arXiv subjects

Margot Leemker

Publications and source records attributed to Margot Leemker.

14 recordsLinked to original sources

arXiv2026

Hunting for methanol in the water rich, planet forming disk around HL Tau

Methanol, the simplest complex organic molecule found in space, is considered a key compound necessary for the formation of chemical species of prebiotic interest. Methanol detections in protoplanetary disks remain scarce, even though it is frequently detected in the material surrounding other Young Stellar Objects. We investigate the presence of methanol in the protoplanetary disk around the HL Tau protostar, motivated by the detection of spatially resolved warm water emission. Given the similar volatility of methanol and water, thermally desorbed gas-phase methanol is expected to emit from the same region of the HL Tau disk where water vapour has been observed. Accordingly, we selected and imaged the most promising ALMA archival observations to search for rotational methanol lines. We found no methanol emission in the analysed archival datasets. Assuming optically thin emission and LTE, we derive stringent upper limits on the methanol column density for different excitation temperatures: < 7.2 x 10^(14) cm^(-2) at 100 K and < 1.8 x 10^(15) cm^(-2) at 200 K, assuming a circular emitting region with a radius of 17 au (~ 0.12''). Furthermore, we obtain a stringent upper limit on the methanol-to-water column density ratio (< 0.55 x 10^(-3) at 100 K and < 1.4x 10^(-3) at 200 K), which is, on average, an order of magnitude lower than the values measured for other Young Stellar Objects and Solar System comets. We argue that the most likely explanation for the methanol non-detection in HL Tau is the presence of optically thick dust in the central region of the disk, which obscures part of the methanol emission. The upper limit on the methanol-to-water ratio in the HL Tau disk is at least an order of magnitude smaller than most clouds, YSOs and comets, possibly due to radiative transfer and/or excitation effects, or due to a different chemical evolution compared to the other sources.

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arXiv2026

Water vapor emission at the warm cavity wall of the HD 100546 disk as revealed by ALMA

We present spatially resolved ALMA observations of the water line at 183 GHz in the disk around the Herbig star HD 100546. The water vapor emission peaks at the inner edge of the warm dust cavity, located ~15 au from the central star. We attribute this to thermal desorption at the water snowline, shifted outward at the dust cavity wall directly heated by the intense radiation. This represents the first spatially resolved image of the water snowline using ALMA observations of the main water isotopologue in a protoplanetary disk. The water emission morphology peaking inside the first dust ring is consistent with previous ALMA detections of oxygen-bearing complex organic molecules in the disk, including thermally desorbed methanol. These findings signal that warm cavities of transition disks provide ideal targets to directly reconstruct the spatial distribution of water vapor and the snowline location with ALMA, and directly connect water vapor emission to ice desorption of complex organic species.

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arXiv2025

The chemical diversity of giant-planet nurseries as revealed by ALMA

With the giant exoplanet occurrence rate peaking around stars of 1.5-2 solar masses, there is strong motivation to characterize the disks that set their formation conditions. Observations with the Atacama Large Millimeter/submillimeter Array (ALMA) allow us to investigate both the availability of different molecules in disks and infer the radial distribution of elemental abundances, enabling us to make connections to exoplanet systems. Here we present a survey of six transition disks around young F-, A-, and B-type stars using ALMA. We find 13C18O, CS, SO, and H2CO in all six systems, as well as ten additional molecules in a subset of disks, including detections of H2S, 33SO, and CH3OCH3. Using these data, and literature data where available, we construct the first comprehensive picture of Herbig disk chemistry. We find clear correlations between molecular tracers of C/O>1 environments (e.g., CS, C2H) and disk mass, as traced by C18O line flux. In contrast, tracers of C/O<1 environments (e.g., SO, CH3OH) do not show significant correlations with disk mass. Interestingly, these molecules are relatively brighter in lower-mass disks, with their presence primarily linked to disks with central cavities and spirals. Finally, we show that the observed chemical diversity seen across Herbig disks leads to varying C/O regimes at the orbital radii of candidate proto-planets identified within these disks. When comparing these inferred disk C/O ratios with those measured for directly imaged exoplanets, we find a notable overlap and show that low C/O gas is common on 10's of au scales in Herbig disks.

