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M. Mueller

Publications and source records attributed to M. Mueller.

At least 55 records · Page 3Linked to original sources
arXiv2010

"TNOs are Cool": A survey of the trans-Neptunian region I. Results from the Herschel Science Demonstration Phase (SDP)

The goal of the Herschel Open Time Key programme "TNOs are Cool!" is to derive the physical and thermal properties for a large sample of Centaurs and trans-Neptunian objects (TNOs), including resonant, classical, detached and scattered disk objects. We present results for seven targets either observed in PACS point-source, or in mini scan-map mode. Spitzer-MIPS observations were included for three objects. The sizes of these targets range from 100 km to almost 1000 km, five have low geometric albedos below 10%, (145480) 2005 TB190 has a higher albedo above 15%. Classical thermal models driven by an intermediate beaming factor of $η$=1.2 or $η$-values adjusted to the observed colour temperature fit the multi-band observations well in most cases. More sophisticated thermophysical models give very similar diameter and albedo values for thermal inertias in the range 0-25 Jm-2s-0.5K-1, consistent with very low heat conductivities at temperatures far away from the Sun. The early experience with observing and model strategies will allow us to derive physical and thermal properties for our complete Herschel TNO sample of 140 targets as a benchmark for understanding the solar system debris disk, and extra-solar ones as well.

astro-ph.EP↗
arXiv2010

In-situ direct visualization of irradiated e-beam patterns on unprocessed resists using atomic force microscopy

We introduce an in-situ characterization method of resists used for e-beam lithography. The technique is based on the application of an atomic force microscope which is directly mounted below the cathode of an electron-beam lithography system. We demonstrate that patterns irradiated by the e-beam can be efficiently visualized and analyzed in surface topography directly after the e-beam exposure. This in-situ analysis takes place without any development or baking steps, and gives access to the chemical (or latent) image of the irradiated resist.

cond-mat.mtrl-sci↗
arXiv2009

Parameter Estimation and Confidence Regions in the Method of Light Curve Simulations for the Analysis of Power Density Spectra

The Method of Light Curve Simulations is a tool that has been applied to X-ray monitoring observations of Active Galactic Nuclei (AGN) for the characterization of the Power Density Spectrum (PDS) of temporal variability and measurement of associated break frequencies (which appear to be an important diagnostic for the mass of the black hole in these systems as well as their accretion state). It relies on a model for the PDS that is fit to the observed data. The determination of confidence regions on the fitted model parameters is of particular importance, and we show how the Neyman construction based on distributions of estimates may be implemented in the context of light curve simulations. We believe that this procedure offers advantages over the method used in earlier reports on PDS model fits, not least with respect to the correspondence between the size of the confidence region and the precision with which the data constrain the values of the model parameters. We plan to apply the new procedure to existing RXTE and XMM observations of Seyfert I galaxies as well as RXTE observations of the Seyfert II galaxy NGC 4945.

astro-ph.HE↗
arXiv2008

Coarse-grained models for fluids and their mixtures: Comparison of Monte Carlo studies of their phase behavior with perturbation theory and experiment

The prediction of the equation of state and the phase behavior of simple fluids (noble gases, carbon dioxide, benzene, methane, short alkane chains) and their mixtures by Monte Carlo computer simulation and analytic approximations based on thermodynamic perturbation theory is discussed. Molecules are described by coarse grained (CG) models, where either the whole molecule (carbon dioxide, benzene, methane) or a group of a few successive CH_2 groups (in the case of alkanes) are lumped into an effective point particle. Interactions among these point particles are fitted by Lennard-Jones (LJ) potentials such that the vapor-liquid critical point of the fluid is reproduced in agreement with experiment; in the case of quadrupolar molecules a quadrupole-quadrupole interaction is included. These models are shown to provide a satisfactory description of the liquid-vapour phase diagram of these pure fluids. Investigations of mixtures, using the Lorentz-Berthelot (LB) combining rule, also produce satisfactory results if compared with experiment, while in some previous attempts (in which polar solvents were modelled without explicitly taking into account quadrupolar interaction), strong violations of the LB rules were required. For this reason, the present investigation is a step towards predictive modelling of polar mixtures at low computational cost. These very simple coarse-grained models of small molecules developed here should be useful e.g. for simulations of polymer solutions with such molecules as solvent.

