001 Q4 (NEAT) compared to the observed range in other comets based on millimeter/submillimeter observations, and a significant upper limit on the CO production in C/2002 T7 (LINEAR) is derived. Depletion of CO suggests partial evaporation from the surface layers during previous visits to the outer Solar System and agrees with previous measurements of dynamically new comets.

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