arXiv subjects

M. T. Beltrán

Publications and source records attributed to M. T. Beltrán.

At least 55 records · Page 3Linked to original sources

arXiv2020

SEDIGISM-ATLASGAL: Dense Gas Fraction and Star Formation Efficiency Across the Galactic Disk

By combining two surveys covering a large fraction of the molecular material in the Galactic disk we investigate the role the spiral arms play in the star formation process. We have matched clumps identified by ATLASGAL with their parental GMCs as identified by SEDIGISM, and use these giant molecular cloud (GMC) masses, the bolometric luminosities, and integrated clump masses obtained in a concurrent paper to estimate the dense gas fractions (DGF$_{\rm gmc}=\sum M_{\rm clump}/M_{\rm gmc}$) and the instantaneous star forming efficiencies (i.e., SFE$_{\rm gmc} = \sum L_{\rm clump}/M_{\rm gmc}$). We find that the molecular material associated with ATLASGAL clumps is concentrated in the spiral arms ($\sim$60% found within $\pm$10 km s$^{-1}$ of an arm). We have searched for variations in the values of these physical parameters with respect to their proximity to the spiral arms, but find no evidence for any enhancement that might be attributable to the spiral arms. The combined results from a number of similar studies based on different surveys indicate that, while spiral-arm location plays a role in cloud formation and HI to H$_2$ conversion, the subsequent star formation processes appear to depend more on local environment effects. This leads us to conclude that the enhanced star formation activity seen towards the spiral arms is the result of source crowding rather than the consequence of a any physical process.

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arXiv2020

The GUAPOS project: G31.41+0.31 Unbiased ALMA sPectral Observational Survey -- I. Isomers of C$_{2}$H$_{4}$O$_{2}$

Understanding the degree of chemical complexity that can be reached in star-forming regions, together with the identification of precursors of the building blocks of life in the interstellar medium, is one of the goals of astrochemistry. Unbiased spectral surveys with large bandwidth and high spectral resolution are thus needed, to resolve line blending in chemically rich sources and identify complex organic molecules. This kind of observations has been successfully carried out, mainly towards the Galactic Center, a region that shows peculiar environmental conditions. We present an unbiased spectral survey at 3mm of one of the most chemically rich hot molecular cores located outside the Galactic Center, in the high-mass star-forming region G31.41+0.31. In this first paper, we present the survey and discuss the detection of the 3 isomers of C$_{2}$H$_{4}$O$_{2}$: methyl formate, glycolaldehyde and acetic acid. Observations were carried out with ALMA and cover the entire Band 3 from 84 to 116 GHz with an angular resolution of $1.2^{''}$x$1.2^{''}$ and a spectral resolution of $\sim0.488$ MHz. The transitions of the 3 molecules have been analyzed with the software XCLASS. All three isomers were detected and methyl formate and acetic acid abundances in G31 are the highest detected up to now, if compared to sources in literature. The size of the emission varies among the three isomers with acetic acid showing the most compact emission while methyl formate the most extended. The comparison with chemical models suggests the necessity of grain-surface routes for the formation of methyl formate in G31, while for glycolaldehyde both scenarios could be feasible. Proposed grain-surface reaction for acetic acid is not able to reproduce the observed abundance in this work, while gas-phase scenario should be further tested due to large uncertainties.

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arXiv2020

Evolutionary study of complex organic molecules in high-mass star-forming regions

We have studied four complex organic molecules (COMs), methyl formate ($CH_3OCHO$), dimethyl ether ($CH_3OCH_3$), formamide ($NH_2CHO$), and ethyl cyanide ($C_2H_5CN$), towards a large sample of 39 high-mass star-forming regions representing different evolutionary stages, from early to evolved phases. We aim to identify potential correlations between the molecules and to trace their evolutionary sequence through the star formation process. We analysed spectra obtained at 3, 2, and 0.9 mm with the IRAM-30m telescope. We derived the main physical parameters for each species by fitting the molecular lines. We compared them and evaluated their evolution, also taking several other interstellar environments into account. We report detections in 20 sources, revealing a clear dust absorption effect on column densities. Derived abundances are ~$10^{-10}-10^{-7}$ for $CH_3OCHO$ and $CH_3OCH_3$, ~$10^{-12}-10^{-10}$ for $NH_2CHO$, and ~$10^{-11}-10^{-9}$ for $C_2H_5CN$. The abundances of $CH_3OCHO$, $CH_3OCH_3$, and $C_2H_5CN$ are very strongly correlated (r>0.92) across ~4 orders of magnitude. $CH_3OCHO$ and $CH_3OCH_3$ show the strongest correlations in most parameters, and a nearly constant ratio (~1) over a remarkable ~9 orders of magnitude in luminosity for a wide variety of sources: pre-stellar to evolved cores, low- to high-mass objects, shocks, Galactic clouds, and comets. This indicates that COMs chemistry is likely early developed and then preserved through evolved phases. Moreover, the molecular abundances clearly increase with evolution. We consider $CH_3OCHO$ and $CH_3OCH_3$ to be most likely chemically linked: they could e.g. share a common precursor, or be formed one from the other. We propose a general scenario for all COMs, involving a formation in the cold, earliest phases of star formation and a following increasing desorption with the progressive heating of the evolving core.

