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Maria Bergemann

Publications and source records attributed to Maria Bergemann.

At least 19 recordsLinked to original sources

Payne4GAIN: NLTE Corrections for Red Giants in Milky Way Mapper using H-Band Neural Network Emulators

The majority of spectroscopic surveys assume local thermodynamic equilibrium (LTE) during the modeling of stellar spectra. This assumption begins to break down for luminous stars, like the red giants targeted by SDSS-V's Milky Way Mapper Survey in its Galactic Genesis program. In this work, we present non-LTE (NLTE) abundances for 360,000 red giant stars in Milky Way Mapper DR19, from infrared APOGEE spectra. We generate NLTE spectra using precomputed departure coefficient grids for Na, Mg, Si, Al, Ca, Ti, Mn, and Ni. To fit APOGEE spectra at scale, we train neural network emulators (NNEs) to synthesize LTE and NLTE H-band spectra. After verifying that the NNEs are accurate, we fit the APOGEE spectra with ASPCAP results that fall within the same parameter range as the training data. We find strong NLTE effects on the order of 0.1\,dex for Al, Mn, and Ti, and smaller effects for Si and Ni. We provide a catalog of the results of our LTE and NLTE fits, as well as NLTE-corrected ASPCAP abundances using a polynomial fit correction.

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Evidence for elemental diffusion in the eclipsing binary star AI Phoenicis

AI Phe is an eclipsing binary star with an orbital period of 24.6 days for which the surface gravity and effective temperature are known from direct measurements to very high precision and accuracy. We have obtained high-quality spectroscopy of the K0IV star during the total eclipse of the F7V companion, and also obtained spectra with a very high signal-to-noise ratio for this star and its F7V companion using the spectral disentangling technique. We have used these spectra to measure the abundances of iron and magnesium for both stars. We compare the values of [Fe/H] and [Mg/H] for the F7V star and the K0IV star to stars in M67, an open cluster of similar age and metallicity to AI Phe. We find that our [Fe/H] and [Mg/H] measurements clearly show the signature of elemental diffusion in the F7V star. This suggests that AI Phe can be used to test models of single stars that include diffusion and mixing of elements.

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A method to derive self-consistent NLTE astrophysical parameters for 4 million high-resolution 4MOST stellar spectra in half a day with invertible neural networks

Modern spectroscopic surveys obtain spectra for millions of stars. However, classical spectroscopic methods can often be computationally expensive, rendering them impractical for the analysis of large datasets. We introduce a novel simulation-based deep-learning approach for the efficient analysis of high-resolution stellar spectra to be obtained with the upcoming high-resolution 4MOST spectrograph. We used a suite of synthetic non-local thermodynamic equilibrium (NLTE) spectra generated with Turbospectrum to mimic 4MOST observations and trained a conditional invertible neural network (cINN) for the purpose of predicting self-consistently stellar surface parameters and chemical abundances. The cINN is a neural network architecture that estimates full posterior distributions for the target stellar properties, providing an intrinsic uncertainty estimate. We evaluated the predictive performance of the trained cINN model on both synthetic data and observed spectra of stars. We found that our new cINN trained on NLTE synthetic spectra is capable of recovering stellar parameters with average errors ($\sigma$) of $33$ K for $T_\mathrm{eff}$, $0.16$ dex for $\log(g)$, and $0.12$ dex for [Fe/H], $0.1$ dex for [Ca/Fe], $0.11$ for [Mg/Fe], and $0.51$ dex for [Li/Fe], respectively, at a signal to noise ratio of 250 per Angstrom. From the analysis of the observed spectra of Gaia-ESO / 4MOST / PLATO benchmark stars, we verified that our NLTE estimates for stellar parameters and abundances are consistent with results obtained with the independent code TSFitPy. We conclude that the NLTE cINN is robust and can, theoretically, evaluate 4 million high-resolution 4MOST spectra in less than a day, using GPU acceleration.

