arXiv subjects

M. Sanz-Novo

Publications and source records attributed to M. Sanz-Novo.

13 recordsLinked to original sources

arXiv2026

The Galactic centre G+0.633-0.0604 molecular cloud: A new astrochemical gold mine: I. Gas physical properties

In the Central Molecular Zone (CMZ), shocks play a key role in triggering star formation and driving chemical enrichment. The Sgr B2 complex is a prime template, hosting massive protoclusters (N, M, S) and the northern G+0.693 cloud, which exhibits shock-induced prestellar signatures. We report on G+0.633-0.0604, a newly identified shock-dominated and chemically rich cloud at the southern edge of Sgr B2, where the next star formation episodes are proposed. We characterise its physical properties and the shocks shaping it. We present analyses on CH$_3$CCH, CH$_3$CN, HC$_3$N, HNCO and several isotopologues of CO to infer the gas $T_{\rm kin}$ and density, using high-sensitivity spectral surveys from the Yebes 40m, IRAM 30m and APEX radio telescopes that covered ~100 GHz across the 31-275 GHz range. We also used 3 mm IRAM 30m mosaics (13'$\times$13') of Sgr B2 in HC$_3$N, HNCO and C$_2$H$_5$OH to probe G+0.633 environment. We identify three velocity components: a narrow main one (C1, $v_{\rm LSR}$~48.5 km/s; FWHM~10 km/s), and two broader, fainter components at higher velocities, C2 (~61 km/s; ~13 km/s) and C3 (~89 km/s; ~18 km/s), all showing similar properties ($T_{\rm kin}$~55-90 K, $N_{\rm H_2}$~(3-7)$\times$10$^{22}$ cm$^{-2}$, $n_{\rm H_2}$~(0.5-2.5)$\times$10$^{4}$ cm$^{-3}$) and extended distributions. C1 delineates G+0.633 physically and coincides with a peak in HNCO, supporting a shock-driven origin likely rooted in the cloud-cloud collision shaping Sgr B2 and also traced by C2, which extends north to G+0.693. C3 is kinematically unlinked and related to large-scale CMZ dynamics. Of the three, C1 may represent a very early protocluster phase, yet to be confirmed. G+0.633 thus emerges as a new shock-dominated CMZ cloud resembling G+0.693, providing another unique laboratory to investigate how shocks drive molecular complexity and regulate the onset of cluster formation in the CMZ.

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arXiv2026

The Galactic centre G+0.633-0.0604 molecular cloud: A new astrochemical gold mine: II. Chemical richness

In recent years, the inventory of interstellar molecules has rapidly grown, yet detections of complex species are confined to a few chemically rich sources, raising the question of whether such complexity is genuinely rare or shaped by observational biases. We present the Galactic Centre G+0.633-0.0604 molecular cloud, located in the southern part of the Sgr B2 complex, as a new and very promising laboratory for the discovery of new interstellar molecules. We analysed data from a high-sensitivity molecular line survey of G+0.633, covering nearly 100 GHz of aggregated bandwidth over the 31$-$275 GHz frequency range with the Yebes 40m, IRAM 30m and APEX radio telescopes. G+0.633 exhibits an exceptionally rich molecular feedstock comparable to that of the chemically rich G+0.693 cloud in the northern part of Sgr B2, establishing it as its 'astrochemical twin'. We report new robust interstellar detections of 15 astrochemically relevant species, most of prebiotic interest, previously identified only in G+0.693 or a very limited number of sources. These species include urea, $C$- and $N$-cyanomethanimine, ethanolamine, glycolamide, carbonic acid, and dimethyl sulphide. Our results reveal that the extraordinary molecular complexity observed in G+0.693 is not unique, but may instead reflect a natural outcome of shock-dominated chemistry in the Galactic Centre. The G+0.633 and G+0.693 clouds exhibit remarkably similar excitation conditions and comparable molecular abundances, establishing them as an ideal benchmarking pair for astrochemical studies. Moreover, G+0.633 offers a clear advantage for molecular observations over G+0.693 owing to the significantly narrower linewidths of its molecular line emission, nearly half as broad as those characteristic of G+0.693, making it an exceptionally powerful target for guiding the search for increasingly complex molecules in the ISM.

