arXiv subjects

Marco Merkli

Publications and source records attributed to Marco Merkli.

53 records · Page 3Linked to original sources

arXiv2012

Electron Transfer Reactions: Generalized Spin-Boson Approach

We introduce a mathematically rigorous analysis of a generalized spin-boson system for the treatment of a donor-acceptor (reactant-product) quantum system coupled to a thermal quantum noise. The donor/acceptor probability dynamics describes transport reactions in chemical processes in presence of a noisy environment -- such as the electron transfer in a photosynthetic reaction center. Besides being rigorous, our analysis has the advantages over previous ones that (1) we include a general, non energy-conserving system-environment interaction, and that (2) we allow for the donor or acceptor to consist of multiple energy levels lying closely together. We establish explicit expressions for the rates and the efficiency (final donor-acceptor population difference) of the reaction. In particular, we show that the rate increases for a multi-level acceptor, but the efficiency does not.

math-ph↗

arXiv2011

Entanglement Evolution via Quantum Resonances

We consider two qubits interacting with local and collective thermal reservoirs. Each spin-reservoir interaction consists of an energy exchange and an energy conserving channel. We prove a resonance representation of the reduced dynamics of the spins, valid for all times t>=0, with errors (small interaction) estimated rigorously, uniformly in time. Subspaces associated to non-interacting energy differences evolve independently, partitioning the reduced density matrix into dynamically decoupled clusters of jointly evolving matrix elements. Within each subspace the dynamics is markovian with a generator determined entirely by the resonance data of the full Hamiltonian. Based on the resonance representation we examine the evolution of entanglement (concurrence). We show that, whenever thermalization takes place, entanglement of any initial state dies out in a finite time and will not return. For a concrete class of initially entangled spin states we find explicit bounds on entanglement survival and death times in terms of the initial state and the resonance data.

math-ph↗

arXiv2010

A Universality Property of Gaussian Analytic Functions

We consider random analytic functions defined on the unit disk of the complex plane as power series such that the coefficients are i.i.d., complex valued random variables, with mean zero and unit variance. For the case of complex Gaussian coefficients, Peres and Virág showed that the zero set forms a determinantal point process with the Bergman kernel. We show that for general choices of random coefficients, the zero set is asymptotically given by the same distribution near the boundary of the disk, which expresses a universality property. The proof is elementary and general.

math.PR↗

arXiv2010

Dynamical Localization of Quantum Walks in Random Environments

The dynamics of a one dimensional quantum walker on the lattice with two internal degrees of freedom, the coin states, is considered. The discrete time unitary dynamics is determined by the repeated action of a coin operator in U(2) on the internal degrees of freedom followed by a one step shift to the right or left, conditioned on the state of the coin. For a fixed coin operator, the dynamics is known to be ballistic. We prove that when the coin operator depends on the position of the walker and is given by a certain i.i.d. random process, the phenomenon of Anderson localization takes place in its dynamical form. When the coin operator depends on the time variable only and is determined by an i.i.d. random process, the averaged motion is known to be diffusive and we compute the diffusion constants for all moments of the position.

math-ph↗

arXiv2009

Repeated and continuous interactions in open quantum systems

We consider a finite quantum system S coupled to two environments of different nature. One is a heat reservoir R (continuous interaction) and the other one is a chain C of independent quantum systems E (repeated interaction). The interactions of S with R and C lead to two simultaneous dynamical processes. We show that for generic such systems, any initial state approaches an asymptotic state in the limit of large times. We express the latter in terms of the resonance data of a reduced propagator of S+R and show that it satisfies a second law of thermodynamics. We analyze a model where both S and E are two-level systems and obtain the asymptotic state explicitly (lowest order in the interaction strength). Even though R and C are not direcly coupled, we show that they exchange energy, and we find the dependence of this exchange in terms of the thermodynamic parameters. We formulate the problem in the framework of W*-dynamical systems and base the analysis on a combination of spectral deformation methods and repeated interaction model techniques. We do not use master equation approximations.

math-ph↗

arXiv2008

A resonance theory for open quantum systems with time-dependent dynamics

We develop a resonance theory to describe the evolution of open systems with time-dependent dynamics. Our approach is based on piecewise constant Hamiltonians: we represent the evolution on each constant bit using a recently developed dynamical resonance theory, and we piece them together to obtain the total evolution. The initial state corresponding to one time-interval with constant Hamiltonian is the final state of the system corresponding to the interval before. This results in a non-markovian dynamics. We find a representation of the dynamics in terms of resonance energies and resonance states associated to the Hamiltonians, valid for all times $t\geq 0$ and for small (but fixed) interaction strengths. The representation has the form of a path integral over resonances. We present applications to a spin-fermion system, where the energy levels of the spin may undergo rather arbitrary crossings in the course of time. In particular, we find the probability for transition between ground- and excited state at all times.

