arXiv subjects

Maria E. Steinrueck

Publications and source records attributed to Maria E. Steinrueck.

18 recordsLinked to original sources

arXiv2026

JWST MEP - A World Under Spotty Starlight: Detection of CO2 and H2O in the Hot Saturn WASP-52b with JWST NIRSpec G395H

Exoplanets orbiting active stars offer distinct challenges for atmospheric characterization with the JWST. Among such worlds, the hot Saturn WASP-52b (Teq $\sim$ 1300 K) orbits an active K-dwarf that complicates transmission spectroscopy via stellar contamination. Here, we present the first JWST NIRSpec G395H (2.8-5.2 $μ$m) limb-averaged transmission spectrum of WASP-52b obtained through the JWST Morning/Evening Program (GO-3969), which aims to measure limb asymmetries across a sample of hot giant exoplanets. Our spectrum reveals the first detection of CO2 in WASP-52b's atmosphere (ln B = 54 / >10$σ$), with a retrieved abundance of log CO2 = -5.09 (+1.09/-1.14), and confirmation of H2O (ln B = 5.9 / $\sim$3-4$σ$), with an abundance of log H2O = -3.41 (+1.04/-1.04). We find a steep near-infrared slope that cannot be explained solely by H2O absorption, necessitating unocculted starspots (ln B = 5.7 / $\sim$3-4$σ$), though with properties that vary across our data reductions. The shape and amplitude of the molecular bands additionally suggest high-altitude (<10 mbar) inhomogeneous clouds covering $\approx$40 $\pm$ 20% of the terminator (ln B = 1.9 / $\sim$2.5$σ$), which provides evidence for the morning-evening terminator differences that are consensus predictions of general circulation models. WASP-52b's atmospheric metallicity can be sub-solar, solar, or super-solar, due to order-of-magnitude uncertainties in the molecular abundances caused by degeneracies between compositions, clouds, and starspots. However, chemical equilibrium retrievals provide a similar statistical fit while favoring a tighter constraint with a super-solar metallicity (M/H = 14.8 (+12.1/-5.9) $\times$ solar). These results highlight that chemical detections and aerosol properties may still be recovered for planets orbiting active stars via transmission spectroscopy.

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arXiv2026

Three dimensional temporal evolution of photochemical haze in exoplanet atmospheres I. Description and test application to HD 189733b

The formation and global spatial distribution of photochemically produced haze particles remain a key process in exoplanet atmospheres for understanding their observed properties. We aim to develop a flexible haze particle formation and evolution model suitable for time-dependent exoplanet atmosphere simulations. Inspired by recent 2D photochemical modelling efforts, we include a simple activation timescale mechanism to emulate a delayed formation of solid haze particles. We couple our new microphysical haze formation scheme, mini-haze, to the Exo-FMS general circulation model (GCM) and simulate an idealised HD 189733b case study to examine the 3D spatial distribution and sizes of haze particles. Our results suggest that for our chosen haze formation efficiency, particles do not grow beyond $\sim$30 nm, in line with previous detailed 1D modelling. We find the haze spatial distribution follows the vertical velocity structure of the atmosphere, with equatorial convergence patterns of material deeper in the atmosphere at $\sim$10$^{-2}$ bar. The resulting global distribution leads to enhanced haze opacity at the east and west limbs of the atmosphere. In our test cases, radiative feedback from haze opacity can strongly affect the temperature-pressure structures in the upper atmosphere depending on the production rate. Our synthetic spectra results suggest that longer haze-production timescales give rise to stronger haze opacity effects on the observed transmission spectra compared to short-timescale dayside formation, but the stronger thermal feedback from nightside formation leads to an overall larger dayside emission flux. Our current simulations represent a step towards investigating self-consistent haze formation and evolution with chemical feedback effects in 3D, and can be readily applied to other objects of interest, such as sub-Neptune atmospheres.

