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M. W. Kunz

Publications and source records attributed to M. W. Kunz.

At least 19 recordsLinked to original sources

Thermodynamics and collisionality in firehose-susceptible high-$β$ plasmas

We study the evolution of collisionless plasmas that, due to their macroscopic evolution, are susceptible to the firehose instability, using both analytic theory and hybrid-kinetic particle-in-cell simulations. We establish that, depending on the relative magnitude of the plasma $β$, the characteristic timescale of macroscopic evolution, and the ion-Larmor frequency, the saturation of the firehose instability in high-$β$ plasmas can result in three qualitatively distinct thermodynamic (and electromagnetic) states. By contrast with the previously identified `ultra-high-beta' and `Alfvén-inhibiting' states, the newly identified `Alfvén-enabling' state, which is realised when the macroscopic evolution time $τ$ exceeds the ion-Larmor frequency by a $β$-dependent parameter, can support linear Alfvén waves and Alfvénic turbulence because the magnetic tension associated with the plasma's macroscopic magnetic field is never completely negated by anisotropic pressure forces. We characterise these states in detail, including their saturated magnetic-energy spectra. The effective collision operator associated with the firehose fluctuations is also described; we find it to be well approximated in the Alfvén-enabling state by a simple quasilinear pitch-angle scattering operator. The box-averaged collision frequency is $ν_{\rm eff} \sim β/τ$, in agreement with previous results, but certain sub-populations of particles scatter at a much larger (or smaller) rate depending on their velocity in the direction parallel to the magnetic field. Our findings are essential for understanding low-collisionality astrophysical plasmas including the solar wind, the intracluster medium of galaxy clusters and black-hole accretion flows. We show that all three of these plasmas are in the Alfvén-enabling regime of firehose saturation and discuss the implications of this result.

astro-ph.HE

Self-organization in collisionless, high-$β$ turbulence

The MHD equations, as a collisional fluid model that remains in local thermodynamic equilibrium (LTE), have long been used to describe turbulence in myriad space and astrophysical plasmas. Yet, the vast majority of these plasmas, from the solar wind to the intracluster medium (ICM) of galaxy clusters, are only weakly collisional at best, meaning that significant deviations from LTE are not only possible but common. Recent studies have demonstrated that the kinetic physics inherent to this weakly collisional regime can fundamentally transform the evolution of such plasmas across a wide range of scales. Here we explore the consequences of pressure anisotropy and Larmor-scale instabilities for collisionless, $β\gg 1$ turbulence, focusing on the role of a self-organizational effect known as `magneto-immutability'. We describe this self-organization analytically through a high-$β$, reduced ordering of the CGL-MHD equations, finding that it is a robust inertial-range effect that dynamically suppresses magnetic-field-strength fluctuations, anisotropic-pressure stresses, and dissipation due to heat fluxes. As a result, the turbulent cascade of Alfvénic fluctuations continues below the putative viscous scale to form a robust, nearly conservative, MHD-like inertial range. These findings are confirmed numerically via Landau-fluid CGL-MHD turbulence simulations that employ a collisional closure to mimic the effects of microinstabilities. We find that microinstabilities occupy a small ($\sim 5\%$) volume-filling fraction of the plasma, even when the pressure anisotropy is driven strongly towards its instability thresholds. We discuss these results in the context of recent predictions for ion-versus-electron heating in low-luminosity accretion flows and observations implying suppressed viscosity in ICM turbulence.

astro-ph.HE

The structure of cluster merger shocks: turbulent width and the electron heating timescale

We present a new 2 Ms Chandra observation of the cluster merger Abell 2146, which hosts two huge M~2 shock fronts each ~500 kpc across. For the first time, we resolve and measure the width of cluster merger shocks. The best-fit width for the bow shock is 17+/-1 kpc and for the upstream shock is 10.7+/-0.3 kpc. A narrow collisionless shock will appear broader in projection if its smooth shape is warped by local gas motions. We show that both shock widths are consistent with collisionless shocks blurred by local gas motions of 290+/-30 km/s. The upstream shock forms later on in the merger than the bow shock and is therefore expected to be significantly narrower. From the electron temperature profile behind the bow shock, we measure the timescale for the electrons and ions to come back into thermal equilibrium. We rule out rapid thermal equilibration of the electrons with the shock-heated ions at the 6 sigma level. The observed temperature profile instead favours collisional equilibration. For these cluster merger shocks, which have low sonic Mach numbers and propagate through a high $β$ plasma, we find no evidence for electron heating over that produced by adiabatic compression. Our findings are expected to be valid for collisionless shocks with similar parameters in other environments and support the existing picture from the solar wind and supernova remnants. The upstream shock is consistent with this result but has a more complex structure, including a ~2 keV increase in temperature ~50 kpc ahead of the shock.