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arXiv2019

The Hi-GAL catalogue of dusty filamentary structures in the Galactic Plane

The recent data collected by {\it Herschel} have confirmed that interstellar structures with filamentary shape are ubiquitously present in the Milky Way. Filaments are thought to be formed by several physical mechanisms acting from the large Galactic scales down to the sub-pc fractions of molecular clouds, and they might represent a possible link between star formation and the large-scale structure of the Galaxy. In order to study this potential link, a statistically significant sample of filaments spread throughout the Galaxy is required. In this work we present the first catalogue of $32,059$ candidate filaments automatically identified in the Hi-GAL survey of the entire Galactic Plane. For these objects we determined morphological (length, $l^{a}$, and geometrical shape) and physical (average column density, $N_{\rm H_{2}}$, and average temperature, $T$) properties. We identified filaments with a wide range of properties: 2$'$\,$\leq l^{a}\leq$\, 100$'$, $10^{20} \leq N_{\rm H_{2}} \leq 10^{23}$\,cm$^{-2}$ and $10 \leq T\leq$ 35\,K. We discuss their association with the Hi-GAL compact sources, finding that the most tenuous (and stable) structures do not host any major condensation and we also assign a distance to $\sim 18,400$ filaments for which we determine mass, physical size, stability conditions and Galactic distribution. When compared to the spiral arms structure, we find no significant difference between the physical properties of on-arm and inter-arm filaments. We compared our sample with previous studies, finding that our Hi-GAL filament catalogue represents a significant extension in terms of Galactic coverage and sensitivity. This catalogue represents an unique and important tool for future studies devoted to understanding the filament life-cycle.

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arXiv2019

ALMA and ROSINA detections of phosphorus-bearing molecules: the interstellar thread between star-forming regions and comets

To understand how Phosphorus-bearing molecules are formed in star-forming regions, we have analysed ALMA observations of PN and PO towards the massive star-forming region AFGL 5142, combined with a new analysis of the data of the comet 67P/Churyumov-Gerasimenko taken with the ROSINA instrument onboard Rosetta. The ALMA maps show that the emission of PN and PO arises from several spots associated with low-velocity gas with narrow linewidths in the cavity walls of a bipolar outflow. PO is more abundant than PN in most of the spots, with the PO/PN ratio increasing as a function of the distance to the protostar. Our data favor a formation scenario in which shocks sputter phosphorus from the surface of dust grains, and gas-phase photochemistry induced by UV photons from the protostar allows efficient formation of the two species in the cavity walls. Our analysis of the ROSINA data has revealed that PO is the main carrier of P in the comet, with PO/PN>10. Since comets may have delivered a significant amount of prebiotic material to the early Earth, this finding suggests that PO could contribute significantly to the phosphorus reservoir during the dawn of our planet. There is evidence that PO was already in the cometary ices prior to the birth of the Sun, so the chemical budget of the comet might be inherited from the natal environment of the Solar System, which is thought to be a stellar cluster including also massive stars.

