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Makoto Naka

Publications and source records attributed to Makoto Naka.

At least 19 recordsLinked to original sources

Two routes to quantum anomalous Hall states in altermagnets

We theoretically propose two possible routes to realizing quantum anomalous Hall states in altermagnetic materials. We consider a minimal square-lattice Hubbard model with antisymmetric spin-orbit coupling associated with an orthorhombic crystal structure, which supports a topologically trivial altermagnetic state. By incorporating Rashba-type spin-orbit coupling and external perturbations, we demonstrate that this trivial state can be turned into topological altermagnetic phases in two distinct ways. The first route is driven by a staggered potential that breaks the symmetry connecting crystallographically equivalent sublattices, leading to a topological altermagnetic ground state characterized by a quantized Hall conductivity $\left| σ_{xy} \right|=e^2/h$ and a Chern number $C=1$. The second route is realized by applying a magnetic field perpendicular to the two-dimensional plane. The resulting topological state appears as a metastable state in the magnetic hysteresis loop, exhibiting a quantized Hall conductivity $\left| σ_{xy} \right|=2e^2/h$ associated with a Chern number $C=2$. We show that these topological transitions are accompanied by characteristic gap closings at the Brillouin-zone boundary, with the number of gap-closing points determining the Chern number. Ribbon-geometry calculations reveal chiral edge states consistent with the bulk topological invariants and demonstrate distinct spin polarizations between the $C=1$ and $C=2$ states. Our results establish experimentally accessible routes to quantized anomalous Hall responses in altermagnets.

cond-mat.str-el

Quantum Mechanism of Piezomagnetism in Higher-Spin Altermagnets

We investigate piezomagnetism in higher-spin altermagnets with easy-plane single-ion anisotropy using a flavor-wave approach. We show that quantum fluctuations of higher-spin collective modes provide a microscopic origin of the piezomagnetic response. For integer spins, the relevant branch softens and evolves into a Higgs-like amplitude mode on approaching the large-$D$ transition, endowing the excitation with a sizable dipolar component and producing a pronounced enhancement of piezomagnetism. By contrast, in half-integer systems the higher-spin branches are progressively separated from the low-energy dipolar sector as the anisotropy increases, which suppresses their contribution to the response. This integer-half-integer contrast directly links macroscopic piezomagnetism to the low-energy fate of multipolar excitations. Our results establish piezomagnetism as a probe of higher-spin quantum dynamics and identify higher-spin altermagnets as a promising setting for quantum magnetoelastic responses.

cond-mat.str-el

Phase-modulated superconductivity via altermagnetism

Stimulated by recent interest in altermagnets, a novel class of antiferromagnets with macroscopic time-reversal symmetry breaking, we investigate the coexistence of altermagnetism and superconductivity. By developing a Ginzburg--Landau theory based on microscopic models, we show that a phase-modulated Fulde--Ferrell superconducting state is stabilized via altermagnetic spin splitting, in contrast to the typical amplitude-modulated states that occur under the uniform Zeeman field. We apply our framework to different models to compare the resulting phase diagrams: a two-sublattice model with altermagnetic order, a continuum model with an anisotropic Zeeman field mimicking altermagnetic spin splitting, and a conventional square-lattice model with two kinds of anisotropic Zeeman fields. We show that the multisublattice structure is crucial for realizing the phase-modulated superconductivity, and highlight spin-split altermagnets as a promising platform for exploring this exotic superconductivity without external magnetic fields.