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arXiv2026

The Galactic Centre G+0.633-0.0604 Molecular Cloud: A New Gold Mine for Astrochemistry

Astrochemistry is living a golden age, with more than a quarter of the ~350 molecules in the current interstellar census having been detected over the last three years. One of the sources driving this progress is the G+0.693-0.027 cloud, located in the northern part of the Galactic Centre Sgr B2 complex. In this contribution, we present the astrochemical characterisation of G+0.633-0.0604, a newly discovered chemically rich molecular cloud at the southern edge of Sgr B2. With an inventory of >120 species, G+0.633 provides robust second detections of several prebiotic molecules only reported towards G+0.693, establishing it as the first confirmed astrochemical twin of G+0.693 while demonstrating that the extraordinary chemistry of this cloud is not unique. Furthermore, G+0.633 offers an observational advantage over G+0.693 since it displays half narrower linewidths. Together, G+0.633 and G+0.693 form a unique benchmark pair for unveiling molecular complexity and prebiotic chemistry in the interstellar medium.

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arXiv2026

Chemical modelling of interstellar MgS

The detection of magnesium sulphide (MgS) and sodium sulphide (NaS) towards the Galactic Center molecular cloud G+0.693 constitutes the first detection of metal sulphides in the interstellar medium (ISM). However, there is scarce information about the key reactions (either in the gas phase or on grains) involved in their formation. In this paper, we model the chemistry of MgS simulating the passage of a low-velocity shock to recover the abundances recently measured towards G+0.693. Through this chemical modelling, we analyse the dominant reactions involved in the formation and destruction of this molecule, their associated chemical time-scales, and the depletion factor needed to recover the observed abundances. We build the initial chemical network of MgS by using SiS as a proxy for this metal sulphide, and we investigate the exothermicity of these and additional, uniquely proposed reactions through quantum chemical computations. We run a three-phase model (initial translucent cloud, cloud collapse phase and shock interaction stage) that mimics the evolution and physical conditions of G+0.693. Our results show that a depletion factor of 1000 is required for elemental Mg to recover the observed abundances of MgS. This implies that potentially more than 99.9% of Mg is locked in dust grains. The dominant reaction leading to the formation of MgS is the neutral-neutral reaction between MgH and S in the gas phase. This work represents the first analysis of the chemistry of the metal-sulphide MgS and suggests that Mg is largely incorporated into dust grains, most likely in the form of silicates. However, additional laboratory and/or theoretical studies of the key MgS formation reactions are essential to obtain more reliable constraints. Future missions, such as PRIMA, will provide insights into the amount of metal-sulphides locked into interstellar dust grains.

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arXiv2026

High $^{12}$C/$^{13}$C isotopic ratios toward G+0.693-0.027: evidence for gas inflow to the Central Molecular Zone

Isotopic ratios are key tracers of Galactic chemical evolution because different isotopes are synthesized through distinct stellar nucleosynthesis processes. While the $^{12}$C/$^{13}$C ratio increases with galactocentric distance across the Galactic disc, measurements in the Central Molecular Zone (CMZ) have historically yielded low values ($\sim$3-30), often affected by high optical depths. We aim to determine the initial $^{12}$C/$^{13}$C ratio of the parent material of the CMZ molecular cloud G+0.693$-$0.027 using optically thin molecular tracers and correcting for isotopic fractionation. We analyzed an ultra-high-sensitivity spectral survey obtained with the IRAM 30m and Yebes 40m telescopes, detecting single and double $^{13}$C isotopologues of HC$_3$N and HC$_5$N. Column densities and isotopic ratios were derived and compared with astrochemical models including $^{13}$C- and $^{15}$N-isotopologues to quantify isotopic fractionation. We derive $^{12}$C/$^{13}$C ratios of $36.7\pm1.0$ for HC$_3$N (using double $^{13}$C isotopologues) and $38.8\pm1.5$ for HC$_5$N, significantly higher than previous CMZ estimates based on simpler molecules. The models indicate low to intermediate isotopic fractionation at early times ($<3\times10^4$ yr), implying an initial $^{12}$C/$^{13}$C ratio of $\sim$48 for the gas from which present-day CMZ molecular clouds formed. The inferred range (37-48) is consistent with values observed at Galactocentric distances of 3-5 kpc, supporting a scenario in which the CMZ is replenished by gas inflows from the Galactic disc driven by the Galactic bar, with a possible contribution from less chemically processed material accreted from external systems such as dwarf galaxies.

