arXiv subjects

Manuela Lippi

Publications and source records attributed to Manuela Lippi.

11 recordsLinked to original sources

arXiv2026

Chemical Complexity in the Early Stages of Star Formation in the SKAO Era

About 350 molecules have been identified in the interstellar medium (ISM), including complex molecules relevant to prebiotic chemistry. A remarkable level of molecular diversity has been observed from the earliest stages of star formation, providing the initial chemical inventory inherited by planetary systems. Radio observations have played a pivotal role in these discoveries, starting with the identification of the first polyatomic molecule, $\text{NH}_3$ (Cheung et al. 1968). (Sub-)millimeter observations have revealed complex organic molecules of prebiotic relevance, including formamide ($\text{NH}_2\text{CHO}$), glycolaldehyde ($\text{CH}_2\text{OHCHO}$), and even urea ($(\text{NH}_2)_2\text{CO}$), and hydroxylamine ($\text{NH}_2\text{OH}$), which are possible precursors of RNA nucleotides (Ceccarelli et al. 2023; Jim\'enez-Serra et al. 2020). However, in dense protostellar regions, dust opacity hampers the detection of molecular emission. Additionally, large molecules and those containing heavy atoms, which have rotational transitions at lower frequencies, often remain inaccessible to current instruments. The Square Kilometre Array Observatory (SKAO) will provide an unprecedented combination of sensitivity and angular resolution at radio wavelengths. This will allow for the detection of prebiotic species and offer new insights into the chemical pathways that shape emerging planetary systems (Jim\'enez-Serra et al. 2022). This chapter details the scientific questions and advancements that the SKAO, and more specifically, SKA-Mid equipped with the Band 5 receivers, will pursue in the field of astrochemistry, focusing on the chemical complexity in both high-mass and solar-type star-forming regions.

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arXiv2026

Unveiling Complex Chemistry in Planet-forming Disks with the SKAO

The chemical composition of planets is inherited from that of the natal protoplanetary disk at the time of planet formation. In recent years, we have made huge progress in characterizing disk chemistry. (Sub-)millimeter interferometers, such as ALMA, allowed us to detect emission lines from simple to complex organic molecules and to probe their radial and vertical distribution in disks. On the other hand, JWST has started to unveil the composition of disk ices, and line emission from the innermost disk regions. The advent of SKA will open new domains in the field, by observing emission lines from heavier molecules including heavy carbon chains and rings, and prebiotic molecules with peak emission in the cm range. Moreover, SKA will probe molecular emission from regions which are obscured by dust opacity at mm wavelengths, hence from the disk midplane, and often from the inner 30 au region. These observations will constrain the initial conditions for disk evolution and planet formation, allowing us to predict the chemical composition of the forming planets and their atmospheres. Comparison with forthcoming results on exoplanet atmospheres and on the chemistry of pristine bodies in the Solar System will provide new hints on the origin and evolution of planetary systems including our own.

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arXiv2026

Jets and Outflows in Young Stellar Objects with the SKAO

Jets and outflows are ubiquitous phenomena associated with the formation of young stellar objects (YSOs). They play a crucial role in removing angular momentum from the accreting system and in regulating star-formation efficiency. Theoretical studies and observations with ALMA and VLA have shown that jets and winds may have a crucial role in promoting dust growth in the envelope-disc system and in shaping the physical and chemical properties of the surrounding environment. Despite these significant advances, many fundamental questions remain unanswered regarding the acceleration, collimation, and chemical impact of jets and outflows from YSOs. The SKA-project will overcome the limitations of current mm/cm-facilities by enabling high-angular resolution and high-sensitivity cm-observations, crucial for probing jets/outflows near YSOs. Radio recombination lines, combined with proper motions, offer a unique opportunity to study the 3D-kinematics of jets. Non-thermal linearly polarised synchrotron emission will allow measuring magnetic field strength and morphology at unprecedented scales of a few au. Observations of dust emission in outflow cavities will allow studying how dust grows and is eventually transported from the disc to the envelope and back. Finally, the SKA-project will allow exploring the dust composition and chemical enrichment in shocks, where sputtering/shattering of grains cause the release of their mantles and refractory cores in the gas-phase. Complementary to ALMA's detection of simple and complex organic molecules, the SKAO will probe, for the first time, long carbon chains/rings, several Cl-, Al-, Mg-, and other metal-bearing species (missed by current sub-mm facilities).

