Maria Concetta Canino

arXiv2026

Sub-doppler trace-gas photoacoustic spectroscopy

Molecules are emerging as new benchmark for metrology and fundamental physics research, driving the demand for spectroscopic techniques combining high sensitivity and resolution. Photoacoustic spectroscopy has proven to combine high sensitivity with appealing features like compactness, wavelength-independent and background-free detection. To date, photoacoustic sensing has mostly been focused on high-pressure applied trace-gas analysis, while accessing the low-pressure regime has been considered not compatible with efficient acoustic wave propagation. However, sensing gas samples at low pressure is the key to get access to high-resolution spectroscopy. Here, we demonstrate that sub-Doppler saturation spectroscopy can be performed on low-pressure trace gases in a cavity-enhanced photoacoustic sensor with mW-level mid-infrared radiation. Moreover, we show that the same setup can be operated at higher pressure, enabling trace-gas detection with 5 parts-per-billion sensitivity with a laser power as low as 35 microwatts. This allows to extend the unique advantages of the photoacoustic technique to metrology and fundamental physics and provides the mid-infrared with a cost-effective, flexible tool combining high sensitivity and resolution.

physics.optics↗

arXiv2025

Self-mixing-based photoacoustic sensing

Versatile, ultracompact, easy-to-handle, high-sensitivity sensors are compelling tools for in situ pivotal applications, such as medical diagnostics, security and safety assessments, and environmental control. In this work, we combine photoacoustic spectroscopy and feedback interferometry, proposing a novel trace-gas sensor equipped with a self-mixing readout. This scheme demonstrates a readout sensitivity comparable to that of bulkier state-of-the-art balanced Michelson-interferometric schemes, achieving the same spectroscopic performance in terms of signal-to-noise ratio (SNR) and minimum detection limit (MDL). At the same time, the self-mixing readout benefits from a reduced size and a lower baseline, paving the way for future system downsizing and integration while offering a higher detectability for lower gas concentrations. Moreover, the intrinsic wavelength independence of both self-mixing and photoacoustic techniques allows the applicability and tailorability of the sensor to any desired spectral range.

physics.app-ph↗