cond-mat.supr-con

Nonrelativistic Piezomagnetic Effect in an Organic Altermagnet

We theoretically study the piezomagnetic effect on the altermagnetic state in $κ$-type molecular conductors, focusing on its nonrelativistic mechanism. By introducing shear stress as a monoclinic distortion, we evaluate variations in the effective tight-binding model using first-principles calculations. Using the derived parameters, we investigate the Hubbard model and its effective Heisenberg model on the two-dimensional (distorted) $κ$-type lattice within mean-field approximation. We show that the system exhibits the piezomagnetic effect, i.e., a net magnetization induced at finite temperatures in the undoped insulating state and both in the ground state and at finite temperatures upon doping. In a real-space picture, this uniform magnetization arises from the ferrimagnetic spin structure due to inequivalent spin sites induced by lattice distortion. Meanwhile, in a momentum-space picture, it stems from the {\it s}-wave spin splitting of the electron and magnon bands, independent of spin-orbit coupling. We find that this nonrelativistic piezomagnetism remains finite, but becomes smaller in the limit of strong dimerization where the energy gap between the bonding and antibonding orbitals is infinitely large and the {\it d}-wave altermagnetic spin splitting is absent, highlighting the importance of the multi-orbital nature.

cond-mat.str-el

Altermagnetic Perovskites

Altermagnet is a class of antiferromagnets, which shows a staggered spin ordering with wave vector ${\bm q}=0$, while its net magnetization is canceled out in the limit of zero relativistic spin-orbit coupling. The simplest case is when the up and down spins are ordered on two crystallographically equivalent sublattice sites within the unit cell that are not connected by translation, and consequently, the system breaks the macroscopic time-reversal symmetry. Accordingly, it exhibits non-relativistic spin splitting in the energy band and characteristic cross-correlation phenomena between spin, charge, and lattice (orbital) degrees of freedom. This is in contrast to conventional Néel-type antiferromagnets with ${\bm q} \neq 0$ conserving the macroscopic time-reversal symmetry, where the time-reversal operation flipping of spins combined with translation can make the system identical to the original state. Altermagneticsm is universally latent in various magnetic materials that have been considered as simple collinear-type antiferromagnets. In this article, we focus on perovskites with chemical formula {\it ABX}$_3$, which are typical playgrounds for strongly correlated electron systems, and overview their altermagnetic aspects that have been overlooked in the past researches, based on microscopic model studies revealing the mechanisms of their properties. We display that a combination of a variety of antiferromagnetic ordering and the commonly-seen lattice distortions in perovskites gives rise to a non-relativistic spin splitting whose mechanism does not rely on the spin-orbit coupling and its consequent spin current generation, and the anomalous Hall effect in the presence of the spin-orbit coupling.

cond-mat.str-el

Spin-Orbital Ordering in Alkali Superoxides

Akali superoxides AO2 (A=Na, K, Rb, Cs), due to an open p shell of the oxygen ion O2^- with degenerate pi orbitals, have spin and orbital degrees of freedom. The complex magnetic, orbital, and structural phase transitions observed experimentally in this family of materials are only partially understood. Based on density functional theory, we derive a strong-coupling effective model for the isostructural compounds AO2 (A=K, Rb, Cs) from a two-orbital Hubbard model. We find that CsO2 has highly frustrated exchange interactions in the a-b plane, while the frustration is weaker for RbO2 and KO2. We solve the resulting Kugel-Khomskii model in the mean-field approximation. We show that CsO2 exhibits an antiferro-orbital (AFO) order with the ordering vector q=(1,0,0) and a stripe antiferromagnetic order with q=(1/2,0,0), which is consistent with recent neutron scattering experiments. We discuss the role of the pi-orbital degrees of freedom for the experimentally observed magnetic transitions and interpret the as-yet-unidentified T_s2=70K transition in CsO2 as an orbital ordering transition.

cond-mat.str-el

Fulde-Ferrell-Larkin-Ovchinnikov state induced by antiferromagnetic order in $κ$-type organic conductors

