arXiv subjects

M. Zannese

Publications and source records attributed to M. Zannese.

8 recordsLinked to original sources

arXiv2026

Searching for the elusive CH2+ with the James Webb Space Telescope. Another carbocation to constrain astrochemical networks

Carbocations are key species in interstellar chemistry, providing entry points for building larger hydrocarbons. CH+, and more recently, CH3+, have been detected. Other carbocations await detection to provide a comprehensive view of the astrochemical network that is at work in the interstellar medium. We search for CH2+ in objects in which CH3+ was detected and evaluate the most favorable conditions for detecting the elusive CH2+ reactive cation. We calculated the CH2+ rotational and rovibrational transitions expected to contribute in the mid- to far-infrared, focusing on the lower-energy rovibrational levels. We then calculated CH2+ infrared emission spectra at different excitation temperatures and compared them to JWST spectra of the externally irradiated disk d203-506 in Orion, where CH+ and CH3+ have already been detected. We used thermochemical models to predict the abundance and spatial morphology of CH2+ to better understand its nondetection. The comparison to JWST spectra allowed us to provide excitation-temperature-dependent upper limits to the excited column density. These are several times lower than those detected for CH+ and CH3+ in their excited states. Based on model calculations for photodissociation regions and assuming similar excitation temperatures, the upper limit derived from observations and CH2+ model spectrum is either slightly above or below the column density expected from models of photodissociation regions. We provide a list of tabulated transitions to allow the community to search for this carbocation in future observations as CH2+ is key in providing observational constraints on astrochemical models.

astro-ph.GA↗

arXiv2026

Velocity-resolved [O I] 63,145 um, [C II] 158 um, and OH mapping along the Orion BN/KL explosive outflow and irradiated shocks

Stellar mergers produce explosive outflows that serve as transient sources of IR line luminosity and inject mechanical energy early into the natal molecular cloud. We present the first velocity-resolved maps of the [O I] 63 and 145 um fine-structure line emission from the wide-angle outflow in Orion BN/KL, the nearest explosive outflow. The data were obtained with SOFIA and include sensitive [C II] 158 um and OH maps. They allowed us to disentangle the quiescent cloud gas from the outflow, traced by a broader [O I] component with a line FWHM of about 20-30 km/s and exhibiting a spatial distribution similar to that of the shock-excited H2 emission seen with JWST. The OH 119 um line shows a prominent P-Cygni profile covering 160 km/s, similar to the very broad CO lines. The total [O I] 63 and 145 line luminosity is remarkably high, 86.5 L_sun, comparable to the H2 and CO line luminosities, implying an outflow mass-loss rate of (9.1+/-2.6)x10^-3 M_sun/yr and a mass of 3.3-5.9 M_sun. The [O I] 63 / 145 and [O I] 63 / [C II] 158 intensity ratios reach very high values in the line wings (20-30 and 40-60, respectively), exceeding those found in PDRs. These ratios are consistent with the presence of dense (10^5 to 10^6 cm^-3 ) and warm (~500 K) postshock gas. We analyzed the fine-structure line-wing intensities using magnetized shock models that include UV irradiation, to which the [C II] 158 line intensity is particularly sensitive. We find that the [O I] and [C II] intensities are consistent with emission from dissociative J-type shocks with velocities of 30-40 km/s and preshock gas densities of a few 10^4 cm^-3, illuminated by external UV radiation generated by surrounding fast shocks and possibly by massive (proto)stars in the region. We also report a broad [O I] emission feature around the BN star, which we attribute to an unresolved outflow or wind bow shock.

astro-ph.GA↗

arXiv2026

JWST observations of photodissociation regions. IV. Carbonaceous emission band sub-components in NGC 7023 have distinct spatial distributions

We analyze JWST spectroscopy of the northwest filament of NGC7023, where the relatively soft radiation field results in a photodissociation region with an extended atomic hydrogen region, and strongly pronounced variations of the carbonaceous emission band profiles. We focus on the 16.4 and 17.4 um bands and their relation to the main bands at 3.3, 3.4, 5.2, 5.7, 6.2, 7.7, 8.6, 11.3, and 12.7 um, and aim to identify which bands and sub-features originate from co-spatial emission carriers. We apply a PAHFIT spectral decomposition to measure the emission bands and their individual sub-components, and produce maps that spatially resolve the main dissociation front (DF1). Nearly all emission maps peak at DF1, while the relative intensity in the atomic hydrogen region (ATM) varies strongly. We classify the features into spatial distribution types based on the intensity ratio in ATM relative to DF1. Most bands are of type I (low ATM/DF1; 3.3, 3.4, 5.2, 5.7, 11.3 um) or II (medium ATM/DF1; 16.2, 7.7, 8.6, 12.7, 16.4 um), while only few are of type III (high ATM/DF1; 11.0, 17.4 um). A breakdown of the 5.7, 7.7, 11.3 and 12.7 um bands into blue and red sub-components reveals that contributions on the blue side are of type III, while those on the red side are of type I or II. These strongly differing spatial distributions reveal that at least two different populations contribute to the 16-18 um range, and that these populations are also connected to the profiles of the 5.7, 7.7, 11.3, and 12.7 um bands. The maps further indicate a continued evolution of these profiles toward the central cavity of NGC7023, where fullerene emission (C60) was previously detected. We speculate that the population of emission carriers could be in an intermediate photochemical evolution stage that precedes fullerene formation.