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arXiv2025

Very Large Telescope Observations of Interstellar Comet 3I/ATLAS. II. From Quiescence to Glow: Dramatic Rise of Ni i Emission and Incipient CN Outgassing at Large Heliocentric Distances*

We report VLT spectroscopy of the interstellar comet 3I/ATLAS (C/2025~N1) from $r_{\rm h}\!\simeq\!4.4$ to $2.85$~au using X-shooter (300--550\,nm, $R\!\simeq\!3000$) and UVES (optical, $R\!\simeq\!35k-80k$). The coma is dust-dominated with a fairly constant red optical continuum slope ($\sim$21--22\%/1000\AA). We report detection of CN emission and also detect numerous Ni\,\textsc{ii}~lines while Fe\,\textsc{i}~remains undetected, potentially implying efficiently released gas-phase Ni. At $r_{\rm h}\!\simeq\!3.14$~au we derive $3\sigma$ limits of $Q({\rm OH})<{1.48\times10^{26}}\ {\rm s^{-1}}$, but find no indications for [O\,\textsc{i}], C$_2$, C$_3$ or NH$_2$. From our latest X-shooter measurements conducted on 2025-08-21 ($r_{\rm h} = 2.85$\,au) we measure production rates of $\log~Q(\mathrm{CN}) = {24.81\pm 0.01}$ molecules s$^{-1}$ and $\log~Q$(Ni) $= {23.30\pm0.07}$ atoms s$^{-1}$, and characterize their evolution as the comet approaches perihelion.~We observe a steep heliocentric-distance scaling for the production rates $Q(\mathrm{Ni}) \propto r_h^{{-7.7 \pm 1.0}}$ and for $Q(\mathrm{CN}) \propto r_h^{{-6.7 \pm 0.2}}$, and predict a Ni--CO$_{(2)}$ correlation if the Ni\,\textsc{ii}\ emission is driven by the carbonyl formation channel.~Energetic considerations of activation barriers show that this behavior is inconsistent with direct sublimation of canonical metal/sulfide phases and instead favors low--activation--energy release from dust, e.g.~photon-stimulated desorption or mild thermolysis of metalated organics or Ni-rich nanophases, possibly including Ni--carbonyl-like complexes.~These hypotheses are testable with future coordinated ground-based and space-based monitoring as 3I becomes more active during its continued passage through the solar system.

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arXiv2025

Snapshot of a new interstellar comet: 3I/ATLAS has a red and featureless spectrum

The interstellar comet 3I/ATLAS is only the third interstellar object to be discovered. Pre-perihelion measurements provide a unique opportunity to study its activity and composition, which may alter as it is heated in the coming months. We provide an initial baseline from optical spectroscopic observations obtained only two days after discovery, using the MUSE instrument on the VLT on 2025 July 3, while 3I was at 4.47 au from the Sun and 3.46 au from the Earth. These observations confirm the cometary nature of 3I, and reveal a red coma with a spectral slope of $(18\pm4)\%/1000$~\AA, redder than most Solar System comets but similar to the surface colour of some Solar System Trans-Neptunian Objects or Centaurs. We searched for but did not detect gas emission from C$_2$, NH$_2$, CN, and [OI], which is consistent with volatile non-detections for Solar System comets at this heliocentric distance. At present, the coma appears entirely dusty. Future observations of 3I as it comes closer to the Sun will provide an invaluable opportunity to witness the evolution of its activity, study its composition, test predictions of interstellar object population models, and compare 3I to Solar System comets.

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arXiv2024

The pre-perihelion evolution of the activity of comet C/2017 K2 (PANSTARRS) during the water ice-line crossover

