arXiv subjects

M. Sardar

Publications and source records attributed to M. Sardar.

12 recordsLinked to original sources

arXiv2022

Evolution of magnetic and transport properties in Cu doped pyrochlore iridate Eu2(Ir1-xCux)2O7

We have investigated the effect of Cu substitution in Eu2(Ir1-xCux)2O7 with the help of magnetic and transport property measurements. XPS measurement reveals that each Cu2+ converts Ir4+ to double amount of Ir5+ ions. The metal-insulator transition temperature (T_MI) is obtained around 120 K. In the insulating phase, at lower temperature below 50 K, the temperature dependent resistivity follows a power law dependence and the magnitude of the exponent increases with Cu concentrations. The temperature dependent thermopower is observed to follow the electrical resistivity down to 50 K, except for a sudden drop in thermopower at temperature below 50 K. We find negligible Hall voltage in the metallic regime of the samples but a sudden Hall voltage is developed below 50 K. We observe bifurcation in zero field cooled and field cooled (ZFC-FC) magnetization below irreversibility temperature, exchange bias and negative magnetoresistance at 3 K and the magnitude of all these properties increases with Cu concentrations. In the insulating region (below 6 K) there exists a linear specific heat and its coefficient decreases with Cu doping which indicates the reduction of spinon contribution with Cu doping.

cond-mat.str-el↗

arXiv2020

Role of f-d exchange interaction and Kondo scattering in Nd doped pyrochlore Iridate (Eu1-xNdx)2Ir2O7

We report study of magnetization, resistivity, magnetoresistance and specific heat of the pyrochlore Iridate (Eu1-xNdx)2Ir2O7 with x=0.0, 0.5 and 1.0, where spin orbit coupling, electronic correlation, magnetic frustration and Kondo scattering coexists. Metal insulator transition temperature (T_MI) decrease with increase in Nd content but always coincides with magnetic irreversibility temperature (field induced moment). Resistivity below T_MI do not fit with either activated (gap) or to any power law (gapless) dependence. The Curie constant show surprising result, that Nd induces singlet correlation (reduction of para-moment) in Ir sublattice. Magnetoresistance is negative at low temperatures below 10 K and increases strongly with increase in x and vary quadratically with field switching over to linear dependence above 50 kOe. Low temperature specific heat shows Schottky peak, coming from Nd moments, showing existence of doublet split in Nd energy level, arising from f-d exchange interaction. All materials show presence of a linear specific heat in the insulating region. The coefficient of linear specific heat for x= 0.0 does not vary with external magnetic field but varies superlinearly for x = 1.0 materials. We argue that linear specific heat probably rules out weakly correlated phases like Weyl fermions. We propose that with the introduction of Nd at Eu site the system evolves from chiral spin liquid with gapless spinon excitations with a very small charge gap to Kondo type interaction superposed on chiral spin liquid coexisting with long range antiferromagnetic ordering. Huge increase of magnetoresistance with increase in Nd concentrations shows importance of Kondo scattering in the chiral spin liquid material by rare earth moments.

cond-mat.str-el↗

arXiv2013

Magnetic hysteresis loop as a probe to distinguish single layer from many layer graphitic structure

In this report we have pointed out that magnetic hysteresis loop can be used as a probe to distinguish a single layer from a many layer graphitic structure. Chemically we have synthesized graphitic oxide (GO) and reduced graphitic oxide (RGO) for this investigation. We observe ferromagnetic like hysteresis loops for both GO and RGO below a certain applied critical magnetic field and above this critical field we observe cross-over of the positive magnetization to negative magnetization leading to diamagnetic behaviour. This cross-over is more dominant for the case of many layer graphitic structure. Upon annealing of GO in air the critical cross-over field decreases and the magnetization increases for multilayer graphitic structure. Possible reasons for all these observations and phenomena is presented here.

cond-mat.mes-hall↗

arXiv2013

Anamolous reduction of magnetic coercivity of graphene oxide and reduced graphene oxide upon cooling

In this report we present the temperature evolution of magnetic coercivity of graphene oxide (GO) and reduced graphene oxide (RGO). We report an anamolous decrease in coercivity of GO and RGO with decreasing temperature. We could explain this anamolous behavior invoking the inherent presence of ripple in graphene. We observe antiferromagnetic and ferromagnetic behavior at room temperature for GO and RGO respectively, but at low temperatures both shows paramagnetic behavior.

cond-mat.mtrl-sci↗

arXiv2010

Cooperative ordering of superparamagnetic ZnO nanograins

In this paper we have tried to understand the precise nature of magnetism in ZnO nanoparticles. Cooling field dependence of magnetic hysteresis and coercive field was observed for high temperature annealed sample indicating cooperative magnetic correlation and ordering within the agglomerated nanograins. The increasing induced internal magnetic field along the direction of external field for the high temperature annealed sample has been fitted with the modified Weiss-Brillouin model indicating emergence of long range intergrain interaction among the superparamagnetic grains. We propose a simple idea that explains the reduction of magnetisation due to vortex state like flux closure situation.

cond-mat.mtrl-sci↗

arXiv2010

How Gold nanoparticle acquires magnetism? - Formation of large orbital moment at the interface