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arXiv2026

Aromatic rings in the Central Molecular Zone: Benzonitrile

In recent years, several aromatic molecules (benzene-based rings) have been detected in the cold molecular cloud TMC-1, with its CN-derivative, benzonitrile (c-C$_6$H$_5$CN), also identified in other nearby cold sources. However, observed abundances differ significantly from chemical model predictions, indicating an incomplete understanding of its chemistry and motivating searches in distinct environments. We report new detections of benzonitrile in two warmer molecular clouds of the Central Molecular Zone (CMZ): G+0.693-0.027 and G+0.633-0.0604. Using Yebes 40m ultra-deep surveys in the 31--50 GHz range, we performed LTE and non-LTE analyses to derive the physical parameters of the emission. We obtain column densities of $N$=(7.4$\pm$0.5)$\times10^{12}$ and (2.60$\pm$0.13)$\times10^{12}$ cm$^{-2}$, corresponding to abundances relative to H$_2$ of (6$\pm$1)$\times10^{-11}$ and (4.3$\pm$0.9)$\times10^{-11}$, consistent with values in cold Galactic clouds. The HC$_7$N/benzonitrile ratio is lower (2.15-2.4) than in colder sources (4.5-30), suggesting environmental effects and a relative enhancement of aromatic chemistry in the CMZ. These results confirm that benzonitrile is widespread and can survive in harsher environments (e.g., high temperatures, shocks, enhanced cosmic-ray ionization) than those in Galactic cold clouds. This suggests that aromatics are stable and abundant species that can significantly contribute to the total budget of interstellar carbon in molecular clouds. A top-down formation scenario, involving fragmentation of larger carbonaceous species, is consistent with the nearly constant abundances observed with molecular size.

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arXiv2026

Expanding the C$_3$H$_6$O$_2$ Isomeric Interstellar Inventory: Discovery of Lactaldehyde and Methoxyacetaldehyde in G+0.693-0.027

The tentative detection of 3-hydroxypropanal (HO(CH$_2$)$_2$C(O)H) toward the Galactic center molecular cloud G+0.693-0.027 prompts a systematic survey in this source aimed at detecting all C$_3$H$_6$O$_2$ isomers with available spectroscopy. We use an ultra-deep broadband spectral survey of G+0.693-0.027, carried out with the Yebes 40 m and IRAM 30 m telescopes, to conduct the astronomical search. We report the first interstellar detection of lactaldehyde (CH$_3$CH(OH)C(O)H) and methoxyacetaldehyde (CH$_3$OCH$_2$C(O)H), together with the second detections (i.e., confirmation) of methyl acetate (CH$_3$C(O)OCH$_3$) and hydroxyacetone (CH$_3$C(O)CH$_2$OH), and new detections in this source of both $anti$- and $gauche$- conformers of ethyl formate (CH$_3$CH$_2$OC(O)H), the latter tentatively. In contrast, neither propionic acid, CH$_3$CH$_2$C(O)OH, nor glycidol, c-CH$_2$OCHCH$_2$OH (i.e., the most and the least stable species within the C$_3$H$_6$O$_2$ family, respectively) were detected, and we provide upper limits on their fractional abundances of $\leq$1.5 $\times$ 10$^{-10}$ and $\leq$3.7 $\times$ 10$^{-11}$. Interestingly, all C$_3$H$_6$O$_2$ isomers can be synthesized through radical-radical reactions on the surface of dust grains, ultimately tracing back to CO as the parent molecule. We suggest that formation of the detected isomers is mainly driven by successive hydrogenation of CO, producing CH$_3$OH and CH$_3$CH$_2$OH as the primary parent species. Conversely, propionic acid is thought to originate from the oxygenation of CO via the HOCO intermediate, which help us rationalize its non-detection. Overall, our findings notably expand the known chemical inventory of the interstellar medium and provide direct observational evidence that increasingly complex chemistry involving O-bearing species occurs in space.

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arXiv2025

Piecing together formic acid isomerism in dark clouds. Detection of cis-formic acid in TMC-1 and astrochemical modeling

The presence of molecular isomers in interstellar environments has become a topic of growing interest within the astrochemical community. Contrary to predictions based on thermodynamic equilibrium, recent observations reveal a diverse array of high-energy isomers and conformers. One of the most iconic molecular isomers detected in space, formic acid (HCOOH, FA), has been the focus of extensive theoretical research aimed at understanding its speciation into cis and trans conformers in dark clouds and photodissociation regions. In this work, we report the detection of c-FA, the higher-energy conformer, using ultrasensitive observations of TMC-1. This detection adds to previous findings in the Barnard-5 and L483 dark clouds. The derived trans-to-cis isomer ratio in TMC-1, 17.5, closely matches those observed in other sources, suggesting that the same chemical processes are at play across these environments. To investigate this, we conducted detailed astrochemical gas-grain models tailored to formic acid isomerism to explain the observed ratios. Our models successfully reproduce the observed trans/cis ratios and indicate that the presence of cis-formic acid can be attributed to the release of c-FA from grains, followed by isomerization driven by the excess energy released during the desorption process, a process that we name as isomerization upon desorption. The models also show that the isomerization of t-FA to c-FA in the gas phase is negligible at 10 K, meaning the observed ratios are a direct consequence of the formation pathways of both isomers on the surface of dust grains. However, at higher temperatures, quantum tunneling mediated direct isomerization in the gas becomes significant, and the ratios converge toward the thermodynamic equilibrium value.