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arXiv2019

Origin of the PN molecule in star-forming regions: the enlarged sample

Phosphorus nitride (PN) is the P-bearing species with the highest number of detections in star-forming regions. Multi-line studies of the molecule have shown that the excitation temperature of PN is usually lower than the gas kinetic temperature, suggesting that PN is likely in conditions of sub-thermal excitation. We present an analysis of PN which takes the possible sub-thermal excitation conditions into account in a sample of 24 massive star-forming regions. We observed PN (2-1), (3-2), (4-3), and (6-5) with the IRAM-30m and APEX telescopes and detected PN lines in 15 of them. Together with 9 similar sources detected in PN in previous works, we have analysed the largest sample of star-forming regions to date, made of 33 sources with 24 detections in total (among which 13 are new detections). Hence, we have increased the number of star-forming regions detected in PN by more than a factor 2. Our analysis indicates that the PN lines are indeed sub-thermally excited, but well described by a single excitation temperature. We have compared line profiles and fractional abundances of PN and SiO, a typical shock tracer, and found that almost all objects detected in PN have high-velocity SiO wings. Moreover, the SiO and PN abundances with respect to H2 are correlated over several orders of magnitude, and uncorrelated with gas temperature. This clearly shows that the production of PN is strongly linked to the presence of shocked gas, and rules out alternative scenarios based on thermal evaporation from iced grain mantles.

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arXiv2019

ALMA resolves the hourglass magnetic field in G31.41+0.31

Context. Submillimeter Array (SMA) 870 micron polarization observations of the hot molecular core G31.41+0.31 revealed one of the clearest examples up to date of an hourglass-shaped magnetic field morphology in a high-mass star-forming region. Aims. To better establish the role that the magnetic field plays in the collapse of G31.41+0.31, we carried out Atacama Large Millimeter/submillimeter Array (ALMA) observations of the polarized dust continuum emission at 1.3 mm with an angular resolution four times higher than that of the previous (sub)millimeter observations to achieve an unprecedented image of the magnetic field morphology. Methods. We used ALMA to perform full polarization observations at 233 GHz (Band 6). The resulting synthesized beam is 0.28"x0"20 which, at the distance of the source, corresponds to a spatial resolution of ~875 au. Results. The observations resolve the structure of the magnetic field in G31.41+0.31 and allow us to study the field in detail. The polarized emission in the Main core of G31.41+0.41is successfully fit with a semi-analytical magnetostatic model of a toroid supported by magnetic fields. The best fit model suggests that the magnetic field is well represented by a poloidal field with a possible contribution of a toroidal component of ~10% of the poloidal component, oriented southeast to northwest at ~ -44 deg and with an inclination of ~-45 degr. The magnetic field is oriented perpendicular to the northeast to southwest velocity gradient detected in this core on scales from 1E3-1E4 au. This supports the hypothesis that the velocity gradient is due to rotation and suggests that such a rotation has little effect on the magnetic field. The strength of the magnetic field estimated in the central region of the core with the Davis-Chandrasekhar-Fermi method is ~8-13 mG and implies that the mass-to-flux ratio in this region is slightly supercritical ...

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arXiv2019

Fragmentation, rotation and outflows in the high-mass star-forming region IRAS 23033+5951. A case study of the IRAM NOEMA large program CORE

The formation process of high-mass stars (>8M$_\odot$) is poorly constrained, particularly, the effects of clump fragmentation creating multiple systems and the mechanism of mass accretion onto the cores. We study the fragmentation of dense gas clumps, and trace the circumstellar rotation and outflows by analyzing observations of the high-mass (~500M$_\odot$) star-forming region IRAS 23033+5951. Using the Northern Extended Millimeter Array (NOEMA) in three configurations and the IRAM 30-m single-dish telescope at 220GHz, we probe the gas and dust emission at an angular resolution of ~0.45arcsec, corresponding to 1900au. In the mm continuum emission, we identify a protostellar cluster with at least four mm-sources, where three of them show a significantly higher peak intensity well above a signal-to-noise ratio of 100. Hierarchical fragmentation from large to small spatial scales is discussed. Two fragments are embedded in rotating structures and drive molecular outflows, traced by $^{13}$CO (2-1) emission. The velocity profiles across two of the cores are similar to Keplerian but are missing the highest velocity components close to the center of rotation, which is a common phenomena from observations like these, and other rotation scenarios are not excluded entirely. Position-velocity diagrams suggest protostellar masses of ~6 and 19M$_\sun$. Rotational temperatures from fitting CH$_3$CN ($12_K-11_K$) spectra are used for estimating the gas temperature and by that the disk stability against gravitational fragmentation, utilizing Toomre's $Q$ parameter. [We] identify only one candidate disk to be unstable against gravitational instability caused by axisymmetric perturbations. The dominant sources cover different evolutionary stages within the same maternal gas clump. The appearance of rotation and outflows of the cores are similar to those found in low-mass star-forming regions.

