arXiv subjects

M. Majumder

Publications and source records attributed to M. Majumder.

27 records · Page 2Linked to original sources

arXiv2016

Long-range and short-range magnetic correlations, and microscopic origin of net magnetization in the spin-1 trimer chain compound CaNi3P4O14

Spin-spin correlations and microscopic origin of net magnetization in the spin-1 trimer chain compound CaNi3P4O14 have been investigated by powder neutron diffraction. The present study reveals a 3D long-range magnetic ordering below 16 K where the magnetic structure consists of ferromagnetic trimers that are coupled ferromagnetically along the spin-chain. The moment components along the a and c axes arrange antiferromagnetically. Our study establishes that the uncompensated moment components along the b axis result in a net magnetization per unit cell. The magnetic structure, determined in the present study, is in agreement with the results of recent first principles calculation; however, it is in contrast to a fascinating experimental prediction of ferrimagnetic ordering based on the periodicity of the exchange interactions in CaNi3P4O14. Our study also confirms the presence of broad diffuse magnetic scattering, due to 1D short-range spin-spin correlations, over a wide temperature range below ~50 K down to a temperature well below the Tc. Total neutron scattering analysis by the RMC method reveals that the dominating spin-spin correlation above Tc is ferromagnetic and along the b axis. The nearest neighbour spin-spin correlations along the a and c axes are found to be weakly antiferromagnetic. The nature of the trimer spin structure of the short-range state is similar to that of the 3D long-range ordered state. The present investigation of microscopic nature of the magnetic ground state also explains the condition required for the 1/3 magnetization plateau to be observed in the trimer spin-chains. In spite of the S=1 trimer chain system, the present compound CaNi3P4O14 is found to be a good realization of 3D magnet below the Tc=16 K with full ordered moment values of ~2 mu_B/Ni2+ (1.98 and 1.96 mu_B/Ni2+ for two Ni sites, respectively) at 1.5 K.

cond-mat.str-el↗

arXiv2015

S=1/2 quantum critical spin ladders produced by orbital ordering in Ba2CuTeO6

The ordered hexagonal perovskite Ba2CuTeO6 hosts weakly coupled S=1/2 spin ladders produced by an orbital ordering of Cu2+. The magnetic susceptibility chi(T) of Ba2CuTeO6 is well described by that expected for isolated spin ladders with exchange coupling of J~86 K but shows a deviation from the expected thermally activated behavior at low temperatures below T*~25 K. An anomaly in chi(T), indicative of magnetic ordering, is observed at T_mag=16 K. No clear signature of long-range ordering, however, is captured in NMR, specific heat or neutron diffraction measurements at and below T_mag. The marginal magnetic transition, indicative of strong quantum fluctuations, is evidence that Ba2CuTeO6 is in very close proximity to a quantum critical point between a magnetically ordered phase and a gapped spin liquid controlled by inter-ladder couplings.

cond-mat.str-el↗

arXiv2015

Towards ferromagnetic quantum criticality in FeGa3-xGex: 71Ga NQR as a zero field microscopic probe

71Ga NQR, magnetization and specific heat measurements have been performed on polycrystalline Ge doped FeGa3 samples. A crossover from an insulator to a correlated local moment metal in the low doping regime and the evolution of itinerant ferromagnet upon further doping is found. For the nearly critical concentration at the threshold of ferromagnetic order, xC=0.15, (1/T1T) exhibits a pronounced T4/3 power law over two orders of magnitude in temperature which indicates 3D quantum critical ferromagnetic fluctuations. Furthermore, for the ordered x = 0.2 sample (TC = 6 K) 1/T1T could be fitted well in the frame of Moriya's SCR theory for weakly FM systems with 1/T1T proportional to chi. In contrast to this, the low doping regime nicely displays local moment behavior where 1/T1T proportional to chi2 is valid. For temperature tending to zero the Sommerfeld ratio = (C/T) is enhanced (70 mJ/mole-K2 for x = 0.1) which indicates the formation of heavy 3d-electrons.

cond-mat.str-el↗

arXiv2015

Frustrated three-dimensional antiferromagnet Li$_{2}$CuW$_{2}$O$_{8}$: $^7$Li NMR and the effect of non-magnetic dilution

We report a $^7$Li nuclear magnetic resonance (NMR) study of a frustrated three-dimensional \mbox{spin-$\frac12$} antiferromagnet Li$_{2}$CuW$_{2}$O$_{8}$ and also explore the effect of non-magnetic dilution. The magnetic long-range ordering in the parent compound at $T_{\rm N}\simeq$ 3.9~K was detected from the drastic line broadening and a peak in the spin-lattice relaxation rate ($1/T_1$). The NMR spectrum above $T_{\rm N}$ broadens systematically, and its full width at half maximum (FWHM) tracks the static spin susceptibility. From the analysis of FWHM vs. static susceptibility, the coupling between the Li nuclei and Cu$^{2+}$ ions was found to be purely dipolar in nature. The magnitude of the maximum exchange coupling constant is $J_{\rm max}/k_{\rm B}\simeq 13$\,K. NMR spectra below $T_{\rm N}$ broaden abruptly and transform into a double-horn pattern reflecting the commensurate nature of the spin structure in the ordered state. Below $T_{\rm N}$, 1/$T_1$ follows a $T^5$ behavior. The frustrated nature of the compound is confirmed by persistent magnetic correlations at high temperatures well above $T_{\rm N}$. The dilution of the spin lattice with non-magnetic Zn atoms has dramatic influence on $T_N$ that decreases exponentially similar to quasi-one-dimensional antiferromagnets, even though Li$_2$CuW$_2$O$_8$ has only a weak one-dimensional anisotropy. Heat capacity of doped samples follows power law ($C_{\rm p} \propto T^α$) below $T_{\rm N}$, and the exponent ($α$) decreases from 3 in the parent compound to 1 in the 25\% doped sample.