astro-ph.GA↗

arXiv2025

JWST observations of photodissociation regions: II. Warm molecular Hydrogen spectroscopy in the Horsehead nebula

H2 is the most abundant molecule in the interstellar medium and is a useful tool to study photodissociation regions, where radiative feedback from massive stars on molecular clouds is dominant. The James Webb Space Telescope, with its high spatial resolution, sensitivity, and wavelength coverage provides unique access to the detection of most of H2 lines and the analysis of its spatial morphology. Our goal is to use H2 line emission detected with the JWST in the Horsehead nebula to constrain the physical parameters (e.g., extinction, gas temperature, thermal pressure) throughout the PDR and its geometry. The study of H2 morphology reveals that FUV-pumped lines peak closer to the edge of the PDR than thermalized lines. From H2 lines, we estimate the value of extinction throughout the PDR. We find that AV is increasing from the edge of the PDR to the second and third H2 filaments. Then, we study the H2 excitation in different regions across the PDR. The temperature profile shows that the observed gas temperature is quite constant throughout the PDR, with a slight decline in each of the dissociation fronts. This study also reveals that the OPR is far from equilibrium. We observe a spatial separation of para and ortho rovibrational levels, indicating that efficient ortho-para conversion and preferential ortho self-shielding are driving the spatial variations of the OPR. Finally, we derive a thermal pressure in the first filament around P > 6x10$^6$ K cm$^{-3}$, about ten times higher than that of the ionized gas. We highlight that template stationary 1D PDR models cannot account for the intrinsic 2D structure and the very high temperature observed in the Horsehead nebula. We argue the highly excited, over-pressurized H2 gas at the edge of the PDR interface could originate from the mixing between the cold and hot phase induced by the photo-evaporation of the cloud.

astro-ph.GA↗

arXiv2025

JWST Observations of Photo-dissociation Regions. II. Aliphatic/Aromatic Carbonaceous Dust, Ices, and Gas Phase Spectral Line Inventory

This paper provides an overview of the spectroscopic data obtained by the JWST Guaranteed Time Observations (GTO) program 1192, "The Physics and Chemistry of PDR Fronts", including an inventory of the spatially resolved dust, gas, and molecular content in the Horsehead nebula and the NW filament of NGC~7023. We demonstrate the unique capability of this high spatial resolution data set to elucidate the evolution of gas and dust at the interface between stars and their natal clouds at the scale at which the physics and chemistry occur. The Disassociation Regions (PDRs) in the Horsehead nebula and the North West (NW) filament of NGC 7023 were mapped with a spectral resolution 1000-3000 and a spatial resolution of ~2e-4 pc between 0.97-28um. Spectra extracted from template regions yield a large number of atomic, ionized, and molecular lines. Full line lists and extracted spectra for all 10 regions are provided through CDS. Absorption from H$_2$O, CO$_2$, and CO ices are identified in 3 regions in NGC 7023. In this overview, we have focused on the spectral region between 3 and 5 um which is dominated by emission from aromatic and aliphatic carbon bonds to illustrate the power of the data set. We confirm the entrainment of aromatic carbonaceous species in the photo-evaporative flow from the PDR surface into the H\,{\sc{ii}} region in the Horsehead. No aliphatic emission is present in the outflow, indicating the complete removal of aliphatic bonds when exposed to strong UV fields. There is a clear detection of deuterium substitution in the carbon bonds. Aliphatic D-substitution is more efficient relative to aromatic D-substitution, ranging from N$_{D}$/N$_{H}$ ~ 0.1-0.3 for aliphatics compared to ~0.03 for the aromatics.

astro-ph.GA↗

arXiv2025

PDRs4All XV: CH radical and H$_3^+$ molecular ion in the irradiated protoplanetary disk d203-506

