arXiv subjects

Marco Finazzi

Publications and source records attributed to Marco Finazzi.

At least 19 recordsLinked to original sources

arXiv2026

Nonlinear Self-Action across Temporal Regimes in Resonant Dielectric Metasurfaces

Quasi-bound states in the continuum (qBICs) enable exceptional field confinement, strongly reducing the pump intensity threshold for nonlinear light-matter interaction in dielectric metasurfaces. As a result, nonlinear self-action effects, often elusive in bulk nonlinear media, emerge at moderate excitation intensities. Here, nonlinear self-action in resonantly enhanced third-harmonic (TH) generation from a dielectric metasurface supporting a qBIC resonance is investigated across distinct temporal excitation regimes. These regimes establish different coupling conditions between the excitation and the resonant mode, causing the same nonlinear self-action to emerge through complementary intensity-dependent signatures. Under spectrally narrow picosecond excitation, resonance-enhanced TH generation shows pronounced deviations from cubic scaling at high intensities. In contrast, broadband femtosecond excitation transiently drives the resonance, encoding the nonlinear response in the spectral reshaping and broadening of the TH signal. Simulations reproduce both regimes: continuous-wave modeling captures picosecond power scaling and the role of higher-order nonlinear susceptibilities, while time-domain simulations resolve femtosecond dynamics. These results clarify how pulse duration, bandwidth, and resonant coupling determine the observable signatures of nonlinear self-action in resonant dielectric metasurfaces, linking field confinement to conversion efficiency, power-law scaling, and ultrafast spectral dynamics.

physics.optics↗

arXiv2026

Efficient photon-pair emission from a nanostructured resonator and its theoretical description

Spontaneous parametric down-conversion (SPDC) in subwavelength nanostructures is a promising source of quantum light, owing to its multifunctionality and ability to generate complex quantum states. Nevertheless, the mechanisms governing photon-pair generation in such systems remain only partially understood. In particular, experimental investigations of key emission properties in individual resonators, such as directionality and spectral distribution, are still lacking, and predictive theoretical frameworks have not yet been experimentally validated. Here, we report the first measurement of the directional and spectral distributions of photon pairs generated via SPDC in a nanostructured resonator. Both distributions exhibit resonant behaviour, which we describe using an extended quasi-normal-mode theory. This comparison is enabled by photon-pair count rates of up to 0.45 Hz/mW -- to our knowledge, the highest reported for a nanostructured resonator. Our results provide new physical insight into nanoscale SPDC and represent an important step toward designing of efficient miniaturized quantum light sources.

quant-ph↗

arXiv2026

Polarization-Multiplexed Bloch Surface Wave Sensing of Single-Strand DNA Growth

Refractometric biosensing is a vital label-free tool for the real time detection and interaction analysis of biological and chemical substances. Nanophotonic platforms like Surface Plasmon Resonance (SPR) have played a critical role in providing refractometric sensing capabilities for clinical diagnostics and environmental monitoring. However, traditional systems operating in a single-polarization state cannot fully characterize complex optical properties such as birefringence, which is crucial to resolve many complex biological interactions. Although Bloch Surface Wave (BSW) sensors can support both TE and TM modes, a key capability SPR lacks, they have historically been implemented in single-mode configurations. In this paper, we present a polarization multiplexed BSW refractometric sensing system, simultaneously tracking the resonant wavelength shifts of both TE and TM BSW modes through time. Our technique was applied to investigate single-strand DNA growth during rolling circle amplification (RCA). To accurately recover the time-dependent birefringence, capturing dynamics of the DNA growth and orientation of its chains, we implemented a two-stage modeling approach based on the TMM. First, we utilized a wavelength-dependent surface sensitivity model, confining refractive index changes to the immediate layer above the crystal, to distinguish isotropic background dynamics from birefringent signals. Following the onset of RCA, we transitioned to a model that accounted for the vertical growth of the DNA layers in time. By fitting this model to the TE and TM resonant shifts, we monitor the growth rate of the single-strand DNA layer as well as the refractive index along the two polarization components. Our findings demonstrate the platform's ability to resolve the structural evolution of complex bimolecular interactions associated with conformational changes.

physics.optics↗

arXiv2026

Efficient and tunable narrowband second-harmonic generation by a large-area etchless lithium niobate metasurface