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Observational constraints on the origin of the elements. X. Combining NLTE and machine learning for chemical diagnostics of 4 million stars in the 4MIDABLE-HR survey

We present the 4MOST-HR resolution Non-Local Thermal Equilibrium (NLTE) Payne artificial neural network (ANN), trained on $404\,793$ new FGK spectra with 16 elements computed in NLTE. This network will be part of the Stellar Abundances and atmospheric Parameters Pipeline (SAPP), which will analyse 4 million stars during the five year long 4MOST consortium 4: 4MOST MIlky way Disc And BuLgE High-Resolution (4MIDABLE-HR) survey. A fitting algorithm using this ANN is also presented that is able to fully-automatically and self-consistently derive both stellar parameters and elemental abundances. The ANN is validated by fitting 121 observed spectra of low-mass FGKM type stars, including main-sequence dwarf, subgiant and giant stars down to [Fe/H] $\approx -3.3$ degraded to 4MOST-HR resolution of $R\approx20\,000$, and comparing the derived abundances with the output of the classical radiative transfer code TSFitPy. We are able to recover all 18 elemental abundances with a bias~$<0.13$ and spread~$<0.16$\,dex, although the typical values are $<0.09$ dex for most elements. These abundances are compared to the OMEGA+ Galactic Chemical Evolution model, showcasing for the first time, the expected performance and results obtained from high-resolution spectra of the quality expected to be obtained with 4MOST. The expected Galactic trends are recovered, and we highlight the potential of using many chemical elements to constrain the formation history of the Galaxy.

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Classical Cepheids in the Galactic thin disk I. Abundance gradients via non-local thermodynamic equilibrium spectral analysis

Classical Cepheids (CCs) have long been considered excellent tracers of the chemical evolution of the Milky Way's young disk. We present a homogeneous, NLTE spectroscopic analysis of 401 Galactic CCs, based on 1,351 high-resolution optical spectra, spanning Galactocentric distances from 4.6 to 29.3 kpc. Using PySME with MARCS atmospheres and state-of-the-art grids of NLTE departure coefficients, we derive atmospheric parameters and abundances for key species tracing multiple nucleosynthetic channels. Our sample-the largest CC NLTE dataset to date-achieves high internal precision and enables robust modeling of present-day thin-disk abundance patterns and radial gradients. We estimate abundance gradients using three analytic prescriptions (linear, logarithmic, bilinear with a break) within a Bayesian, outlier-robust framework, and we also apply Gaussian Process Regression to capture non-parametric variations. We find that NLTE atmospheric parameters differ systematically from LTE determinations. Moreover, iron and most elemental abundance profiles are better described by non-linear behavior rather than by single-slope linear models: logarithmic fits generally outperform simple linear models, while bilinear fits yield inconsistent break radii across elements. Gaussian Process models reveal a consistent outer-disk flattening of [X/H] for nearly all studied elements. The [X/Fe] ratios are largely flat with Galactocentric radius, indicating coherent chemical scaling with iron across the thin disk, with modest positive offsets for Na and Al and mild declines for Mn and Cu. Comparison with recent literature shows overall agreement but highlights NLTE-driven differences, especially in outer-disk abundances. These results provide tighter empirical constraints for chemo-dynamical models of the Milky Way and set the stage for future NLTE mapping with upcoming large spectroscopic surveys.

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Solar carbon abundance from 3D non-LTE modelling of the diagnostic lines of the CH molecule

The spectral lines of the CH molecule are a key carbon (C) abundance diagnostic in FGKM-type stars. These lines are detectable in metal-rich and, in contrast to atomic C lines, also in metal-poor late-type stars. However, only 3D LTE analyses of the CH lines have been performed so far. We test the formation of CH lines in the solar spectrum, using for the first time, 3D Non-LTE (NLTE) models. We also aim to derive the solar photospheric abundance of C, using the diagnostic transitions in the optical (4218 - 4356 $\r{A}$) and infrared (33025 - 37944 $\r{A}$). We use the updated NLTE model molecule from Popa et al. 2023 and different solar 3D radiation-hydrodynamics model atmospheres. The models are contrasted against new spatially-resolved optical solar spectra, and the center-to-limb variation (CLV) of CH lines is studied. We find generally small ($\sim$0.01 dex) NLTE effects in the optical and IR diagnostic CH A-X lines in the solar atmosphere. Both 3D NLTE and 3D LTE spectral modelling yield an excellent fit to the solar intensity observations at all viewing angles. The 1D LTE and 1D NLTE models fail to describe the line CLV, and lead to underestimated solar C abundances. The 3D NLTE modelling of diagnostic lines in the optical and IR yields a carbon abundance of A(C)=8.52$\pm$0.07 dex. The estimate is in agreement with recent results based on neutrino fluxes measured by Borexino. 3D NLTE modelling and tests on spatially-resolved solar data are essential to derive robust solar abundances. The analysis presented here focuses on CH, but we expect that similar effects will be present for other molecules of astrophysical interest.