cond-mat.stat-mech↗
arXiv2008

Constraints on the Low-Energy Cutoff in the Electron Distribution of the PKS 0637-752 Jet

We re-analyze the Chandra ACIS spectrum of the kpc-scale jet in PKS 0637-752 to investigate the possible low energy cutoff in the relativistic electron spectrum producing the non-thermal radiation in the scenario of inverse Compton emission off the cosmic microwave background. This was among the first objects targeted by the Chandra Observatory and gives a unique opportunity to study the low energy X-ray emission free of detector contamination. As previously reported in the literature, the spectrum can be fit by a power law, with the slope predicted by the radio spectrum, modified by low energy absorption through the Galaxy as determined from the spectrum of the quasar core and by HI 21 cm observations. We obtain a marginally better fit with an model of inverse Compton emission produced by an electron population that exhibits a cutoff at (gamma_min delta_10) between about 50 and 80 (assuming Gamma = delta). This range for gamma_min is higher than has previously been assumed in broad-band spectral fits to the jet emission. The observed optical flux can be used to place a lower limit on gamma_min; the constraint is not very strong, but does suggest that gamma_min must be higher than 1 to avoid overproducing the optical emission. We investigate the effect of uncertainties in the column density for galactic absorption as well as the calibration of Chandra for these early observations. Finally, we discuss the implication of these limits on the jet luminosity in this source.

astro-ph↗
arXiv2008

Trap assisted creation of giant molecules and Rydberg-mediated coherent charge transfer in a Penning trap

We study two ions confined in a Penning trap. We show that electronically highly excited states exist in which an electron is delocalized among the two ions forming a giant molecule of several micrometer size. At energies close to the top of the Coulomb barrier these molecular states can be regarded as superpositions of Rydberg states of individual ions. We illuminate the possibility to observe coherent charge transfer between the ions. Beyond a critical principal quantum number the electron can coherently tunnel through the Coulomb barrier to an adjacent doubly charged ion. The tunneling occurs on timescales on which the dynamics of the nuclei can be considered frozen and radiative decay can be neglected.

quant-ph↗
arXiv2008

Diameters and albedos of three sub-kilometer Near Earth Objects derived from Spitzer observations

Near Earth Objects (NEOs) are fragments of remnant primitive bodies that date from the era of Solar System formation. At present, the physical properties and origins of NEOs are poorly understood. We have measured thermal emission from three NEOs -- (6037) 1988 EG, 1993 GD, and 2005 GL -- with Spitzer's IRAC instrument at 3.6, 4.5, 5.8, and 8.0 microns (the last object was detected only at 5.8 and 8.0 microns). The diameters of these three objects are 400 m, 180 m, and 160 m, respectively, with uncertainties of around 20% (including both observational and systematic errors). For all three the geometric albedos are around 0.30, in agreement with previous results that most NEOs are S-class asteroids. For the two objects detected at 3.6 and 4.5 microns, diameters and albedos based only on those data agree with the values based on modeling the data in all four bands. This agreement, and the high sensitivity of IRAC, show the promise of the Spitzer Warm Mission for determining the physical parameters for a large number of NEOs.

astro-ph↗
arXiv2008

Trapped Rydberg Ions: From Spin Chains to Fast Quantum Gates

We study the dynamics of Rydberg ions trapped in a linear Paul trap, and discuss the properties of ionic Rydberg states in the presence of the static and time-dependent electric fields constituting the trap. The interactions in a system of many ions are investigated and coupled equations of the internal electronic states and the external oscillator modes of a linear ion chain are derived. We show that strong dipole-dipole interactions among the ions can be achieved by microwave dressing fields. Using low-angular momentum states with large quantum defect the internal dynamics can be mapped onto an effective spin model of a pair of dressed Rydberg states that describes the dynamics of Rydberg excitations in the ion crystal. We demonstrate that excitation transfer through the ion chain can be achieved on a nanosecond timescale and discuss the implementation of a fast two-qubit gate in the ion chain.