Optical resonances in nanostructures enable strong enhancement of nonlinear processes at the nanoscale, such as second-harmonic generation (SHG), with high-$Q$ modes providing intensified light--matter interactions and sharp spectral selectivity for applications in filtering, sensing, and nonlinear spectroscopy. Thanks to the recent advances in thin-film lithium niobate (TFLN) technology, these key features can be now translated to lithium niobate for realizing novel nanoscale nonlinear optical platforms. Here, we demonstrate a large-area metasurface, realized by scalable nanoimprint lithography, comprising a slanted titanium dioxide (TiO$_2$) nanograting on etchless TFLN for efficient narrowband SHG. This is enabled by the optimal coupling of quasi-bound state in the continuum (q-BIC) modes with a narrowband pulsed laser pump. The demonstrated normalized SHG efficiency is $0.15\%\,\mathrm{cm}^2/\mathrm{GW}$, which is among the largest reported for LN metasurfaces. The low pump peak intensity ($3.64~\mathrm{kW}/\mathrm{cm}^2$) employed, which enables SHG even by continuous-wave pumping, allows envisioning integrated and portable photonic applications. SHG wavelength tuning from $870$ to $920~\mathrm{nm}$ with stable output power as well as polarization control is also achieved by off-normal pump illumination. This versatile platform opens new opportunities for sensing, THz generation and detection, and ultrafast electro-optic modulation of nonlinear optical signals.

physics.optics↗

arXiv2025

Electro-optical modulation of light polarization in a nonlocal lithium niobate metasurface

We report the experimental realization of a LiNbO3 metasurface for electro-optic modulation of light polarization in the telecommunication band. High-Q quasi-bound states in the continuum are emploied to enhance the modulation of amplitude and phase of an impinging beam by a driving electric field, leading to efficient polarization rotation and conversion. We quantified modulation effects under a CMOS-compatible bias at 1 MHz frequency, achieving a variation of 5% in the Stokes parameters and a variation of the polarization ellipse angles of about 3{\deg} for the transmitted light. These results demonstrate that dynamic polarization and phase modulation can be attained in a compact platform, highlighting the potential of high-Q resonant LiNbO3 metasurfaces for enhanced light-matter interaction in subwavelength electro-optic devices.

physics.optics↗

arXiv2025

Optically induced orbital polarization in bulk germanium

Optical orientation has been proven as a powerful tool to inject spin-polarized electron and hole populations in III-V and group-IV semiconductors. In particular, the absorption of circularly-polarized light in bulk Ge generates a spin-oriented population of electrons in the conduction band with a spin-polarization up to 50%, whereas the hole spin-polarization, opposite to the electron one, can even reach values up to 83%. In this letter, we theoretically investigate the optical injection of orbital polarization by means of circularly-polarized light in bulk Ge and we show that the latter considerably exceeds 100% for holes and photon energies close to the direct Ge gap. These results suggest that Ge is a convenient platform for future development of orbitronics and opto-orbitronic devices.

cond-mat.mtrl-sci↗

arXiv2025

Leveraging Low Index Contrast to Reduce the Polarization Anisotropy in One-Dimensional Photonic Crystals

One-dimensional photonic crystals (1DPCs) are widely used platforms for guiding, filtering, and enhancing light at the nanoscale. Traditionally, designs have favored high refractive index contrast to maximize the photonic band gap (PBG) size. Here, we demonstrate that low-index contrast systems offer a powerful and underexplored route to achieving improved optical functionalities. In particular, we show that low index contrast enables more closely aligned PBGs for transverse electric (TE) and transverse magnetic (TM) polarizations, allowing for broadband superposition of TE and TM Bloch Surface Waves (BSWs). As a demonstration of this functionality, we use this approach to design 1DPCs capable of generating planar superchiral fields for enhanced circular dichroism spectroscopy. To realize such structures, we use an automated design framework based on multi-objective genetic optimization. By comparing optimized designs in both high and low index contrast regimes, we find that low index contrast systems yield significantly greater overlap between the TE and TM BSW dispersion relations and exhibit a pronounced reduction in optical anisotropy - both of which contribute to enhanced optical chirality across the operational bandwidth. Furthermore, simulations reveal that these low index contrast structures offer improved robustness to fabrication tolerances and support a wider dynamic range of chiral analyte concentrations. In addition to their optical performance advantages, low-index contrast systems are naturally compatible with polymeric materials, which offer benefits such as low cost, sustainability, and mechanical flexibility. While this work focuses on mode alignment and its consequences for surface wave behavior, the underlying principles have broader implications for polarization-independent photonic technologies, including optical sensing, computing, and spectral filtering.