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arXiv2019

Young massive star cluster formation in the Galactic Centre is driven by global gravitational collapse of high-mass molecular clouds

Young massive clusters (YMCs) are the most compact, high-mass stellar systems still forming at the present day. The precursor clouds to such systems are, however, rare due to their large initial gas mass reservoirs and rapid dispersal timescales due to stellar feedback. Nonetheless, unlike their high-z counterparts, these precursors are resolvable down to the sites of individually forming stars, and hence represent the ideal environments in which to test the current theories of star and cluster formation. Using high angular resolution (1$^{\prime\prime}$ / 0.05pc) and sensitivity ALMA observations of two YMC progenitor clouds in the Galactic Centre, we have identified a suite of molecular line transitions -- e.g. c-C$_{3}$H$_{2} $($7-6$) -- that are believed to be optically thin, and reliably trace the gas structure in the highest density gas on star-forming core scales. We conduct a virial analysis of the identified core and proto-cluster regions, and show that half of the cores (5/10) and both proto-clusters are unstable to gravitational collapse. This is the first kinematic evidence of global gravitational collapse in YMC precursor clouds at such an early evolutionary stage. The implications are that if these clouds are to form YMCs, then they likely do so via the "conveyor-belt" mode, whereby stars continually form within dispersed dense gas cores as the cloud undergoes global gravitational collapse. The concurrent contraction of both the cluster-scale gas and embedded (proto)stars ultimately leads to the high (proto)stellar density in YMCs.

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arXiv2019

The SOMA Radio Survey. I. Comprehensive SEDs Of High-Mass Protostars From Infrared To Radio And The Emergence Of Ionization Feedback

We study centimeter continuum emission of eight high- and intermediate-mass protostars that are part of the SOFIA Massive (SOMA) Star Formation Survey, thus building extended spectral energy distributions (SEDs) from the radio to the infrared. We discuss the morphology seen in the centimeter continuum images, which are mostly derived from archival VLA data, and the relation to infrared morphology. We use the SEDs to test new models of high-mass star formation including radiative and disk-wind feedback and associated free-free and dust continuum emission (Tanaka, Tan, & Zhang 2016). We show that interferometric data of the centimeter continuum flux densities provide additional, stringent tests of the models by constraining the ionizing luminosity of the source and help to break degeneracies encountered when modeling the infrared-only SEDs, especially for the protostellar mass. Our derived parameters are consistent with physical parameters estimated by other methods such as dynamical protostellar masses. We find a few examples of additional stellar sources in the vicinity of the high-mass protostars, which may be low-mass young stellar objects. However, the stellar multiplicity of the regions, at least as traced by radio continuum emission, appears to be relatively low.

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arXiv2018

First ALMA maps of HCO, an important precursor of complex organic molecules, towards IRAS 16293-2422

The formyl radical HCO has been proposed as the basic precursor of many complex organic molecules such as methanol (CH$_3$OH) or glycolaldehyde (CH$_2$OHCHO). Using ALMA, we have mapped, for the first time at high angular resolution ($\sim$1$^{\prime\prime}$, $\sim$140 au), HCO towards the Solar-type protostellar binary IRAS 16293$-$2422, where numerous complex organic molecules have been previously detected. We also detected several lines of the chemically related species H$_2$CO, CH$_3$OH and CH$_2$OHCHO. The observations revealed compact HCO emission arising from the two protostars. The line profiles also show redshifted absorption produced by foreground material of the circumbinary envelope that is infalling towards the protostars. Additionally, IRAM 30m single-dish data revealed a more extended HCO component arising from the common circumbinary envelope. The comparison between the observed molecular abundances and our chemical model suggests that whereas the extended HCO from the envelope can be formed via gas-phase reactions during the cold collapse of the natal core, the HCO in the hot corinos surrounding the protostars is predominantly formed by the hydrogenation of CO on the surface of dust grains and subsequent thermal desorption during the protostellar phase. The derived abundance of HCO in the dust grains is high enough to produce efficiently more complex species such as H$_2$CO, CH$_3$OH, and CH$_2$OHCHO by surface chemistry. We found that the main formation route of CH$_2$OHCHO is the reaction between HCO and CH$_2$OH.