quant-ph↗
arXiv2007

Comparison of Dissipative Particle Dynamics and Langevin thermostats for out-of-equilibrium simulations of polymeric systems

In this work we compare and characterize the behavior of Langevin and Dissipative Particle Dynamics (DPD) thermostats in a broad range of non-equilibrium simulations of polymeric systems. Polymer brushes in relative sliding motion, polymeric liquids in Poiseuille and Couette flows, and brush-melt interfaces are used as model systems to analyze the efficiency and limitations of different Langevin and DPD thermostat implementations. Widely used coarse-grained bead-spring models under good and poor solvent conditions are employed to assess the effects of the thermostats. We considered equilibrium, transient, and steady state examples for testing the ability of the thermostats to maintain constant temperature and to reproduce the underlying physical phenomena in non-equilibrium situations. The common practice of switching-off the Langevin thermostat in the flow direction is also critically revisited. The efficiency of different weight functions for the DPD thermostat is quantitatively analyzed as a function of the solvent quality and the non-equilibrium situation.

cond-mat.soft↗
arXiv2007

Equation of State for Macromolecules of Variable Flexibility in Good Solvents: A Comparison of Techniques for Monte Carlo Simulations of Lattice Models

The osmotic equation of state for the athermal bond fluctuation model on the simple cubic lattice is obtained from extensive Monte Carlo simulations. For short macromolecules (chain length N=20) we study the influence of various choices for the chain stiffness on the equation of state. Three techniques are applied and compared in order to critically assess their efficiency and accuracy: the repulsive wall method, the thermodynamic integration method (which rests on the feasibility of simulations in the grand canonical ensemble), and the recently advocated sedimentation equilibrium method, which records the density profile in an external (e.g. gravitation-like) field and infers, via a local density approximation, the equation of state from the hydrostatic equilibrium condition. We confirm the conclusion that the latter technique is far more efficient than the repulsive wall method, but we find that the thermodynamic integration method is similarly efficient as the sedimentation equilibrium method. For very stiff chains the onset of nematic order enforces the formation of isotropic-nematic interface in the sedimentation equilibrium method leading to strong rounding effects and deviations from the true equation of state in the transition regime.

cond-mat.soft↗
arXiv2006

Interaction-induced Renormalization of Andreev Reflection

We analyze the charge transport between a one-dimensional weakly interacting electron gas and a superconductor within the scaling approach in the basis of scattering states. We derive the renormalization group equations, which fully account for the intrinsic energy dependence due to Andreev reflection. A strong renormalization of the corresponding reflection phase is predicted even for a perfectly transparent metal-superconductor interface. The interaction-induced suppression of the Andreev conductance is shown to be highly sensitive to the normal state resistance, providing a possible explanation of experiments with carbon-nanotube/superconductor junctions by Morpurgo et al. [Science 286, 263 (2001)].

cond-mat.mes-hall↗
arXiv2005

A Simple Model for Simple Aging in Glassy Yttrium-Hydrides

A simple explanation for the logarithmic aging of the photoconductivity in yttriumhydride is proposed. We show that the scaling (``simple'' aging) of the relaxation response with the illumination time t_w is consistent with the superposition of independently relaxing excitations with time offsets distributed over a window of width t_w.

cond-mat.dis-nn↗
arXiv2005

Phase transitions in nanosystems caused by interface motion: The Ising bi-pyramid with competing surface fields

The phase behavior of a large but finite Ising ferromagnet in the presence of competing surface magnetic fields +/- H_s is studied by Monte Carlo simulations and by phenomenological theory. Specifically, the geometry of a double pyramid of height 2L is considered, such that the surface field is positive on the four upper triangular surfaces of the bi-pyramid and negative on the lower ones. It is shown that the total spontaneous magnetization vanishes (for L -> infinity) at the temperature T_f(H), related to the "filling transition" of a semi-infinite pyramid, which can be well below the critical temperature of the bulk. The discontinuous vanishing of the magnetization is accompanied by a susceptibility that diverges with a Curie-Weiss power law, when the transition is approached from either side. A Landau theory with size-dependent critical amplitudes is proposed to explain these observations, and confirmed by finite size scaling analysis of the simulation results. The extension of these results to other nanosystems (gas-liquid systems, binary mixtures, etc.) is briefly discussed.