astro-ph.HE

Insensitivity of a turbulent laser-plasma dynamo to initial conditions

It has recently been demonstrated experimentally that a turbulent plasma created by the collision of two inhomogeneous, asymmetric, weakly magnetised laser-produced plasma jets can generate strong stochastic magnetic fields via the small-scale turbulent dynamo mechanism, provided the magnetic Reynolds number of the plasma is sufficiently large. In this paper, we compare such a plasma with one arising from two pre-magnetised plasma jets whose creation is identical save for the addition of a strong external magnetic field imposed by a pulsed magnetic field generator (`MIFEDS'). We investigate the differences between the two turbulent systems using a Thomson-scattering diagnostic, X-ray self-emission imaging and proton radiography. The Thomson-scattering spectra and X-ray images suggest that the presence of the external magnetic field has a limited effect on the plasma dynamics in the experiment. While the presence of the external magnetic field induces collimation of the flows in the colliding plasma jets and the initial strengths of the magnetic fields arising from the interaction between the colliding jets are significantly larger as a result of the external field, the energy and morphology of the stochastic magnetic fields post-amplification are indistinguishable. We conclude that, for turbulent laser-plasmas with super-critical magnetic Reynolds numbers, the dynamo-amplified magnetic fields are determined by the turbulent dynamics rather than the seed fields and modest changes in the initial flow dynamics of the plasma, a finding consistent with theoretical expectations and simulations of turbulent dynamos.

physics.plasm-ph

Adaptive critical balance and firehose instability in an expanding, turbulent, collisionless plasma

Using hybrid-kinetic particle-in-cell simulation, we study the evolution of an expanding, collisionless, magnetized plasma in which strong Alfvénic turbulence is persistently driven. Temperature anisotropy generated adiabatically by the plasma expansion (and consequent decrease in the mean magnetic-field strength) gradually reduces the effective elasticity of the field lines, causing reductions in the linear frequency and residual energy of the Alfvénic fluctuations. In response, these fluctuations modify their interactions and spatial anisotropy to maintain a scale-by-scale "critical balance" between their characteristic linear and nonlinear frequencies. Eventually the plasma becomes unstable to kinetic firehose instabilities, which excite rapidly growing magnetic fluctuations at ion-Larmor scales. The consequent pitch-angle scattering of particles maintains the temperature anisotropy near marginal stability, even as the turbulent plasma continues to expand. The resulting evolution of parallel and perpendicular temperatures does not satisfy double-adiabatic conservation laws, but is described accurately by a simple model that includes anomalous scattering. Our results have implications for understanding the complex interplay between macro- and micro-scale physics in various hot, dilute, astrophysical plasmas, and offer predictions concerning power spectra, residual energy, ion-Larmor-scale spectral breaks, and non-Maxwellian features in ion distribution functions that may be tested by measurements taken in high-beta regions of the solar wind.

astro-ph.HE

Gravito-turbulence and dynamo in poorly ionised protostellar discs. I. Zero-net-flux case

In their early stages, protoplanetary discs are sufficiently massive to undergo gravitational instability (GI). This instability is thought to be involved in mass accretion, planet formation via gas fragmentation, the generation of spiral density waves, and outbursts. A key and very recent area of research is the interaction between the GI and magnetic fields in young protoplanetary discs, in particular whether this instability is able to sustain a magnetic field via a dynamo. We conduct three-dimensional, stratified shearing-box simulations using two independent codes, PLUTO and Athena++, to characterise the GI dynamo in poorly ionised protostellar discs subject to ambipolar diffusion. We find that the dynamo operates across a large range of ambipolar Elssaser number Am (which characterises the strength of ambipolar diffusion) and is particularly strong in the regime Am=10-100, with typical magnetic to thermal energy ratios of order unity. The dynamo is only weakly dependent on resolution (at least for Am <100), box size, and cooling law. The magnetic field is produced by the combination of differential rotation and large-scale vertical roll motions associated with spiral density waves. Our results have direct implications for the dynamo process in young protoplanetary discs and possibly some regions of AGN discs.