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arXiv2025

Pristine ices in a planet-forming disk revealed by heavy water

Water is essential to our understanding of the planet-formation process and habitability on Earth. Although trace amounts of water are seen across all phases of star and planet formation, the bulk of the water reservoir often goes undetected, hiding crucial parts of its journey from giant molecular clouds to planets. This raises the question of whether water molecules in comets and (exo-)planets is largely inherited from the interstellar medium or if the water molecules are destroyed and then reformed in the disk. Water isotopologue ratios involving doubly deuterated water (D$_2$O) are a sensitive tracer to answer this question. We present strong evidence of inheritance through an enhancement of D$_2$O in the outbursting V883 Ori disk. The high D$_2$O/H$_2$O ratio of $(3.2 \pm 1.2) \times 10^{-5}$ is consistent with values seen in protostellar envelopes and a comet and is two orders of magnitude higher than expected if water is reprocessed. The high deuteration of the heaviest isotopologues D$_2$O/HDO = $(2.3 \pm 1.0) \times $HDO/H$_2$O further establishes the inheritance of water. We conclude that water ice in disks originates from the earliest phases of star formation, providing the missing link between cold dark clouds and (exo-)comets.

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arXiv2025

Ice sublimation in the dynamic HD 100453 disk reveals a rich reservoir of inherited complex organics

Protoplanetary disks around luminous young A-type stars are prime observational laboratories to determine the abundances of complex organic molecules (COMs) present during planet formation. In contrast to their lower stellar mass counterparts, these warmer disks contain the sublimation fronts of complex molecules such as CH3OH on spatial scales accessible with the Atacama Large Millimeter/submillimeter Array (ALMA). We present ALMA observations of the Herbig Ae disk HD 100453 that uncover a rich reservoir of COMs sublimating from the dust cavity edge. In addition to CH3OH, we detect 13CH3OH for the first time in a Class II disk, revealing a factor of three enhancement of 13C in the disk large organics. A tentative detection of CH2DOH is also reported, resulting in a D/H of 1-2%, which is consistent with the expected deuterium enhancement from the low temperature CH3OH formation in molecular clouds and with the deuteration of CH3OH measured in comets. The detection of methyl-formate (CH3OCHO), at only a few percent level of CH3OH is an order of magnitude lower compared to claims towards other organic-rich Herbig Ae disks but is more in line with organic abundance patterns towards the earlier stages of star formation. Together these data provide multiple lines of evidence that disks, and therefore the planet and comet-forming materials, contain inherited interstellar ices and perhaps the strongest evidence to date that much of the interstellar organic ice composition survives the early stages of planet formation.

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arXiv2025

ALMA reveals thermal and non-thermal desorption of methanol ice in the HD 100546 protoplanetary disk

Methanol (CH$_3$OH) and formaldehyde (H$_2$CO) are chemically coupled organic molecules proposed to act as an intermediate step between simple molecules and more complex prebiotic compounds. Their abundance distributions across disks regulate the prebiotic potential of material at different disk radii. We present observations of multiple methanol and formaldehyde transitions toward the Herbig Ae disk HD 100546 obtained with ALMA, building upon the previous serendipitous detection of methanol in this source. We find that methanol has a higher rotational temperature ($T_\mathrm{rot}$) than formaldehyde towards both the centrally concentrated emission component in the inner disk ($0-110$ au) and a radially separate dust ring farther out in the disk ($180-260$ au). $T_\mathrm{rot}$ decreases for methanol and formaldehyde from the inner ($152^{+35}_{-27}$ K and $76^{+9}_{-8}$ K) to the outer disk ($52^{+8}_{-6}$ K and $31^{+2}_{-2}$ K), suggesting that we are tracing two different chemical environments. $T_\mathrm{rot}$ for both species in the inner disk is consistent with thermal desorption as the origin, while the outer disk reservoir is driven by non-thermal desorption. The CH$_3$OH/H$_2$CO column density ratio decreases from $14.6^{+5.2}_{-4.6}$ in the inner disk to $1.3^{+0.3}_{-0.2}$ in the outer disk, consistent with modelling predictions. The CH$_3$OH/H$_2$CO column density ratio for the inner disk is consistent with the median value in the range of column density ratios compiled from Solar System comets which would have formed at a similar distance. This supports the notion that interstellar ice is inherited and preserved by protoplanetary disks around solar-mass and intermediate-mass stars as we are seeing 'fresh' ice sublimation, as well as providing more evidence for the presence of prebiotic precursor molecules in planet-forming regions.

