Searcharxiv⌕ Search

arXiv subjects

M. de Llano

Publications and source records attributed to M. de Llano.

At least 37 records · Page 2Linked to original sources

Cooper pairs as bosons

Although BCS pairs of fermions are known not to obey Bose-Einstein (BE) commutation relations nor BE statistics, we show how Cooper pairs (CPs), whether the simple original ones or the CPs recently generalized in a many-body Bethe-Salpeter approach, being clearly distinct from BCS pairs at least obey BE statistics. Hence, contrary to widespread popular belief, CPs can undergo BE condensation to account for superconductivity if charged, as well as for neutral-atom fermion superfluidity where CPs, but uncharged, are also expected to form.

cond-mat.supr-con↗

The BCS-Bose Crossover Theory

We contrast {\it four} distinct versions of the BCS-Bose statistical crossover theory according to the form assumed for the electron-number equation that accompanies the BCS gap equation. The four versions correspond to explicitly accounting for two-hole-(2h) as well as two-electron-(2e) Cooper pairs (CPs), or both in equal proportions, or only either kind. This follows from a recent generalization of the Bose-Einstein condensation (GBEC) statistical theory that includes not boson-boson interactions but rather 2e- and also (without loss of generality) 2h-CPs interacting with unpaired electrons and holes in a single-band model that is easily converted into a two-band model. The GBEC theory is essentially an extension of the Friedberg-T.D. Lee 1989 BEC theory of superconductors that excludes 2h-CPs. It can thus recover, when the numbers of 2h- and 2e-CPs in both BE-condensed and noncondensed states are separately equal, the BCS gap equation for all temperatures and couplings as well as the zero-temperature BCS (rigorous-upper-bound) condensation energy for all couplings. But ignoring either 2h- {\it or} 2e-CPs it can do neither. In particular, only {\it half} the BCS condensation energy is obtained in the two crossover versions ignoring either kind of CPs. We show how critical temperatures $T_{c}$ from the original BCS-Bose crossover theory in 2D require unphysically large couplings for the Cooper/BCS model interaction to differ significantly from the $T_{c}$s of ordinary BCS theory (where the number equation is substituted by the assumption that the chemical potential equals the Fermi energy).

cond-mat.supr-con↗

BEC, BCS and BCS-Bose Crossover Theories in Superconductors and Superfluids

For the Cooper/BCS model interaction in superconductors (SCs) it is shown: a) how BCS-Bose crossover picture transition temperatures Tc, defined self-consistently by both the gap and fermion-number equations, require unphysically large couplings to differ significantly from the Tc of ordinary BCS theory defined without the number equation since here the chemical potential is assumed equal to the Fermi energy; how although ignoring either hole- or electron-Cooper-pairs in the recent "complete boson-fermion model": b) one obtains the precise BCS gap equation for all temperatures T, but c) only half the zero-temperature BCS condensation energy emerges. Results (b) and (c) are also expected to hold for neutral-fermion superfluids (SFs)--such as liquid $^3$He, neutron matter and trapped ultra-cold fermion atomic gases--where the pair-forming two-fermion interaction of course differs from the Cooper/BCS one for SCs.

cond-mat.supr-con↗

High-Tc Superconductivity via BCS and BEC Unification: A Review

Though commonly unrecognized, a superconducting BCS condensate consists of equal numbers of two-electron (2e) and two-hole (2h) Cooper pairs (CPs). A complete (in the sense that 2h-CPs are not ignored) boson-fermion statistical model, however, is able to depart from this perfect 2e-/2h-CP symmetry and yields robustly higher T_c's without abandoning electron-phonon dynamics. The complete model reduces to all the known statistical theories of superconductors, including the BCS-Bose "crossover" picture but going considerably beyond it.

cond-mat.supr-con↗

Cooper Pairing Revisited

We recall the fundamental fact that Cooper pairs defined without ignoring two- hole pairs along with two-particle ones leads to a purely imaginary pair energy when the problem is based on the ideal Fermi gas sea. However, bound finite- lifetime pairs are recovered when it is based on the BCS ground-state Fermi sea. Their excitation energy is gapped at zero total momenta and then rises linearly in either 2D or 3D, making them similar to 3D plasmons which however rise quadratically.

cond-mat.supr-con↗

Generalized Cooper pairing and Bose-Einstein condensation

A Bethe-Salpeter treatment of Cooper pairs (CPs) based on an ideal Fermi gas (IFG) "sea"' yields the familiar negative-energy, two-particle bound-state if two-hole CPs are ignored, but is meaningless otherwise as it gives purely-imaginary energies. However, when based on the BCS ground state, legitimate two-particle "moving" CPs emerge but as positive-energy, finite-lifetime resonances for nonzero center-of-mass momentum, with a \textit{linear}dispersion leading term. Bose-Einstein condensation of such pairs may thus occur in exactly two dimensions as it cannot with quadratic dispersion.