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arXiv2025

Horizontal and vertical exoplanet thermal structure from a JWST spectroscopic eclipse map

Highly-irradiated giant exoplanets known as "ultra-hot Jupiters" are anticipated to exhibit large variations of atmospheric temperature and chemistry as a function of longitude, latitude, and altitude. Previous observations have hinted at these variations, but the existing data have been fundamentally restricted to probing hemisphere-integrated spectra, thereby providing only coarse information on atmospheric gradients. Here we present a spectroscopic eclipse map of an extrasolar planet, resolving the atmosphere in multiple dimensions simultaneously. We analyze a secondary eclipse of the ultra-hot Jupiter WASP-18b observed with the NIRISS instrument on JWST. The mapping reveals weaker longitudinal temperature gradients than were predicted by theoretical models, indicating the importance of hydrogen dissociation and/or nightside clouds in shaping global thermal emission. Additionally, we identify two thermally distinct regions of the planet's atmosphere: a "hotspot" surrounding the substellar point and a "ring" near the dayside limbs. The hotspot region shows a strongly inverted thermal structure due to the presence of optical absorbers and a water abundance marginally lower than the hemispheric average, in accordance with theoretical predictions. The ring region shows colder temperatures and poorly constrained chemical abundances. Similar future analyses will reveal three-dimensional thermal, chemical, and dynamical properties of a broad range of exoplanet atmospheres.

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arXiv2025

Limb Asymmetries on WASP-39b: A Multi-GCM Comparison of Chemistry, Clouds, and Hazes

With JWST, observing separate spectra of the morning and evening limbs of hot Jupiters has finally become a reality. The first such observation was reported for WASP-39b, where the evening terminator was observed to have a larger transit radius by about 400 ppm and a stronger 4.3 $μ$m CO$_2$ feature than the morning terminator. Multiple factors, including temperature differences, photo/thermochemistry, clouds and hazes, could cause such limb asymmetries. To interpret these new limb asymmetry observations, a detailed understanding of how the relevant processes affect morning and evening spectra grounded in forward models is needed. Focusing on WASP-39b, we compare simulations from five different general circulation models (GCMs), including one simulating disequilibrium thermochemistry and one with cloud radiative feedback, to the recent WASP-39b limb asymmetry observations. We also post-process the temperature structures of all simulations with a 2D photochemical model and one simulation with a cloud microphysics model. Although the temperatures predicted by the different models vary considerably, the models are remarkably consistent in their predicted morning--evening temperature differences. Several equilibrium-chemistry simulations predict strong methane features in the morning spectrum, not seen in the observations. When including disequilibrium processes, horizontal transport homogenizes methane, and these methane features disappear. However, even after including photochemistry and clouds, our models still cannot reproduce the observed ${\sim}2000$ ppm asymmetry in the CO$_2$ feature. A combination of factors, such as varying metallicity and unexplored parameters in cloud models, may explain the discrepancy, emphasizing the need for future models integrating cloud microphysics and feedback across a broader parameter space.

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arXiv2025

The Impact of Different Haze Types on the Atmosphere and Observations of Hot Jupiters: 3D Simulations of HD 189733b, HD209458b and WASP-39b

We present the results from the simulations of the atmospheres of hot-Jupiters HD189733b, HD209458b and WASP-39b, assuming the presence of three different types of haze. Using a 3D General Circulation Model, the Unified Model, we capture the advection, settling and radiative impact of Titan-like, water-world-like and soot-like haze, with a particle radius of 1.5 nm. We show that the radiative impact of haze leads to drastic changes in the thermal structure and circulation in the atmosphere. We then show that in all our simulations, 1) the superrotating jet largely determines the day-to-night haze distribution, 2) eddies drive the latitudinal haze distribution, and 3) the divergent and eddy component of the wind control the finer structure of the haze distribution. We further show that the stronger the absorption strength of the haze, the stronger the superrotating jet, lesser the difference of the day-to-night haze distribution, and larger the transit depth in the synthetic transmission spectrum. We also demonstrate that the presence of such small hazes could result in a stronger haze opacity over the morning terminator in all three planets. This could lead to an observable terminator asymmetry in WASP-39b, with the morning terminator presenting a larger transit depth than the evening terminator. This work suggests that, although it might not be a typical detection feature for hot-Jupiters, an observed increase in transit depth over the morning terminator across the UV and optical wavelength regime could serve as a strong indicator of the presence of haze.