Comets, relics from the early solar system, consist of dust and ice. The ice sublimates as comets approach the Sun, ejecting dust from their nuclei seen as activity. Different volatiles sublimate at different Sun-comet distances and eject dust of unique sizes, structures, and compositions. In this study, we present new polarimetric observations of Oort-cloud comet C/2017 K2 (PANSTARRS) in R and I-filter domains before, during, and after its crossover of the water-ice sublimation regime at phase angles of 15.9\arcdeg, 10.5\arcdeg, and 20.0\arcdeg, respectively. Combining multiband optical imaging data covering a wide range of heliocentric distances ($\sim$14$-$2.3 au), we aim to characterize the preperihelion evolution of cometary activity as well as the properties of its coma dust. Two discontinuous brightening events were observed: at $\sim$6 au presumably associated with changes in CO-like supervolatile ice activity, and at $\sim$2.9 au when water ice took over. Particularly, the latter activation is accompanied by changes in coma morphology and color whose trends differ between the inner ($\sim$10$^3$-km) and outer ($\sim$10$^4$-km) parts of the coma. No polarimetric discontinuities on the comet were observed over the inner coma region, all epochs showing phase-angle and wavelength dependencies compatible with those of active comets observed in similar observing geometry. During this period, the underlying dust continuum overwhelmed H$α$ emission at around 656.3 nm, suggesting less water ice on the comet's surface than expected. We discuss K2's coma environment by combining numerical simulations of light scattered by dust and place the observations within the context of the comet's evolution.

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arXiv2024

Destruction of interstellar methyl cyanide (CH3CN) via collisions with He+ ions

Methyl cyanide is one of the simplest interstellar complex organic molecules, widely detected in young solar analogues, shocked regions, protoplanetary disks and comets. CH3CN can be considered a key species to explore the chemical connections between planet forming disks and comets. For such comparison to be meaningful kinetics data for the reactions leading to CH3CN formation and destruction must be updated. We focus on the destruction of methyl cyanide through collisions with He+. A combined experimental and theoretical methodology is employed to obtain cross sections (CSs) and branching ratios (BRs) as a function of collision energy, from which reaction rate coefficients $k(T)$ are calculated in the temperature range from 10 to 300 K. CSs and BRs are measured using a guided ion beam set-up. A theoretical treatment based on an analytical formulation of the potential energy surfaces (PESs) for the charge exchange process is developed. The method employs a Landau Zener model to obtain reaction probabilities at crossings between the entrance and exit PESs, and an adiabatic centrifugal sudden approximation to calculate CSs and k(T). Rates and BRs differ from those predicted from widely-used capture models. In particular, the rate coefficient at 10 K is estimated to be almost one order of magnitude smaller than what reported in the KIDA database. As for BRs, the charge exchange is completely dissociative and the most abundant fragments are HCCN+/CCNH+, HCNH+ and CH2+. Our results, combined with a revised chemical network for formation of CH3CN, support the hypothesis that methyl cyanide in protoplanetary disks could be mostly the product of gas-phase processes rather than grain chemistry, as currently proposed. These findings are expected to have implications in the comparison of the abundance ratios of N-bearing molecules observed in disks with cometary abundance ratios

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arXiv2023

Coma environment of comet C/2017 K2 around the water ice sublimation boundary observed with VLT/MUSE

We report a new imaging spectroscopic observation of Oort-cloud comet C/2017 K2 (hereafter K2) on its way to perihelion at 2.53 au, around a heliocentric distance where H2O ice begins to play a key role in comet activation. Normalized reflectances over 6 500--8 500 AA for its inner and outer comae are 9.7+/-0.5 and 7.2+/-0.3 % (10^3 AA)^-1, respectively, the latter being consistent with the slope observed when the comet was beyond the orbit of Saturn. The dust coma at the time of observation appears to contain three distinct populations: mm-sized chunks prevailing at <~10^3 km; a 10^5-km steady-state dust envelope; and fresh anti-sunward jet particles. the dust chunks dominate the continuum signal and are distributed over a similar radial distance scale as the coma region with redder dust than nearby. they also appear to be co-spatial with OI1D, suggesting that the chunks may accommodate H2O ice with a fraction (>~1 %) of refractory materials. The jet particles do not colocate with any gas species detected. The outer coma spectrum contains three significant emissions from C2(0,0) Swan band, OI1D, and CN(1,0 red band, with an overall deficiency in NH2. Assuming that all OI1D flux results from H2O dissociation, we compute an upper limit on the water production rate Q_H2O of ~7 x 10^28 molec s^-1 (with an uncertainty of a factor of two). the production ratio log[Q_C2/Q_CN] of K2 suggests that the comet has typical carbon-chain composition, with the value potentially changing with distance from the Sun. Our observations suggest that water ice-containing dust chunks (>0.1 mm) near K2's nucleus emitted beyond 4 au may be responsible for its very low gas rotational temperature and the discrepancy between its optical and infrared lights reported at similar heliocentric distances.