math-ph↗

arXiv2008

Random repeated interaction quantum systems

We consider a quantum system S interacting sequentially with independent systems E_m, m=1,2,... Before interacting, each E_m is in a possibly random state, and each interaction is characterized by an interaction time and an interaction operator, both possibly random. We prove that any initial state converges to an asymptotic state almost surely in the ergodic mean, provided the couplings satisfy a mild effectiveness condition. We analyze the macroscopic properties of the asymptotic state and show that it satisfies a second law of thermodynamics. We solve exactly a model in which S and all the E_m are spins: we find the exact asymptotic state, in case the interaction time, the temperature, and the excitation energies of the E_m vary randomly. We analyze a model in which S is a spin and the E_m are thermal fermion baths and obtain the asymptotic state by rigorous perturbation theory, for random interaction times varying slightly around a fixed mean, and for small values of a coupling constant.

math-ph↗

arXiv2008

Infinite Products of Random Matrices and Repeated Interaction Dynamics

Let $Ψ_n$ be a product of $n$ independent, identically distributed random matrices $M$, with the properties that $Ψ_n$ is bounded in $n$, and that $M$ has a deterministic (constant) invariant vector. Assuming that the probability of $M$ having only the simple eigenvalue 1 on the unit circle does not vanish, we show that $Ψ_n$ is the sum of a fluctuating and a decaying process. The latter converges to zero almost surely, exponentially fast as $n\to\infty$. The fluctuating part converges in Cesaro mean to a limit that is characterized explicitly by the deterministic invariant vector and the spectral data of ${\mathbb E}[M]$ associated to 1. No additional assumptions are made on the matrices $M$; they may have complex entries and not be invertible. We apply our general results to two classes of dynamical systems: inhomogeneous Markov chains with random transition matrices (stochastic matrices), and random repeated interaction quantum systems. In both cases, we prove ergodic theorems for the dynamics, and we obtain the form of the limit states.

math.PR↗

arXiv2006

Level shift operators for open quantum systems

Level shift operators describe the second order displacement of eigenvalues under perturbation. They play a central role in resonance theory and ergodic theory of open quantum systems at positive temperatures. We exhibit intrinsic properties of level shift operators, properties which stem from the structure of open quantum systems at positive temperatures and which are common to all such systems. They determine the geometry of resonances bifurcating from eigenvalues of positive temperature Hamiltonians and they relate the Gibbs state, the kernel of level shift operators, and zero energy resonances. We show that degeneracy of energy levels of the small part of the open quantum system causes the Fermi Golden Rule Condition to be violated and we analyze ergodic properties of such systems.

math-ph↗

arXiv2005

Asymptotics of repeated interaction quantum systems

A quantum system $\s$ interacts in a successive way with elements $\ee$ of a chain of identical independent quantum subsystems. Each interaction lasts for a duration $τ$ and is governed by a fixed coupling between $\s$ and $\ee$. We show that the system, initially in any state close to a reference state, approaches a {\it repeated interaction asymptotic state} in the limit of large times. This state is $τ$--periodic in time and does not depend on the initial state. If the reference state is chosen so that $\s$ and $\ee$ are individually in equilibrium at positive temperatures, then the repeated interaction asymptotic state satisfies an average second law of thermodynamics.

math-ph↗

arXiv2004

Statistical Mechanics of Thermodynamic Processes

In this note we describe some results concerning non-relativistic quantum systems at positive temperature and density confined to macroscopically large regions of physical space which are under the influence of some local, time-dependent external forces. We are interested in asymptotic properties of such systems.

math-ph↗

arXiv2004

Another Return of 'Return to Equilibrium'