cond-mat.stat-mech↗
arXiv2005

A global investigation of phase equilibria using the Perturbed-Chain Statistical-Associating-Fluid-Theory (PC-SAFT) approach

The recently developed Perturbed-Chain Statistical Associating Fluid Theory (PC-SAFT) is investigated for a wide range of model parameters including the parameter m representing the chain length and the thermodynamic temperature T and pressure p. This approach is based upon the first-order thermodynamic perturbation theory for chain molecules developed by Wertheim and Chapman et al. and includes dispersion interactions via the second-order perturbation theory of Barker and Henderson. We systematically study a hierarchy of models which are based on the PC-SAFT approach using analytical model calculations and Monte Carlo simulations. For one-component systems we find that the analytical model in contrast to the simulation results exhibits two phase-separation regions in addition to the common gas-liquid coexistence region: One phase separation occurs at high density and low temperature. The second demixing takes place at low density and high temperature where usually the ideal gas phase is expected in the phase diagram. These phenomena, which are referred to as "liquid-liquid" and "gas-gas" equilibria, give rise to multiple critical points in one-component systems, as well as to critical end points (CEP) and equilibria of three fluid phases, which can usually be found in multicomponent mixtures only. Furthermore, it is shown that the "liquid-liquid" demixing in this model is not a consequence of a "softened" repulsive interaction as assumed in the theoretical derivation of the model. Experimental data for the melt density of polybutadiene with molecular mass Mw=45000g/mol are correlated here using the PC-SAFT equation. It is shown that the discrepancies in modeling the polymer density at ambient temperature and high pressure can be traced back to ...

cond-mat.soft↗
arXiv2004

Long Range Bond-Bond Correlations in Dense Polymer Solutions

The scaling of the bond-bond correlation function $C(s)$ along linear polymer chains is investigated with respect to the curvilinear distance, $s$, along the flexible chain and the monomer density, $ρ$, via Monte Carlo and molecular dynamics simulations. % Surprisingly, the correlations in dense three dimensional solutions are found to decay with a power law $C(s) \sim s^{-ω}$ with $ω=3/2$ and the exponential behavior commonly assumed is clearly ruled out for long chains. % In semidilute solutions, the density dependent scaling of $C(s) \approx g^{-ω_0} (s/g)^{-ω}$ with $ω_0=2-2ν=0.824$ ($ν=0.588$ being Flory's exponent) is set by the number of monomers $g(ρ)$ contained in an excluded volume blob of size $ξ$. % Our computational findings compare well with simple scaling arguments and perturbation calculation. The power-law behavior is due to self-interactions of chains on distances $s \gg g$ caused by the connectivity of chains and the incompressibility of the melt. %

cond-mat.soft↗
arXiv2004

The glass transition and the Coulomb gap in electron glasses

We establish the connection between the presence of a glass phase and the appearance of a Coulomb gap in disordered materials with strongly interacting electrons. Treating multiparticle correlations in a systematic way, we show that in the case of strong disorder a continuous glass transition takes place whose Landau expansion is identical to that of the Sherrington-Kirkpatrick spin glass. We show that the marginal stability of the glass phase controls the physics of these systems: it results in slow dynamics and leads to the formation of a Coulomb gap.

cond-mat.dis-nn↗
arXiv2004

The Phase Diagram of Random Heteropolymers

We propose a new analytic approach to study the phase diagram of random heteropolymers, based on the cavity method. For copolymers we analyze the nature and phenomenology of the glass transition as a function of sequence correlations. Depending on these correlations, we find that two different scenarios for the glass transition can occur. We show that, beside the much studied possibility of an abrupt freezing transition at low temperature, the system can exhibit, upon cooling, a first transition to a soft glass phase with fully broken replica symmetry and a continuously growing degree of freezing as the temperature is lowered.

cond-mat.dis-nn↗