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arXiv2025

Out on a Limb: The Signatures of East-West Asymmetries in Transmission Spectra from General Circulation Models

In the era of JWST, observations of hot Jupiter atmospheres are becoming increasingly precise. As a result, the signature of limb asymmetries due to temperature or abundance differences and the presence of aerosols can now be directly measured using transmission spectroscopy. Using a grid of general circulation models (GCMs) with varying irradiation temperature (1500 K - 4000 K) and prescriptions of cloud formation, we simulate 3D ingress/egress and morning/evening-limb transmission spectra. We aim to assess the impact that clouds, 3D temperature structure, and non-uniform distribution of gases have on the observed spectra, and how these inhomogeneities can be identified. A second goal is to assess the relative merits of two separate methods (ingress/egress v.s. morning/evening-limb spectroscopy) for isolating atmospheric asymmetries. From our models, it is evident that an east-west temperature difference is the leading order effect for producing ingress/egress or morning/evening-limb spectral differences. We additionally find that clouds contribute strongly to the observed limb asymmetry at moderate irradiation temperatures in our grid ($\sim 2000 \mathrm{K} < T_{\mathrm{irr}} < 3500 \mathrm{K}). At lower temperatures clouds equally dominate the optical depth on both limbs, while at higher temperatures the entire terminator region remains cloud-free. We develop limb asymmetry metrics that can be used to assess the degree of east-west asymmetry for a given planet and predict trends in these metrics with respect to irradiation temperature that are indicative of various physical processes. Our results are useful for predicting and diagnosing the signatures of limb asymmetries in JWST spectra.

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arXiv2025

The radiative effects of photochemical hazes on the atmospheric circulation and phase curves of sub-Neptunes

Measuring the atmospheric composition of hazy sub-Neptunes like GJ~1214b through transmission spectroscopy is difficult because of the degeneracy between mean molecular weight and haziness. It has been proposed that phase curve observations can break this degeneracy because of the relationship between mean molecular weight (MMW) and phase curve amplitude. However, photochemical hazes can strongly affect phase curve amplitudes as well. We present a large set of GCM simulations of the sub-Neptune GJ~1214b that include photochemical hazes with varying atmospheric composition, haze opacity and haze optical properties. In our simulations, photochemical hazes cause temperature changes of up to 200~K, producing thermal inversions and cooling deeper regions. This results in increased phase curve amplitudes and adds a considerable scatter to the phase curve amplitude--metallicity relationship. However, we find that if the haze production rate is high enough to significantly alter the phase curve, the secondary eclipse spectrum will exhibit either emission features or strongly muted absorption features. Thus, the combination of a white-light phase curve and a secondary eclipse spectrum can successfully distinguish between a hazy, lower MMW and a clear, high MMW scenario.

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arXiv2025

Clouds and Hazes in GJ 1214b's Metal-Rich Atmosphere

The sub-Neptune GJ 1214b has an infamously flat transmission spectrum, likely due to thick aerosols in its atmosphere. A recent JWST MIRI spectroscopic phase curve of GJ 1214 b added to this picture, suggesting a highly reflective and metal-rich atmosphere. Using a 3D General Circulation Model with both photochemical hazes and condensate clouds, we characterize how different aerosol types affect the atmospheric structure of GJ 1214 b and manifest in its spectroscopic phase curve. Additionally, we reanalyze the original GJ 1214 b JWST phase curve. The reanalysis shows a hotter nightside, similar dayside temperature, and a lower, but still elevated, Bond albedo (0.42 +/- 0.11) than the original results. We find that a scenario with both clouds and hazes is most consistent with the JWST phase curve. Reflective clouds or hazes are needed to explain the large Bond albedo, and hazes or a super-solar metallicity help account for the several hundred Kelvin day-night temperature difference measured by the phase curve.

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arXiv2024

New insights into the internal structure of GJ 1214 b informed by JWST

Recent JWST observations of the sub-Neptune GJ 1214 b suggest that it hosts a high-metallicity (>100x solar), hazy atmosphere. Emission spectra of the planet show molecular absorption features, most likely due to atmospheric H2O. In light of this new information, we conduct a thorough reevaluation of the planet's internal structure. We consider interior models with mixed H/He/H2O envelopes of varying composition, informed by atmospheric constraints from the JWST phase curve, in order to determine possible bulk compositions and internal structures. Self-consistent atmospheric models consistent with the JWST observations are used to set boundary conditions for the interior. We find that a total envelope mass fraction of at least 8.1% is required to explain the planet's mass and radius. Regardless of H2O content, the maximum H/He mass fraction of the planet is 5.8%. We find that a 1:1 ice-to-rock ratio along with 3.4-4.8% H/He is also a permissible solution. In addition, we consider a pure H2O (steam) envelope and find that such a scenario is possible, albeit with a high ice-to-rock ratio of at least 3.76:1, which may be unrealistic from a planet formation standpoint. We discuss possible formation pathways for the different internal structures that are consistent with observations. Since our results depend strongly on the atmospheric composition and haze properties, more precise observations of the planet's atmosphere would allow for further constraints on its internal structure. This type of analysis can be applied to any sub-Neptune with atmospheric constraints to better understand its interior.