The property of ``{\it return to equilibrium}'' is established for a class of quantum-mechanical models describing interactions of a (toy) atom with black-body radiation, or of a spin with a heat bath of scalar bosons, under the assumption that the interaction strength is {\it sufficiently weak}. For models describing the first class of systems, our upper bound on the interaction strength is {\it independent} of the temperature $T$, (with $0<T\leq T_0<\infty$), while, for the spin-boson model, it tends to zero logarithmically, as $T\to 0$. Our result holds for interaction form factors with physically realistic infrared behaviour. Three key ingredients of our analysis are: a suitable concrete form of the Araki-Woods representation of the radiation field, Mourre's positive commutator method combined with a recent virial theorem, and a norm bound on the difference between the equilibrium states of the interacting and the non-interacting system (which, for the system of an atom coupled to black-body radiation, is valid for {\it all} temperatures $T\geq 0$, assuming only that the interaction strength is sufficiently weak).

math-ph↗

arXiv2004

Stability of Equilibria with a Condensate

We consider a quantum system composed of a spatially infinitely extended free Bose gas with a condensate, interacting with a small system (quantum dot) which can trap finitely many Bosons. Due to spontaneous symmetry breaking in the presence of the condensate, the system has many equilibrium states for each fixed temperature. We extend the notion of Return to Equilibrium to systems possessing a multitude of equilibrium states and show in particular that a condensate coupled to a quantum dot has the property of Return to Equilibrium in a weak coupling sense: any local perturbation of an equilibrium state of the coupled system, evolving under the interacting dynamics, converges in the long time limit to an asymptotic state. The latter is, modulo an error term, an equilibrium state which {\it depends} in an explicit way on the local perturbation (an effect due to long-range correlations). The error term vanishes in the small coupling limit. We deduce the stability result from properties of structure and regularity of eigenvectors of the generator of the dynamics, called the Liouville operator. Among our technical results is a Virial Theorem for Liouville type operators which has new applications to systems with and without a condensate.

math-ph↗

arXiv2004

Positive Commutators in Non-Equilibrium Statistical Mechanics

The method of positive commutators, developed for zero temperature problems over the last twenty years, has been an essential tool in the spectral analysis of Hamiltonians in quantum mechanics. We extend this method to positive temperatures, i.e. to non-equilibrium quantum statistical mechanics. We use the positive commutator technique to give an alternative proof of a fundamental property of a certain class of large quantum systems, called {\it Return to Equilibrium}. This property says that equilibrium states are (asymptotically) stable: if a system is slightly perturbed from its equilibrium state, then it converges back to that equilibrium state as time goes to infinity.

math-ph↗

arXiv2004

Ionization of Atoms in a Thermal Field

We study the stationary states of a quantum mechanical system describing an atom coupled to black-body radiation at positive temperature. The stationary states of the non-interacting system are given by product states, where the particle is in a bound state corresponding to an eigenvalue of the particle Hamiltonian, and the field is in its equilibrium state. We show that if Fermi's Golden Rule predicts that a stationary state disintegrates after coupling to the radiation field then it is unstable, provided the coupling constant is sufficiently small (depending on the temperature). The result is proven by analyzing the spectrum of the thermal Hamiltonian (Liouvillian) of the system within the framework of $W^*$-dynamical systems. A key element of our spectral analysis is the positive commutator method.

math-ph↗

arXiv2004

Thermal Ionization

In the context of an idealized model describing an atom coupled to black-body radiation at a sufficiently high positive temperature, we show that the atom will end up being ionized in the limit of large times. Mathematically, this is translated into the statement that the coupled system does not have any time-translation invariant state of positive (asymptotic) temperature, and that the expectation value of an arbitrary finite-dimensional projection in an arbitrary initial state of positive (asymptotic) temperature tends to zero, as time tends to infinity. These results are formulated within the general framework of $W^*$-dynamical systems, and the proofs are based on Mourre's theory of positive commutators and a new virial theorem. Results on the so-called standard form of a von Neumann algebra play an important role in our analysis.

math-ph↗

arXiv2003

Dissipative Transport: Thermal Contacts and Tunnelling Junctions

The general theory of simple transport processes between quantum mechanical reservoirs is reviewed and extended. We focus on thermoelectric phenomena, involving exchange of energy and particles. Entropy production and Onsager relations are relevant thermodynamic notions which are shown to emerge from the microscopic description. The theory is illustrated on the example of two reservoirs of free fermions coupled through a local interaction. We construct a stationary state and determine energy- and particle currents with the help of a convergent perturbation series. We explicitly calculate several interesting quantities to lowest order, such as the entropy production, the resistance, and the heat conductivity. Convergence of the perturbation series allows us to prove that they are strictly positive under suitable assumptions on the interaction between the reservoirs.

math-ph↗