arXiv subjects

M. Lebeda

Publications and source records attributed to M. Lebeda.

2 recordsLinked to original sources

arXiv2024

Strong impact of low-level substitution of Mn by Fe on the magnetoelectric coupling in $TbMnO_{3}$

The correlation between static magnetoelectric coupling and magnetic structure was investigated in $TbMn_{0.98}Fe_{0.02}O_{3}$ with magnetic field up to 8 T and down to 2 K. Single-crystal neutron diffraction experiments reveal a substantial increase in the temperature dependence of the incommensurate modulation wave vector of the antiferromagnetic phase as the magnetic field strength increases. Magnetic field-dependent pyroelectric current measurements revealed significantly higher magnetoelectric coupling at magnetic fields below 4 T than in pure TbMnO3. This is due to the higher sensitivity of the incommensurably modulated cycloid structure to weak magnetic fields. Detailed analysis of our data confirmed that the ferroelectric polarization is induced by inverse Dzyaloshinskii-Moriya interaction for magnetic field strength up to 4 T, but at higher fields a departure from theoretical predictions is ascertained, giving evidence for an additional, as yet misunderstood, contribution to magnetoelectric coupling. It shows that a small 2% substitution of Mn3+ by Fe3+ has a strong impact on the magnetic structure, promoting the destabilization of the incommensurably modulated magnetic cycloidal structure of $TbMnO_{3}$ in a magnetic field above 5 T. We demonstrate that the magnetoelectric coupling magnitude can be tuned through suitable substitutional elements, even at low level, inducing local lattice distortions with different electronic and magnetic properties.

cond-mat.mtrl-sci↗

arXiv2023

Modifying the magnetoelectric coupling in TbMnO$_3$ by low-level Fe$^{3+}$ substitution

We report a comprehensive study of the low-level substitution of Mn$^{3+}$ by Fe$^{3+}$ effect on the static and dynamic magnetoelectric coupling in TbMn$_{1-x}$Fe$_x$O$_3$ ($x=0$, 0.02 and 0.04). The cationic substitution has a large impact on the balance between competitive magnetic interactions and, as a result, on the stabilization of the magnetic structures and ferroelectric phase at low temperatures. Low-lying electromagnon excitation is activated in the cycloidal modulated antiferromagnetic and ferroelectric phase in TbMnO$_3$, while it is observed up to TN in the Fe-substituted compounds, pointing for different mechanisms for static and dynamic magnetoelectric coupling. A second electrically active excitation near 40 cm$^{-1}$ is explained by means of Tb3+ crystal-field effects. This excitation is observed up to room temperature, and exhibits a remarkable 15 cm$^{-1}$ downshift on cooling in Fe-substituted compounds. Both electromagnon and crystal-field excitations are found to be coupled to the polar phonons with frequencies up to 250 cm$^{-1}$. Raman spectroscopy reveals a spin-phonon coupling below TN in pure TbMnO$_3$, but the temperature where the coupling start to be relevant increases with Fe concentration and reaches 100 K in TbMn$_{0.96}$Fe$_{0.04}$O$_3$. The anomalies in the T-dependence of magnetic susceptibility above TN are well accounted by spin-phonon coupling and crystal-field excitation, coupled to oxygen motions.

cond-mat.mtrl-sci↗