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arXiv2024

Inhomogeneous terminators on the exoplanet WASP-39 b

Transmission spectroscopy has been a workhorse technique over the past two decades to constrain the physical and chemical properties of exoplanet atmospheres. One of its classical key assumptions is that the portion of the atmosphere it probes -- the terminator region -- is homogeneous. Several works in the past decade, however, have put this into question for highly irradiated, hot ($T_{eq}\gtrsim 1000$ K) gas giant exoplanets both empirically and via 3-dimensional modelling. While models predict clear differences between the evening (day-to-night) and morning (night-to-day) terminators, direct morning/evening transmission spectra in a wide wavelength range has not been reported for an exoplanet to date. Under the assumption of precise and accurate orbital parameters on WASP-39 b, here we report the detection of inhomogeneous terminators on the exoplanet WASP-39 b, which allows us to retrieve its morning and evening transmission spectra in the near-infrared ($2-5\ μ$m) using JWST. We observe larger transit depths in the evening which are, on average, $405 \pm 88$ ppm larger than the morning ones, also having qualitatively larger features than the morning spectrum. The spectra are best explained by models in which the evening terminator is hotter than the morning terminator by $177^{+65}_{-57}$ K with both terminators having C/O ratios consistent with solar. General circulation models (GCMs) predict temperature differences broadly consistent with the above value and point towards a cloudy morning terminator and a clearer evening terminator.

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arXiv2024

Sulphur dioxide in the mid-infrared transmission spectrum of WASP-39b

The recent inference of sulphur dioxide (SO$_2$) in the atmosphere of the hot ($\sim$1100 K), Saturn-mass exoplanet WASP-39b from near-infrared JWST observations suggests that photochemistry is a key process in high temperature exoplanet atmospheres. This is due to the low ($<$1 ppb) abundance of SO$_2$ under thermochemical equilibrium, compared to that produced from the photochemistry of H$_2$O and H$_2$S (1-10 ppm). However, the SO$_2$ inference was made from a single, small molecular feature in the transmission spectrum of WASP-39b at 4.05 $μ$m, and therefore the detection of other SO$_2$ absorption bands at different wavelengths is needed to better constrain the SO$_2$ abundance. Here we report the detection of SO$_2$ spectral features at 7.7 and 8.5 $μ$m in the 5-12 $μ$m transmission spectrum of WASP-39b measured by the JWST Mid-Infrared Instrument (MIRI) Low Resolution Spectrometer (LRS). Our observations suggest an abundance of SO$_2$ of 0.5-25 ppm (1$σ$ range), consistent with previous findings. In addition to SO$_2$, we find broad water vapour absorption features, as well as an unexplained decrease in the transit depth at wavelengths longer than 10 $μ$m. Fitting the spectrum with a grid of atmospheric forward models, we derive an atmospheric heavy element content (metallicity) for WASP-39b of $\sim$7.1-8.0 $\times$ solar and demonstrate that photochemistry shapes the spectra of WASP-39b across a broad wavelength range.

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arXiv2024

Nightside clouds and disequilibrium chemistry on the hot Jupiter WASP-43b

Hot Jupiters are among the best-studied exoplanets, but it is still poorly understood how their chemical composition and cloud properties vary with longitude. Theoretical models predict that clouds may condense on the nightside and that molecular abundances can be driven out of equilibrium by zonal winds. Here we report a phase-resolved emission spectrum of the hot Jupiter WASP-43b measured from 5-12 $μ$m with JWST's Mid-Infrared Instrument (MIRI). The spectra reveal a large day-night temperature contrast (with average brightness temperatures of 1524$\pm$35 and 863$\pm$23 Kelvin, respectively) and evidence for water absorption at all orbital phases. Comparisons with three-dimensional atmospheric models show that both the phase curve shape and emission spectra strongly suggest the presence of nightside clouds which become optically thick to thermal emission at pressures greater than ~100 mbar. The dayside is consistent with a cloudless atmosphere above the mid-infrared photosphere. Contrary to expectations from equilibrium chemistry but consistent with disequilibrium kinetics models, methane is not detected on the nightside (2$σ$ upper limit of 1-6 parts per million, depending on model assumptions).

