arXiv subjects

Marcel Moura

Publications and source records attributed to Marcel Moura.

16 recordsLinked to original sources

arXiv2026

Dynamic multiphase flow triggers chaotic mixing in porous media

Solute mixing plays a pivotal role in a broad spectrum of chemical and biological processes across natural and engineered porous media. However, current understanding of mixing dynamics remains largely constrained to steady flows in fully or partially water-saturated environments. Multiphase flow systems are generally unsteady, with moving fluid interfaces and flow paths that change in time. Despite the widespread occurrence of dynamic multiphase flows, their impacts on solute mixing are largely unknown. Here, we use experiments and numerical simulations to investigate the effect of dynamic two-phase flow on the stretching and folding of fluid elements, a fundamental mechanism driving solute mixing and reactions in porous media. We find that dynamic two-phase flows induce chaotic mixing, characterized by exponential stretching of fluid elements, leading to strongly enhanced mixing compared to steady single phase flows. By extensive numerical multiphase flow simulations, we establish dynamic steady states where we reliably measure the mean fluid stretching rate as a function of flow rate. We show that stretching is maximized at an optimum flow rate which balances fluid shear deformation against the frequency of flow reorientation by the intermittent motion of the fluid interface. The findings are rationalized by a mechanistic model linking basic multiphase flow characteristics to the stretching rate, opening new perspectives to understand and control mixing and reactions in a wide range of multiphase flow systems.

physics.flu-dyn↗

arXiv2026

A comparison of different image analysis techniques for mapping spatiotemporal pH and carbon dissolution in density-driven convection of CO2 in water

Density-driven convection enhances the carbon dissolution rate, which is significant for the geological carbon storage. This process will also influence the spatiotemporal pH and carbon concentrations of the underground fluid. To illuminate the convection mechanism, it is critical to understand the evolution of those properties within the porous media. However, determining the spatiotemporal pH and concentration within porous media is always challenging. This study employed a combination of three pH indicators that can track a wide range in pH from 4 to 9.5 in a convection experiment. Furthermore, we compared three image-processing techniques: Hue, gray-difference, and angular representation of RGB color space $\mathbf{(\phi,\theta)}$ for quantifying color changes from the universal $\text{pH}$ indicator arising from the carbon convection. The characterized colors were mapped into pH by calibrating against benchmark solutions. The comparative results demonstrate that the color quantified by the Hue technique is most robust, showing invariance to fluid thickness, camera settings, and LED luminance. In the convection experiments, it produces a continuous spatial distribution of pH and concentration level in the system. In contrast, the $\mathbf{(\phi,\theta)}$ and gray-difference techniques were more sensitive to environmental variations. They also have significant limitations for $\text{pH}$ interpolation in the critical range due to their non-monotonic calibration paths. Although all methods ultimately produced similar estimates of total dissolved carbon, the Hue technique offers greater stability and universality for high-resolution, dynamic measurements of pH and carbon concentration in the convection experiments.

physics.flu-dyn↗

arXiv2025

Patterning surface textured plates with a viscoplastic fluid

The deposition of a viscoplastic fluid onto a substrate can be achieved by simply moving apart two plates initially separated by a fluid filled gap, where the footprint shape depends on the initiation of a fingering instability. Here, we present another approach for the controlled deposition of a viscoplastic fluid by designing the macroscopic structures of the solid substrate. Through experiments in a lifted Hele-Shaw cell, we explore how slot, square, pyramid, and triangle-shaped patterns affect the dynamics of liquid deposition. These substrate structures directly control the final shape of the viscoplastic fluid footprint. It turns out that these substrate patterns have little influence on the normal adhesive force acting on the plates.