astro-ph.EP

Self-sustaining sound in collisionless, high-beta plasma

Using analytical theory and hybrid-kinetic numerical simulations, we demonstrate that, in a collisionless plasma, long-wavelength ion-acoustic waves (IAWs) with amplitudes $δn/n_0 \gtrsim 2/β$ (where $β\gg{1}$ is the ratio of thermal to magnetic pressure) generate sufficient pressure anisotropy to destabilize the plasma to firehose and mirror instabilities. These kinetic instabilities grow rapidly to reduce the pressure anisotropy by pitch-angle scattering and trapping particles, respectively, thereby impeding the maintenance of Landau resonances that enable such waves' otherwise potent collisionless damping. The result is wave dynamics that evince a weakly collisional plasma: the ion distribution function is near-Maxwellian, the field-parallel flow of heat resembles its Braginskii form (except in regions where large-amplitude magnetic mirrors strongly suppress particle transport), and the relations between various thermodynamic quantities are more `fluid-like' than kinetic. A nonlinear fluctuation-dissipation relation for self-sustaining IAWs is obtained by solving a plasma-kinetic Langevin problem, which demonstrates suppressed damping, enhanced fluctuation levels, and weakly collisional thermodynamics when IAWs with $δn/n_0 \gtrsim 2/β$ are stochastically driven. We investigate how our results depend upon the scale separation between the wavelength of the IAW and the Larmor radius of the ions, and discuss briefly their implications for our understanding of turbulence and transport in the solar wind and the intracluster medium of galaxy clusters.

astro-ph.HE

Time-resolved fast turbulent dynamo in a laser plasma

Understanding magnetic-field generation and amplification in turbulent plasma is essential to account for observations of magnetic fields in the universe. A theoretical framework attributing the origin and sustainment of these fields to the so-called fluctuation dynamo was recently validated by experiments on laser facilities in low-magnetic-Prandtl-number plasmas ($\mathrm{Pm} < 1$). However, the same framework proposes that the fluctuation dynamo should operate differently when $\mathrm{Pm} \gtrsim 1$, the regime relevant to many astrophysical environments such as the intracluster medium of galaxy clusters. This paper reports a new experiment that creates a laboratory $\mathrm{Pm} \gtrsim 1$ plasma dynamo for the first time. We provide a time-resolved characterization of the plasma's evolution, measuring temperatures, densities, flow velocities and magnetic fields, which allows us to explore various stages of the fluctuation dynamo's operation. The magnetic energy in structures with characteristic scales close to the driving scale of the stochastic motions is found to increase by almost three orders of magnitude from its initial value and saturate dynamically. It is shown that the growth of these fields occurs exponentially at a rate that is much greater than the turnover rate of the driving-scale stochastic motions. Our results point to the possibility that plasma turbulence produced by strong shear can generate fields more efficiently at the driving scale than anticipated by idealized MHD simulations of the nonhelical fluctuation dynamo; this finding could help explain the large-scale fields inferred from observations of astrophysical systems.

physics.plasm-ph

Electron-only magnetic reconnection in plasma turbulence

Hybrid-Vlasov-Maxwell simulations of magnetized plasma turbulence including non-linear electron-inertia effects in a generalized Ohm's law are presented. When fluctuation energy is injected on scales sufficiently close to ion-kinetic scales, the ions efficiently become de-magnetized and electron-scale current sheets largely dominate the distribution of the emerging current structures, in contrast to the usual picture, where a full hierarchy of structure sizes is generally observed. These current sheets are shown to be the sites of electron-only reconnection (e-rec), in which the usual electron exhausts are unaccompanied by ion outflows and which are in qualitative agreement with those recently observed by MMS in the Earth's turbulent magnetosheath, downstream of the bow shock. Some features of the e-rec phenomenology are shown to be consistent with an electron magnetohydrodynamic description. Simulations suggest that this regime of collisionless reconnection may be found in turbulent systems where plasma processes, such as micro-instabilities and/or shocks, overpower the more customary turbulent cascade by directly injecting energy close to the ion-kinetic scales.