We theoretically investigate superconductivity under a spin-split band structure owing to a collinear-type antiferromagnetic order in quasi-two-dimensional organic compounds $κ$-(BEDT-TTF)$_2X$. We find that the magnetic order can induce a Fulde--Ferrell--Larkin--Ovchinnikov (FFLO) state, where the Cooper pair possesses a finite center-of-mass momentum. We show this from two types of analyses: (1) an effective model where simple intraband attractive interactions are assumed, and (2) many-body calculations of the repulsive Hubbard model based on the fluctuation-exchange approximation and the linearized Eliashberg equation. Our results show the possibility of realizing the FFLO state without applying an external magnetic field.

cond-mat.supr-con

Correlated Zak insulator in organic antiferromagnets

Searching for topological insulators in solids is one of the main issues of modern condensed matter physics since robust gapless edge or surface states of the topological insulators can be used as building blocks of next-generation devices. Enhancing spin-orbit couplings is a promising way to realize topological insulators in solids, whereas the amplitude of the spin-orbit couplings is not sufficiently large in most materials. Here we show a way to realize a topological state characterized by the quantized Zak phase, termed the Zak insulator, with spin-polarized edges in organic antiferromagnetic Mott insulators without relying on the spin-orbit coupling. The obtained Zak insulator can have a large charge gap compared to the conventional topological insulators, since Coulomb interactions mainly govern the amplitude of the charge gap in the antiferromagnetic Mott insulators. Besides the mean-field analysis, we demonstrate that the Zak insulator survives against electron correlation effects by calculating the many-body Zak phase. Our finding provides an unprecedented way to realize a topological state in strongly correlated electron systems.

cond-mat.str-el

Anomalous Hall effect in antiferromagnetic perovskites

We theoretically study the anomalous Hall effect (AHE) in perovskites with antiferromagnetic (AFM) orderings. By studying the multiorbital Hubbard model for $d$ electrons in perovskite transition metal oxides under the GdFeO$_3$-type distortion within the Hartree-Fock approximation, we investigate the behavior of intrinsic AHE owing to the atomic spin-orbit coupling via the linear response theory. We consider the cases where there exist two ($d^2$) and three ($d^3$) electrons in the $t_{2g}$ orbitals, and show that AFM ordered states can exhibit AHE. In the $d^2$ case, $C$-type AFM states give rise to dc AHE in metals and optical (finite-$ω$) AHE in insulators accompanying orbital ordering, while in the $d^3$ case, a $G$-type AFM insulating state supports the optical AHE. By resolving the components in the spin patterns compatible with the space group symmetry, we specify the collinear AFM component to be responsible for the AHE, rather than the small ferromagnetic component. We discuss the microscopic origin of the AHE: the collinear AFM spin structure produces a nonzero Berry phase from the triangular units of the lattice, activated by the complex orbital mixing terms owing to the GdFeO$_3$-type distortion, and results in the microscopic Lorentz force.

cond-mat.str-el

Phonon renormalization effects accompanying the 6 K anomaly in the Quantum Spin Liquid Candidate $κ$-(BEDT-TTF)$_{2}$Cu$_{2}$(CN)$_{3}$

The low-temperature state of the quantum spin liquid candidate $κ$-(BEDT-TTF)$_{2}$Cu$_{2}$(CN)$_{3}$ emerges via an anomaly at $T^{*}\sim6$ K. Although signatures of this anomaly have been revealed in various quantities, its origin has remained unclear. Here we report inelastic neutron scattering measurements on single crystals of $κ$-(BEDT-TTF)$_{2}$Cu$_{2}$(CN)$_{3}$, aiming at studying phonon renormalization effects at $T^{*}$. A drastic change was observed in the phonon damping across $T^{*}$ for a breathing mode of BEDT-TTF dimers at $E=4.7$ meV. The abrupt change in the phonon damping is attributed to a phase transition into a valence bond solid state based on an effective model describing the spin-charge coupling in this dimer-Mott system.

cond-mat.str-el

Antiferromagnetic State in $κ$-type Molecular Conductors: Spin Splitting and Mott Gap