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3D Non-LTE radiation transfer: theory and applications to stars, exoplanets, and kilonovae

Most of the physical information about astrophysical objects is obtained via the analysis of their electromagnetic spectra. Observed data coupled with radiation transfer models in physical conditions representative of stars, planets, kilonovae, and ISM, yield constrains on their physical structure, gas flow dynamics at the surface, mass loss, and detailed chemical composition of the systems. All these core astrophysical parameters are just as reliable as the physical quality of the models that are employed for simulations of radiation transfer. Recent advanced in multi-D transfer modelling with Non-Local Thermodynamic Equilibrium (NLTE) in inhomogeneous time-dependent systems revealed systematic shortcomings of canonical models. Owing to major complexities of solving coupled multi-frequency RT equations in 3D geometry, a number of approximations have been introduced. This review presents an overview of the physical problem, standard solutions, and recent methodological advances. We also provide an overview of main results in the area of 3D NLTE radiation transfer and its applications to modelling diverse astrophysical environments, including FGKM type- and OBA-type stars, multi-epoch spectra of kilonovae, and atmospheres of rocky and gaseous exoplanets.

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M3DIS -- A grid of 3D radiation-hydrodynamics stellar atmosphere models for stellar surveys. II. Carbon-enhanced metal-poor stars

Understanding the origin and evolution of carbon-enhanced metal-poor (CEMP) stars is key to tracing the Galaxy's early chemical enrichment. We investigate how realistic 3D radiation-hydrodynamics (RHD) model atmospheres affect carbon abundances in CEMP stars and implications for their classification and Galactic chemical evolution (GCE). We focus on biases from traditional 1D hydrostatic models. We use the M3DIS code to compute 3D RHD model atmospheres for main-sequence and sub-giant stars over a wide range of metallicities and carbon enhancements. Synthetic spectra of the CH G-band are calculated with 3D radiative transfer and compared to spectra from classical 1D MARCS models. We derive abundance corrections and apply them to a large SAGA database sample to quantify effects on the carbon abundance distribution and CEMP classification. Our new 3D CEMP models predict cooler upper atmospheric layers than in 1D models, resulting in stronger CH absorption and lower inferred carbon abundances by up to -0.9 dex at the lowest metallicities. Carbon enhancement in the atmosphere itself increases molecular opacities and leads to radiative re-heating, partly offsetting adiabatic cooling in 3D models and reducing 3D-1D abundance corrections. Applying these corrections lowers the CEMP fraction by up to 20% below [Fe/H]=-3 and alters the relative contribution of CEMP sub-classes. The fraction of CEMP-no stars increases while the number of CEMP-r/s stars decreases, due to the downward revision of absolute carbon abundances. These changes bring the Galactic carbon distribution into better agreement with GCE models assuming a 20% contribution from faint supernovae. Realistic model atmospheres are essential to reliably reconstruct the Galaxy's early chemical enrichment history.

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A nearly pristine star from the Large Magellanic Cloud

The first stars formed out of pristine gas, causing them to be so massive that none are expected to have survived until today. If their direct descendants were sufficiently low-mass stars, such stars could exist today and would be recognizable by having the lowest metallicities (abundance of elements heavier than helium). We present the independent identification and detailed chemical analysis of the star SDSS J0715-7334, finding ultra-low elemental abundances of both iron and carbon ([Fe/H] = -4.3, [C/Fe] < -0.2) and total metallicity Z < 7.8 x 10^{-7} (log Z/Zsun < -4.3). The star's orbit indicates that it originates from the halo of the Large Magellanic Cloud. Its heavy element abundance pattern can be explained by a primordial supernova with an initial mass of 30 solar masses. This star is over ten times more chemically pristine than the most extreme high-redshift galaxies currently found by the James Webb Space Telescope. It is sufficiently metal-poor that current models of low-mass star formation require dust cooling to explain its existence.