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arXiv2025

High-energy interstellar isomers: cis-N-methylformamide in the G+0.693-0.027 molecular cloud

Isomerism in complex organic molecules provides key insights into the formation mechanisms and physical conditions of the interstellar medium (ISM). Among the C$_2$H$_5$NO isomers, only acetamide and trans-N-methylformamide (trans-NMF) have been detected in space. The recent detection of higher-energy isomers in other chemical families raises questions about the formation and abundance of less stable isomers. We used ultra-sensitive wide-band spectral surveys obtained with the Yebes 40 m and IRAM 30 m telescopes to search for cis-NMF towards the Galactic Centre molecular cloud G+0.693-0.027. We present the first detection of cis-NMF in the ISM, with 55 unblended or slightly blended transitions, 44 of which were new transitions identified based on extrapolated spectroscopic data. Due to the lack of collisional rate coefficients, a quasi-non-LTE analysis, which separated the transitions into different K$_a$ ladders, was used to determine the excitation conditions. The resulting trans/cis-NMF isomeric ratio of 2.9$\pm$0.6 deviates significantly from thermodynamic expectations, suggesting that kinetic non-equilibrium processes and stereospecific chemical pathways are responsible for the formation of cis-NMF in this environment. The detection of cis-NMF expands the known inventory of interstellar C$_2$H$_5$NO isomers and challenges the assumption that isomer abundances strictly correlate with thermodynamic stability. Laboratory and theoretical studies propose formation via CH$_3$NCO hydrogenation or spin-forbidden reactions involving CH$_2$ and NH$_2$CHO, though these may not reflect typical ISM conditions. This finding highlights the need for further investigation into isomerisation mechanisms and constrains astrochemical models of complex organic molecules.

astro-ph.GA↗

arXiv2024

Excitation and spatial study of a prestellar cluster towards G+0.693-0.027 in the Galactic centre

Star formation in the central molecular zone (CMZ) is suppressed with respect to that of the Galactic disk, and this is likely related to its high turbulent environment. This turbulence impedes the potential detection of prestellar cores. We present the temperature, density, and spatial structure of the CMZ molecular cloud G+0.693-0.027, which has been proposed to host a prestellar cluster in the Sgr B2 region. We analysed multiple HC$_{3}$N rotational transitions that were observed with the IRAM 30m, APEX, Yebes 40m, and GBT radio telescopes, together with SMA+APEX spatially resolved maps. The spectral shape of HC$_{3}$N lines shows three velocity components: a broad component with a line width of 23 km s$^{-1}$ (C1), and two narrow components with line widths of 7.2 and 8.8 km s$^{-1}$ (C2 and C3). This suggests that a fraction of the molecular gas in this cloud is undergoing turbulence dissipation. From a non-local thermodynamic equilibrium analysis we have found H$_{2}$ densities of 2$\times$10$^{4}$ cm$^{-3}$, 5$\times$10$^{4}$ cm$^{-3}$, and 4$\times$10$^{5}$ cm$^{-3}$ and kinetic temperatures of 140 K, 30 K, and 80 K for C1, C2, and C3, respectively. The spatially resolved maps confirm that the colder and high-density condensations C2 and C3, which peak in the 70-85 km s$^{-1}$ velocity range, are embedded in a more diffuse and warmer gas (C1). The larger-scale structure of the Sgr B2 region shows a hole at 40-50 km s$^{-1}$ that is likely due to a small cloud that shocked the Sgr B2 region and is spatially related with a massive cloud at 60-80 km s$^{-1}$. We propose that the impacting small cloud sequentially triggered the formation of Sgr B2(M), (N), and (S) and the condensations in G+0.693-0.027 during its passage. Based on the analysis of the masses of the two condensations and on the virial parameters, C2 might expand, while C3 might further fragment or collapse.