physics.flu-dyn↗

arXiv2025

Droplet spreading in a wedge: A route to fluid rheology for power-law liquids

Measuring the rheology of liquids typically requires precise control over shear rates and stresses. Here, we describe an alternative route for predicting the characteristic features of a power-law fluid by simply observing the capillary spreading dynamics of viscous droplets in a wedge-shaped geometry. In this confined setting, capillary and viscous forces interact to produce a spreading dynamics described by anomalous diffusion, a process where the front position grows as a power-law in time with an exponent that differs from the value $1/2$ found in classical diffusion. We derive a nonlinear diffusion equation that captures this behavior, and we show that the diffusion exponent is directly related to the rheological exponent of the fluid. We verify this relationship by using both experiments and simulations for different power-law fluids. As the predictions are independent from flow-specific details, this approach provides a robust tool for inferring rheological properties from the spreading dynamics.

physics.flu-dyn↗

arXiv2024

Interface instability of two-phase flow in a three-dimensional porous medium

We present an experimental study of immiscible, two-phase fluid flow through a three-dimensional porous medium consisting of randomly-packed, monodisperse glass spheres. Our experiments combine refractive-index matching and laser-induced fluorescence imaging to resolve the morphology and stability of the moving interface resulting from the injection of one fluid into another. The imposed injection rate sets a balance between gravitational and viscous forces, producing interface morphologies which range from unstable collections of tangled fingers at low rates to stable sheets at high rates. The image data are complemented by time-resolved pressure measurements. We develop a stability criterion for the fluid interface based on the analysis of the 3D images and the pressure data. This criterion involves the Darcy permeability in each of the two phases and the time derivative of the pressure drop across the medium. We observe that the relative permeability encountered by the invading fluid is modified by the imposed flow rate in our experiment, which impacts the two-phase flow dynamics. We show that, in addition to the balance between the relevant forces driving the dynamics, local regions of crystalline order in the beadpack (crystallites) affect the stability of the invading front. This work provides insights into how disorder on multiple length scales in porous media can interact with viscous, capillary, and gravitational forces to determine the stability and dynamics of immiscible fluid interfaces.

physics.flu-dyn↗

arXiv2024

Fluctuation-dissipation theorems and the measurement of the Onsager coefficients for two-phase flow in porous media

We propose a new methodology for the experimental measurement of the Onsager coefficients of porous media flows by application of the fluctuation-dissipation theorem. The experimental setup consists of a steady-state flow condition in which two incompressible fluids are simultaneously injected into a modified Hele-Shaw cell. The cell is transparent and allows direct visualization of the dynamics via regular optical imaging methods. The fluctuations in the phase saturations are obtained and, by computing the temporal correlations of their time derivatives, we gain access to the Onsager coefficients. This work gives experimental grounding to recent theoretical development on the applications of the fluctuation-dissipation theorems to porous media flows.

physics.flu-dyn↗

arXiv2024

Interaction between corner and bulk flows during drainage in granular porous media

Drainage in porous media can be broken down into two main mechanisms: a primary piston-like displacement of the interfaces through the bulk of pore bodies and throats, and a secondary slow flow through corners and films in the wake of the invasion front. In granular porous media, this secondary drainage mechanism unfolds in connected pathways of pendular structures, such as capillary bridges and liquid rings, formed between liquid clusters. To represent both mechanisms, we proposed a dynamic dual-network model for drainage, considering that a gas displaces a wetting liquid from quasi-2D granular porous media. For this model, dedicated analyses of the capillary bridge shapes and hydraulic conductivity were conducted so that the secondary drainage mechanism could be properly quantified at finite speeds. With the model, an investigation of the wetting-phase connectivity and flow during drainage was carried out, covering a broad range of flow conditions. Results indicate that the span of liquid-connected structures in the unsaturated region, as well as their ability to contribute to flow, varies significantly with Capillary and Bond numbers.

cond-mat.soft↗

arXiv2024

Mapping dissolved carbon in space and time: An experimental technique for the measurement of pH and total carbon concentration in density driven convection of CO$_2$ dissolved in water