cond-mat.mtrl-sci↗

arXiv2015

Anisotropic Ru3+ 4d5 magnetism in the alpha-RuCl3 honeycomb system: susceptibility, specific heat and Zero field NMR

Hexagonal alpha-Ru trichloride single crystals exhibit a strong magnetic anisotropy and we show that upon applying fields up to 14 T in the honeycomb plane the successive magnetic order at T1 = 14 K and T2 = 8 K could be completely suppressed whereas in the perpendicular direction the magnetic order is robust. Furthermore the field dependence of chi(T) implies coexisting ferro- and antiferromagnetic exchange between in-plane components of Ru^3+-spins, whereas for out-of-plane components a strong antiferromagnetic exchange becomes evident. 101^Ru zero-field nuclear magnetic resonance in the ordered state evidence a complex (probably non coplanar chiral) long-range magnetic structure. The large orbital moment on Ru^3+ is found in density-functional calculations.

cond-mat.str-el↗

arXiv2013

Local electromagnetic properties of magnetic pnictides: A comparative study probed by NMR measurement

75As and 31P NMR studies are performed in PrCoAsO and NdCoPO respectively. The Knight shift data in PrCoAsO indicate the presence of an antiferromagnetic interaction between the 4f moments along the c axis in the ferromagnetic state of Co 3d moments. We propose a possible spin structure in this system. The 75As quadrupolar coupling constant, $ν_Q$ increases continuously with the decrease of temperature and is found to vary linearly with the intrinsic spin susceptibility, Kiso. This indicates a possibility of the presence of a coupling between charge density and spin density fluctuations. Further, 31P NMR Knight shift and spin lattice relaxation rate (1/T1) in the paramagnetic state of NdCoPO indicate that the differences between LaCoPO and NdCoPO with SmCoPO are due to the decrement of inter layer separation and not due to the moments of 4f electrons. Nuclear spin lattice relaxation time (T1) in NdCoPO shows weak anisotropy at 300 K. Using self consistent renormalization (SCR)theory of itinerant ferromagnet, it is shown that in the ab plane, the spin fluctuations are three dimensional ferromagnetic in nature. From SCR theory the important spin fluctuation parameters ($T_0$, $T_A$, $\bar{F}_1$) are evaluated. The similarities and dissimilarities of the NMR results in As and P based systems, with different rare earths have also been discussed.

cond-mat.str-el↗

arXiv2012

Evidence of structural phase transition in superconducting SmFeAsO_(1-x)F_x from 19^F NMR

We report the resistivity, magnetization and 19^F NMR results in polycrystalline sample of SmFeAsO_(0.86)F_(0.14). The resistivity and the magnetization data show a sharp drop at 48 K indicating the superconducting transition. The nuclear spin-lattice rate (1/T_1) and spin-spin relaxation rate (1/T_2) clearly show the existence of a structural phase transition near 163 K in the sample which also undergo superconducting transition. This finding creates interest to explore whether this is unique for only Sm based systems or it is also present in other rare-earth based 1111 superconductors.

cond-mat.supr-con↗

arXiv2012

Crossover of the dimensionality of 3d spin fluctuations in LaCoPO

dc magnetization and 31^P spin lattice relaxation rate in the polycrystalline sample of LaCoPO suggest a spin fluctuation dominated ferromagnetically ordered state. Moreover, NMR data clearly indicate a crossover from 2D to 3D spin fluctuations across T_C. In contrast to isotropic hyperfine field, H_hf at the 31^P site in LaFePO, H_hf is anisotropic in LaCoPO. The data of spin lattice relaxation rate also exhibit anisotropic spin fluctuation. The anisotropy vanishes near T_C.

cond-mat.str-el↗

arXiv2010

Study of electron spin dynamics in grain aligned LaCoPO: an itinerant ferromagnet

139La NMR study was performed in grain aligned (c|| H0) sample of LaCoPO and polycrystalline LaFePO. Knight shift is isotropic and temperature independent in LaFePO. It is strongly temperature dependent and anisotropic in LaCoPO. The spin-lattice relaxation rate in LaCoPO clearly reveals the existence of 3D spin fluctuations both in the paramagnetic and ferromagnetic state over and above the dominant 2D spin fluctuations in the paramagnetic state, observed earlier from 31P NMR measurements in the same oriented sample. The spin fluctuation parameters in LaCoPO determined from 139La NMR relaxation and magnetization data, using the self consistent renormalization (SCR) theory, are in close agreement and follow the universal Rhodes-Wohlfarth curve.

cond-mat.str-el↗