Spectroscopic surveys with the SKA probing the ionized and molecular Milky Way
Radio spectroscopic surveys provide us with a comprehensive picture of the Milky Way across many physical and chemical regimes. Spectral lines primarily probe the multi-phase gaseous interstellar medium (ISM) from its ionized to atomic and molecular phases, and constrain both local and galaxy-scale kinematics and structure through Doppler shifts. By investigating the physical and chemical properties and distribution of the ISM, the processes driving star formation and galaxy evolution can be studied in detail. This motivates line surveys of our Galaxy that allow us to use the range of physical conditions found in the Milky Way as a template for understanding star formation in extragalactic environments. In this chapter, we describe the science enabled by the spectroscopy of small molecules and radio recombination lines of atoms toward a range of Galactic environments with the SKA. We address questions concerning the processes that dictate the formation of molecular clouds (OH, CH), the properties of warm, ionized gas and the potential of HII regions in understanding the structure of the Galaxy (radio recombination lines), and the impact of CO-dark molecular gas across various density regimes on star formation and galaxy evolution (OH, H2CO). We propose a survey that includes the inner and outer Galaxy disk, characterized by a broad range of densities, temperatures, and metallicities. Deep, wide-field observations of small molecules will be uniquely accessible with SKA, providing key insights on the condition of interstellar medium in galaxies and its impact on star formation.