Informing spectral models for dense plasmas with K-edge absorption measurements of warm dense copper
Warm dense matter remains a challenging regime to characterize experimentally and to model with predictive accuracy. Recent experimental platforms have been developed to generate, characterize, and diagnose uniform warm dense matter, enabling detailed comparisons with models. Here, we present experiments conducted at the OMEGA laser facility that compress and heat a buried layer target to warm dense matter conditions, where the targets are heated to temperatures of approximately 20 eV and compressed to densities of 25 g/cm^3. We probe the warm dense plasma using x-ray absorption spectroscopy, using the K-edge and bound-bound absorption features to constrain the temperature and charge state distribution of the plasma. We compare these measurements with two types of models: collisional-radiative models with detailed electronic structure and ad-hoc density effects, and a multi-ion model based on density functional theory in combination with excited-state projector augmented-wave potentials. Neither approach fully reproduces the observed data, We show that the broad structure and position of the K-edge region can be modeled using density functional theory in combination with excited-state projector augmented-wave potentials. The density functional theory results are contrasted with a collisional-radiative model approach that incorporates ad-hoc density effects, which show incomplete agreement with the experimental observations, highlighting a need for improved density-dependent atomic modeling in warm dense plasmas.