arXiv subjects

Marcus T. Lexander

Publications and source records attributed to Marcus T. Lexander.

4 recordsLinked to original sources

arXiv2025

eT 2.0: An efficient open-source molecular electronic structure program

The eT program is an open-source electronic structure program with emphasis on performance and modularity. As its name suggests, the program features extensive coupled cluster capabilities, performing well compared to other electronic structure programs, and, in some cases, outperforming commercial alternatives. However, eT is more than a coupled cluster program; other models based on wave function theory (such as full and reduced space configuration interaction and a variety of self-consistent field models) and density functional theory are supported. The second major release of the program, eT 2.0, has specialized functionality for strong light-matter coupling conditions. In addition, it includes a wide range of optimizations and algorithmic improvements, as well as new capabilities for exploring potential energy surfaces and for modeling experiments in the UV and X-ray regimes. Molecular gradients are now available at the coupled cluster level, and high-accuracy spectroscopic simulations are available at reduced computational cost within the multilevel coupled cluster and multiscale frameworks. We present the modifications to the program since its first major release, eT 1.0, highlighting some notable new features and demonstrating the performance of the new version relative to the first release and to other established electronic structure programs.

physics.chem-ph↗

arXiv2025

SpinAdaptedSecondQuantization.jl 1.0 -- A Simple and Pedagogical Approach to Symbolic Quantum Chemistry

The development of new electronic structure methods is a very time consuming and error prone process when done by hand. SpinAdaptedSecondQuantization is an open-source Julia package we have developed for working with automated electronic structure theory development. The code focuses on being user-friendly and extensible, allowing for easy use of both user- and pre-defined fermionic and/or bosonic operators, tensors, and orbital spaces. This allows the code to be used to efficiently investigate and prototype new electronic structure methods for many different types of systems. This includes both exotic systems with wave functions consisting of different kinds of particles at once, as well as new parametrizations for traditional many-electron systems. The code is spin-adapted, working directly with spin-adapted fermionic operators, and can easily be used to derive common electronic structure theory equations and expressions, such as the coupled cluster energy, ground and excited state equations, one- and two-electron density matrices, etc. Additionally, the code can translate expressions into code, accelerating the process of going from ideas to implemented methods.

physics.chem-ph↗

arXiv2024

Realistic ab initio predictions of excimer behavior under collective light-matter strong coupling

Experiments show that light-matter strong coupling affects chemical properties, though the underlying mechanism remains unclear. We present an ab initio quantum electrodynamics coupled cluster method for the collective strong coupling regime. The model accurately describes electronic and electron-photon correlation within a molecular subsystem, while a simplified description of the collective polaritonic excitations allows for realistic microscopic light-matter couplings. We illustrate the model by investigating the potential energy surfaces of the argon dimer. This provides a prototype for excimers, and we analyze the ground and excited state vibrational levels. In the collective regime (small light-matter coupling, large number of molecules), the ground state potential energy surface and the first vibrational levels of the excited state are not changed significantly. However, collective strong coupling produces an abrupt transition in the vibrational landscape of the excimer, causing higher levels to behave similarly to ground state vibrations. Beyond a critical collective coupling strength, the excimer formation is thus inhibited.

physics.chem-ph↗

arXiv2024

Strong coupling electron-photon dynamics: a real-time investigation of energy redistribution in molecular polaritons

We analyze the real-time electron-photon dynamics in long-range polariton-mediated energy transfer using a real-time quantum electrodynamics coupled cluster (RT-QED-CC) model, which allows for spatial and temporal visualization of transport processes. We compute the time evolution of photonic and molecular observables, such as the dipole moment and the photon coordinate, following the excitation of the system induced by short laser pulses. Our simulation highlights the different time scales of electrons and photons under light-matter strong coupling, the role of dark states, and the differences with the electronic (F\"orster and Dexter) energy exchange mechanisms. The developed method can simulate multiple high-intensity laser pulses while explicitly retaining electronic and electron-photon correlation and is thus suited for nonlinear optics and transient absorption spectroscopies of molecular polaritons.

physics.chem-ph↗