We present an experimental technique for determining the pH and the total carbon concentration when \ch{CO2} diffuses and flows in water. The technique employs three different pH indicators, which, when combined with an image analysis technique, provides a dynamic range in pH from 4.0 to 9.5. In contrast to usual techniques in which a single pH indicator is used, the methodology presented allows not only to produce a binary classification (pH larger or smaller than a given threshold) but to access a much more complete continuous spatial distribution of pH and concentration levels in the system. We calibrate the method against benchmark solutions and further demonstrate its potential by measuring the pH and total carbon concentration in a density driven convection (DDC) of carbon-enriched water. The motivation for testing the method in this particular experiment comes from the fact that DDC plays a pivotal role in the efficiency of engineered carbon storage processes. The application of the technique presented here provided a direct window for the analysis of the spatial distribution of captured carbon in the DDC flow.

physics.flu-dyn↗

arXiv2024

Emergence of dissipation and hysteresis from interactions among reversible, non-dissipative units: The case of fluid-fluid interfaces

We examine the nonequilibrium nature of two-phase fluid displacements in a quasi-two-dimensional medium (a model open fracture), in the presence of localized constrictions ("defects"), from a theoretical and numerical standpoint. Our analysis predicts the capillary energy dissipated in abrupt interfacial displacements (jumps) across defects, and relates it to the corresponding hysteresis cycle, e.g. in pressure-saturation. We distinguish between "weak" (reversible interface displacement, exhibiting no hysteresis and dissipation) and "strong" (irreversible) defects. We expose the emergence of dissipation and irreversibility caused by spatial interactions, mediated by interfacial tension, among otherwise weak defects. We exemplify this cooperative behavior for a pair of weak defects and establish a critical separation distance, analytically and numerically, verified by a proof-of-concept experiment.

physics.flu-dyn↗

arXiv2023

A simplified pore-scale model for slow drainage including film-flow effects

Film flow through networks of corners and capillary bridges can establish connections between seemingly isolated clusters during drainage in porous media. Coupled with drainage through the bulk of pores and throats, the flow through these networks constitutes a secondary drainage mechanism that can significantly affect fluid configurations and residual saturations. In order to investigate the prevalence of this drainage mechanism, we propose a quasi-static pore-network model based on modifying the trapped-cluster-identification algorithm in an invasion-percolation model. With the modification, wetting-phase connectivity could be provided by direct successions of pores and throats, represented by sites and bonds, as well as by chains of interconnected capillary bridges. The advancement of the fluid interface in the porous matrix was determined by the bonds' invasion thresholds, calculated based on local capillary pressure values that could be perturbed to accommodate gravitational effects. With the proposed model, experimentally verified phenomena related to slow drainage in granular porous media were reproduced, showing good qualitative agreement.

physics.flu-dyn↗

arXiv2022

Competing gravitational and viscous efects in 3D two-phase flow investigated with a table-top optical scanner

We present experiments and theory describing the transition from viscosity-stabilized flow to gravitationally unstable fingering for two-phase flow in a 3D synthetic porous medium. Observation is made possible by the use of our newly developed table-top 3D-scanner based on optical index matching and laser-induced fluorescence, which is described in detail. In the experiment, a more dense, more viscous fluid injected at a fixed flow-rate from a point source at the top of the flow cell displaces a less viscous, less dense fluid. We observe a stable invasion zone near the inlet, which increases in size with increasing flow rates, and presents initially a close to hemispherical shape. At later times, the invasion front transits to an unstable mode and a fingering flow regime. The transition occurs at a predicted critical radius, Rc, corresponding to the zero of the combined viscous and gravitational pressure gradient.

physics.flu-dyn↗

arXiv2022

Stable and unstable capillary fingering in porous media with a gradient in grains size

We present a theoretical and experimental investigation of slow drainage in porous media with a gradient in the grains size (and hence in the typical pores' throats), in an external gravitational field. We mathematically show that such structural gradient and external force have a similar effect on the obtained drainage patterns, when they stabilise the invasion front. With the help of a newly introduced experimental set-up, based on the 3D-print of transparent porous matrices, we illustrate this equivalence, and extend it to the case where the front is unstable. We also present some invasion-percolation simulations of the same phenomena, which are inline with our theoretical and experimental results. In particular, we show that the width of stable drainage fronts mainly scales with the spatial gradient of the average pore invasion threshold and with the local distribution of this (disordered) threshold. The scaling exponent results from percolation theory and is -0.57 for 2D systems. Overall, we propose a unifying theory for the up-scaling of dual fluid flows in most classical scenarii.

