arXiv subjects

M. L. R. van 't Hoff

Publications and source records attributed to M. L. R. van 't Hoff.

6 recordsLinked to original sources

arXiv2026

Complex Organic Molecules in Protostars with ALMA Spectral Surveys (COMPASS) V. Tracing cavity walls and shocked knots with nonthermally desorbed CH$_3$OH in BHR71-IRS1

Complex organic molecules are detected in both cold molecular clouds and the warm inner regions of protostars. Whether they are eventually inherited by protostars and planets or whether their chemistry is reset by in situ reactions remains unclear. Understanding the desorption mechanisms of these molecules is essential for tracing their chemical evolution. As part of the ALMA Large Program Complex Organic Molecules in Protostars with ALMA Spectral Surveys (COMPASS), we investigate the CH$_3$OH emission that extends beyond the hot corino of BHR71-IRS1. We identified extended CH$_3$OH emission around BHR71-IRS1. We assessed characteristic emission structures by applying a principal component analysis. The physical properties of their line-emitting gas were derived under the local thermodynamic equilibrium (LTE) assumption through both rotational diagram and spectral modeling analyses. In total, 26 extended CH$_3$OH lines have been detected. These emission lines are distributed across (1) X-shaped cavity walls, (2) northern and southern shocked knots, and (3) eastern and southeastern components. The cavity walls exhibit excitation temperatures of $\sim$ 25~K and column densities of $\sim$ 10$^{14}$~cm$^{-2}$, while the knots show relatively higher excitation temperatures (70$-$120~K) and column densities ($10^{14}-10^{16}$~cm$^{-2}$). The physical properties of eastern and southeastern components are not well constrained under LTE conditions. Plausible desorption mechanisms are evaluated by comparing the physical parameters with model predictions. The low excitation temperatures and narrow line widths in the cavity walls favor a reactive desorption scenario driven by far-ultraviolet irradiation from IRS1. In contrast, the knots with higher excitation temperatures and column densities support the dust sputtering scenario induced by C-type shocks.

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arXiv2026

Complex Organic Molecules in Protostars with ALMA Spectral Surveys (COMPASS) -- IV. Methyl cyanide isotopologues toward BHR71-IRS1

Methyl cyanide is one of the most abundant nitrogen-bearing complex organic molecules observed in the gas phase around low- and high-mass protostars. However, very few observations exist with a broad enough frequency coverage and sufficiently high sensitivity to systematically characterize its minor isotopologues toward such regions. We add to this number by analyzing data toward BHR71-IRS1 taken as part of the Complex Organic Molecules in Protostars with ALMA Spectral Surveys (COMPASS) Large Program over a ~33 GHz frequency range. We studied as many isotopologues of methyl cyanide as possible toward BHR71-IRS1. We found the column densities and excitation temperatures via spectral fitting and assuming local thermodynamic equilibrium. We then compared the derived column density ratios with those toward IRAS 16293-2422 A and B, V883 Ori, G31.41+0.31, and Sgr B2(N2b). We detect CH3CN, CH3CN $v_8$=1, 13-CH3CN, CH3-13-CN, CH3C-15-N, CH2DCN, and CHD2CN. The column density ratio of 13-CH3CN/CH3-13-CN is around unity, in agreement with previous observations. The CH2DCN/CH3CN ratios are similar for all the low-mass objects but are ~1 order of magnitude higher than those toward Sgr B2(N2b). This could be due to a warmer pre-stellar phase or a different formation timescale of Sgr B2(N2b). The D/H ratios found from methyl cyanide isotopologues agree well with those of methanol toward BHR71-IRS1, likely pointing to the formation and deuteration of methyl cyanide in a similar star-formation phase as methanol (i.e., the pre-stellar phase). We find an increase in the methyl cyanide D/H ratios with the number of deuterium atoms, which suggests that the deuterated isotopologues may form later in the pre-stellar phase. Future COMPASS studies will increase the sample size of low-mass systems with methyl cyanide analysis and potentially examine some of the trends observed here statistically.

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arXiv2026

Complex Organic Molecules in Protostars with ALMA Spectral Surveys (COMPASS): I. Overview of the ALMA Large Program

It remains a fundamental research question in astrochemistry to characterize the inventory of complex organic molecules formed during the early stages of star formation, which may affect the eventual chemical composition of protoplanetary disks and potentially planets. The Atacama Large Millimeter/submillimeter Array (ALMA) provides the angular resolution and sensitivity to zoom in on the hot (T > 100 K) gas surrounding embedded solar-type protostars and chart their molecular inventories with high accuracy. The ALMA Large Program Complex Organic Molecules in Protostars with ALMA Spectral Surveys (COMPASS) aims to provide comprehensive inventories of the molecular content of a sample of protostellar sources to understand the chemical impact of their environments and evolutionary stages. COMPASS is an unbiased spectral survey of 11 line-rich Class 0 and I protostellar sources in the spectral range from 279.0 to 311.7 GHz at 0.15-0.5" angular resolution with ALMA, corresponding to the inner ~100 au (radius) around the targeted sources. This paper provides an overview of the COMPASS program and the adopted strategy in terms of observational setups and targeted sources. We also present a qualitative comparison of the spatial distributions of selected molecules and the relative strengths of the line fluxes of selected complex organics. The qualitative comparisons suggest that chemical differences between sources may be present, for example, between the abundances of groups of oxygen- and nitrogen-bearing species, but also that such variations occur at levels smaller than an order of magnitude. Quantitative comparisons of abundances at these levels require the large bandwidth of the survey, as well as a careful analysis of the excitation and strengths of the several thousands of lines detected toward each source in the survey, as will be explored in forthcoming papers.

