SearcharxivSearch

arXiv subjects

M. Servol

Publications and source records attributed to M. Servol.

2 recordsLinked to original sources

Anisotropy of Ultrafast Strain in $V_2O_3$ Thin Films: Out-of-Equilibrium Phase Transitions under Interfacial Clamping

Ultrafast photoinduced insulator-to-metal transitions in correlated materials are often mediated by lattice distortions, yet the role of interfacial lattice constraints in shaping nonequilibrium pathways remains largely unexplored. We use azimuth-resolved time-resolved X-ray diffraction to track orientation-dependent strain dynamics in granular V$_2$O$_3$ thin films on c-cut sapphire, where thermal-expansion mismatch imposes anisotropic interfacial strain. Across the thermal transition, the azimuthal profile of the (110)$_H$ strain inverts curvature, providing direct evidence of partial clamping of the hexagonal basal-plane lattice (a$_H$,b$_H$). After photoexcitation of the antiferromagnetic insulating phase, the structural response remains clamp-limited: weakly constrained grain families reach the full basal-plane contraction characteristic of the metallic-like state, whereas strongly constrained families exhibit a strongly reduced distortion. Fluence-dependent measurements further disentangle transformed fraction from clamping-limited lattice distortion. Our results show that interfacial clamping acts as a static selector for ultrafast phase switching and provide a general route to quantify anisotropic strain dynamics in heterostructures.

cond-mat.mtrl-sci

Ultrafast non-thermal laser excitation of gigahertz longitudinal and shear acoustic waves in spin-crossover molecular crystals [$Fe(PM-AzA)_{2}$$(NCS)_{2}$]

We report GHz longitudinal as well as shear acoustic phonons photoexcitation and photodetection using femtosecond laser pulses in a spin-crossover molecular crystal. From our experimental observation of time domain Brillouin scattering triggered by the photoexcitation of acoustic waves across the low-spin (LS) to high-spin (HS) thermal crossover, we reveal a link between molecular spin state and photoexcitation of coherent GHz acoustic phonons. In particular, we experimentally evidence an unconventional non-thermal pathway for the laser excitation of GHz phonons. We also provide experimental insight on the optical and mechanical parameters evolution across the LS/HS spin crossover temperature T$_{1/2}$.

cond-mat.mtrl-sci