physics.optics↗

arXiv2024

All-optical polarization control and routing by nonlinear interferometry at the nanoscale

Optical metasurfaces are rapidly establishing as key-enabling platforms for nanophotonics applications. Along with the ability of taming light in subwavelength thicknesses, they can feature multiple functionalities in one device. The generation and control of light polarization by metasurfaces already provided a route towards ultracompact polarimetry devices in the linear regime. If translated to the nonlinear optical regime it may become a key-enabling tool in nonlinear imaging, optical holography and sensing. Here, we report the experimental ultrafast all-optical polarization modulation of upconverted light by all-dielectric metasurfaces via nonlinear interferometry. By controlling the relative phase between a pump beam at $\omega$ and its frequency-double replica at 2$\omega$, we can set the phase relation between two frequency-degenerate upconverted processes at 3$\omega$ $-$ Sum-Frequency Generation (SFG) and Third-Harmonic Generation (THG) $-$ stemming from an AlGaAs metasurface. By exploiting the opposite parity of the two nonlinear process and tuning their relative powers, we can achieve modulation of the polarization states of the light emitted at 3$\omega$ between linear and circular states with a degree of circular polarization (DOCP) up to 83$\%$. In particular, circularly polarized light features opposite handedness symmetrically located in the Fourier space, at coincidence with the first diffraction orders of the metasurface. Moreover, by toggling the phase delay by $\pi$, the handedness can be fully switched between the diffraction. Our work adds an additional layer of modulation in polarization beyond intensity to all-optical routing with precise phase control. The capability to route circular polarization states in the k-space holds significant potential for chiral sensing and advanced imaging techniques.

physics.optics↗

arXiv2024

Efficient GHz electro-optical modulation with a nonlocal lithium niobate metasurface in the linear and nonlinear regime

Electro-optical modulation is widely employed for optical signal processing and in laser technology. To date, it is efficiently realized in integrated photonic systems as well as in bulk optics devices. Yet, the achievement of modulators exploiting Pockels effect in flat optics, essential to scale down the electric radiation-optical control in free space, currently lag behind bulk and on-chip integrated platforms in terms efficiency and speed. We bridge this gap realizing a metasurface based on lithium niobate (LiNbO3) on insulator that leverages on resonances with quality-factor as high as 8e3 to achieve fast electrical modulation of both linear and nonlinear optical properties. LiNbO3, well known for its high nonlinear susceptibility and wide transparency window across the infrared and visible spectrum, is employed to realize an asymmetric, one-dimensional array of nanowires, exhibiting resonances with linewidth < 0.2 nm. By applying a CMOS-compatible electrical bias, the metasurface imparts a relative reflectivity modulation around 0.1, with a modulation efficiency, defined as relative modulation per applied Volt, larger than 0.01 V^-1 on a bandwidth of about 1 GHz. We also demonstrated more than one order of magnitude intensity modulation of the second harmonic seeded by a continuous-wave laser, with a modulation efficiency of about 0.12 V^-1. This dual modulation capability, rooted in the interplay between optical resonances and electric field manipulation, holds significant potential for cutting-edge applications in high-speed photonics, nonlinear optics, and reconfigurable communication systems. Our findings highlight the transformative potential of LiNbO3-based metasurfaces for integration into next-generation optical technologies that demand rapid, efficient electrical control of light.

physics.optics↗

arXiv2023

All-optical free-space routing of upconverted light by metasurfaces via nonlinear interferometry