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arXiv2023

Evidence for ubiquitous carbon grain destruction in hot protostellar envelopes

Earth is deficient in carbon and nitrogen by up to ${\sim}4$ orders of magnitude compared with the Sun. Destruction of (carbon- and nitrogen-rich) refractory organics in the high-temperature planet forming regions could explain this deficiency. Assuming a refractory cometary composition for these grains, their destruction enhances nitrogen-containing oxygen-poor molecules in the hot gas ($\gtrsim 300$K) after the initial formation and sublimation of these molecules from oxygen-rich ices in the warm gas (${\sim}150$K). Using observations of $37$ high-mass protostars with ALMA, we find that oxygen-containing molecules (CH$_3$OH and HNCO) systematically show no enhancement in their hot component. In contrast, nitrogen-containing, oxygen-poor molecules (CH$_3$CN and C$_2$H$_3$CN) systematically show an enhancement of a factor ${\sim} 5$ in their hot component, pointing to additional production of these molecules in the hot gas. Assuming only thermal excitation conditions, we interpret these results as a signature of destruction of refractory organics, consistent with the cometary composition. This destruction implies a higher C/O and N/O in the hot gas than the warm gas, while, the exact values of these ratios depend on the fraction of grains that are effectively destroyed. This fraction can be found by future chemical models that constrain C/O and N/O from the abundances of minor carbon, nitrogen and oxygen carriers presented here.

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arXiv2021

Complex organic molecules in low-mass protostars on Solar System scales -- II. Nitrogen-bearing species

The chemical inventory of planets is determined by the physical and chemical processes that govern the early phases of star formation. The aim is to investigate N-bearing complex organic molecules towards two Class 0 protostars (B1-c and S68N) at millimetre wavelengths with ALMA. Next, the results of the detected N-bearing species are compared with those of O-bearing species for the same and other sources. ALMA observations in Band 6 ($\sim$ 1 mm) and Band 5 ($\sim$ 2 mm) are studied at $\sim$ 0.5" resolution, complemented by Band 3 ($\sim$ 3 mm) data in a $\sim$ 2.5" beam. NH2CHO, C2H5CN, HNCO, HN13CO, DNCO, CH3CN, CH2DCN, and CHD2CN are identified towards the investigated sources. Their abundances relative to CH3OH and HNCO are similar for the two sources, with column densities that are typically an order of magnitude lower than those of O-bearing species. The largest variations, of an order of magnitude, are seen for NH2CHO abundance ratios with respect to HNCO and CH3OH and do not correlate with the protostellar luminosity. In addition, within uncertainties, the N-bearing species have similar excitation temperatures to those of O-bearing species ($\sim$ 100 $\sim$ 300 K). The similarity of most abundances with respect to HNCO, including those of CH2DCN and CHD2CN, hints at a shared chemical history, especially the high D/H ratio in cold regions prior to star formation. However, some of the variations in abundances may reflect the sensitivity of the chemistry to local conditions such as temperature (e.g. NH2CHO), while others may arise from differences in the emitting areas of the molecules linked to their different binding energies in the ice. The two sources discussed here add to the small number of sources with such a detailed chemical analysis on Solar System scales. Future JWST data will allow a direct comparison between the ice and gas abundances of N-bearing species.

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arXiv2020

Chemically tracing the water snowline in protoplanetary disks with HCO$^+$

[Abridged] Planet formation is expected to be enhanced around snowlines in protoplanetary disks, in particular around the water snowline. However, the close proximity of the water snowline to the host star and water in the Earth's atmosphere makes a direct detection of the water snowline in protoplanetary disks challenging. Following earlier work on protostellar envelopes, the aim of this research is to investigate the validity of HCO$^+$ and H$^{13}$CO$^+$, as tracers of the water snowline in protoplanetary disks, as HCO$^+$ is destroyed by gas-phase water. Two small chemical networks are used to predict the HCO$^+$ abundance in a typical Herbig Ae disk. Subsequently, the corresponding emission profiles are modelled for H$^{13}$CO$^+$ and HCO$^+$ $J=2-1$, which provides the best balance between brightness and optical depth effects of the continuum emission. The HCO$^+$ abundance jumps by two orders of magnitude just outside the water snowline at 4.5 AU. We find that the emission of H$^{13}$CO$^+$ and HCO$^+$ is ring-shaped due to three effects: destruction of HCO$^+$ by gas-phase water, continuum optical depth, and molecular excitation effects. The presence of gas-phase water causes an additional drop of only $\sim$13% and 24% in the center of the disk, for H$^{13}$CO$^+$ and HCO$^+$, respectively. For the much more luminous outbursting source V883Ori, our models predict that the effect of dust and excitation are not limiting if the snowline is located outside $\sim$40 AU. Our analysis of ALMA observations of HCO$^+$ $J=3-2$ is consistent with the water snowline located around 100 AU. The HCO$^+$ abundance drops steeply around the water snowline, but dust and excitation can conceal the drop in HCO$^+$ emission due to the water snowline. Therefore, locating the water snowline with HCO$^+$ in Herbig disks is very difficult, but it is possible for outbursting sources like V883Ori.

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