arXiv subjects

M. de Souza

Publications and source records attributed to M. de Souza.

39 records · Page 3Linked to original sources

arXiv2009

Rare earth magnetism in CeFeAsO: A single crystal study

Single crystals of CeFeAsO, large enough to study the anisotropy of the magnetic properties, were grown by an optimized Sn-flux technique. The high quality of our single crystals is apparent from the highest residual resistivity ratio, RRR = 12, reported among undoped RFeAsO compounds (R=rare earth) as well as sharp anomalies in resistivity, specific heat, C(T), and thermal expansion at the different phase transitions. The magnetic susceptibility chi(T) presents a large easy-plane anisotropy consistent with the lowest crystal electric field doublet having a dominant Gamma_6 character. Curie-Weiss like susceptibilities for magnetic field parallel and perpendicular to the crystallographic c-axis do not reveal an influence of a staggered field on the Ce site induced by magnetic ordering of the Fe. Furthermore, the standard signatures for antiferromagnetic order of Ce at T_N = 3.7 K observed in chi(T) and C(T) are incompatible with a Zeeman splitting Delta = 10 K of the CEF ground state doublet at low temperature due to the Fe-magnetic order as previously proposed. Our results can be reconciled with the earlier observation by assuming a comparatively stronger effect of the Ce-Ce exchange leading to a reduction of this Zeeman splitting below 15 K.

cond-mat.supr-con↗

arXiv2008

Evidence for Lattice Effects at the Charge-Ordering Transition in (TMTTF)$_2$X

High-resolution thermal expansion measurements have been performed for exploring the mysterious "structureless transition" in (TMTTF)$_{2}$X (X = PF$_{6}$ and AsF$_{6}$), where charge ordering at $T_{CO}$ coincides with the onset of ferroelectric order. Particularly distinct lattice effects are found at $T_{CO}$ in the uniaxial expansivity along the interstack $\textbf{\textit{c*}}$-direction. We propose a scheme involving a charge modulation along the TMTTF stacks and its coupling to displacements of the counteranions X$^{-}$. These anion shifts, which lift the inversion symmetry enabling ferroelectric order to develop, determine the 3D charge pattern without ambiguity. Evidence is found for another anomaly for both materials at $T_{int}$ $\simeq$ 0.6 $\cdot$ $T_{CO}$ indicative of a phase transition related to the charge ordering.

cond-mat.str-el↗

arXiv2007

Anomalous Lattice Response at the Mott Transition in a Quasi-2D Organic Conductor

Discontinuous changes of the lattice parameters at the Mott metal-insulator transition are detected by high-resolution dilatometry on deuterated crystals of the layered organic conductor $κ$-(BEDT-TTF)$_{2}$Cu[N(CN)$_{2}$]Br. The uniaxial expansivities uncover a striking and unexpected anisotropy, notably a zero-effect along the in-plane c-axis along which the electronic interactions are relatively strong. A huge thermal expansion anomaly is observed near the end-point of the first-order transition line enabling to explore the critical behavior with very high sensitivity. The analysis yields critical fluctuations with an exponent $\tildeα \simeq$ 0.8 $\pm$ 0.15 at odds with the novel criticality recently proposed for these materials [Kagawa \textit{et al.}, Nature \textbf{436}, 534 (2005)]. Our data suggest an intricate role of the lattice degrees of freedom in the Mott transition for the present materials.

cond-mat.str-el↗