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Testing stellar yield prescriptions in OMEGA+: Implications for rising sodium abundances in young thick disc stars

We recently identified an upturn in [Na/Fe] for the population of Solar-type stars in the Galactic young thick disc ($-0.3 < \mathrm{[Fe/H]} < +0.3$) at super-Solar metallicity in data from the GALactic Archaeology with HERMES (GALAH) survey. In this work, we investigate the origin of this unexplained sodium enrichment ([Na/Fe] $\approx 0$--$0.6$~dex) using the OMEGA$+$ galactic chemical evolution code. We explore the rise of [Na/Fe] using four combinations of nucleosynthetic yields from the literature, considering contributions from core-collapse supernovae, asymptotic giant branch stars, and Type~Ia supernovae. Our analysis focuses on two possible drivers of the Na enhancement: a metallicity-dependent increase in Na production from core-collapse supernovae at super-Solar metallicities, and enrichment from metal-rich AGB stars. We adopt two sets of Type~Ia supernova yields, one assuming exclusively Chandrasekhar-mass explosions and the other assuming only sub-Chandrasekhar-mass explosions. We find that the assumed Type~Ia explosion scenario has little influence on the resulting [Na/Fe] evolution, and that all chemical evolution models tested fail to reproduce the observed Na enrichment in the young thick-disc population at super-Solar metallicity. Our results suggest a possible ``under-pollution effect'' by Type~Ia supernovae -- the dominant producers of iron -- in the Solar-type stellar population of the Galactic disc. These findings provide a step toward understanding the origin of the anomalous sodium enrichment at super-Solar metallicities in the Galactic disc.

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Observational constraints on the origin of the elements. IX. 3D NLTE abundances of metals in the context of Galactic Chemical Evolution Models and 4MOST

Historically, various methods have been employed to understand the origin of the elements, including observations of elemental abundances which have been compared to Galactic Chemical Evolution (GCE) models. It is also well known that 1D Local Thermodynamic Equilibrium (LTE) measurements fail to accurately capture elemental abundances. Non-LTE (NLTE) effects may play a significant role, and neglecting them leads to erroneous implications in galaxy modelling. In this paper, we calculate 3D NLTE abundances of seven key iron-peak and neutron-capture elements (Mn, Co, Ni, Sr, Y, Ba, Eu) based on carefully assembled 1D LTE literature measurements, and investigate their impact within the context of the OMEGA+ GCE model. Our findings reveal that 3D NLTE abundances are significantly higher for iron-peak elements at [Fe/H]< -3, with (for the first time ever) [Ni/Fe] and (confirming previous studies) [Co/Fe] on average reaching 0.6-0.8 dex, and [Mn/Fe] reaching -0.1 dex, which current 1D core-collapse supernova (CCSN) models cannot explain. We also observe a slightly higher production of neutron-capture elements at low metallicities, with 3D NLTE abundances of Eu being higher by +0.2 dex at [Fe/H]= -3. 3D effects are most significant for iron-peak elements in the very metal-poor regime, with average differences between 3D NLTE and 1D NLTE {reaching} up to 0.15 dex. Thus, ignoring 3D NLTE effects introduces significant biases, so including {them} should be considered whenever possible.

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The Chemical Composition of the Sun

This chapter provides a brief introduction to the chemical composition of the Sun. The focus of the chapter is on results obtained from the physical analysis of the solar photosphere. Data obtained from meteorites, solar wind and corona measurements, as well as helioseismology, and solar neutrinos are briefly reviewed. The elemental and isotopic composition of the solar system is derived by combining the solar and meteoritic data. The cosmochemical and astronomical abundance scales are described. The results of the determinations of the protosolar chemical composition, as well as the initial and present-day mass fractions of hydrogen, helium, and metals (X, Y, Z) for the solar system are presented in extensive tables. All tables are also available in machine-readable form via Zenodo https://doi.org/10.5281/zenodo.14988840

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Solar System Elemental Abundances from the Solar Photosphere and CI-Chondrites