physics.plasm-ph

Fluctuation dynamo in a weakly collisional plasma

The turbulent amplification of cosmic magnetic fields depends upon the material properties of the host plasma. In many hot, dilute astrophysical systems, such as the intracluster medium (ICM) of galaxy clusters, the rarity of particle--particle collisions allows departures from local thermodynamic equilibrium. These departures exert anisotropic viscous stresses on the plasma motions that inhibit their ability to stretch magnetic-field lines. We present a numerical study of the fluctuation dynamo in a weakly collisional plasma using magnetohydrodynamic (MHD) equations endowed with a field-parallel viscous (Braginskii) stress. When the stress is limited to values consistent with a pressure anisotropy regulated by firehose and mirror instabilities, the Braginskii-MHD dynamo largely resembles its MHD counterpart. If instead the parallel viscous stress is left unabated -- a situation relevant to recent kinetic simulations of the fluctuation dynamo and to the early stages of the dynamo in a magnetized ICM -- the dynamo changes its character, amplifying the magnetic field while exhibiting many characteristics of the saturated state of the large-Prandtl-number (${\rm Pm}\gtrsim{1}$) MHD dynamo. We construct an analytic model for the Braginskii-MHD dynamo in this regime, which successfully matches magnetic-energy spectra. A prediction of this model, confirmed by our simulations, is that a Braginskii-MHD plasma without pressure-anisotropy limiters will not support a dynamo if the ratio of perpendicular and parallel viscosities is too small. This ratio reflects the relative allowed rates of field-line stretching and mixing, the latter of which promotes resistive dissipation of the magnetic field. In all cases that do exhibit a dynamo, the generated magnetic field is organized into folds that persist into the saturated state and bias the chaotic flow to acquire a scale-dependent spectral anisotropy.

astro-ph.HE

[Plasma 2020 Decadal] The Material Properties of Weakly Collisional, High-Beta Plasmas

This white paper, submitted for the Plasma 2020 Decadal Survey, concerns the physics of weakly collisional, high-beta plasmas -- plasmas in which the thermal pressure dominates over the magnetic pressure and in which the inter-particle collision time is comparable to the characteristic timescales of bulk motions. This state of matter, although widespread in the Universe, remains poorly understood: we lack a predictive theory for how it responds to perturbations, how it transports momentum and energy, and how it generates and amplifies magnetic fields. Such topics are foundational to the scientific study of plasmas, and are of intrinsic interest to those who regard plasma physics as a fundamental physics discipline. But these topics are also of extrinsic interest: addressing them directly informs upon our understanding of a wide variety of space and astrophysical systems, including accretion flows around supermassive black holes, the intracluster medium (ICM) between galaxies in clusters, and regions of the near-Earth solar wind. Specific recommendations to advance this field of study are discussed.

physics.plasm-ph

Dual phase-space cascades in 3D hybrid-Vlasov-Maxwell turbulence

To explain energy dissipation via turbulence in collisionless, magnetized plasmas, the existence of a dual real- and velocity-space cascade of ion-entropy fluctuations below the ion gyroradius has been proposed. Such a dual cascade, predicted by the gyrokinetic theory, has previously been observed in gyrokinetic simulations of two-dimensional, electrostatic turbulence. For the first time we show evidence for a dual phase-space cascade of ion-entropy fluctuations in a three-dimensional simulation of hybrid-kinetic, electromagnetic turbulence. Some of the scalings observed in the energy spectra are consistent with a generalized theory for the cascade that accounts for the spectral anisotropy of critically balanced, intermittent, sub-ion-Larmor-scale fluctuations. The observed velocity-space cascade is also anisotropic with respect to the magnetic-field direction, with linear phase mixing along magnetic-field lines proceeding mainly at spatial scales above the ion gyroradius and nonlinear phase mixing across magnetic-field lines proceeding at perpendicular scales below the ion gyroradius. Such phase-space anisotropy could be sought in heliospheric and magnetospheric data of solar-wind turbulence and has far-reaching implications for the dissipation of turbulence in weakly collisional astrophysical plasmas.

physics.plasm-ph

Kinetic simulations of the interruption of large-amplitude shear-Alfvén waves in a high-beta plasma