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arXiv2018

Chasing discs around O-type (proto)stars - ALMA evidence for an SiO disc and disc wind from G17.64+0.16

We present high angular resolution 0.2 arcsec continuum and molecular emission line Atacama Large Millimeter/sub-millimeter Array (ALMA) observations of G17.64+0.16 in Band 6 (220GHz) taken as part of a campaign in search of circumstellar discs around (proto)-O-stars. At a resolution of 400au the main continuum core is essentially unresolved and isolated from other strong and compact emission peaks. At a resolution of 400au the main continuum core is essentially unresolved and isolated from other strong and compact emission peaks. We detect SiO (5-4) emission that is marginally resolved and elongated in a direction perpendicular to the large-scale outflow seen in the 13CO (2-1) line using the main ALMA array in conjunction with the Atacama Compact Array (ACA). Morphologically, the SiO appears to represent a disc-like structure. Using parametric models we show that the position-velocity profile of the SiO is consistent with the Keplerian rotation of a disc around an object between 10-30Mo in mass, only if there is also radial expansion from a separate structure. The radial motion component can be interpreted as a disc wind from the disc surface. Models with a central stellar object mass between 20 and 30Mo are the most consistent with the stellar luminosity (100000 Lo) and indicative of an O-type star. The H30a millimetre recombination line (231.9GHz) is also detected, but spatially unresolved, and is indicative of a very compact, hot, ionised region co-spatial with the dust continuum core. Accounting for all observables, we suggest that G17.64 is consistent with a O-type young stellar object in the final stages of protostellar assembly, driving a wind, but that has not yet developed into a compact HII region. The existance and detection of the disc in G17.64 is likely related to its isolated and possibly more evolved nature, traits which may underpin discs in similar sources.

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arXiv2018

Accelerating infall and rotational spin-up in the hot molecular core G31.41+0.31

As part of our effort to search for circumstellar disks around high-mass stellar objects, we observed the well-known core G31.41+0.31 with ALMA at 1.4 mm with an angular resolution of~0.22" (~1700 au). The dust continuum emission has been resolved into two cores namely Main and NE. The Main core, which has the stronger emission and is the more chemically rich, has a diameter of ~5300 au, and is associated with two free-free continuum sources. The Main core looks featureless and homogeneous in dust continuum emission and does not present any hint of fragmentation. Each transition of CH3CN and CH3OCHO, both ground and vibrationally excited, as well as those of CH3CN isotopologues, shows a clear velocity gradient along the NE-SW direction, with velocity linearly increasing with distance from the center, consistent with solid-body rotation. However, when comparing the velocity field of transitions with different upper level energies, the rotation velocity increases with increasing energy of the transition, which suggests that the rotation speeds up towards the center. Spectral lines towards the dust continuum peak show an inverse P-Cygni profile that supports the existence of infall in the core. The infall velocity increases with the energy of the transition suggesting that the infall is accelerating towards the center of the core, consistent with gravitational collapse. Despite the monolithic appearance of the Main core, the presence of red-shifted absorption, the existence of two embedded free-free sources at the center, and the rotational spin-up are consistent with an unstable core undergoing fragmentation with infall and differential rotation due to conservation of angular momentum. Therefore, the most likely explanation for the monolithic morphology is that the large opacity of the dust emission prevents the detection of any inhomogeneity in the core.

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arXiv2018

Nitrogen fractionation in high-mass star-forming cores across the Galaxy

The fractionation of nitrogen (N) in star-forming regions is a poorly understood process. To put more stringent observational constraints on the N-fractionation, we have observed with the IRAM-30m telescope a large sample of 66 cores in massive star-forming regions. We targeted the (1-0) rotational transition of HN$^{13}$C, HC$^{15}$N, H$^{13}$CN and HC$^{15}$N, and derived the $^{14}$N/$^{15}$N ratio for both HCN and HNC. We have completed this sample with that already observed by Colzi et al. (2018), and thus analysed a total sample of 87 sources. The $^{14}$N/$^{15}$N ratios are distributed around the Proto-Solar Nebula value with a lower limit near the terrestrial atmosphere value ($\sim$272). We have also derived the $^{14}$N/$^{15}$N ratio as a function of the Galactocentric distance and deduced a linear trend based on unprecedented statistics. The Galactocentric dependences that we have found are consistent, in the slope, with past works but we have found a new local $^{14}$N/$^{15}$N value of $\sim$400, i.e. closer to the Prosolar Nebula value. A second analysis was done, and a parabolic Galactocentric trend was found. Comparison with Galactic chemical evolution models shows that the slope until 8 kpc is consistent with the linear analysis, while the flattening trend above 8 kpc is well reproduced by the parabolic analysis.