Solar photospheric abundances and CI-chondrite compositions are reviewed and updated to obtain representative solar system abundances of the elements and their isotopes. The new photospheric abundances obtained here lead to higher solar metallicity. Full 3D NLTE photospheric analyses are only available for 11 elements. A quality index for analyses is introduced. For several elements, uncertainties remain large. Protosolar mass fractions are H (X = 0.7060), He (Y = 0.2753), and for metals Li to U (Z = 0.0187). The protosolar (C+N)/H agrees within 13% with the ratio for the solar core from the Borexino experiment. Elemental abundances in CI-chondrites were screened by analytical methods, sample sizes, and evaluated using concentration frequency distributions. Aqueously mobile elements (e.g., alkalis, alkaline earths, etc.) often deviate from normal distributions indicating mobilization and/or sequestration into carbonates, phosphates, and sulfates. Revised CI-chondrite abundances of non-volatile elements are similar to earlier estimates. The moderately volatile elements F and Sb are higher than before, as are C, Br and I, whereas the CI-abundances of Hg and N are now significantly lower. The solar system nuclide distribution curves of s-process elements agree within 4% with s-process predictions of Galactic chemical evolution models. P-process nuclide distributions are assessed. No obvious correlation of CI-chondritic to solar elemental abundance ratios with condensation temperatures is observed, nor is there one for ratios of CI-chondrites/solar wind abundances.

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Performance of the Stellar Abundances and atmospheric Parameters Pipeline adapted for M dwarfs I. Atmospheric parameters from the spectroscopic module

M dwarfs are important targets in the search for Earth-like exoplanets due to their small masses and low luminosities. Several ongoing and upcoming space missions are targeting M dwarfs for this reason, and the ESA PLATO mission is one of these. In order to fully characterise a planetary system the properties of the host star must be known. For M dwarfs we can derive effective temperature, surface gravity, metallicity, and abundances of various elements from spectroscopic observations in combination with photometric data. The Stellar Abundances and atmospheric Parameters Pipeline (SAPP) has been developed as a prototype for one of the stellar science softwares within the PLATO consortium, it is aimed at FGK stars. We have modified it to be able to analyse the M dwarf among the PLATO targets. The current version of the pipeline for M dwarfs mostly relies on spectroscopic observations. The data processing is based on the machine learning algorithm The Payne and fits a grid of model spectra to an observed spectrum to derive effective temperature and metallicity. We use spectra in the H-band, as the near-infrared region is beneficial for M dwarfs. A method based on synthetic spectra was developed for the continuum normalisation of the spectra, taking into account the pseudo-continuum formed by numerous lines of the water molecule. Photometry is used to constrain the surface gravity. We tested the modified SAPP on spectra of M dwarfs from the APOGEE survey. Our validation sample of 26 stars includes stars with interferometric observations and binaries. We found a good agreement between our values and reference values from a range of studies. The overall uncertainties in the derived effective temperature, surface gravity, and metallicity is 100 K, 0.1 dex, and 0.15 dex, respectively. We find that the modified SAPP performs well on M dwarfs and identify possible areas of future development.

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NLTE abundances of Eu for a sample of metal-poor stars in the Galactic Halo and Metal-poor Disk with 1D and <3D> models

Accurate measurements of europium abundances in cool stars are essential for an enhanced understanding of the r-process mechanisms. We measure the abundance of Eu in solar spectra and a sample of metal-poor stars in the Galactic halo and metal-poor disk, with the metallicities ranging from \GG{$-2.4$} to $-0.5$ dex, using non-local thermodynamic equilibrium (NLTE) line formation. We compare these measurements with Galactic Chemical Evolution (GCE) models to \GG{explore the impact of the NLTE corrections on the contribution of r-process site in Galactic chemical evolution. In this work, we use NLTE line formation, as well as one-dimensional (1D) hydrostatic and spatial averages of 3D hydrodynamical ($<$3D$>$) model atmospheres to measure the abundance of Eu based on both the Eu II 4129 \AA\ and Eu II 6645 \AA\ lines for solar spectra and metal-poor stars. We find that \GG{for Eu II 4129 \AA\ line the NLTE modelling leads to higher (0.04 dex) solar Eu abundance in 1D and higher (0.07 dex) in \GG{$<$3D$>$} NLTE while} NLTE modelling leads to higher (0.01 dex) solar Eu abundance in 1D and lower (0.03 dex) in \GG{$<$3D$>$} NLTE for Eu II 6645 \AA\ line. Although the NLTE corrections for the Eu II $\lambda$ 4129 \AA\ and Eu II $\lambda$ 6645 \AA\ lines are opposite, the discrepancy between the abundances derived from these individual lines reduces after applying NLTE corrections, highlighting the critical role of NLTE abundance determinations. By comparing these measurements with Galactic chemical evolution (GCE) models, we find that the \G{amount of NLTE correction does not require significant change of the parameters for Eu production} in the GCE models.