We numerically investigate the dynamical properties of $κ$-type molecular conductors in their antiferromagnetic Mott insulating state. By treating the extended Hubbard model on the two-dimensional $κ$-type lattice within the Lanzcos exact diagonalization method, we calculate the one-particle spectral function $A(\boldsymbol{k}, ω)$ and the optical absorption spectra taking advantage of twisted boundary conditions. We find spin splitting in $A(\boldsymbol{k}, ω)$ predicted by a previous Hartree-Fock study [M. Naka et al., Nat. Commun. 10, 4305 (2019)]; namely, their up- and down-spin components become different in the general $\boldsymbol{k}$-points of the Brillouin zone, even without the spin-orbit coupling. Furthermore, we demonstrate the variation in the optical properties near the Mott gap by the presence or absence of the antiferromagnetic order, tuned by a small staggered magnetic field.

cond-mat.str-el

Spin Seebeck Effect in Nonmagnetic Excitonic Insulators

We propose a mechanism of the spin Seebeck effect attributed to excitonic condensation in a nonmagnetic insulator. We analyze a half-filled two-orbital Hubbard model with a crystalline field splitting in the strong coupling limit. In this model, the competition between the crystalline field and electron correlations brings about an excitonic insulating state, where the two orbitals are spontaneously hybridized. Using the generalized spin-wave theory and Boltzmann transport equation, we find that a spin current generated by a thermal gradient is observed in the excitonic insulating state without magnetic fields. The spin Seebeck effect originates from spin-split collective excitation modes although the ground state does not exhibit any magnetic orderings. This peculiar phenomenon is inherent in the excitonic insulating state, whose order parameter is time-reversal odd and yields a spin splitting for the collective excitation modes. We also find that the spin current is strongly enhanced and its direction is inverted in the vicinity of the phase transition to another magnetically ordered phase. We suggest that the present phenomenon is possibly observed in perovskite cobaltites with the GdFeO$_3$-type lattice distortion.

cond-mat.str-el

Perovskite as a spin current generator

We theoretically show that materials with perovskite-type crystal structures provide a platform for spin current generation, taking advantage of a mechanism requiring neither the spin-orbit coupling nor a ferromagnetic moment, but is based on spin-split band structures in certain kinds of collinear antiferromagnetic states. By investigating a multiband Hubbard model for transition metal compounds by means of the Hartree-Fock approximation and the Boltzmann transport theory, we find that a pure spin current is induced by an electric field applied to a C-type antiferromagnetic metallic phase. The spin current generation originates from a cooperative effect of spatially anisotropic electron transfer integrals owing to the GdFeO$_3$-type lattice distortion, which is ubiquitous in many perovskites, and the collinear spin configuration. We discuss our finding from the symmetry point of view, in comparison with other spin current generator candidates with collinear antiferomagnetism. We also propose several ways to detect the phenomenon in candidate perovskite materials.

cond-mat.str-el

Strong enhancement of magnetic susceptibility induced by spin-nematic fluctuations in an excitonic insulating system with spin-orbit coupling

Effects of the spin-orbit coupling (SOC) and magnetic field on excitonic insulating (EI) states are investigated. We introduce the two-orbital Hubbard model with the crystalline field splitting, which is a minimal model for discussing the exciton condensation in strongly correlated electron systems, and analyze its effective Hamiltonian in the strong correlation limit by using the mean-field theory. In the absence of the SOC and magnetic field, the ground state changes from the nonmagnetic band-insulating state to the EI state by increasing the Hund coupling. In an applied magnetic field, the magnetic moment appears in the EI state, which is continuously connected to the forced ferromagnetic state. On the other hand, in the presence of the SOC, they are separated by a phase boundary. We find that the magnetic susceptibility is strongly enhanced in the EI phase near the boundary with a small SOC. This peculiar behavior is attributed to the low-energy fluctuation of the spin nematicity inherent in the high-spin local state stabilized by the Hund coupling. The present study not only reveals the impact of the SOC for the EI state but also sheds light on the role of quantum fluctuations of the spin nematicity for the EI state.