All-optical modulation yields the promise of high-speed information processing. In this frame, metasurfaces are rapidly gaining traction as ultrathin multifunctional platforms for light management. Among the featured functionalities, they enable light wavefront manipulation and, more recently, demonstrated the ability to perform light-by-light manipulation through nonlinear optical processes. Here, by employing a nonlinear periodic metasurface, we demonstrate all-optical routing of telecom photons upconverted to the visible range. This is achieved via the interference between two frequency-degenerate upconversion processes, namely third-harmonic and sum-frequency generation, stemming from the interaction of a pump pulse with its frequency-doubled replica. By tuning the relative phase and polarization between these two pump beams, and concurrently engineering the nonlinear emission of the individual elements of the metasurfaces (meta-atoms) along with its pitch, we route the upconverted signal among the diffraction orders of the metasurface with a modulation efficiency up to 90%. Thanks to the phase control and the ultrafast dynamics of the underlying nonlinear processes, free-space all-optical routing could be potentially performed at rates close to the employed optical frequencies divided by the quality factor of the optical resonances at play. Our approach adds a further twist to optical interferometry, which is a key-enabling technique in a wide range of applications, such as homodyne detection, radar interferometry, LiDAR technology, gravitational waves detection, and molecular photometry. In particular, the nonlinear character of light upconversion combined with phase sensitivity is extremely appealing for enhanced imaging and biosensing.

physics.optics↗

arXiv2022

Meta-Optics with Lithium Niobate

The rapid development of metasurfaces - 2D ensembles of engineered nanostructures - is presently fostering a steady drive towards the miniaturization of many optical functionalities and devices to a subwavelength size. The material platforms for optical metasurfaces are rapidly expanding and for the past few years, we are seeing a surge in establishing meta-optical elements from high-index, highly transparent materials with strong nonlinear and electro-optic properties. Crystalline lithium niobate (LN), a prime material of choice in integrated photonics, has shown great promise for future meta-optical components, thanks to its large electro-optical coefficient, second-order nonlinear response and broad transparency window ranging from the visible to the mid-infrared. Recent advances in nanofabrication technology have indeed marked a new milestone in the miniaturization of LN platforms, hence enabling the first demonstrations of LN-based metasurfaces. These seminal works set the first steppingstone towards the realization of ultra-flat monolithic nonlinear light sources with emission ranging from the visible to the infrared, efficient sources of correlated photon pairs, as well as electro-optical devices. Here, we review these recent advances, discussing potential perspectives for applications in light conversion and modulation shaping as well as quantum optics, with a critical eye on the potential setbacks and limitations of this emerging field.

physics.optics↗

arXiv2021

Modelling photothermal induced resonance microscopy: the role of interface thermal resistances

Infrared (IR) nanospectroscopy by photothermal induced resonance (PTIR) is a novel experimental technique that combines the nanoscale resolution granted by atomic force microscopy (AFM) and the chemical labelling made possible by IR absorption spectroscopy. While the technique has developed enormously over the last decade from an experimental point of view, the theoretical modelling of the signal still varies significantly throughout the literature and misses a solid benchmark. Here, we report an analysis focused on the electromagnetic and thermal simulations of a PTIR experiment. Thanks to a control experiment where the signal is acquired as a function of the thickness of a polymer film and for different tip geometries, we find clear evidence that the interface thermal resistances play a key role in the determination of the measured signal and should therefore always be accounted for by any quantitative modelling.

cond-mat.mtrl-sci↗

arXiv2021

Electric Field Modulation of Spin Transport

The finite spin lifetime in solids is often considered a major hindrance for the development of spintronic devices, which typically require cryogenic temperatures to mitigate this phenomenon. In this work we show that this feature can instead be exploited to realize a scheme where spin transport is modulated at room temperature by a modest electric field. A field directed antiparallel (parallel) to the spin-diffusion velocity can in fact largely increase (decrease) the spin-transport length compared with the zero field case. We find that applying an electric field E = 24 V/cm along a 40 mm-long path in germanium results in about one order of magnitude modulation of the spin-polarized electrons entering in the detector. The present work demonstrates that electric fields can be exploited for guiding spins over macroscopic distances and for realizing fast, room temperature modulation of spin accumulation.

cond-mat.mtrl-sci↗

arXiv2021

Third-harmonic light polarization control in magnetically-resonant silicon metasurfaces

Nonlinear metasurfaces have become prominent tools for controlling and engineering light at the nanoscale. Usually, the polarization of the total generated third harmonic is studied. However, diffraction orders may present different polarizations. Here, we design an high quality factor silicon metasurface for third harmonic generation and perform back focal plane imaging of the diffraction orders, which present a rich variety of polarization states. Our results demonstrate the possibility of tailoring the polarization of the generated nonlinear diffraction orders paving the way to a higher degree of wavefront control.