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arXiv2021

No evidence of phosphine in the atmosphere of Venus by independent analyses

The detection of phosphine (PH3) in the atmosphere of Venus has been recently reported based on millimeter-wave radio observations (Greaves et al. 2020), and its re-analyses (Greaves et al. 2021a/b). In this Matters Arising we perform an independent reanalysis, identifying several issues in the interpretation of the spectroscopic data. As a result, we determine sensitive upper-limits for PH3 in Venus' atmosphere (>75 km, above the cloud decks) that are discrepant with the findings in G2020 and G2021a/b. The measurements target the fundamental first rotational transition of PH3 (J=1-0) at 266.944513 GHz, which was observed with the James Clerk Maxwell Telescope (JCMT) in June 2017 and with the Atacama Large Millimeter/submillimeter Array (ALMA) in March 2019. This line's center is near the SO2 (J=309,21-318,24) transition at 266.943329 GHz (only 1.3 km/s away from the PH3 line) which represents a potential source of contamination. The JCMT and ALMA data, as presented in G2020, are at spectral resolutions comparable to the frequency separation of the two lines. Moreover, the spectral features identified are several km/s in width, and therefore do not permit distinct spectroscopic separation of the candidate spectral lines of PH3 and SO2. We present the radiative transfer modelling we have performed and then discuss the ALMA and JCMT analyses in turn.

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arXiv2020

Synergies between ground-based and space-based observations in the solar system and beyond

Telescope and detector developments continuously enable deeper and more detailed studies of astronomical objects. Larger collecting areas, improvement in dispersion and detector techniques, and higher sensitivities allow detection of more molecules in a single observation, at lower abundances, resulting in better constraints of the targets physical and chemical conditions. Improvements on current telescopes, and not to mention future observatories, both in space and on the ground, will continue this trend, ever improving our understanding of the Universe. Planetary exploration missions carry instrumentation to unexplored areas, and reveal details impossible to observe from the Earth by performing in-situ measurements. Space based observatories allow observations of object at wavelength ranges absorbed by the Earths atmosphere. The depth of understanding from all of these studies can be greatly enhanced by combining observations: ground-based and space-based, low-resolution and high-resolution, local and global-scale, similar observations over a broader or different spectra range, or by providing temporal information through follow-ups. Combined observations provide context and a broader scope of the studied object, and in this white paper, we outline a number of studies where observations are synergistically applied to increase the scientific value of both datasets. Examples include atmospheric studies of Venus, Mars, Titan, comets, Jupiter, as well as more specific cases describing synergistic studies in the Juno mission, and ground-based radar studies for near Earth objects. The examples aim to serve as inspiration for future synergistic observations, and recommendations are made based on the lessons learned from these examples.

astro-ph.IM↗

arXiv2020

The Crucial Role of Ground- and Space-Based Remote Sensing Studies of Cometary Volatiles in the Next Decade (2023-2032)

The study of comets affords a unique window into the birth, infancy, and subsequent history of the solar system. There is strong evidence that comets incorporated pristine interstellar material as well as processed nebular matter, providing insights into the composition and prevailing conditions over wide swaths of the solar nebula at the time of planet formation. Dynamically new Oort cloud comets harbor primitive ices that have been stored thousands of astronomical units from the Sun and have suffered minimal thermal or radiative processing since their emplacement ~4.5 Gyr ago. Periodic, more dynamically evolved comets such as the Halley-type and Jupiter-family comets reveal the effects of lives spent over a range of heliocentric distances, including perihelion passages into the very inner solar system. Systematically characterizing the information imprinted in the native ice compositions of these objects is critical to understanding the formation and evolution of the solar system, the presence of organic matter and water on the terrestrial planets, the chemistry present in protoplanetary disks around other stars, and the nature of interstellar interlopers such as 2I/Borisov. Although comet rendezvous and sample return missions can provide remarkable insights into the properties of a few short-period comets, the on-sky capacity necessary to perform population-level comet studies while simultaneously remaining sensitive to the paradigm-challenging science that individual comets can reveal can only be provided by remote sensing observations. Here we report the state-of-the-art in ground- and space-based remote sensing of cometary volatiles, review the remarkable progress of the previous decade, articulate the pressing questions that ground- and space-based work will address over the next ten years, and advocate for the technology and resources necessary to realize these aspirations.

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