cond-mat.soft↗

arXiv2021

Burst dynamics, up-scaling and dissipation of slow drainage in porous media

We present a theoretical and experimental investigation of drainage in porous media. The study is limited to stabilized fluid fronts at moderate injection rates, but it takes into account capillary, viscous, and gravitational forces. In this theory the work applied on the system, the energy dissipation, the final saturation and the width of the stabilized fluid front can all be calculated if we know the dimensionless fluctuation number, the wetting properties, the surface tension between the fluids, the fractal dimensions of the invasion front and the invading structure, and the exponent describing the divergence of the correlation length in percolation. This theoretical description explains how the Haines jumps' local activity and dissipation relate to dissipation on larger scales.

physics.flu-dyn↗

arXiv2020

Visualization by optical fluorescence of two-phase flow in a three-dimensional porous medium

Slow flow of a single fluid through a porous medium is well understood on a macroscopic level through Darcy's law, a linear relation between flow rate and a combination of pressure differences, viscosity, and gravitational forces. Two-phase flow is complicated by the interface separating the fluids, but understanding of two-dimensional, two-phase flow has been obtained from experiments using transparent cells. In most three-dimensional media, however, visual observation is difficult. Here, we present preliminary results of experiments on a model medium consisting of randomly packed glass spheres, in which one fluorescent liquid invades another. By refractive index matching and scanning with a sheet-shaped laser beam, we obtain slices of the flow patterns, which we combine into three-dimensional pictures. We observe a compact region of invading fluid, surrounded by finger-like protrusions. The compact region becomes more dominant with increasing invader flow rate. The patterns are theoretically analyzed in terms of the interplay between gravitational, viscous, and capillary forces.

cond-mat.soft↗

arXiv2017

Verification of a dynamic scaling for the pair correlation function during the slow drainage of a porous medium

We give experimental grounding for the remarkable observation made by Furuberg et al. in Ref. [furuberg1988] of an unusual dynamic scaling for the pair correlation function $N(r,t)$ during the slow drainage of a porous medium. The authors of that paper have used an invasion percolation algorithm to show numerically that the probability of invasion of a pore at a distance $r$ away and after a time $t$ from the invasion of another pore, scales as $N(r,t)\propto r^{-1}f\left(r^{D}/t\right)$, where $D$ is the fractal dimension of the invading cluster and the function $f(u)\propto u^{1.4}$, for $u \ll 1$ and $f(u)\propto u^{-0.6}$, for $u \gg 1$. Our experimental setup allows us to have full access to the spatiotemporal evolution of the invasion, which was used to directly verify this scaling. Additionally, we have connected two important theoretical contributions from the literature to explain the functional dependency of $N(r,t)$ and the scaling exponent for the short-time regime ($t \ll r^{D}$). A new theoretical argument was developed to explain the long-time regime exponent ($t \gg r^{D}$).

physics.flu-dyn↗

arXiv2017

Critical behavior in porous media flow

The intermittent burst dynamics during the slow drainage of a porous medium is studied experimentally. We have shown that this system satisfies a set of conditions known to be true for critical systems, such as intermittent activity with bursts extending over several time and length scales, self-similar macroscopic fractal structure and $1/f^α$ power spectrum. Additionally, we have verified a theoretically predicted scaling for the burst size distribution, previously assessed via numerical simulations. The observation of $1/f^α$ power spectra is new for porous media flows and, for specific boundary conditions, we notice the occurrence of a transition from $1/f$ to $1/f^2$ scaling. An analytically integrable mathematical framework was employed to explain this behavior.

physics.flu-dyn↗