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arXiv2023

Photochemical hazes dramatically alter temperature structure and atmospheric circulation in 3D simulations of hot Jupiters

Photochemical hazes are expected to form in hot Jupiter atmospheres and may explain the strong scattering slopes and muted spectral features observed in the transmission spectra of many hot Jupiters. Absorption and scattering by photochemical hazes have the potential to drastically alter temperature structure and atmospheric circulation of these planets but have previously been neglected in general circulation models (GCMs). We present GCM simulations of hot Jupiter HD 189733b that include photochemical hazes as a radiatively active tracer fully coupled to atmospheric dynamics. The influence of haze radiative feedback strongly depends on the assumed haze optical properties. For soot hazes, two distinct thermal inversions form, separated by a local temperature minimum around 10$^{-5}$ bar caused by upwelling on the dayside mixing air with low haze abundance upwards. The equatorial jet broadens and slows down. The horizontal distribution of hazes remains relatively similar to simulations with radiatively passive tracers. For Titan-type hazes, the equatorial jet accelerates and extends to much lower pressures, resulting in a dramatically different 3D distribution of hazes compared to radiatively passive or soot hazes. Further experimental and observational studies to constrain the optical properties of photochemical hazes will therefore be crucial for understanding the role of hazes in exoplanet atmospheres. In the dayside emission spectrum, for both types of hazes the amplitude of near-infrared features is reduced, while the emitted flux at longer wavelengths ($>$4 $μ$m) increases. Haze radiative feedback leads to increased phase curve amplitudes in many infrared wavelength regions, mostly due to stronger dayside emission.

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arXiv2023

A reflective, metal-rich atmosphere for GJ 1214b from its JWST phase curve

There are no planets intermediate in size between Earth and Neptune in our Solar System, yet these objects are found around a substantial fraction of other stars. Population statistics show that close-in planets in this size range bifurcate into two classes based on their radii. It is hypothesized that the group with larger radii (referred to as "sub-Neptunes") is distinguished by having hydrogen-dominated atmospheres that are a few percent of the total mass of the planets. GJ 1214b is an archetype sub-Neptune that has been observed extensively using transmission spectroscopy to test this hypothesis. However, the measured spectra are featureless, and thus inconclusive, due to the presence of high-altitude aerosols in the planet's atmosphere. Here we report a spectroscopic thermal phase curve of GJ 1214b obtained with JWST in the mid-infrared. The dayside and nightside spectra (average brightness temperatures of 553 $\pm$ 9 and 437 $\pm$ 19 K, respectively) each show >3$σ$ evidence of absorption features, with H$_2$O as the most likely cause in both. The measured global thermal emission implies that GJ 1214b's Bond albedo is 0.51 $\pm$ 0.06. Comparison between the spectroscopic phase curve data and three-dimensional models of GJ 1214b reveal a planet with a high metallicity atmosphere blanketed by a thick and highly reflective layer of clouds or haze.

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arXiv2023

The Hazy and Metal-Rich Atmosphere of GJ 1214 b Constrained by Near and Mid-Infrared Transmission Spectroscopy

The near-infrared transmission spectrum of the warm sub-Neptune exoplanet GJ 1214 b has been observed to be flat and featureless, implying a high metallicity atmosphere with abundant aerosols. Recent JWST MIRI LRS observations of a phase curve of GJ 1214 b showed that its transmission spectrum is flat out into the mid-infrared. In this paper, we use the combined near- and mid-infrared transmission spectrum of GJ 1214 b to constrain its atmospheric composition and aerosol properties. We generate a grid of photochemical haze models using an aerosol microphysics code for a number of background atmospheres spanning metallicities from 100 to 1000 $\times$ solar, as well as a steam atmosphere scenario. The flatness of the combined data set largely rules out atmospheric metallicities $\leq$300 $\times$ solar due to their large corresponding molecular feature amplitudes, preferring values $\geq$1000 $\times$ solar and column haze production rates $\geq$10$^{-10}$ g cm$^{-2}$ s$^{-1}$. The steam atmosphere scenario with similarly high haze production rates also exhibit sufficiently small molecular features to be consistent with the transmission spectrum. These compositions imply that atmospheric mean molecular weights $\geq$15 g mol$^{-1}$ are needed to fit the data. Our results suggest that haze production is highly efficient on GJ 1214 b and could involve non-hydrocarbon, non-nitrogen haze precursors. Further characterization of GJ 1214 b's atmosphere would likely require multiple transits and eclipses using JWST across the near and mid-infrared, potentially complemented by groundbased high resolution transmission spectroscopy.