physics.optics↗

arXiv2020

Tunable broadband light emission from graphene

Graphene is an ideal material for integrated nonlinear optics thanks to its strong light-matter interaction and large nonlinear optical susceptibility. Graphene has been used in optical modulators, saturable absorbers, nonlinear frequency converters, and broadband light emitters. For the latter application, a key requirement is the ability to control and engineer the emission wavelength and bandwidth, as well as the electronic temperature of graphene. Here, we demonstrate that the emission wavelength of graphene$'$ s broadband hot carrier photoluminescence can be tuned by integration on photonic cavities, while thermal management can be achieved by out-of-plane heat transfer to hexagonal boron nitride. Our results pave the way to graphene-based ultrafast broadband light emitters with tunable emission.

physics.optics↗

arXiv2020

Enhanced nonlinear optical response of single metal-dielectric nanocavities resonating in the near-infrared

Harmonic generation mechanisms are of great interest in nanoscience and nanotechnology, since they allow generating visible light by using near-infrared radiation, which is particularly suitable for its endless applications in bio-nanophotonics and opto-electronics. In this context, multilayer metal-dielectric nanocavities are widely used for light confinement and waveguiding at the nanoscale. They exhibit intense and localized resonances that can be conveniently tuned in the near-infrared and are therefore ideal for enhancing nonlinear effects in this spectral range. In this work, we experimentally investigate the nonlinear optical response of multilayer metal-dielectric nanocavities. By engineering their absorption efficiency and exploiting their intrinsic interface-induced symmetry breaking, we achieve one order of magnitude higher second-harmonic generation efficiency compared to gold nanostructures featuring the same geometry and resonant behavior. In particular, while the third order nonlinear susceptibility is comparable with that of bulk Au, we estimate a second order nonlinear susceptibility of the order of 1 pm/V, which is comparable with that of typical nonlinear crystals. We envision that our system, which combines the advantages of both plasmonic and dielectric materials, might enable the realization of composite and multi-functional nano-systems for an efficient manipulation of nonlinear optical processes at the nanoscale.

physics.optics↗

arXiv2019

Plasmonic superchiral lattice resonances in the mid-infrared

Recent efforts in the field of surface-enhanced spectroscopies have focused on the paradigm of superchirality, entailing the engineering of the local electromagnetic fields to boost the enantiospecific interaction between light and chiral molecules. In this framework, approaches based on both metallic and dielectric nanostructures have been proposed and have also recently been extended to vibrational circular dichroism in the mid-infrared. In this work, we design, fabricate and characterize arrays of chiral plasmonic slits featuring enhanced chiral fields in the mid-infrared. We exploit collective lattice resonances to further enhance the local intensity and to generate sharp features in the circular dichroism spectra of the platform. Such features are ideally suited to test the superchiral coupling with the vibrational resonances of chiral molecules.

cond-mat.mes-hall↗

arXiv2019

Evidence for cascaded third harmonic generation in non-centrosymmetric gold nanoantennas

The optimization of nonlinear optical processes at the nanoscale is a crucial step for the development of nanoscale photon sources for quantum-optical networks. The development of innovative plasmonic nanoantenna designs and hybrid nanostructures to enhance optical nonlinearities in very small volumes represents one of the most promising routes. In such systems, the upconversion of photons can be achieved with high efficiencies via third-order processes, such as third harmonic generation (THG), thanks to the resonantly-enhanced volume currents. Conversely, second-order processes, such as second harmonic generation (SHG), are often inhibited by the symmetry of metal lattices and of common nanoantenna geometries. SHG and THG processes in plasmonic nanostructures are generally treated independently, since they both represent a small perturbation in the light-matter interaction mechanisms. In this work, we demonstrate that this paradigm does not hold in general, by providing evidence of a cascaded process in THG, which is fueled by SHG and sizably contributes to the overall yield. We address this mechanism by unveiling an anomalous fingerprint in the polarization state of the nonlinear emission from non-centrosymmetric gold nanoantennas and point out that such cascaded processes may also appear for structures that exhibit only moderate SHG yields - signifying its general relevance in plasmon-enhanced nonlinear optics. The presence of this peculiar mechanism in THG from plasmonic nanoantennas at telecommunication wavelengths allows gaining further insight on the physics of plasmon-enhanced nonlinear optical processes. This could be crucial in the realization of nanoscale elements for photon conversion and manipulation operating at room-temperature.

cond-mat.mes-hall↗