Using two-dimensional hybrid-kinetic simulations, we explore the nonlinear "interruption" of standing and traveling shear-Alfvén waves in collisionless plasmas. Interruption involves a self-generated pressure anisotropy removing the restoring force of a linearly polarized Alfvénic perturbation, and occurs for wave amplitudes $δB_{\perp}/B_{0}\gtrsim β^{\,-1/2}$ (where $β$ is the ratio of thermal to magnetic pressure). We use highly elongated domains to obtain maximal scale separation between the wave and the ion gyroscale. For standing waves above the amplitude limit, we find that the large-scale magnetic field of the wave decays rapidly. The dynamics are strongly affected by the excitation of oblique firehose modes, which transition into long-lived parallel fluctuations at the ion gyroscale and cause significant particle scattering. Traveling waves are damped more slowly, but are also influenced by small-scale parallel fluctuations created by the decay of firehose modes. Our results demonstrate that collisionless plasmas cannot support linearly polarized Alfvén waves above $δB_{\perp}/B_{0}\sim β^{\,-1/2}$. They also provide a vivid illustration of two key aspects of low-collisionality plasma dynamics: (i) the importance of velocity-space instabilities in regulating plasma dynamics at high $β$, and (ii) how nonlinear collisionless processes can transfer mechanical energy directly from the largest scales into thermal energy and microscale fluctuations, without the need for a scale-by-scale turbulent cascade.

physics.plasm-ph

Multi-Species Measurements of the Firehose and Mirror Instability Thresholds in the Solar Wind

The firehose and mirror instabilities are thought to arise in a variety of space and astrophysical plasmas, constraining the pressure anisotropies and drifts between particle species. The plasma stability depends on all species simultaneously, meaning that a combined analysis is required. Here, we present the first such analysis in the solar wind, using the long-wavelength stability parameters to combine the anisotropies and drifts of all major species (core and beam protons, alphas, and electrons). At the threshold, the firehose parameter was found to be dominated by protons (67%), but also to have significant contributions from electrons (18%) and alphas (15%). Drifts were also found to be important, contributing 57% in the presence of a proton beam. A similar situation was found for the mirror, with contributions of 61%, 28%, and 11% for protons, electrons, and alphas, respectively. The parallel electric field contribution, however, was found to be small at 9%. Overall, the long-wavelength thresholds constrain the data well (<1% unstable), and the implications of this are discussed.

physics.space-ph

Suppression of thermal conduction in a mirror-unstable plasma

The ICM plasma is subject to firehose and mirror instabilities at scales of order the ion Larmor radius. The mirror instability generates fluctuations of magnetic-field strength $δB / B \sim 1$. These fluctuations act as magnetic traps for the heat-conducting electrons, suppressing their transport. We calculate the effective parallel thermal conductivity in the ICM in the presence of the mirror fluctuations for different stages of the evolution of the instability. The mirror fluctuations are limited in amplitude by the maximum and minimum values of the field strength, with no large deviations from the mean value. This key property leads to a finite suppression of thermal conduction at large scales. We find suppression down to $\approx 0.2$ of the Spitzer value for the secular phase of the perturbations' growth, and $\approx 0.3$ for their saturated phase. The effect operates in addition to other suppression mechanisms and independently of them. Globally, fluctuations $δB / B \sim 1$ can be present on much larger scales, of the order of the scale of turbulent motions. However, we do not expect large suppression of thermal conduction by these, because their scale is considerably larger than the collisional mean free path of the ICM electrons. The obtained suppression of thermal conduction by a factor of $\sim 5$ appears to be characteristic and potentially universal for a weakly collisional mirror-unstable plasma.

astro-ph.HE

Pressure-anisotropy-driven microturbulence and magnetic-field evolution in shearing, collisionless plasma