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arXiv2024

Characterising the molecular line emission in the asymmetric Oph-IRS 48 dust trap: Temperatures, timescales, and sub-thermal excitation

The ongoing physical and chemical processes in planet-forming disks set the stage for planet formation. The asymmetric disk around the young star Oph-IRS 48 has one of the most well-characterised chemical inventories, showing molecular emission from a wide variety of species at the dust trap. One of the explanations for the asymmetric structure is dust trapping by a perturbation-induced vortex. We aim to constrain the excitation properties of the molecular species SO$_2$, CH$_3$OH, and H$_2$CO. We further characterise the extent of the molecular emission, through the determination of important physical and chemical timescales at the location of the dust trap. We also investigate whether the potential vortex can influence the observable temperature structure of the gas. Through a pixel-by-pixel rotational diagram analysis, we create rotational temperature and column density maps for SO$_2$ and CH$_3$OH, while temperature maps for H$_2$CO are created using line ratios. We find temperatures of $T\sim$55 K and $T\sim$125 K for SO$_2$ and CH$_3$OH, respectively, while the line ratios point towards temperatures of T$\sim$150-300 K for H$_2$CO. The rotational diagram of CH$_3$OH is dominated by scatter and subsequent non-LTE RADEX calculations suggest that both CH$_3$OH and H$_2$CO must be sub-thermally excited. The temperatures suggest that SO$_2$ comes from a layer deep in the disk, while CH$_3$OH and H$_2$CO originate from a higher layer. While a potential radial gradient is seen in the temperature map of SO$_2$, we do not find any hints of a vortex influencing the temperature structure. The determined turbulent mixing timescale is not able to explain the emitting heights of the molecules, but the photodissociation timescales are able to explain the wider azimuthal extents of SO$_2$ and H$_2$CO compared to CH$_3$OH, where a secondary, gas-phase formation reservoir is required for H$_2$CO.

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arXiv2024

Volatile composition of the HD 169142 disk and its embedded planet

The composition of a planet's atmosphere is intricately linked to the chemical makeup of the protoplanetary disk in which it formed. Determining the elemental abundances from key volatiles within disks is therefore essential for establishing connections between the composition of disks and planets. The disk around the Herbig Ae star HD 169142 is a compelling target for such a study due to its molecule-rich nature and the presence of a newly-forming planet between two prominent dust rings. In this work, we probe the chemistry of the HD 169142 disk at small spatial scales, drawing links between the composition of the disk and the planet-accreted gas. Using thermochemical models and archival data, we constrain the elemental abundances of volatile carbon, oxygen, and sulfur. Carbon and oxygen are only moderately depleted from the gas phase relative to their interstellar abundances, with the inner 60 au appearing enriched in volatile oxygen. The C/O ratio is approximately solar within the inner disk and rises above this in the outer disk, as expected across the H2O snowline. The gas-phase sulfur abundance is depleted by a factor of 1000, consistent with a number of other protoplanetary disks. Interestingly, the observed SiS emission near the HD 169142 b protoplanet vastly exceeds chemical model predictions, supporting previous hypotheses suggesting its origin in shocked gas or a localised outflow. We contextualise our findings in terms of the potential atmospheric composition of the embedded planet, and highlight the utility of sulfur-bearing molecules as probes of protoplanetary disk chemistry.

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arXiv2024

Measuring the $\mathrm{^{34}S}$ and $\mathrm{^{33}S}$ isotopic ratios of volatile sulfur during planet formation