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arXiv2018

The fragmentation properties of massive protocluster gas clumps: an ALMA study

Fragmentation of massive dense molecular clouds is the starting point in the formation of rich clusters and massive stars. Theory and numerical simulations indicate that the population of the fragments (number, mass, diameter, separation) resulting from the gravitational collapse of such clumps is probably regulated by the balance between the magnetic field and the other competitors of self-gravity, in particular turbulence and protostellar feedback. We have observed 11 massive, dense and young star-forming clumps with the Atacama Large Millimeter Array (ALMA) in the thermal dust continuum emission at $\sim 1$~mm with an angular resolution of 0.25 arcseconds with the aim of determining their population of fragments. We find fragments on sub-arcsecond scales in 8 out of the 11 sources. The ALMA images indicate two different fragmentation modes: a dominant fragment surrounded by companions with much smaller mass and size, and many ($\geq 8$) fragments with a gradual change in masses and sizes. On average, the largest number of fragments is found towards the warmer and more massive clumps. Also, the warmer clumps tend to form fragments with larger mass and size. To understand the role of the different physical parameters to regulate the final population of the fragments, we have simulated the collapse of a massive clump of $100$ and $300$ M$_{\odot}$ having different magnetic support. The simulations indicate that: (1) fragmentation is inhibited when the initial turbulence is low, independent of the other physical parameters. (2) a filamentary distribution of the fragments is favoured in a highly magnetised clump. We conclude that the clumps that show many fragments distributed in a filamentary-like structure are likely characterised by a strong magnetic field, while the others are possible also in a weaker magnetic field.

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arXiv2018

On the origin of phosphorus nitride in star-forming regions

We present multi-transition observations of PN towards a sample of nine massive dense cores in different evolutionary stages. Using transitions with different excitation conditions, we have found for the first time that the excitation temperatures of PN are in the range 5-30 K. To investigate the main chemical route for the PN formation (surface-chemistry vs. gas-phase chemistry), and the dominant desorption mechanism (thermal vs. shock), we have compared our results with those obtained from molecules tracing different chemical and physical conditions (SiO, SO, CH3OH, and N2H+). We have found that the PN line profiles are very well correlated with those of SiO and SO in six out of the nine targets, which indicates that PN may be released by sputtering of dust grains due to shocks. This finding is corroborated by a faint but statistically significant positive trend between the PN abundance and those of SiO and SO. However, in three objects the PN lines have no hints of high velocity wings, which indicates an alternative origin of PN. Overall, our results indicate that the origin of PN is not unique, as it can be formed in protostellar shocks, but also in colder and more quiescent gas through alternative pathways.

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arXiv2017

Chemical modelling of glycolaldehyde and ethylene glycol in star-forming regions

Glycolaldehyde (HOCH$_2$CHO) and ethylene glycol ((CH$_2$OH)$_2$) are two complex organic molecules detected in the hot cores and hot corinos of several star-forming regions. The ethylene glycol/glycolaldehyde abundance ratio seems to show an increase with the source luminosity. In the literature, several surface-chemistry formation mechanisms have been proposed for these two species. With the UCLCHEM chemical code, we explored the different scenarios and compared the predictions for a range of sources of different luminosities with the observations. None of the scenarios reproduce perfectly the trend. A better agreement is, however, found for a formation through recombination of two HCO radicals followed by successive hydrogenations. The reaction between HCO and CH$_2$OH could also contribute to the formation of glycolaldehyde in addition to the hydrogenation pathway. The predictions are improved when a trend of decreasing H$_2$ density within the core region with T $\geq$ 100 K as a function of luminosity, is included in the model. Destruction reactions of complex organic molecules in the gas phase would also need to be investigated, since they can affect the abundance ratios once the species have desorbed in the warm inner regions of the star-forming regions.

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arXiv2017

Phosphorus-bearing molecules in the Galactic Center

Phosphorus (P) is one of the essential elements for life due to its central role in biochemical processes. Recent searches have shown that P-bearing molecules (in particular PN and PO) are present in star-forming regions, although their formation routes remain poorly understood. In this Letter, we report observations of PN and PO towards seven molecular clouds located in the Galactic Center, which are characterized by different types of chemistry. PN is detected in five out of seven sources, whose chemistry is thought to be shock-dominated. The two sources with PN non-detections correspond to clouds exposed to intense UV/X-rays/cosmic-ray radiation. PO is detected only towards the cloud G+0.693$-$0.03, with a PO/PN abundance ratio of $\sim$1.5. We conclude that P-bearing molecules likely form in shocked gas as a result of dust grain sputtering, while are destroyed by intense UV/X-ray/cosmic ray radiation.

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