The nonlinear state of a high-beta collisionless plasma is investigated when an imposed linear shear amplifies or diminishes a uniform magnetic field, driving pressure anisotropies and hence firehose/mirror instabilities. The evolution of the resulting microscale turbulence is considered when the shear is switched off or reversed after one shear time (mimicking local behaviour of a macroscopic flow), so a new macroscale configuration is superimposed on the microscale state left behind by the previous one. There is a threshold value of plasma beta: when $β\llΩ/S$ (ion cyclotron frequency/shear rate), the emergence of firehose/mirror fluctuations driven unstable by shear and their disappearance when the shear is removed/reversed are quasi-instantaneous compared to the shear time, viz., the decay time of these fluctuations is $\simβ/Ω\ll 1/S$ (this result follows from the free decay of the fluctuations being constrained by the same marginal-stability thresholds as their growth). In contrast, when $β\gtrsimΩ/S$ ("ultra-high" beta), the old microscale state can only be removed on the shear timescale. In this regime, driven firehose fluctuations grow secularly to order-unity amplitudes, compensating for the decay of the mean field and so pinning pressure anisotropy at marginal stability with no appreciable scattering of particles---which is unlike what happens at moderate $β$. When the shear reverses, the shearing away of this firehose turbulence compensates for the increase in the mean field and thus prevents growth of the pressure anisotropy, stopping the system from going mirror-unstable. Therefore, at ultra-high beta, the system stays close to the firehose threshold, the mirror instability is largely suppressed, while the mean magnetic energy barely changes at all. Implications for plasma dynamo and thus the origin of cosmic magnetism are discussed.

astro-ph.HE

Inertial-Range Kinetic Turbulence in Pressure-Anisotropic Astrophysical Plasmas

A theoretical framework for low-frequency electromagnetic (drift-)kinetic turbulence in a collisionless, multi-species plasma is presented. The result generalises reduced magnetohydrodynamics (RMHD) and kinetic RMHD (Schekochihin et al. 2009) for pressure-anisotropic plasmas, allowing for species drifts---a situation routinely encountered in the solar wind and presumably ubiquitous in hot dilute astrophysical plasmas (e.g. intracluster medium). Two main objectives are achieved. First, in a non-Maxwellian plasma, the relationships between fluctuating fields (e.g., the Alfven ratio) are order-unity modified compared to the more commonly considered Maxwellian case, and so a quantitative theory is developed to support quantitative measurements now possible in the solar wind. The main physical feature of low-frequency plasma turbulence survives the generalisation to non-Maxwellian distributions: Alfvenic and compressive fluctuations are energetically decoupled, with the latter passively advected by the former; the Alfvenic cascade is fluid, satisfying RMHD equations (with the Alfven speed modified by pressure anisotropy and species drifts), whereas the compressive cascade is kinetic and subject to collisionless damping. Secondly, the organising principle of this turbulence is elucidated in the form of a generalised kinetic free-energy invariant. It is shown that non-Maxwellian features in the distribution function reduce the rate of phase mixing and the efficacy of magnetic stresses; these changes influence the partitioning of free energy amongst the various cascade channels. As the firehose or mirror instability thresholds are approached, the dynamics of the plasma are modified so as to reduce the energetic cost of bending magnetic-field lines or of compressing/rarefying them. Finally, it is shown that this theory can be derived as a long-wavelength limit of non-Maxwellian slab gyrokinetics.

astro-ph.HE

The Effect of Anisotropic Viscosity on Cold Fronts in Galaxy Clusters

Cold fronts -- contact discontinuities in the intracluster medium (ICM) of galaxy clusters -- should be disrupted by Kelvin-Helmholtz (K-H) instabilities due to the associated shear velocity. However, many observed cold fronts appear stable. This opens the possibility to place constraints on microphysical mechanisms that stabilize them, such as the ICM viscosity and/or magnetic fields. We performed exploratory high-resolution simulations of cold fronts arising from subsonic gas sloshing in cluster cores using the grid-based Athena MHD code, comparing the effects of isotropic Spitzer and anisotropic Braginskii viscosity (expected in a magnetized plasma). Magnetized simulations with full Braginskii viscosity or isotropic Spitzer viscosity reduced by a factor f ~ 0.1 are both in qualitative agreement with observations in terms of suppressing K-H instabilities. The RMS velocity of turbulence within the sloshing region is only modestly reduced by Braginskii viscosity. We also performed unmagnetized simulations with and without viscosity and find that magnetic fields have a substantial effect on the appearance of the cold fronts, even if the initial field is weak and the viscosity is the same. This suggests that determining the dominant suppression mechanism of a given cold front from X-ray observations (e.g. viscosity or magnetic fields) by comparison with simulations is not straightforward. Finally, we performed simulations including anisotropic thermal conduction, and find that including Braginskii viscosity in these simulations does not significant affect the evolution of cold fronts; they are rapidly smeared out by thermal conduction, as in the inviscid case.

astro-ph.CO