cond-mat.supr-con↗

Kirkwood Phase Transition for Boson and Fermion Hard-Sphere Systems

The London ground-state energy formula as a function of number density $ρ$ for a system of boson hard spheres of diameter $c$ at zero temperature (corrected for the reduced mass of a pair of particles in a ``sphere-of-influence'' picture) generalized to describe fermion hard-sphere systems with four and two intrinsic degrees of freedom such as helium-three or neutron matter and symmetric nuclear matter, respectively, is proposed as the crystalline energy branch for hard-sphere systems. For the fluid branch we use the well-known, exact, low-density equation-of-state expansions for many-boson and many-fermion systems, appropriately extrapolated to physical densities. Here, via a double-tangent construction the crystallization and melting densities for boson and fermion hard spheres are determined. They agree well with variational Monte Carlo, density-functional, and Green Function Monte Carlo calculations.

cond-mat.stat-mech↗

Bose-Einstein condensation in real space

We illustrate how Bose-Einstein condensation occurs not only in momentum space but also in coordinate (or real) space. Analogies between the isotherms of a van der Waals gas of extended (or finite-diameter) identical atoms and the point (or zero-diameter) particles of an ideal Bose gas allow one to conclude that, in contrast to the van der Waals case, the volume per particle can go to zero in the pure Bose condensate phase precisely because the particle diameter is zero.

cond-mat.stat-mech↗

Anomalous behavior of ideal Fermi gas below two dimensions

Normal behavior of the thermodynamic properties of a Fermi gas in $d>2$ dimensions, integer or not, means monotonically increasing or decreasing of its specific heat, chemical potential or isothermal sound velocity, all as functions of temperature. However, for $0 2$ (known as the Bose-Einstein condensation), it is nevertheless an intriguing structural anomaly which we exhibit in detail.

cond-mat.stat-mech↗

BCS and BEC Finally Unified: A Brief Review

We review efforts to unify both the Bardeen, Cooper and Schrieffer (BCS) and Bose-Einstein condensation (BEC) pictures of superconductivity. We have finally achieved this in terms of a "\textit{complete} boson-fermion (BF) model" (CBFM) that reduces in special cases to all the main continuum (as opposed to "spin") statistical theories of superconductivity. Our BF model is "complete" in the sense that not only two-electron (2e) but also two-hole (2h) Cooper pairs (CPs) are allowed in arbitrary proportions. In contrast, BCS-Bogoliubov theory--which can also be considered as the theory of a mixture of kinematically independent electrons, 2e- and 2h-CPs--allows only equal, 50%-50%, mixtures of the two kinds of CPs. This is obvious from the perfect symmetry about $μ$, the electron chemical potential, of the well-known Bogoliubov $v^{2}(ε)$ and $u^{2}(ε)$ coefficients, where $ε$ is the electron energy. The CBFM is then applied to see: a) whether the BCS model interaction for the electron-phonon dynamical mechanism is sufficient to predict the unusually high values of $T_{c}$ (in units of the Fermi temperature) of $\simeq 0.01-0.1$ exhibited by the so-called ``exotic'' superconductors \cite{Brandow} in both 2D and 3D--relative to the low values of $\lesssim 10^{-3}$ more or less correctly predicted by BCS theory for conventional, elemental superconductors; and b) whether it can at least suggest, if not explain, why "hole superconductors" have higher $T_{c}$'s.

cond-mat.supr-con↗

Harmonically Trapped Quantum Gases

We solve the problem of a Bose or Fermi gas in $d$-dimensions trapped by $% δ\leq d$ mutually perpendicular harmonic oscillator potentials. From the grand potential we derive their thermodynamic functions (internal energy, specific heat, etc.) as well as a generalized density of states. The Bose gas exhibits Bose-Einstein condensation at a nonzero critical temperature $T_{c}$ if and only if $d+δ>2$, and a jump in the specific heat at $T_{c}$ if and only if $d+δ>4$. Specific heats for both gas types precisely coincide as functions of temperature when $d+δ=2$. The trapped system behaves like an ideal free quantum gas in $d+δ$ dimensions. For $δ=0$ we recover all known thermodynamic properties of ideal quantum gases in $d$ dimensions, while in 3D for $δ=$ 1, 2 and 3 one simulates behavior reminiscent of quantum {\it wells, wires}and{\it dots}, respectively.

cond-mat.stat-mech↗

Pre-formed Cooper pairs and Bose-Einstein condensation in cuprate superconductors

A two-dimensional (2D) assembly of noninteracting, temperature-dependent, pre-formed Cooper pairs in chemical/thermal equilibrium with unpaired fermions is examined in a binary boson-fermion statistical model as the Bose-Einstein condensation (BEC) singularity temperature $T_{c}$ is approached from above. Compared with BCS theory (which is {\it not} a BEC theory) substantially higher $T_{c}$'s are obtained without any adjustable parameters, that fall roughly within the range of empirical $T_{c}$'s for quasi-2D cuprate superconductors.

