arXiv subjects

M. Matsukawa

Publications and source records attributed to M. Matsukawa.

13 recordsLinked to original sources

arXiv2020

Structural, physical and photocatalytic properties of mixed-valence double-perovskite Ba$_{2}$Pr(Bi,Sb)O$_{6}$ semiconductor synthesized by citrate pyrolysis technique

We demonstrated crystal structures, magnetic, optical, and photocatalytic properties of the B-site substituted double perovskite Ba$_{2}$Pr(Bi$_{1-x}$Sb$_{x}$)O$_{6}$ ($x$=0, 0.1, 0.2, 0.5 and 1.0) synthesized by the citrate pyrolysis method. The single-phase polycrystalline samples with the light Sb substitution crystallized in a monoclinic structure ($I2/m$). Magnetization measurements on all the samples showed that the effective magnetic moments are located around 3 $μ_{B}$ , indicating the valence mixing states between Pr$^{3+}$ and Pr$^{4+}$.The magnitudes of band gap energy for the two end member samples were estimated from the optical measurements to be $E_{g}$ =1.06 eV at $x$=0 and 2.71 eV at $x$=1.0. The Ba$_{2}$Pr(Bi$_{1-x}$Sb$_{x}$)O$_{6}$ ($x$=0, and 0.1) powders obtained by the present technique exhibited enhanced photocatalytic activities when compared to the same compounds prepared by the conventional solid state method. Our findings suggest that the higher photocatalytic activities strongly depend on powder preparation method as well as the band gaps and charge separation.

cond-mat.mtrl-sci↗

arXiv2010

Effect of pressure on the magnetic, transport, and thermal-transport properties of the electron-doped manganite CaMn$_{1-x}$Sb$_{x}$O$_{3}$

We have demonstrated the effect of hydrostatic pressure on magnetic and transport properties, and thermal transport properties in electron-doped manganites CaMn$_{1-x}$Sb$_{x}$O$_{3}$. The substitution of Sb$^{5+}$ ion for Mn $^{4+}$site of the parent matrix causes one-electron doping with the chemical formula CaMn$^{4+}_{1-2x}$Mn$^{3+}_{x}$Sb$^{5+}_{x}$O$_{3}$ accompanied by a monotonous increase in unit cell volume as a function of $x$. Upon increasing the doping level of Sb, the magnitudes of both electrical resistivity and negative Seebeck coefficient are suppressed at high temperatures, indicating the electron doping. Anomalous diamagnetic behaviors at $x=0.05$ and 0.08 are clearly observed in field cooled dc magnetization. The effect of hydrostatic pressure on dc magnetization is in contrast to the chemical pressure effect due to Sb doping. The dynamical effect of ac magnetic susceptibility measurement points to the formation of the magnetically frustrated clusters such as FM clusters embedded in canted AFM matrix.

cond-mat.str-el↗

arXiv2008

Colossal electroresistance and colossal magnetoresistive step in paramagnetic insulating phase of single crystalline bilayered manganite(La$_{0.4}$Pr$_{0.6}$)$_{1.2}$Sr$_{1.8}$Mn$_{2}$O$_{7}$

We report a significant decrease in the low-temperature resistance induced by the application of an electric current on the $ab$-plane in the paramagnetic insulating (PMI) state of (La$_{0.4}$Pr$_{0.6}$)$_{1.2}$Sr$_{1.8}$Mn$_{2}$O$_{7}$. A colossal electroresistance effect attaining -95% is observed at lower temperatures. A colossal magnetoresistive step appears near 5T at low temperatures below 10K, accompanied by an ultrasharp width of the insulator-metal transition. Injection of higher currents to the crystal causes a disappearance of the steplike transition. These findings have a close relationship with the presence of the short-range charge-ordered clusters pinned within the PMI matrix of the crystal studied.

cond-mat.mtrl-sci↗

arXiv2008

Effect of pressure on steplike magnetostriction of single crystalline (La$_{0.4}$Pr$_{0.6}$)$_{1.2}$Sr$_{1.8}$Mn$_{2}$O$_{7}$ bilayered manganite

e report the effect of pressure on the steplike magnetostriction of single crystalline bilayered manganite (LaPr)1.2Sr1.8Mn2O8, for our understandings of the ultrasharp nature of the field-induced first-order transition from a paramagnetic insulator to a ferromagnetic metal phase. The application of pressure suppresses a steplike transformation and causes a broad change in the magnetostriction. The injection of an electric current to the crystal also weakens the steplike variation in both the magnetostriction and magnetoresistance. The stabilization of ferromagnetic interaction or the delocalization of charge carriers is promoted with the applied pressure or applied current, resulting in the suppressed steplike behavior. Our findings suggest that the step phenomenon is closely related to the existence of localized carriers such as the short-range charge-orbital ordered clusters.