Stable isotopic ratios constitute powerful tools for unraveling the thermal and irradiation history of volatiles. In particular, we can use our knowledge of the isotopic fractionation processes active during the various stages of star, disk and planet formation to infer the origins of different volatiles with measured isotopic patterns in our own solar system. Observations of planet-forming disks with the Atacama Large Millimeter/submillimeter Array (ALMA) now readily detect the heavier isotopologues of C, O and N, while the isotopologue abundances and isotopic fractionation mechanisms of sulfur species are less well understood. Using ALMA observations of the SO and SO2 isotopologues in the nearby, molecule-rich disk around the young star Oph-IRS 48 we present the first constraints on the combined 32S/34S and 32S/33S isotope ratios in a planet-forming disk. Given that these isotopologues likely originate in relatively warm gas (>50 K), like most other Oph-IRS 48 volatiles, SO is depleted in heavy sulfur while SO2 is enriched compared to solar system values. However, we cannot completely rule out a cooler gas reservoir, which would put the SO sulfur ratios more in line with comets and other solar system bodies. We also constrain the S18O/SO ratio and find the limit to be consistent with solar system values given a temperature of 60 K. Together these observations show that we should not assume solar isotopic values for disk sulfur reservoirs, but additional observations are needed to determine the chemical origin of the abundant SO in this disk, inform on what isotopic fractionation mechanism(s) are at play, and aid in unravelling the history of the sulfur budget during the different stages of planet formation.

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arXiv2024

An ALMA molecular inventory of warm Herbig Ae disks: I. Molecular rings, asymmetries and complexity in the HD 100546 disk

Observations of disks with the Atacama Large Millimeter/submillimeter Array (ALMA) allow us to map the chemical makeup of nearby protoplanetary disks with unprecedented spatial resolution and sensitivity. The typical outer Class II disk observed with ALMA is one with an elevated C/O ratio and a lack of oxygen-bearing complex organic molecules, but there are now some interesting exceptions: three transition disks around Herbig Ae stars all show oxygen-rich gas traced via the unique detections of the molecules SO and CH3OH. We present the first results of an ALMA line survey at 337 to 357 GHz of such disks and focus this paper on the first Herbig Ae disk to exhibit this chemical signature - HD 100546. In these data, we detect 19 different molecules including NO, SO and CH3OCHO (methyl formate). We also make the first tentative detections of H213CO and 34SO in protoplanetary disks. Multiple molecular species are detected in rings, which are, surprisingly, all peaking just beyond the underlying millimeter continuum ring at 200 au. This result demonstrates a clear connection between the large dust distribution and the chemistry in this flat outer disk. We discuss the physical and/or chemical origin of these sub-structures in relation to ongoing planet formation in the HD 100546 disk. We also investigate how similar and/or different the molecular make up of this disk is to other chemically well-characterised Herbig Ae disks. The line-rich data we present motivates the need for more ALMA line surveys to probe the observable chemistry in Herbig Ae systems which offer unique insight into the composition of disk ices, including complex organic molecules.

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arXiv2024

An ALMA molecular inventory of warm Herbig Ae disks: II. Abundant complex organics and volatile sulphur in the IRS 48 disk

The Atacama Large Millimeter/submillimeter Array (ALMA) can probe the molecular content of planet-forming disks with unprecedented sensitivity. These observations allow us to build up an inventory of the volatiles available for forming planets and comets. Herbig Ae transition disks are fruitful targets due to the thermal sublimation of complex organic molecule (COM) and likely H2O-rich ices in these disks. The IRS 48 disk shows a particularly rich chemistry that can be directly linked to its asymmetric dust trap. Here, we present ALMA observations of the IRS 48 disk where we detect 16 different molecules and make the first robust detections of H213CO, 34SO, 33SO and c-H2COCH2 (ethylene oxide) in a protoplanetary disk. All of the molecular emissions, aside from CO, are colocated with the dust trap and this includes newly detected simple molecules such as HCO+, HCN and CS. Interestingly, there are spatial offsets between different molecular families, including between the COMs and sulphur-bearing species, with the latter being more azimuthally extended and located radially further from the star. The abundances of the newly detected COMs relative to CH3OH are higher than the expected protostellar ratios, which implies some degree of chemical processing of the inherited ices during the disk lifetime. These data highlight IRS 48 as a unique astrochemical laboratory to unravel the full volatile reservoir at the epoch of planet and comet formation and the role of the disk in (re)setting chemical complexity.