Most protoplanetary disks experience a phase in which they are subjected to strong ultraviolet radiation from nearby massive stars. This UV radiation can substantially alter their chemistry by producing numerous radicals and molecular ions. In this Letter we present detailed analysis of the JWST-NIRSpec spectrum of the d203-506 obtained as part of the PDRs4All Early Release Science program. Using state-of-the-art spectroscopic data, we searched for species using a multi-molecule fitting tool, PAHTATmol, that we developed for this purpose. Based on this analysis, we report the clear detection of ro-vibrational emission of the CH radical and likely detection of the H$_3^+$ molecular ion, with estimated abundances of a few times 10$^{-7}$ and approximately 10$^{-8}$, respectively. The presence of CH is predicted by gas-phase models and well explained by hydrocarbon photochemistry. H$_3^+$ is usually formed through reactions of H$_2$ with H$_2^+$ originating from cosmic ray ionization of H$_2$. However, recent theoretical studies suggest that H$_3^+$ also forms through UV-driven chemistry in strongly irradiated ($G_0>$10$^3$), dense ($n_{\rm H} >10^{6}$ cm$^{-3}$) gas. The latter is favored as an explanation for the presence of ``hot'' H$_3^+$ ($T_{\rm ex}\gtrsim$1000 K) in the outer disk layers of d203-506, coinciding with the emission of FUV-pumped H$_2$ and other ``PDR species'', such as CH$^+$, CH$_3^+$, and OH. Our detection of infrared emission from vibrationally excited H$_3^+$ and CH raises questions about their excitation mechanisms and, underscore that UV radiation can have a profound impact on the chemistry of planet forming disks. They also demonstrate the power of JWST pushing the limit for the detection of elusive species in protoplanetary disks.

astro-ph.GA↗

arXiv2025

PDRs4All. XII. FUV-driven formation of hydrocarbon radicals and their relation with PAHs

We present subarcsecond-resolution ALMA mosaics of the Orion Bar PDR in [CI] 609um, C2H (4-3), and C18O (3-2) emission lines complemented by JWST images of H2 and aromatic infrared band (AIB) emission. The rim of the Bar shows very corrugated structures made of small-scale H2 dissociation fronts (DFs). The [CI] 609 um emission peaks very close (~0.002 pc) to the main H2-emitting DFs, suggesting the presence of gas density gradients. These DFs are also bright and remarkably similar in C2H emission, which traces "hydrocarbon radical peaks" characterized by very high C2H abundances, reaching up to several x10^-7. The high abundance of C2H and of related hydrocarbon radicals, such as CH3, CH2, and CH, can be attributed to gas-phase reactions driven by elevated temperatures, the presence of C+ and C, and the reactivity of FUV-pumped H2. The hydrocarbon radical peaks roughly coincide with maxima of the 3.4/3.3 um AIB intensity ratio, a proxy for the aliphatic-to-aromatic content of PAHs. This implies that the conditions triggering the formation of simple hydrocarbons also favor the formation (and survival) of PAHs with aliphatic side groups, potentially via the contribution of bottom-up processes in which abundant hydrocarbon radicals react in situ with PAHs. Ahead of the DFs, in the atomic PDR zone (where [H]>>[H2]), the AIB emission is the brightest, but small PAHs and carbonaceous grains undergo photo-processing due to the stronger FUV field. Our detection of trace amounts of C2H in this zone may result from the photoerosion of these species. This study provides a spatially resolved view of the chemical stratification of key carbon carriers in a PDR. Overall, both bottom-up and top-down processes appear to link simple hydrocarbon molecules with PAHs in molecular clouds; however, the exact chemical pathways and their relative contributions remain to be quantified.

astro-ph.GA↗

arXiv2024

PDRs4All. X. ALMA and JWST detection of neutral carbon in the externally irradiated disk d203-506: Undepleted gas-phase carbon

The gas-phase abundance of carbon, x_C = C/H, and its depletion factors are essential parameters for understanding the gas and solid compositions that are ultimately incorporated into planets. The majority of protoplanetary disks are born in clusters and, as a result, are exposed to external FUV radiation. These FUV photons potentially affect the disk's evolution, chemical composition, and line excitation. We present the first detection of the [CI]609um fine-structure line of neutral carbon (CI), achieved with ALMA, toward one of these disks, d203-506, in the Orion Nebula Cluster. We also report the detection of CI forbidden and permitted lines (from electronically excited states up to 10 eV) observed with JWST in the IR. These lines trace the irradiated outer disk and photo-evaporative wind. Contrary to the common belief that these IR lines are C+ recombination lines, we find that they are dominated by FUV-pumping of CI followed by fluorescence cascades. They trace the transition from atomic to molecular gas, and their intensities scale with G0. The lack of outstanding IR OI fluorescent emission, however, implies a sharper attenuation of external FUV radiation with E > 12 eV (~Lyman-beta). This is related to a lower effective FUV dust absorption cross section compared to that of interstellar grains, implying a more prominent role for FUV shielding by the CI photoionization continuum. The [CI]609um intensity is proportional to N(CI) and can be used to infer x_C. We derive x_C ~ 1.4E-4. This implies that there is no major depletion of volatile carbon compared to x_C measured in the natal cloud, hinting at a young disk. We also show that external FUV radiation impacts the outer disk and wind by vertically shifting the water freeze-out depth, which results in less efficient grain growth and settling. This shift leads to nearly solar gas-phase C/O abundance ratios in these irradiated layers.

astro-ph.GA↗