cond-mat.str-el↗

arXiv2007

Steplike Lattice Deformation of Single Crystalline (La$_{0.4}$Pr$_{0.6}$)$_{1.2}$Sr$_{1.8}$Mn$_{2}$O$_{7}$ Bilayered Manganite

We report a steplike lattice transformation of single crystalline (La$_{0.4}$Pr$_{0.6}$)$_{1.2}$Sr$_{1.8}$Mn$_{2}$O$_{7}$bilayered manganite accompanied by both magnetization and magnetoresistive jumps, and examine the ultrasharp nature of the field-induced first-order transition from a paramagnetic insulator to a ferromagnetic metal phase accompanied by a huge decrease in resistance. Our findings support that the abrupt magnetostriction is closely related to an orbital frustration existing in the inhomogeneous paramagnetic insulating phase rather than a martensitic scenario between competing two phases.

cond-mat.str-el↗

arXiv2006

Anomalous pressure effect on the remanent lattice striction of a (La,Pr)$_{1.2}$Sr$_{1.8}$Mn$_{2}$O$_{7}$ bilayered manganite single crystal

We have studied the pressure effect on magnetostriction, both in the $ab$-plane and along the c-axis, of a (La,Pr)$_{1.2}$Sr$_{1.8}$Mn$_{2}$O$_{7}$ bilayered manganite single crystal over the temperature region where the field-induced ferromagnetic metal (FMM) transition takes place. For comparison, we have also examined the pressure dependence of magnetization curves at the corresponding temperatures. The applied pressure reduces the critical field of the FMM transition and it enhances the remanent magnetostriction. An anomalous pressure effect on the remanent lattice relaxation is observed and is similar to the pressure effect on the remanent magnetization along the c-axis. These findings are understood from the view point that the double-exchange interaction driven FMM state is strengthened by application of pressure.

cond-mat.str-el↗

arXiv2006

Elastic and magnetic properties on field-induced Metal-Insulator transition of bilayer manganese oxide $(La_{1-z} Pr_z)_{1.2} Sr_{1.8} Mn_2 O_7$ ($z$=0.6)

The elastic and magnetic properties of a single crystal of 327 bilayer manganese oxide $(La_{1-z} Pr_z)_{1.2} Sr_{1.8} Mn_2 O_7$ with $z$=0.6 have been investigated by ultrasonic and high-field magnetization measurements. A distinct elastic anomaly was observed at low temperatures and in high magnetic fields when crossing the phase boundary. A pronounced elastic softening as a function of magnetic field ($H$) appears across the boundary of the low-temperature magnetic phase below around 40 K, accompanied by a distinct hysteresis. In the high field region, however, these elastic constants exhibit an increase with increasing a magnetic field in the high-field region. The high-field magnetization measurement characterizing the magnetic state clarified a strong connection between elastic strains and magnetic moments. The new metamagnetic transition was found in the high-field region above 40 K, accompanied with no hysteresis. The present results of elastic constants are discussed in terms of a coupling effect between elastic strains associated with sound waves and relevant magnetic moments, and relevant conduction bands. They are explained reasonably in terms of a strong coupling between elastic strains and magnetic susceptibility $chi$$_{m}$=$partial$$M$/$partial$$H$.

cond-mat.str-el↗

arXiv2006

In-plane thermal conductivity of large single crystals of Sm-substituted (Y$_{1-x}$Sm$_{x}$)Ba$_{2}$Cu$_{3}$O$_{7-δ}$

We have investigated the in-plane thermal conductivity $κ_{ab}(T,H)$ of large single crystals of optimally oxygen-doped (Y$_{1-x}$,Sm$_{x}$)Ba$_{2}$Cu$_{3}$O$_{7-δ}$ ($x$=0, 0.1, 0.2 and 1.0) and YBa$_{2}$(Cu$_{1-y}$Zn$_{y}$)$_{3}$O$_{7-δ}$($y$=0.0071) as functions of temperature and magnetic field (along the c axis). For comparison, the temperature dependence of $κ_{ab}$ for as-grown crystals with the corresponding compositions are presented. The nonlinear field dependence of $κ_{ab}$ for all crystals was observed at relatively low fields near a half of $T_{c}$. We make fits of the $κ(H)$ data to an electron contribution model, providing both the mean free path of quasiparticles $\ell_{0}$ and the electronic thermal conductivity $κ_{e}$, in the absence of field. The local lattice distortion due to the Sm substitution for Y suppresses both the phonon and electron contributions. On the other hand, the light Zn doping into the CuO $_{2}$ planes affects solely the electron component below $T_{c}$, resulting in a substantial decrease in $\ell_{0}$ .