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arXiv2022

CAMEMBERT: A Mini-Neptunes GCM Intercomparison, Protocol Version 1.0. A CUISINES Model Intercomparison Project

With an increased focus on the observing and modelling of mini-Neptunes, there comes a need to better understand the tools we use to model their atmospheres. In this paper, we present the protocol for the CAMEMBERT (Comparing Atmospheric Models of Extrasolar Mini-neptunes Building and Envisioning Retrievals and Transits) project, an intercomparison of general circulation models (GCMs) used by the exoplanetary science community to simulate the atmospheres of mini-Neptunes. We focus on two targets well studied both observationally and theoretically with planned JWST Cycle 1 observations: the warm GJ~1214b and the cooler K2-18b. For each target, we consider a temperature-forced case, a clear sky dual-grey radiative transfer case, and a clear sky multi band radiative transfer case, covering a range of complexities and configurations where we know differences exist between GCMs in the literature. This paper presents all the details necessary to participate in the intercomparison, with the intention of presenting the results in future papers. Currently, there are eight GCMs participating (ExoCAM, Exo-FMS, FMS PCM, Generic PCM, MITgcm, RM-GCM, THOR, and the UM), and membership in the project remains open. Those interested in participating are invited to contact the authors.

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arXiv2021

The near-UV transit of HD 189733b with the XMM-Newton Optical Monitor

We present analysis of XMM-Newton Optical Monitor observations in the near-ultraviolet of HD 189733, covering twenty primary transits of its hot Jupiter planet. The transit is clearly detected with both the UVW2 and UVM2 filters, and our fits to the data reveal transit depths in agreement with that observed optically. The measured depths correspond to radii of $1.059^{+0.046}_{-0.050}$ and $0.94^{+0.15}_{-0.17}$ times the optically-measured radius (1.187 R$_{\rm J}$ at 4950 Å) in the UVW2 and UVM2 bandpasses, respectively. We also find no statistically significant variation in the transit depth across the 8 year baseline of the observations. We rule out extended broadband absorption towards or beyond the Roche lobe at the wavelengths investigated, although observations with higher spectral resolution are required to determine if absorption out to those distances from the planet is present in individual near-UV lines.

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arXiv2020

Global Chemistry and Thermal Structure Models for the Hot Jupiter WASP-43b and Predictions for JWST

The James Webb Space Telescope (JWST) is expected to revolutionize the field of exoplanets. The broad wavelength coverage and the high sensitivity of its instruments will allow characterization of exoplanetary atmospheres with unprecedented precision. Following the Call for the Cycle 1 Early Release Science Program, the Transiting Exoplanet Community was awarded time to observe several targets, including WASP-43b. The atmosphere of this hot Jupiter has been intensively observed but still harbors some mysteries, especially concerning the day-night temperature gradient, the efficiency of the atmospheric circulation, and the presence of nightside clouds. We will constrain these properties by observing a full orbit of the planet and extracting its spectroscopic phase curve in the 5--12 $μ$m range with JWST/MIRI. To prepare for these observations, we performed an extensive modeling work with various codes: radiative transfer, chemical kinetics, cloud microphysics, global circulation models, JWST simulators, and spectral retrieval. Our JWST simulations show that we should achieve a precision of 210 ppm per 0.1 $μ$m spectral bin on average, which will allow us to measure the variations of the spectrum in longitude and measure the night-side emission spectrum for the first time. If the atmosphere of WASP-43b is clear, our observations will permit us to determine if its atmosphere has an equilibrium or disequilibrium chemical composition, providing eventually the first conclusive evidence of chemical quenching in a hot Jupiter atmosphere. If the atmosphere is cloudy, a careful retrieval analysis will allow us to identify the cloud composition.

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