In this paper, we have tried to find out the origin of magnetism in Gold nanoparticles (Au- NPs). We observe that upon incorporating Gold nanoparticles (Au-NPs) in Fe3O4 nanoparticle medium the net magnetisation increases compared to the pure Fe3O4 nanoparticle medium. This increase of magnetization can be attributed to the large orbital magnetic moment formation at the Au/magnetic particle interface indicating that magnetism observed in Au-NPs is an interfacial effect. This interfacial effect has been supported by the observation of sudden transition from positive saturated magnetisation to a negative diamagnetic contribution as a function of magnetic field on citrate coated gold Au-NPs.

cond-mat.mtrl-sci↗

arXiv2009

Enhanced magnetism, memory and aging in Gold-Iron oxide nanoparticle composites

In this report we present systematic magnetic studies of pure iron oxide nanoparticles and gold iron oxide nanocomposite with increasing Au particle size/content. For the magnetic studies of these samples we have measured: (1) zero field cooled (ZFC) and field cooled (FC) magnetization, (2) ac susceptibility, (3) magnetization vs field at various temperatures, (4) thermoremanant magnetization relaxation (TRM) and zero field cooled magnetization relaxation (ZFCM) at fixed temperature for various wait times tw for studying the aging effect, (5) magnetization memory effect and (6) exchange bias as a function of cooling field. The detailed magnetic measurement analysis indicates that the pure Fe3O4 nanoparticles sample behaves like a superparamagnet and on incorporation of gold (Au) nanoparticles the nanocomposite system slowly evolves from superparamagnetic to superspin glass state. The memory and aging effect enhances with the increase of the Au nanoparticle size/content. The most important observation in this study is the enhancement of magnetization with the incorporation of Au nanoparticles. The enhancement increases with the increase in the Au content in the nanocomposite. We have explained the cause of this enhancement of magnetization as due to large orbital magnetic moment formation at the Au/magnetic particle interface.

cond-mat.mtrl-sci↗

arXiv2008

Change in the room temperature magnetic property of ZnO upon Mn doping

We present in this paper the changes in the room temperature magnetic property of ZnO on Mn doping prepared using solvo-thermal process. The zero field cooled (ZFC) and field cooled (FC) magnetisation of undoped ZnO showed bifurcation and magnetic hysteresis at room temperature. Upon Mn doping the magnetic hysteresis at room temperature and the bifurcation in ZFC-FC magnetization vanishes. The results seem to indicate that undoped ZnO is ferromagnetic while on the other hand the Mn doped ZnO is not a ferromagnetic system. We observe that on addition of Mn atoms the system shows antiferromagnetism with very giant magnetic moments.

cond-mat.mtrl-sci↗

arXiv2007

Enhancement of ferromagnetism upon thermal annealing in pure ZnO

We report here enhancement of ferromagnetism in pure ZnO upon thermal annealing with the ferromagnetic transition temperature Tc above room temperature. We observe a finite coercive field upto 300K and a finite thermoremanent magnetization upto 340K for the annealed sample. We propose that magnetic moments can form at anionic vacancy clusters. Ferromagnetism can occur due to either superexchange between vacancy clusters via isolated F+ centers, or through a limited electron delocalization between vacancy clusters. Isolated vacancy clusters or isolated F+ centers give rise to a strong paramagnetic like behaviour below 10K.

cond-mat.mtrl-sci↗

arXiv2005

Conductivity landscape of highly oriented pyrolytic graphite surface containing ribbons and edges

We present an extensive study on electrical spectroscopy of graphene ribbons and edges of highly oriented pyrolytic graphite (HOPG) using atomic force microscope (AFM). We have addressed in the present study two main issues, (1) How does the electrical property of the graphite (graphene) sheet change when the graphite layer is displaced by shear forces? and (2) How does the electrical property of the graphite sheet change across a step edge? While addressing these two issues we observed, (1) variation of conductance among the graphite ribbons on the surface of HOPG. The top layer always exhibits more conductance than the lower layers, (2) two different monolayer ribbons on the same sheet of graphite shows different conductance, (3) certain ribbon/sheet edges show sharp rise in current, (4) certain ribbons/sheets on the same edge shows both presence and absense of the sharp rise in the current, (5) some lower layers at the interface near a step edge shows a strange dip in the current/conductance (depletion of charge). We discuss possible reasons for such rich conducting landscape on the surface of graphite.

cond-mat.other↗

arXiv1995

Enhancement of superconducting correlation due to interlayer tunneling.

Interlayer single particle tunneling between the $Cu-O$ layers suppress the in-plane short range magnetic order (which is modeled as spin density wave (SDW) insulator). Doping over the SDW state kills perfect nesting of the Fermi surface (FS) in certain directions and hence SDW gap reduces to zero in those directions of the FS. Coupling between the planes through interlayer tunneling ($t_{\perp}$) further suppresses the in-plane magnetic SDW-gap and hence becomes anisotropic. Superconductivity arises in the gapless regions of the FS under the `modified spin bag' mechanism. We show that the highest $T_c$ can only be obtained for non-zero $t_{\perp}$ based on this mechanism.

cond-mat↗

arXiv1994

Temperature Dependent Gap Anisotropy from Interlayer Tunneling

A recent experiment by Ma and collaborators shows that the gap anisotropy in ${\rm Bi}_2 {\rm Sr}_2 {\rm Ca}_1 {\rm Cu}_2 {\rm O}_{8+x}$ is strongly temperature dependent. In particular, the superconducting gap along the $Γ- M$ direction shows a weaker temperature dependence than the gap along the $Γ- X$ direction which decreases rapidly with temperature. We explain this novel feature as a natural consequence of the interlayer tunneling mechanism of superconductivity.

cond-mat↗