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M3DIS -- A grid of 3D radiation-hydrodynamics stellar atmosphere models for stellar surveys

Large-scale stellar surveys, such as SDSS-V, 4MOST, WEAVE, and PLATO, require accurate atmospheric models and synthetic spectra of stars for accurate analyses of fundamental stellar parameters and chemical abundances. The primary goal of our work is to develop a new approach to solve radiation-hydrodynamics (RHD) and generate model stellar spectra in a self-consistent and highly efficient framework. We build upon the Copenhagen legacy RHD code, the MULTI3D non-local thermodynamic equilibrium (NLTE) code, and the DISPATCH high-performance framework. The new approach allows us to calculate 3D RHD models of stellar atmospheres on timescales of a few thousand CPU hours and to perform subsequent spectrum synthesis in local thermodynamic equilibrium (LTE) or NLTE for the desired physical conditions within the parameter space of FGK-type stars. We compare the 3D RHD solar model with other available models and validate its performance against solar observations, including the centre-to-limb variation of intensities and key solar diagnostic lines of H and Fe. We show that the performance of the new code allows to overcome the main bottleneck in 3D NLTE spectroscopy and enables calculations of multi-dimensional grids of synthetic stellar observables for comparison with modern astronomical observations.

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The GALAH survey: Tracing the Milky Way's formation and evolution through RR Lyrae stars

Stellar mergers and accretion events have been crucial in shaping the evolution of the Milky Way (MW). These events have been dynamically identified and chemically characterised using red giants and main-sequence stars. RR Lyrae (RRL) variables can play a crucial role in tracing the early formation of the MW since they are ubiquitous, old (t$\ge$10 Gyr) low-mass stars and accurate distance indicators. We exploited Data Release 3 of the GALAH survey to identify 78 field RRLs suitable for chemical analysis. Using synthetic spectra calculations, we determined atmospheric parameters and abundances of Fe, Mg, Ca, Y, and Ba. Most of our stars exhibit halo-like chemical compositions, with an iron peak around [Fe/H]$\approx -$1.40, and enhanced Ca and Mg content. Notably, we discovered a metal-rich tail, with [Fe/H] values ranging from $-$1 to approximately solar metallicity. This sub-group includes almost ~1/4 of the sample, it is characterised by thin disc kinematics and displays sub-solar $\alpha$-element abundances, marginally consistent with the majority of the MW stars. Surprisingly, they differ distinctly from typical MW disc stars in terms of the s-process elements Y and Ba. We took advantage of similar data available in the literature and built a total sample of 535 field RRLs for which we estimated kinematical and dynamical properties. We found that metal-rich RRLs (1/3 of the sample) likely represent an old component of the MW thin disc. We also detected RRLs with retrograde orbits and provided preliminary associations with the Gaia-Sausage-Enceladus, Helmi, Sequoia, Sagittarius, and Thamnos stellar streams.

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Spectacular nucleosynthesis from early massive stars

Stars formed with initial mass over 50 Msun are very rare today, but they are thought to be more common in the early universe. The fates of those early, metal-poor, massive stars are highly uncertain. Most are expected to directly collapse to black holes, while some may explode as a result of rotationally powered engines or the pair-creation instability. We present the chemical abundances of J0931+0038, a nearby low-mass star identified in early followup of SDSS-V Milky Way Mapper, which preserves the signature of unusual nucleosynthesis from a massive star in the early universe. J0931+0038 has relatively high metallicity ([Fe/H] = -1.76 +/- 0.13) but an extreme odd-even abundance pattern, with some of the lowest known abundance ratios of [N/Fe], [Na/Fe], [K/Fe], [Sc/Fe], and [Ba/Fe]. The implication is that a majority of its metals originated in a single extremely metal-poor nucleosynthetic source. An extensive search through nucleosynthesis predictions finds a clear preference for progenitors with initial mass > 50 Msun, making J0931+0038 one of the first observational constraints on nucleosynthesis in this mass range. However the full abundance pattern is not matched by any models in the literature. J0931+0038 thus presents a challenge for the next generation of nucleosynthesis models and motivates study of high-mass progenitor stars impacted by convection, rotation, jets, and/or binary companions. Though rare, more examples of unusual early nucleosynthesis in metal-poor stars should be found in upcoming large spectroscopic surveys.

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