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arXiv2023

Tracing snowlines and C/O ratio in a planet-hosting disk: ALMA molecular line observations towards the HD169142 disk

The composition of a forming planet is set by the material it accretes from its parent protoplanetary disk. Therefore, it is crucial to map the chemical make-up of the gas in disks to understand the chemical environment of planet formation. This paper presents molecular line observations taken with the Atacama Large Millimeter/submillimeter Array of the planet-hosting disk around the young star HD 169142. We detect N2H+, CH3OH, [CI], DCN, CS, C34S, 13CS, H2CS, H2CO, HC3N and c-C3H2 in this system for the first time. Combining these data with the recent detection of SO and previously published DCO+ data, we estimate the location of H2O and CO snowlines and investigate radial variations in the gas phase C/O ratio. We find that the HD 169142 disk has a relatively low N2H+ flux compared to the disks around Herbig stars HD 163296 and MWC 480 indicating less CO freeze-out and place the CO snowline beyond the millimetre disk at ~150 au. The detection of CH3OH from the inner disk is consistent with the H2O snowline being located at the edge of the central dust cavity at ~20 au. The radially varying CS/SO ratio across the proposed H2O snowline location is consistent with this interpretation. Additionally, the detection of CH3OH in such a warm disk adds to the growing evidence supporting the inheritance of complex ices in disks from the earlier, colder stages of star formation. Finally, we propose that the giant HD 169142 b located at 37 au is forming between the CO2 and H2O snowlines where the local elemental make of the gas is expected to have C/O=1.0.

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arXiv2022

The young embedded disk L1527 IRS: constraints on the water snowline and cosmic ray ionization rate from HCO+ observations

The water snowline in circumstellar disks is a crucial component in planet formation, but direct observational constraints on its location remain sparse due to the difficulty of observing water in both young embedded and mature protoplanetary disks. Chemical imaging provides an alternative route to locate the snowline, and HCO$^+$ isotopologues have been shown to be good tracers in protostellar envelopes and Herbig disks. Here we present $\sim$0.5$^{\prime\prime}$ resolution ($\sim$35 au radius) Atacama Large Millimeter/submillimeter Array (ALMA) observations of HCO$^+$ $J=4-3$ and H$^{13}$CO$^+$ $J=3-2$ toward the young (Class 0/I) disk L1527 IRS. Using a source-specific physical model with the midplane snowline at 3.4 au and a small chemical network, we are able to reproduce the HCO$^+$ and H$^{13}$CO$^+$ emission, but for HCO$^+$ only when the cosmic ray ionization rate is lowered to $10^{-18}$ s$^{-1}$. Even though the observations are not sensitive to the expected HCO$^+$ abundance drop across the snowline, the reduction in HCO$^+$ above the snow surface and the global temperature structure allow us to constrain a snowline location between 1.8 and 4.1 au. Deep observations are required to eliminate the envelope contribution to the emission and to derive more stringent constraints on the snowline location. Locating the snowline in young disks directly with observations of H$_2$O isotopologues may therefore still be an alternative option. With a direct snowline measurement, HCO$^+$ will be able to provide constraints on the ionization rate.

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arXiv2022

A major asymmetric ice trap in a planet-forming disk: III. First detection of dimethyl ether

The complex organic molecules (COMs) detected in star-forming regions are the precursors of the prebiotic molecules that can lead to the emergence of life. By studying COMs in more evolved protoplanetary disks we can gain a better understanding of how they are incorporated into planets. This paper presents ALMA band 7 observations of the dust and ice trap in the protoplanetary disk around Oph IRS 48. We report the first detection of dimethyl ether (CH3OCH3) in a planet-forming disk and a tentative detection of methyl formate (CH3OCHO). We determined column densities for the detected molecules and upper limits on non-detected species using the CASSIS spectral analysis tool. The inferred column densities of CH3OCH3 and CH3OCHO with respect to methanol (CH3OH) are of order unity, indicating unusually high abundances of these species compared to other environments. Alternatively, the 12CH3OH emission is optically thick and beam diluted, implying a higher CH3OH column density and a smaller emitting area than originally thought. The presence of these complex molecules can be explained by thermal ice sublimation, where the dust cavity edge is heated by irradiation and the full volatile ice content is observable in the gas phase. This work confirms the presence of oxygen-bearing molecules more complex than CH3OH in protoplanetary disks for the first time. It also shows that it is indeed possible to trace the full interstellar journey of COMs across the different evolutionary stages of star, disk, and planet formation.

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