cond-mat.str-el

Anomalous Hall effect in $κ$-type organic antiferromagnets

We theoretically propose a mechanism for the anomalous Hall effect (AHE) in an antiferrromagnetic (AFM) state of $κ$-type organic conductors. We incorporate the spin-orbit coupling in the effective Hubbard model on the $κ$-type lattice structure taking into account the orientation of the molecules and their arrangement with dimerization. Treating this model by means of the Hartree-Fock approximation and the linear response theory, we find that an intrinsic contribution to the Hall conductivity becomes nonzero in the electron-doped AFM metallic phase with a small canted ferromagnetic moment. We show that, contrary to the conventional wisdom, the spin canting is irrelevant to the Hall response; the nonzero Hall conductivity originates from the collinear component of the AFM order in the presence of the spin-orbit coupling. These features are well explained analytically in the limit of strong dimerization on the anisotropic triangular lattice. Furthermore, we present an intuitive picture for the present AHE by considering the real-space configuration of emergent magnetic fluxes. We also find that the Hall response appears even in the undoped AFM insulating phase at nonzero frequency as the magneto-optical Kerr effect, which is enhanced around the charge transfer excitations. We discuss possible detections of the AHE in ET based compounds.

cond-mat.str-el

Finite Temperature Properties of Geometrically Charge Frustrated Systems

We theoretically study finite temperature properties of interacting fermion systems under geometrical frustration in the charge degree of freedom. Physical quantities such as charge structure factors, the specific heat, and the entropy, of the two-dimensional model of interacting spinless fermions on an anisotropic triangular lattice are numerically calculated using the thermal pure quantum state. By considering the Coulomb interactions up to the next-nearest-neighbor bonds, we elucidate that in the highly frustrated region where a long-period stripe-type charge order (CO) is the ground state, fluctuations of different stripe-type CO patterns become large at finite temperatures. When we further introduce $1/r$-type long-range Coulomb interactions, the ground state unexpectedly recovers the non-stripe-type 3-fold CO pattern characteristic of triangular lattice models with short-range interactions. Our results imply that the BEDT-TTF-based organic conductors exhibiting glass-like behavior locates in the region of the intermediate strength of long-range interactions, where both the stripe- and non-stripe-type CO fluctuations are prominent.

cond-mat.str-el

Optical Response in Excitonic Insulating State: Variational Cluster Approach

Optical responses in an excitonic insulating (EI) system with strong electron correlation are studied. We adopt the two-orbital Hubbard model with a finite energy difference between the two orbitals where the spin state degree of freedom exists. This model is analyzed by the variational cluster approach. In order to include the local electron correlation effect, the vertex correction is taken into account in the formulation of the optical conductivity spectra. We calculate a finite-temperature phase diagram, in which an EI phase appears between a low-spin band insulating state and a high-spin Mott insulating state. Characteristic components of the optical conductivity spectra consisting of a sharp peak and continuum appear in the EI phase. Integrated intensity almost follows the order parameter of the EI state, suggesting that this component is available to identify the EI phases and transitions.

cond-mat.str-el

Spin current generation in organic antiferromagnets

Spin current--a flow of electron spins without a charge current--is an ideal information carrier free from Joule heating for electronic devices. The celebrated spin Hall effect, which arises from the relativistic spin-orbit coupling, enables us to generate and detect spin currents in inorganic materials and semiconductors, taking advantage of their constituent heavy atoms. In contrast, organic materials consisting of molecules with light elements have been believed to be unsuited for spin current generation. Here we show that a class of organic antiferromagnets with checker-plate type molecular arrangements can serve as a spin current generator by applying a thermal gradient or an electric field, even with vanishing spin-orbit coupling. Our findings provide another route to create a spin current distinct from the conventional spin Hall effect and open a new field of spintronics based on organic magnets having advantages of small spin scattering and long lifetime.

cond-mat.str-el