cond-mat.supr-con↗

Two-dimensional Bose-Einstein Condensation in Cuprate Superconductors

Transition temperatures $T_{c}$ calculated using the BCS model electron-phonon interaction without any adjustable parameters agree with empirical values for quasi-2D cuprate superconductors. They follow from a two-dimensional gas of temperature-dependent Cooper pairs in chemical and thermal equilibrium with unpaired fermions in a boson-fermion (BF) statistical model as the Bose-Einstein condensation (BEC) singularity temperature is approached from above. The {\it linear} (as opposed to quadratic) boson dispersion relation due to the Fermi sea yields substantially higher $T_{c}$'s with the BF model than with BCS or pure-boson BEC theories.

cond-mat.supr-con↗

Cooper pairs as resonances

Using the Bethe-Salpeter (BS) equation, Cooper pairing can be generalized to include contributions from holes as well as particles from the ground state of either an ideal Fermi gas (IFG) or of a BCS many-fermion state. The BCS model interfermion interaction is employed throughout. In contrast to the better-known original Cooper pair problem for either two particles or two holes, the generalized Cooper equation in the IFG case has no real-energy solutions. Rather, it possesses two complex-conjugate solutions with purely imaginary energies. This implies that the IFG ground state is unstable when an attractive interaction is switched on. However, solving the BS equation for the BCS ground state reveals two types of {\it real} solutions: one describing moving (i.e., having nonzero total, or center-of-mass, momenta) Cooper pairs as resonances (or bound composite particles with a {\it finite} lifetime), and another exhibiting superconducting collective excitations sometimes known as Anderson-Bogoliubov-Higgs (ABH) modes. A Bose-Einstein-condensation-based picture of superconductivity is addressed.

cond-mat.supr-con↗

Bose-Einstein condensation of nonzero-center-of-mass-momentum Cooper pairs

Cooper pair (CP) binding with both zero and nonzero center-of-mass momenta (CMM) is studied with a set of renormalized equations assuming a short-ranged (attractive) pairwise interfermion interaction. Expanding the associated dispersion relation in 2D in powers of the CMM, in weak-to-moderate coupling a term {\it linear} in the CMM dominates the pair excitation energy, while the quadratic behavior usually assumed in Bose-Einstein (BE)-condensation studies prevails for any coupling {\it only} in the limit of zero Fermi velocity when the Fermi sea disappears, i.e., in vacuum. In 3D this same behavior is observed numerically. The linear term, moreover, exhibits CP breakup beyond a threshold CMM value which vanishes with coupling. This makes all the excited (nonzero-CMM) BE levels with preformed CPs collapse into a single ground level so that a BCS condensate (where only zero CMM CPs are usually allowed) appears in zero coupling to be a special case in either 2D or 3D of the BE condensate of linear-dispersion-relation CPs.

cond-mat.supr-con↗

Cooper pair dispersion relation in two dimensions

The Cooper pair binding energy {\it vs.} center-of-mass-momentum dispersion relation for Bose-Einstein condensation studies of superconductivity is found in two dimensions for a renormalized attractive delta interaction. It crosses over smoothly from a linear to a quadratic form as coupling varies from weak to strong.

cond-mat.str-el↗

Statistical Model of Superconductivity in a 2D Binary Boson-Fermion Mixture

A two-dimensional (2D) assembly of noninteracting, temperature-dependent, composite-boson Cooper pairs (CPs) in chemical and thermal equilibrium with unpaired fermions is examined in a binary boson-fermion statistical model as the superconducting singularity temperature is approached from above. The model is derived from {\it first principles} for the BCS model interfermion interaction from three extrema of the system Helmholtz free energy (subject to constant pairable-fermion number) with respect to: a) the pairable-fermion distribution function; b) the number of excited (bosonic) CPs, i.e., with nonzero total momenta--usually ignored in BCS theory--and with the appropriate (linear, as opposed to quadratic) dispersion relation that arises from the Fermi sea; and c) the number of CPs with zero total momenta. Compared with the BCS theory condensate, higher singularity temperatures for the Bose-Einstein condensate are obtained in the binary boson-fermion mixture model which are in rough agreement with empirical critical temperatures for quasi-2D superconductors

cond-mat.supr-con↗

Cooper pair dispersion relation for weak to strong coupling

Cooper pairing in two dimensions is analyzed with a set of renormalized equations to determine its binding energy for any fermion number density and all coupling assuming a generic pairwise residual interfermion interaction. \ Also considered are Cooper pairs (CPs) with nonzero center-of-mass momentum (CMM)--usually neglected in BCS theory--and their binding energy is expanded analytically in powers of the CMM up to quadratic terms. A Fermi-sea-dependent {\it linear} term in the CMM dominates the pair excitation energy in weak coupling (also called the BCS regime) while the more familiar quadratic term prevails in strong coupling (the Bose regime). The crossover, though strictly unrelated to BCS theory {\it per se,} is studied numerically as it is expected to play a central role in a model of superconductivity as a Bose-Einstein condensation of CPs where the transition temperature vanishes for all dimensionality $d\leq 2$ for quadratic dispersion, but is {\it nonzero} for all $d\geq 1$ for linear dispersion.

cond-mat.supr-con↗