cond-mat.supr-con↗

arXiv2005

Effect of suppression of local distortion on magnetic, electrical and thermal transport properties of Cr substituted bi-layer manganite LaSr$_{2}$Mn$_{2}$O$_{7}$

We have investigated magnetic, electrical and thermal transport properties (Seebeck effect and thermal conductivity) of LaSr$_{2}$Mn$_{2-y}$Cr$_{y}$O$_{7}$ polycrystalline samples ($y$=0.1, 0.2, 0.4 and 0.6). The Cr$^{3+}$ substitution for Mn$^{3+}$ sites causes a removal of $d_{x^2-y^2}$ orbital of $e_g$-electron resulting in a volume shrinkage of lattice. Magnetic measurements reveal the appearance of a glassy behavior for Cr-doped samples, accompanied by both a collapse of the A-type antiferromagnetic structure and the growth of ferromagnetic clusters. Cr-doping effect on electrical transport strongly enhances an insulating behavior over a wide range of temperature, while it suppresses a local minimum of thermoelectric power at lower temperatures. The phonon thermal conduction gradually rises with increasing Cr content, which is contradictory to a typical impurity effect on thermal conductivity. We attribute this to a suppression of local lattice distortion through the introduction of Jahn-Teller inactive ions of Cr$^{3+}$.

cond-mat.str-el↗

arXiv2005

Resistive relaxation in field-induced insulator-metal transition of a (La$_{0.4}$Pr$_{0.6}$)$_{1.2}$Sr$_{1.8}$Mn$_{2}$O$_{7}$ bilayer manganite single crystal

We have investigated the resistive relaxation of a (La$_{0.4}$Pr$_{0.6}$)$_{1.2}$Sr$_{1.8}$Mn$_{2}$O$_{7}$ single crystal, in order to examine the slow dynamics of the field-induced insulator to metal transition of bilayered manganites. The temporal profiles observed in remanent resistance follow a stretched exponential function accompanied by a slow relaxation similar to that obtained in magnetization and magnetostriction data. We demonstrate that the remanent relaxation in magnetotransport has a close relationship with magnetic relaxation that can be understood in the framework of an effective medium approximation by assuming that the first order parameter is proportional to the second order one.

cond-mat.str-el↗

arXiv2004

Superconductivity in Pr2Ba4Cu7O15-delta with metallic double chains

We report superconductivity with $T_{c,onset}$=$\sim$10K in Pr$_{2}$Ba$_{4}$Cu$_{7}$O$_{15-δ}$ compound possessing metallic double chains. A reduction treatment on as-sintered samples causes not only the enhanced metallic conduction but also the appearance of superconductivity accompanied by the c-axis elongation due to oxygen deficiency.

cond-mat.supr-con↗

arXiv2004

Stretched exponential behavior in remanent lattice striction of a (La,Pr)$_{1.2}$Sr$_{1.8}$Mn$_{2}$O$_{7}$ bilayer manganite single crystal

We have investigated the time dependence of remanent magnetostriction in a (La,Pr)$_{1.2}$Sr$_{1.8}$Mn$_{2}$O$_{7}$ single crystal, in order to examine the slow dynamics of lattice distortion in bilayered manganites. A competition between double exchange and Jahn-Teller type orbital-lattice interactions results in the observed lattice profile following a stretched exponential function. This finding suggests that spatial growth of the local lattice distortions coupled with e$_{g}$-electron orbital strongly correlates with the appearance of the field-induced CMR effect.

cond-mat.str-el↗

arXiv2003

Anisotropic phonon conduction and lattice distortions in CMR-type bilayer manganite (La$_{1-z}$Pr$_{z}$)$_{1.2}$Sr$_{1.8}$Mn$_{2}$O$_{7}$ (z=0,0.2,0.4 and 0.6) single crystals

We have undertaken a systematic study of thermal conductivity as a function of temperature and magnetic field of single crystals of the compound (La$_{1-z}$Pr$_{z}$)$_{1.2}$Sr$_{1.8}$Mn$_{2}$O$_{7}$ for $z$(Pr) =0.2,0.4. and 0.6. The lattice distortion due to Pr-substitution and anisotropic thermal conductivity in bilayer manganites are discussed on the basis of different relaxation models of local lattice distortions in metal and insulating states proposed by Maderda et al. The giant magnetothermal effect is scaled as a function of magnetization and discussed on the basis of a systematic variation of the occupation of the $e_g$-electron orbital states due to Pr-substitution.

cond-mat.str-el↗