astro-ph.GA↗

arXiv2024

Discovery of MgS and NaS in the Interstellar Medium and tentative detection of CaO

We report the first detection of the metal-bearing molecules sodium sulfide (NaS) and magnesium sulfide (MgS) and the tentative detection of calcium monoxide (CaO) in the interstellar medium (ISM) towards the Galactic Center molecular cloud G+0.693-0.027. The derived column densities are (5.0+-1.1) x 10$^{10}$ cm$^{-2}$, (6.0+-0.6) x $^{10}$ cm$^{-2}$, and (2.0+-0.5) x $^{10}$ cm$^{-2}$, respectively. This translates into fractional abundances with respect to H$_2$ of (3.7+-1.0) x $10^{-13}$, (4.4+-0.8) x $10^{-13}$, and (1.5+-0.4) x $10^{-13}$, respectively. We have also searched for other Na-, Mg- and Ca-bearing species towards this source but none of them have been detected and thus we provide upper limits for their abundances. We discuss the possible chemical routes involved in the formation of these molecules containing metals under interstellar conditions. Finally, we compare the ratio between sulfur-bearing and oxygen-bearing molecules with and without metals, finding that metal-bearing sulfur molecules are much more abundant than metal-bearing oxygen ones, in contrast with the general trend found in the ratios between other non metal- oxygen- and sulfur-bearing molecules. This further strengthen the idea that sulfur may be little depleted in G+0.693-0.027 as a result of the low velocity shocks present in this source sputtering large amounts of material from dust grains.

astro-ph.GA↗

arXiv2022

Toward the limits of complexity of interstellar chemistry: Rotational spectroscopy and astronomical search for n- and i-butanal

In recent times, large organic molecules of exceptional complexity have been found in diverse regions of the interstellar medium. In this context, we aim to provide accurate frequencies of the ground vibrational state of two key aliphatic aldehydes, n-butanal and its branched-chain isomer, i-butanal, to enable their eventual detection in the interstellar medium. We employ a frequency modulation millimeter-wave absorption spectrometer to measure the rotational features of n- and i-butanal. We use the spectral line survey ReMoCA performed with the Atacama Large Millimeter/submillimeter Array to search for n- and i-butanal toward the star-forming region Sgr B2(N). We also search for both aldehydes toward the molecular cloud G+0.693-0.027 with IRAM 30 m and Yebes 40 m observations. Several thousand rotational transitions belonging to the lowest-energy conformers have been assigned in the laboratory spectra up to 325 GHz. A precise set of the relevant rotational spectroscopic constants has been determined for each structure. We report non-detections of n- and i-butanal toward both sources, Sgr B2(N1S) and G+0.693-0.027. We find that n- and i-butanal are at least 2-6 and 6-18 times less abundant than acetaldehyde toward Sgr B2(N1S), respectively, and that n-butanal is at least 63 times less abundant than acetaldehyde toward G+0.693-0.027. Comparison with astrochemical models indicates good agreement between observed and simulated abundances (where available). Grain-surface chemistry appears sufficient to reproduce aldehyde ratios in G+0.693-0.027; gas-phase production may play a more active role in Sgr B2(N1S). Our astronomical results indicate that the family of interstellar aldehydes in the Galactic center region is characterized by a drop of one order of magnitude in abundance at each incrementation in the level of molecular complexity.

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arXiv2020

Interstellar glycolamide: A comprehensive rotational study and an astronomical search in Sgr B2(N)

Glycolamide is a glycine isomer and also one of the simplest derivatives of acetamide (e.g., one hydrogen atom is replaced with a hydroxyl group), which is a known interstellar molecule. Using a battery of state of the art rotational spectroscopic techniques in the frequency and time domain, around 1500 transitions have been newly assigned. Based on the reliable frequency predictions, we report a radioastronomical search for glycolamide in the well known high-mass star forming region Sgr B2(N) using the ALMA imaging spectral line survey ReMoCA. We also searched for glycolamide toward Sgr B2(N) with the Effelsberg radio telescope. We report the nondetection of glycolamide toward this source with an abundance at least six and five times lower than that of acetamide and glycolaldehyde, respectively. Our astrochemical model suggests that glycolamide may be present in this source at a level just below the upper limit, which was derived from the EMoCA survey. We could also not detect the molecule in the region's extended molecular envelope, which was probed with the Effelsberg telescope. We find an upper limit to its column density that is similar to the column densities obtained earlier for acetamide and glycolaldehyde with the Green Bank Telescope.

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